FINAL REPORT- WATER PURIFICATION - 2011 DEVIKULAM The University of Queensland EWB Challenge 2011 Team Slate Reflection The overarching aim of this project was to provide the community of Devikulam, India, with a reliable supply of uncontaminated drinking water. This was to be achieved through an engineering solution developed to accommodate the issues that would arise for its function within this community. The largest obstacle encountered during this project was in the design development phase where suitable methods of removing turbidity, bacteria and predominantly, salinity, were required to be developed. Increasing the challenge was the initial project aims set down to guide the efficacy of the design to achieve the desired results while maintaining a positive relationship between the social, economic and environmental aspects pertaining to the community where the water purification device was to be implemented. Working as an effective team overall increased the team’s ability to research more methods to purify water initially which gave the team more options when it came to ultimately deciding on a specific method to achieve the prescribed project aims. Furthermore, in this team, the individual strengths of each team member varied which increased overall team synergy as each member had their own responsibility for individual parts of the project and report. By breaking the work up into manageable parts and delegating each to a team member, who had confidence that they could complete the task best, augmented the overall success of the team to produce a comprehensive report and an effective prototype. On reflection, if this project was to be done again there would be greater time put into researching alternative materials that could be used in the installation to provide greater flexibility when certain materials are not available or able to be obtained. Additionally, it would prove beneficial if one of the project aims was stated more clearly to specify making the design a long term option in respect to the working life of all components. The most enjoyable part of the Challenge was how it provided an appropriate introduction to the concept of professional engineering to the students by letting us experience firsthand how to develop project aims and design requirements, create effective designs, decide on the most appropriate design and deal with the issues surrounding the construction of the chosen design. By providing a real life context, it gave the Challenge a different dimension wherein the solutions provided could actually be gauge more specifically as to their impact which is good for feedback for us. FINAL REPORT- WATER PURIFICATION DEVIKULAM 2011 2nd June 2011 Dr. Stefano Freguia Advanced Water Management Centre The University of Queensland St. Lucia, Queensland 4067 Dear Dr. Freguia, Attached is our proposal for the ‘Engineers Without Borders’ project addressing suitable solutions for access to safe drinking water in Devikulam, India. This bid assumes that if it is granted, all parties will work together to develop a mutually agreeable construction schedule. This bid is also based on information provided at this time. Any revisions required at a later date will be subject to price review at that time. For further information, please contact any member of the team: Mitch Smith – 0466 348 606 Danielle Hester – 0415 776 297 Matt Beeston – 0418 122 816 Josh Pellicaan – 0404 741 235 Lawrence Yang – 0425 418 532 Thank you for giving us this opportunity. We look forward to hearing from you. Yours Sincerely, Mitch Smith Danielle Hester Matt Beeston Josh Pellicaan Lawrence Yang Slate Engineering Clean water for a brighter future FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Leading The Way Forward UQ Engineering ENGG1000: P1 – Water Purification nd 2 of June 2011 Mitch Smith: 42676852 Danielle Hester: 42676889 Matt Beeston: 42671642 Josh Pellicaan: 42443960 Lawrence Yang: 42182223 [Type text] [Type text] [Type text] FINAL REPORT- WATER PURIFICATION DEVIKULAM 2011 Executive Summary Pitchandikulam Forest Organisation identified the inadequacy of access to safe drinking water in the village of Devikulam and has initiated an engineering project, in conjunction with Engineers Without Borders, to address the situation. Tests conducted in April 2010 on the Devikulam water supply indicated that salinity, bacteria and turbidity were the main regions of concern. The main goal is to design a water treatment system which renders the water drinkable by international drinking water standards and able to be used for everyday needs. Associated design goals for the project include: • • • • • Building the most cost-effective modular water treatment device; Ensuring it is environmental sustainable; Making it socially and culturally acceptable; Having capacity to supply 10 people with their daily requirements and; Non-reliant on reticulated power. Three water treatment processes were selected as having the greatest potential to fit the requirements and considerations determined by the context. These three methods were: • • • Filtration and adsorption; Biogas distillation and; Solar distillation. A conclusion was drawn to use an innovative solar distillation device consisting of a first stage water filter and then a parabolic trough, with the option to use a biogas system if required. This was the most appropriate method due to the fact it fulfilled the water purification requirements of removing salinity, turbidity and bacteria. The filter’s main directive is to remove nearly 100% of turbidity and bacteria from the feed water. Subsequently, the distillation device will remove salinity and remaining turbidity and bacteria. Preliminary feasibility calculations determined that one person would require 20L of clean water per day for drinking, general hygiene needs and cooking, and thus, a household of ten would require 200L of clean water per day. Calculations conducted on a water treatment system concluded that this method can supply the amount of purified water demanded. It is recommended that a water filter is utilised, as well as a solar distillation device composing of a trough like design (which still relies on the fundamentals of a conventional solar still) be installed to meet the demands of Devikulam for purified water. A mirror of 4000mm and radius of 500mm (with angle of curvature at 180°) was the calculated dimensions for the parabolic mirror trough (assumed sun energy constant) , and for the filter system, an adapted PVC pipe of dimensions 550mm by 250mm. The expectation is that subsequent to the water passing through the full system, the water quality will be of that which satisfies international drinking water standards. FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 [Type text] [Type text] [Type text] FINAL REPORT- WATER PURIFICATION DEVIKULAM 2011 Contents Executive Summary .......................................................................................................... 3 1.0 Introduction ........................................................................................................... 1 1.1 Project Overview ......................................................................................................... 1 1.2 Project Aims and Report Contents .............................................................................. 1 2.0 Problem Definition ................................................................................................. 2 2.0 Task Identification ....................................................................................................... 