La Salle College High School AP Chemistry Summer Homework Assignment DUE on first day of class! Email me with questions as a last resort: [email protected] Name: _______________________________________________ Remember 1 cm3 = 1 mL 1. Metric Conversions. GIVEN METRIC UNIT 1 L = 1 dm3 DESIRED METRIC UNIT 1.42 cm mm 1.21 x 102 cm m 674.5 nm cm 2.345 x 104 m km 809 mL L 8.201 x 10-7 L nL 256000 cm3 L 4.15 x 10-10 L cm3 9.10 x 1011 µg g 0.006793 kg mg 2. Would you expect the following atoms to gain or lose electrons when forming ions? What ion (symbol and charge) is most likely in each case? ELEMENT Li Mg N S Cl Al GAIN OR LOSE ION FORMED 3. Chemical Nomenclature: You should be able to complete this using a periodic table and MINIMAL help from other sources. ITEM A B C D E F G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ CHEMICAL FORMULA KBr MgS AlI3 CHEMICAL NAME Strontium fluoride Potassium nitride Magnesium phosphide Hg2O FeBr3 CoS TiCl4 Tin (II) nitride Cobalt (III) iodide Mercury (II) oxide Chromium (VI) sulfide SrSO3 LiNO2 KMnO4 K2Cr2O7 Chromium (III) hydroxide Magnesium cyanide Lead (IV) carbonate Ammonium acetate N2O4 ICl3 SO2 P2S5 Diboron trioxide Arsenic pentafluoride Dinitrogen monoxide Sulfur hexachloride HC2H3O2 H3PO3 HCl Hydrofluoric acid Sulfurous acid Phosphoric acid 4. Chemical Reactions – Write and BALANCE the following reactions. a. Glucose (C6H12O6) reacts with oxygen gas to produce gaseous carbon dioxide and water vapor. b. Solid iron (III) sulfide reacts with gaseous hydrogen chloride to form solid iron (III) chloride and hydrogen sulfide gas. c. Carbon disulfide liquid reacts with ammonia gas to produce hydrogen sulfide gas and solid ammonium thiocyanate (NH4SCN). d. Aqueous solutions of lead (II) nitrate and sodium phosphate are mixed resulting in the precipitate formation of lead (II) phosphate and aqueous sodium nitrate as the other product. e. Solid zinc reacts with aqueous hydrochloric acid to form aqueous zinc chloride and hydrogen gas. f. Aqueous calcium hydroxide is neutralized by aqueous phosphoric acid to produce solid calcium phosphate and water. 5. Chemical Calculations – You must show the work (on a separate sheet of paper) that leads to your answer to receive credit. Write your answers in the blanks to the left of the question. Remember that: 1 mole element = 6.022 x 1023 atoms 1 mole compound = 6.022 x 1023 molecules or formula units molecules refer to covalent compounds while formula units refer to ionic compounds (mathematically they mean the same thing) Chloral hydrate (C2H3Cl3O2) is a drug formerly used as a sedative and hypnotic. ________________ (i) Calculate the molar mass of chloral hydrate. ________________ (ii) How many moles of chloral hydrate molecules are in 500.0 g of chloral hydrate? ________________ (iii) What is the mass in grams of 2.00 x 10-2 mol chloral hydrate? ________________ (iv) What number of chlorine atoms are in 5.00 g chloral hydrate? ________________ (v) What mass of chloral hydrate would contain 1.00 g Cl? ________________ (vi) What is the mass of exactly 500 molecules of chloral hydrate? 6. You should also know ALL of the polyatomic ions on the next page. Pay attention to those ions ending in –ite versus – ate. You can expect mixed-up polyatomic ion quizzes the first week of school, followed by another week of daily formula-writing quizzes. Helpful Tip: compare the polyatomic ions for the following halogens (notice what changes and what stays the same). Notice that fluorine is NOT include – it does not form polyatomic ions. (CLO)-1 HYPOCHLORITE (BRO)-1 HYPOBROMITE (IO)-1 HYPOIODITE (ClO2)-1 chlorite (BrO2)-1 bromite (IO2)-1 iodite (ClO3)-1 chlorate (BrO3)-1 bromate (IO3)-1 iodate (ClO4)-1 perchlorate (BrO4)-1 perbromate (IO4)-1 periodate POLYATOMIC ION NAME Ammonium Acetate Cyanide Hydrogen carbonate Hydrogen sulfate Hydroxide SYMBOL and OXIDATION NO. NH4+1 CH3COO-1 or C2H3O2-1 CN - 1 HCO3-1 HSO4- 1 OH -1 Hypochlorite NO3-1 NO2-1 ClO-1 Chlorite ClO2-1 Chlorate ClO3-1 Perchlorate ClO4-1 Permanganate Thiocyanate MnO4-1 IO3-1 SCN- 1 Oxalate C2O4- 2 Carbonate CO3-2 CrO4-2 Cr2O7-2 SO4-2 SO3-2 S2O3-2 AsO4-3 PO4-3 PO3-3 Nitrate Nitrite Iodate Chromate Dichromate Sulfate Sulfite Thiosulfate Arsenate Phosphate Phosphite
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