2 2.1 Pre-existing Water Supply ........................................................................................... 2 2.2 Project Goals Identification ......................................................................................... 2 3.0 Project Scope ......................................................................................................... 3 3.0 Project Scope............................................................................................................... 3 3.1 Inclusions and Exclusions ............................................................................................ 3 3.2 Design Assumptions .................................................................................................... 3 4.0 Literature Search .................................................................................................... 4 4.0 Water Purification ....................................................................................................... 4 4.1 Existing Purification Techniques ................................................................................. 4 4.2 Filtration ...................................................................................................................... 4 4.3 Solar Distillation .......................................................................................................... 5 4.4 Biogas .......................................................................................................................... 5 4.5 Sanitation .................................................................................................................... 6 4.6 Parabolic Reflection .................................................................................................... 7 5.0 Initial Design Concepts ........................................................................................... 8 6.0 Technical understanding ........................................................................................ 9 6.0 Sand Filtration ............................................................................................................. 9 6.1 Ceramic Filter Candle .................................................................................................. 9 6.2 Solar Distillation – Cylindrical Pipe .............................................................................. 9 6.2.1 Parabolic Reflection ................................................................................................. 9 6.2.2 Biogas ..................................................................................................................... 10 7.0 Engineering Sketches............................................................................................ 10 7.1 The Filter System ....................................................................................................... 11 7.2 The Solar Still ............................................................................................................. 12 7.3 Flow Diagram............................................................................................................. 13 8.0 Sustainability ....................................................................................................... 14 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.1 Triple Bottom Line Assessment ................................................................................. 14 8.2 Environmental Sustainability .................................................................................... 15 8.3 Life Cycle Assessment ............................................................................................... 15 8.3.1 Water Filter System ............................................................................................... 15 8.3.2 Solar Still ................................................................................................................ 16 8.3.3 Life Cycle Assessment Conclusion ......................................................................... 17 8.4 Social Sustainability ................................................................................................... 17 8.4.1 Community Consultation Plan ............................................................................... 17 8.4.2 Social Benefits........................................................................................................ 18 8.4.3 Cultural Values ....................................................................................................... 19 8.5 Education................................................................................................................... 19 8.5.1 Complete System ................................................................................................... 19 8.5.2 The End User .......................................................................................................... 19 8.5.3 Maintenance Personnel......................................................................................... 19 8.5.4 Sanitation ............................................................................................................... 20 8.6 Economic Sustainability ............................................................................................ 20 8.6.1 Water Filter System ............................................................................................... 20 8.6.2 Solar Still ................................................................................................................ 22 8.6.3 Conclusions ............................................................................................................ 23 9.0 Feasibility............................................................................................................. 23 9.1 Assumptions and Details for Calculations ................................................................. 23 9.1.1 Water Filter System ............................................................................................... 23 9.1.2 Water Still System.................................................................................................. 23 9.2 Removal Efficiency .................................................................................................... 24 9.2.1 Sand Filter .............................................................................................................. 24 9.2.2 Ceramic Water Filter Candle ................................................................................. 25 9.2.3 Solar Distillation Unit ............................................................................................. 25 9.2.4 Overall Removal Expectation ................................................................................ 26 10.0 Failure Modes and Effects Analysis ....................................................................... 27 10.1 Functional Block Diagram ...................................................................................... 27 10.2 Risk Priority Rating Scale ....................................................................................... 27 10.3 FMEA Analysis Chart .............................................................................................. 28 10.4 FMEA Conclusions ................................................................................................. 30 11.0 Conclusions .......................................................................................................... 30 12.0 Recommendations ............................................................................................... 31 [Type text] [Type text] [Type text] FINAL REPORT- WATER PURIFICATION DEVIKULAM 2011 13.0 References ........................................................................................................... 33 14.0 Appendix ............................................................................................................. 35 14.1 Decision Making Matrix ......................................................................................... 35 14.2 Sensitivity Analysis................................................................................................. 35 14.3 Pairwise Comparison ............................................................................................. 35 14.4 Life Cycle Analysis of Filter .................................................................................... 36 14.5 Life Cycle Analysis of Still ....................................................................................... 38 14.6 The Ceramic Water Filter (Doultonusa, 2011)....................................................... 40 14.7 Doulton Ceramic Candles and Cartridge Grades ................................................... 44 14.8 Solar Still System.................................................................................................... 46 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 [Type text] [Type text] [Type text] FINAL REPORT- WATER PURIFICATION DEVIKULAM 2011 Table of Figures Figure 1 Parabolic Mirror Reflection.......................................................................................... 7 Figure 2 Design Criteria Weighting - Pairwise Decisions Matrix Results ................................... 8 Figure 3 Drawings of Water Filter System ............................................................................... 11 Figure 4 Drawings of Distillation System ................................................................................. 12 Figure 5 Flow Diagram of Water Treatment System ............................................................... 13 Figure 6 Life Cycle Analysis of Water Filter.............................................................................. 15 Figure 7 Carbon Emissions for Water Filter (LCA, 2011).......................................................... 16 Figure 8 Life Cycle Analysis of Solar Still .................................................................................. 16 Figure 9 Carbon Emissions for Solar Still (LCA, 2011) .............................................................. 16 Figure 10 Functional Block Diagram of Water Treatment System .......................................... 27 Figure 11 Sources of Carbon Emissions (LCA, 2011) ................................................................ 36 Figure 12 Major Impacting Sources (LCA, 2011)...................................................................... 36 Figure 13 Sources of Carbon Emissions (LCA, 2011) ................................................................ 38 Figure 14 Major Impacting Sources (LCA, 2011)...................................................................... 38 List of Tables Table 1 Report Contents ............................................................................................................ 1 Table 2 Scope of Report ............................................................................................................. 3 Table 3 Strengths and Weaknesses of Filtration (adapted from APEC Water Systems n.d) ..... 5 Table 4 Strengths and Weaknesses of Solar Distillation (Lof, 1961) ......................................... 5 Table 5 Drinking Standards (adapted from WHO 2011) ............................................................ 7 Table 6 Results of Decision Making Matrix ................................................................................ 8 Table 7 Results of Triple Bottom Line Assessment of the Proposed System/s ....................... 14 Table 8 Community Consultation Plan .................................................................................... 18 Table 9 Educational Outcomes of End Users ........................................................................... 19 Table 10 Educational Outcomes of Maintenance Personnel .................................................. 20 Table 11 Cost of Single Water Filter Module ........................................................................... 21 Table 12 Cost of Single Solar Still Module ............................................................................... 22 Table 13 Removal Efficiency - Sand Filter ................................................................................ 24 Table 14 Removal Efficiency - Ceramic Water Filter................................................................ 25 Table 15 Removal Efficiency - Solar Still .................................................................................. 26 Table 16 Decision Making Matrix ............................................................................................ 35 Table 17 Sensitivity Analysis .................................................................................................... 35 Table 18 Pairwise Comparison ................................................................................................. 35 Table 19 Carbon Emissions Produced through Manufacture and Disposal (LCA, 2011) ......... 37 Table 20 Carbon Emissions Produced through Transport (LCA, 2011).................................... 38 Table 21 Carbon Emissions Produced through Manufacture and Disposal (LCA, 2011) ......... 39 Table 22 Carbon Emissions Produced through Transport (LCA, 2011).................................... 40 Table 23 Biodigester Relationship (Camco, 2010) ................................................................... 49 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 1.0 Introduction 1.1 Project Overview Devikulam is a sparsely populated community situated in eastern India. The 320 locals struggle daily to obtain the necessary quantities of water to sustain their everyday lives. Currently the small town relies upon a 30,000L water tank, 3 bores (one of which is saline and another which is not currently functional) and the local pond for their daily water supplies. Access to safe drinking water is a fundamental human right and an indispensable component for maintaining a positive quality of life. The Pitchandikulam Forest Organisation, working in the Kauveli Bioregion (South-East India), had identified that the village of Devikulam has inadequate access to a safe water supply. Engineers Without Borders, paired with the Pitchandikulam Forest Organisation, are in collaboration to find an environmentally sustainable and culturally acceptable solution for the water crisis in Devikulam. 1.2 Project Aims and Report Contents The aim of this project is to provide the community of Devikulam with a reliable supply of uncontaminated drinking water. It is highly desirable to treat the local water to a level equal to, or greater than, the levels set by the World Health Organisation (WHO). It is imperative that the solution is: • • • • Cost effective; Environmentally sustainable; Socially, economically and culturally acceptable and; Perceived as being beneficial. Table 1 Report Contents Heading What will be covered Problem Definition - Project Scope - Literature Search - Initial Design Concepts Technical Understanding Sustainability Feasibility Calculations - Failure Modes and Effects Analysis (FMEA) Conclusions and Recommendations - 1 Task identification, pre-existing water supply and project goals identification What factors the design will address, what factors the design will not address and project/design assumptions Pre-existing water purification methods, identification of plausible treatments, evaluation of plausible water treatment(s) How water treatment method was chosen Description of methods chosen and design drawings Environmental and social sustainability of system evaluated Estimations for water usage, estimation for water production, design dimensions and design assumptions Evaluation of design through safety model Summary of current position and viability of the proposed solution FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 2.0 Problem Definition 2.0 Task Identification The vision of the Pitchandikulam Forest Organisation (PFO) is to provide the community of Devikulam with a reliable and safe supply of water. The primary focus, which was identified by the E.M.S Lab (2010) results, will be on minimising turbidity, eliminating bacteria and salinity of the source water from three bore sites situated in the village and the local pond. By improving the water quality in Devikulam, it is then possible to improve the overall health of the Devikulam community. 2.1 Pre-existing Water Supply The community of Devikulam currently relies on two different water supplies for their daily requirements. Most of the community’s water is supplied by one of the three bores, however, presently “one of the bores has been considered too ‘saline’ and is no longer used by the community for drinking purposes, and another of the bores is not functional at the present time” (EWB 2011). Furthermore, water is supplied to the community through the local pond, however, this water can be “subject to contamination during the monsoon season” (EWB 2011), as water that flows into the pond is contaminated. As identified by the PFO, there are health concerns associated with the consumption of the pond water, and for this reason, a water purification system must be implemented in the community of Devikulam. 2.2 Project Goals Identification The project goals were initially created to come up with a justifiable and acceptable solution for the problem defined in section 2.1. The goals were created in terms of solving the water quality issue, the achievements of functions of the designed module as well as the output of the module. The module will: • • • • • • • • • • Improve the water quality, by addressing the three main factors: salinity, turbidity, bacteria; Treat Turbidity levels to < 0.5 NTU, Salinity levels to < 100 ppm, with a constant pH and no traces of Bacteria; Be an environmentally sustainable and reliable water purification system that provides clean, uncontaminated water for the Devikulam community; Be capable of supplying 10 people with 20 litres of clean water daily; Be a cost effective solution that is can is feasible within the Devikulam economy; Improve in the general health and hygiene of the Devikulam community by reducing levels of diarrhoea attributed to contaminated drinking water; Provide a clean supply of water for drinking, cooking and washing; Not rely upon reticulated power; Be seen as beneficial, effective and maintainable by the villages (Maintenance procedures will be simple and reproducible). Culturally and socially acceptable, not impeding on community values. 2 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 The above goals will be achieved within the Devikulam community so that a sustainable solution will be implemented to benefit the local community. 3.0 Project Scope 3.0 Project Scope The project will be dealing with water purification in the community of Devikulam. The main concept is to treat the contaminated water to an acceptable standard to increase the health of the local community and to provide a clean and reliable water source. The purification system will be designed with the project goals in mind, and will be constructed to remove the contaminants from the water supply. 3.1 Inclusions and Exclusions The project is not capable of covering all the issues that surround the implementation of a water purification system in Devikulam, as such, a large scope would take away from the necessary information regarding the purification system. For this reason parts of the larger picture are being excluded from the project scope so that the report can focus specifically on the important aspects of the water purification system. Table 2 displays the scope of the report: Table 2 Scope of Report In Scope Water treatment capacity Environmental and social sustainability Cost effectiveness Mechanical maintainability Life cycle of purification system Out of Scope Heavy metal cation and anion treatment By-product management Position of module within community Bore’s effect on water access 3.2 Design Assumptions For the report to be specific and address the required areas, assumptions must be made where the information is not clear or accessible. Below are the design assumptions for the water purification system: • • • • • • There is a sufficient water supply to provide the water purification system with water; There will be a 24 hour period in which the water can be purified for the ten people; Each person will only require 20L of water per day (this includes cooking, washing and drinking); The hours of sunlight in a day is approximately the same all year; The villagers will be able to perform small maintenance procedures on the module if required and; The average water consumption is the same for men, women and children for all intents and purposes of the report. The above assumptions were made so that it was possible to start the feasibility and design of the project with respect to the project goals. 3 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 4.0 Literature Search 4.0 Water Purification “Water purification is the process of removing contaminants” (Kostoff et. al 2007), from a water source so to be used for drinking, washing and industrial purposes. Purification occurs to limit the levels of certain components of the water so to reduce the potential associated health risks. “The world health organisation has identified 752 substances that may be present in tap water” (Sutherland 2008), and it is many of these elements that purification aims to remove. From “minerals, fungi, and viruses” to “parasites, viruses and organic matter” (Kostoff et. all 2007) the levels of these elements need to be reduced to minimal quantities for water to be classified drinkable. Water purification techniques have evolved with advancing technology over the past decades, from “simple systems based on the imitation and adaptation of naturally occurring processes” (Brissaud 2006), such as sand filters, to complex multi stage purification techniques that use such techniques as “coagulation, flocculation and deionization” (Kostoff et. al 2007). Many different techniques are still operational around the world depending on the country’s economic situation and needs. 4.1 Existing Purification Techniques Presently there are many different techniques that are used to purify water for a variety of applications. Most purification systems aim to purify water to the standards of the World Health Organisation so that it can be used as a source of drinking water. A combination of reverse osmosis, and filtration is one of the main ways in which water is purified in modern day times. “Reverse osmosis is a membrane based demineralization technique used to separate dissolved solids” (Kucera 2010) from water. By using permeable selective membranes and pressure the system is able to “overcome the ‘osmotic pressure’ allowing water to cross the membrane from high concentration to low” (McIlvaine 2008). This process is used to remove ionic contaminants and other dissolved solids form the water. 4.2 Filtration Filtration is a method of purification used to extract turbidity and sediments from the contaminated water supply. Sand filters are the most commonly used method of filtration before reverse osmosis and other such technologies were developed, and it was successful because it followed a natural system, where water is “filtered through sand in fresh lakes” (Cartwright 2006). The process of filtration involves the pores of the filtrate; the size of the pores determines the effectiveness of the purification system. As the water is gravity fed through the filter, sediment and turbidity are ‘caught’ in the pores between the filtrate, removing them from the water source. However, this lead to the ‘filter becoming ‘backed up’ due to the accumulation of contaminants in the filtrate pores, leading to a reduction in the systems efficacy (Wotton 2002). This is overcome through a backwash technique developed to remove the contaminants and sediments caught within the filtration system, restoring it to its original working state. 4 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Table 3 Strengths and Weaknesses of Filtration (adapted from APEC Water Systems n.d) Strengths • cost effective • • Weaknesses • requires backwashing regularly to maintain filters efficiency environmentally sustainable • requires media disposal and replacement removes majority organic and inorganic • does not remove salts suspended particles removes majority of bacteria • does not remove all chemicals mechanically maintainable • simple operation • • 4.3 Solar Distillation Solar distillation is the technique of harnessing the suns energy (heat) to vaporize water; it is a traditional method for water purification. The concept of purification by distillation is simple, water generally has the lowest boiling point out of all the contaminants, by using the heat of the sun the water can be vaporized before any of the other particulates. By capturing the vaporized water, a purified water supply can be established, as all of the original contaminants have been left behind in the original position. Water has a enthalpy of vaporization of 40.65 KJ/mol (Kucera 2010), meaning that at 373.15oK (100 oC) 40.65KJ/mol is required to transform liquid water into gas. During distillation all this energy is required from the heat of the sun, and during direct sunlight the energy produced by the sun can be up to 590.4 KJ/hour/m2 (Qiblaway et. al 2007). From this it can be seen that it is feasible to gain purified water from distillation as the sun provides all the energy that is required and it comes at no cost. However, there are always complications that arise during this process, problems like heat transfer and sun exposure. Much heat is generally lost through absorption from other materials; this absorption decreases the amount of heat being transferred to the water and in turn the volume of water being vaporized. Table 4 Strengths and Weaknesses of Solar Distillation (Lof, 1961) Strengths • potential for expansion from modular design • removes salinity, turbidity and bacteria • environmentally sustainable • mechanically maintainable • cost effective Weaknesses • limited flow rate • requires solar energy • removal of healthy minerals 4.4 Biogas Biogas is a naturally occurring gas from the decomposition of organic matter. “Biogas is produced through anaerobic digestion or fermentation, whereas hydrocarbons are released as the bi-product” (Jian, 2009). The hydrocarbon that is the main bi-product of the decomposition reaction is methane; along with this there is also a large production of 5 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 carbon dioxide. In third world countries (India), biogas is produced “through the decomposition of cow manure and green waste” (Jian, 2009)). From this methane is collected and used for such activities as cooking and lighting. The use of biogas is a conventional renewable for of energy, however, it can produce large quantities of carbon dioxide and other dangerous gases into the air. Biogas is a replacement for conventional power, and with the unreliability of the power grid in developing parts of the world, it is the only sustainable form of energy. For its production a digester is required, it is here where all of the organic material is broken down for the production of methane. The use of biogas provides a cheap and economically sustainable source of energy for developing countries and isolated communities. The application is biogas technology in isolated communities is one that is technically suitable and sustainable. In communities without reticulated power, a digester can be set up at a minimal cost, which with the constant addition of organic matter can provide a combustible gas free of cost. This gas can be harnessed for heating and cooking, and provides a sustainable alternative to conventional power in isolated and poor communities, allowing for improvements in hygiene and quality of life. 4.5 Sanitation Developing countries have low levels of sanitation and lack basic general health and sanitation. The World Health Organisation estimates that “1100 million people worldwide drink unsafe water” and that the “vast majority of diarrheal disease in the world (88%) is attributed to unsafe drinking water” (Suthar 2009). It is the particulates and sediments in the water which are responsible for the diseases and the reason why the World Health Organisation set drinking water standards so to minimize the risk of potential health detriments. Demonstrated below in Table 3, are the drinking water standards set by the World Health Organisation. There are secondary affects that are also associated with the consumption of contaminated drinking water. It is know that contaminated drinking water is the main cause of diarrheal disease, plus the fact that Devikulam has “low levels of sanitation” (EWB 2011) that ultimately leads to the significant health and hygiene risks to the local inhabitants. The problem associated with drinking contaminated water resonates with the fact that levels of sanitation are low within the Devikulam community. This brings health risks that could have detrimental effects on the surrounding community and is the reason why the drinking water standards set by the World Health Organisation need to be adhered to. 6 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Table 5 Drinking Standards (adapted from WHO 2011) Parameters pH TDS TA TH Na+ Ca2+ Mg2+ CO32HCO3ClSO42F- ISI Standards Acceptable Limit 7.0 – 8.5 500 200 200 50 75 30 75 30 200 200 1 WHO Standards Maximum Permissible Limit 6.5 – 9.2 1,500 600 600 200 100 200 1,000 400 1.5 6.5 – 9.2 500 100 75 150 75 150 200 200 1 4.6 Parabolic Reflection The parabolic mirrors reflective properties are due to its shape, it is this shape where any incident ray of light is reflected onto the focal point above the mirrors surface. The use of a parabolic mirror for distillation is an effective way of heating the water supply; if the source is situated in the focal point of the mirror than all of the energy striking the surface of the mirror will be reflected upon the supply (seen in Figure 1). By using a cylindrical pipe, the focal point of the mirror is situated at the radius of the circle. By incorporating a large surface area into the parabolic mirror design then the efficiency of heating the water supply can be increased to an extent where evaporation comes almost instantaneously. Through this process the purification of the water supply can be a very efficient and an environmentally sustainable Figure 1 Parabolic Mirror Reflection process. 7 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 5.0 Initial Design Concepts For this phase the initial nitial design proposals were evaluated against the project’s aims and if discrepancies appeared then that particular design was forgone. For the process of evaluating the most suitable preliminary design, a Decision Making Matrix (Refer to Appendix 14.1)) was used to appraise the proposed concept designs against four key criteria pertinent to the project’s ct’s core aims. These criteria were: were • • • • Water purification ability (removal efficiencies of turbidity, salinity and bacteria); Cost effectiveness (cost of materials and time period specific specific materials are effective); Sustainability ity (environmental impacts) and; Modular design (capacity to have more than one unit function harmoniously together). Each of the four key criteria were given a weighting scale based on their comparative pertinence ce to one another through the utiliseation of a Pairwise Criteria Matrix (Refer to Appendix 14.2). ). The outcome of this comparison is illustrated in Figure 2.. Design Criteria Weighting 10% 20% 50% Purification ability Cost Effectiveness Sustainability 20% Modular Figure 2 Design Criteria Weighting - Pairwise Decisions Matrix Results Weighting the criteria enabled analysis of the most plausible designs, with the conclusion being eing objective and supported by apposite decision. A five point rating scale was used; founded on relevance to a set standard. In this circumstance the standard was if nothing was implemented to purify water into the Devikulam community. The rating scale was one through the five; much worse, worse, same (standard), better and much better than the standard. Thus, the design with the highest rating total was deemed as the design to proceed with. Table 4 displays the results of the Decision Making Matrix: Table 6 Results of Decision Making Matrix Conventional Solar Still Total 3.5 Parabolic Trough + Rapid Type Filter 4.1 The Decision Making Matrix evaluates evaluate each design in accordance, and respect to, the set criteria which are based on the project’s aims. It can be concluded from this matrix that a parabolic trough plus a rapid type filter be used to effectively, and aligned with project projec aims, 8 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 adequately address the requirements for purified water in the village of Devikulam. (Refer to Appendix 14.3 for Sensitivity Analysis) 6.0 Technical understanding The method of purifying the waste water for the community of Devikulam will be subdivided into 5 sections; sand filtration, ceramic water filtration, parabolic reflection, solar distillation and biogas. All the methods and stages will be clearly stated below. 6.0 Sand Filtration A rapid type sand filter is utilised as the first stage of filtration. During the first phase, contaminated water will be flowing through the sand filter to remove the large organic molecules from the wastewater. This rapid type system is being used as it is the most viable method for first stage filtration. Sand filtration helps to reduce up to 80% of turbidity, up to 5% of organic material, up to 10% of water colour and almost 90% of bacteria and Coliforms from the wastewater. Furthermore, due to its low cost and its efficiency it will be used as the first method of purification. 6.1 Ceramic Filter Candle A ceramic candle water filter is utilised as the second stage of filtration. The main purpose of using the filter candle is to block the passage of any molecules that are larger than water molecules. This process can be also named osmosis. Osmosis is defined as the movement of water molecules from the region of higher water concentration to a region of lower water concentration via a semi-permeable membrane. A ceramic water filter will only allow water or any molecules that are smaller than water molecules to pass though to the other side of the filter. Additionally, the ceramic water filter contains silver substances, which help to incapacitate or kill bacteria and prevent the growth of algae on the receptacle. During this process, the contaminated water is poured in the filter and passes through it into the receptacle below. The receptacle usually is fitted with a tap. Importantly, a ceramic water filter contains activated carbon in the inner core which helps to absorb organic compounds such as chlorine. Therefore, it is expected that once the contaminated water pass through the filter stage of the purification process the only impurity left within the water will be salt. 6.2 Solar Distillation – Cylindrical Pipe Solar Distillation is utilised as the third stage of purification to remove the remaining salt compound from the water. The main purpose of using this technique is to utilise the energy from the sun to generate heat energy to vaporise water. As salt molecules are smaller and have a higher boiling point than water molecules, a solar distillation device is one of the most efficient and low cost techniques available. Water generally has a lower boiling point (100°C) than any other contaminant, by using this knowledge water can be vaporised before any other particulates. Once the vaporised water has cooled down, a purified water supply can be established. However, due to time restrictions and the efficiency of reflection of sunlight, another two main designer features have to be introduced; parabolic reflection and biogas. 6.2.1 Parabolic Reflection Parabolic Reflection is the main design feature of this water treatment device. Due to the time restrictions, the treatment has to be more effective and efficient. The introduction of a parabolic mirror is needed to increase the rate at which the water boils. With the use of a 9 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 parabolic mirror, there is an increase in incident rays of light reflected onto the focal point above the mirrors surface where the water will be positioned. The use of a parabolic mirror for distillation is an effective way to speed up the heating process; if the source is situated in the focal point of the mirror then all of the energy striking the surface of the mirror will be reflected onto the water (providing 100% reflectivity). By using a cylindrical pipe, the focal point of the mirror is situated at the radius of the circle. By incorporating a larger surface area into the parabolic mirror design then the efficiency of heating the water supply can be increased to an extent where evaporation is almost instantaneous. Through this process the purification of the water can be a very efficient and an environmental sustainable process. 6.2.2 Biogas Biogas can be used if the preliminary system of parabolic reflection becomes redundant. The thinking behind having the additional biogas system it that it can be used to provide the water treatment system with energy during times where the preliminary system is out of order or cannot function effectively. Biogas is a naturally occurring gas from the decomposition of organic matter. It acts to heat up the pipe to boil the filtered water when ignited. Thus, the salt will be removed from the water which can now be consumed. 7.0 Engineering Sketches The following drawings show the design and the dimensions of the modular water treatment system (Detailed on following pages). 10 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 7.1 The Filter System Figure 3 Drawings of Water Filter System 11 2011 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 7.2 The Solar Still Figure 4 Drawings of Distillation System 12 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 7.3 Flow Diagram QUICK OVERVIEW Figure 5 Flow Diagram of Water Treatment System IMPURE WATER IN SAND VOID STAGE ONE, SAND FILTER: REDUCES TURBIDITY, REMOVES LARGER PARTICLES, RAPID FLOW HOT WASTE FROM BOILER REINTRODUCED TO SYSTEM, INCREASES EFFICIENCY WATER VAPOUR INTO CONDENSER CONTAINS NO IMPURITIES. CONDENSER STAGE TWO, CERAMIC FILTER: REDUCTION OF TURBIDITY UP TO 99.69% (RUST, SAND, SEDIMENT, ALGAE) REDUCTION UP TO 99.99% REMOVAL UP TO 99.99% BOILER (PARABOLIC MIRROR OR BIOGAS) FRESH CLEAN WATER OUT. QUALITY WITHIN ACCEPTABLE DRINKING REMOVAL UP TO 99.99% REMOVAL OF GUINEA WORM100% HOT WASTE WATER WITH CONCENTRATED SALT, REINTRODUCED INTO BOILER CLEAN WATER OUT, ONLY IMPURITY PRESENT IS SALT. FLOWS TO BOILER WATER FROM FILTER SYSTEM 13 HOLDING TANK: WATER AVAILABLE TO THE VILLAGE AS REQUIRED. FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.0 Sustainability Sustainability is the key issue that faces all designs. Consideration needs to be taken as to whether the design is environmentally, socially and economically sustainable. Table 5 shows the results of a triple bottom line assessment, each issue is then considered in depth in the preceding sections. 8.1 Triple Bottom Line Assessment Table 7 Results of Triple Bottom Line Assessment of the Proposed System/s CRITERIA RESULT (1-5) 2 4 • • • • • 3 • • Energy ENVIRONMENTAL DESCRIPTION Resources • Impact 5 SOCIAL Employment • • • 5 • 5 • • • Culture Education • 5 • Initial Cost ECONOMIC 4 Operational Cost 3 Profit 14 • • • • • • • • PVC piping requires energy to produce, petroleum based. Transportation uses large amounts of energy. Production of ceramic candle filter is energy intensive. Reflective surface production, material is petroleum based. Uses PVC and copper, both non-renewable, but can be recycled. Sand recyclable. Initial impact on environment substantial, due to manufacturing process required for some components. Once system is running negligible impact as it is self sustaining. Environmentally friendly waste produced. Initial setup will create a number of jobs, however these will be unpaid. Ongoing maintenance personnel will be paid to maintain system, small number of jobs created. Respects traditional local values, does not impose Western values upon the community. Aims to improve the standard of living. Is culturally appropriate. Creates an awareness of the risk of poor water and lack of sanitation. Offers the community a chance to increase their knowledge of new technologies. Components can be bought ‘off the shelf’ from local hardware. Single module costing not more then $200 (Filter and Still) Limited operational costs, biogas free. Main operational cost being filter replacement. Solar energy used to heat water. Simple system meaning maintenance cost from staffing perspective is limited. Highly durable, limiting breakages and failure. Community may be able to make profit from salt. Profit not a key requirement, rather improvement on quality of life FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.2 Environmental Sustainability A key goal of the proposed system was to ensure that it had minimal impact on the environment. This has been done by, where possible, using recycled materials and recyclable materials, where this is not possible the materials then selected must give the longest operating life possible. Materials selected for the design have been evaluated to be as environmentally sustainable as possible. Selection considerations has taken into account the manufacture and processing required to produce the materials, the below life cycle assessment summaries all considerations. 8.3 Life Cycle Assessment 8.3.1 Water Filter System A lifecycle assessment has been completed using the Lifecycle analysis calculator available. Assumptions have been made: activated carbon used within the ceramic filter has been assumed as equivalent to the production of clay brick. Assumed lifespan of filter internals is 1 year. The assessment has been broken down into a single module. The assessment for the water filter system can be seen in Figure 9. It is assumed that the modules will be manufactured within Australia and then sent to Devikulam. The assessment has been biased towards producing more waste and C02. COMPLETED FOR SINGLE MODULE Figure 6 Life Cycle Analysis of Water Filter 15 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Figure 7 Carbon Emissions for Water Filter (LCA, 2011) Within the water filter system the sand used in the first stage can be sourced locally, reducing energy usage and C02 emissions. The ceramic filter will however have to be transported into the region and will be an ongoing impact for the life span of the system. 8.3.2 Solar Still The assessment for the solar still system can be seen in Figure 11. The solar still is unique in design and assumptions had to be made for the reflective surface; it is assumed that the energy required to make the reflective material is approximately equivalent to the production of a standard mirror. Figure 8 Life Cycle Analysis of Solar Still Figure 9 Carbon Emissions for Solar Still (LCA, 2011) 16 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.3.3 Life Cycle Assessment Conclusion Each system has been analysed separately increasing energy usage and CO2 production significantly in the transport stage. This will be offset by the exclusion of small components required within the system. There are minimal ongoing energy requirements to run the system. Biogas is used as an alternative to solar when it is unavailable; the biogas is considered carbon neutral and therefore is not considered in the production of CO2. 8.4 Social Sustainability When introducing a new system to a community a key number of points must be considered. These are: • • • • Cultural practices and expectations. Complexity of the system and required level of understanding required to operate the system. Advantage to the community. The long term goal is for the community to manage and maintain the system without outside help. 8.4.1 Community Consultation Plan Communities like to input into ideas/designs that improve their overall community. To assist in understanding the system, community involvement is essential at every level. A strong side-benefit comes from pride and increased self-worth gained from contributing to improved living standards. In order to communicate the proposed system and design with the Devikulam community, it was decided that the most effective method would be a two pronged approach. It was concluded that both approaches must be conveyed using culturally familiar methods, such as dance and stories. The two pronged approach would address the whole community and then focus on educating children at school. The initial proposal would be presented at community gathering in an informal manner. It will be important to utilise the connections and familiarity of the EWB staff currently working with the community to introduce the design and receive feedback. Potential barriers to implementation have been indentified; these must be overcome to increase the chance of success for the systems acceptance. • • • 17 Communication: While English is widely spoken in the community, Tamil is most common and used in everyday conversation. A translator may be required to assist in communication. Technical understanding: The community may not understand how the system works and therefore view the system as ‘suspicious’ believing that it might be ‘bad’. Sanitation: The community needs to understand the risks associated with poor sanitation and how this affects their water. FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 These barriers can be overcome through having an in-depth understanding of the values and beliefs of the community as well as building trust and a repour with the members of the community. The following table has been adapted from the best practice guide and details the community consultation steps for the system. Table 8 Community Consultation Plan CONSULTATION STEPS 1. Presentation Introduction and DESCRIPTION • • • • • • • 2. Installation 3. Education • 4. Trial Period Feedback and • • • 5. Ongoing Evaluation and Community Consultation • • • Approach key members within the community to introduce design. Arrange meeting with whole community to describe the system, its purpose and likely benefits to the community. i.e. Health improvement. Also receive feedback on initial feelings regarding the system. Train maintenance staff. Setup system in appropriate places. Complete training of maintenance staff. Educate the wider community on the system as well as proper sanitation and the benefits of clean water. Implement an education program into schools using culturally appropriate techniques. Monitor operation for a period of 4 weeks. Facilitate meetings with key members of the community to gather feedback. Community meeting to gather wider community feedback on system. Continued monitoring of system. Supervision of maintenance staff until deemed fully competent. Continued facilitation of feedback and suggestions for improvements of the system. (Best Practice Guide for Students and Tutors, 2011) 8.4.2 Social Benefits In undeveloped nation’s illness from water related diseases/bacteria is a common problem and accounts for approx 2.2 million deaths per year globally. (World Health Organisation, 2011). Clean water will improve the overall health of the community through a reduction of water borne illnesses. A side benefit from this will include a generally happier population, a reduction in the strain required to care for ill people allowing for an increase in social interaction and able bodied people fit for work leading to an increase in income. 18 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Education into proper sanitation methods and an understanding of the importance of clean drinking water should also help to raise the living standard. 8.4.3 Cultural Values Research into cultural practices has shown that the proposed design meets cultural expectations and should not infringe on any cultural beliefs or practices. Any problems that arise from feedback showing infringement on cultural beliefs or practices will be dealt with promptly with consultation with community members, allowing the solution to be culturally acceptable. 8.5 Education 8.5.1 Complete System While the proposed system is simple, the community will require education in regard to the system’s use and maintenance. Overall it will be important for all members to have a basic understanding of the system, which will aid in long term acceptance and use of the system. Education will be broken into two sections; the end user (most of the community) and maintenance personnel. 8.5.2 The End User The end users, being the people of the community, will be accessing and using the system on a daily basis. It is highly important that this majority has a basic understanding of the system and it use, as the system is modular, and may be implemented in-home or at the community level. The community must understand that not all water is safe and that the reason for the water purification system is to make the water safe for use. The system will be used by adults and children therefore, a multi-prong approach can be taken, children can be educated at school, along with community meetings and small group demonstrations. Emphasis should be place on the dangers of unclean water and a basic run down of what the system does and how to obtain clean water from it. Table 9 Educational Outcomes of End Users Expected Education Outcomes – The End Users End users should be able to demonstrate: A basic understanding of the system. A basic understanding of the associated risks of unclean water. Use of the system and obtaining clean water. 8.5.3 Maintenance Personnel During building/installation of the system key members of the community will be selected and trained to a higher level of understanding of the system. Proper maintenance is required to ensure the system continues to function as required; these people will maintain and repair the system. Education will include in-depth troubleshooting of problems and how to rectify them, a comprehensive understanding on how the system 19 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 functions as well as cleaning and replacement of components of the system. Selected candidates should be fluent in both English and the local language, they must also be respected members of the community; their understanding and standing within the community will aid in acceptance and continued use of the system. Table 10 Educational Outcomes of Maintenance Personnel Expected education Outcomes – The Maintenance Personnel Maintenance Personal should be able to demonstrate: A complex understanding of the system. A complex understanding of the associated risks of unclean water. Disassemble and reassemble the system. Troubleshoot and rectify problems within the system. 8.5.4 Sanitation Poor sanitation is a key issue within the community, the common practice of open defecation must be addressed whilst being mindful of cultural practices. Educating the community on proper sanitation techniques and associated risk of human/animal waste in their water will aid in reducing the chance of pathogens in the water before purification. As the community has access to the internet this tool can be used to help educate the community in relation to sanitation. If the containments within the water can be reduced/minimised before the water passes into the system, this will reduce the stress on the system, maximising the life span of the components. 8.6 Economic Sustainability 8.6.1 Water Filter System The design cost has been evaluated using the average price of the materials. A number of suppliers were contacted for the pricing of each individual component of the system. The water filter system consists of PVC piping, sand and a ceramic candle water filter. The sand is held in place within the tube by a simple fine mesh membrane. (For details see engineering drawings). 20 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Table 11 Cost of Single Water Filter Module Component Number 1 2 Description PVC pipe, system housing. Wall thickness = 4mm Sand: Bedding Sand, medium grain. 3 End caps for PVC pipe 4 PVC pipe coupling caps 5 6 Doulton ceramic filter candle. Mesh-membrane to hold sand. Specifications Height = 880mm Ø = 250mm Unit Cost Total Cost ($) Quantity $22 per/m 880mm 19.15 Medium grain $63.17/tonne 0.00736m3 = 13.2 kg 0.85 Ø = 250mm capping $4.49 4 17.96 Ø = 250mm $13.74 4 54.96 10 inch unit $19.95 1 24.95 Ø = 250mm 0.049m2 $0.85 1 0.85 TOTAL (AUD) $119.52 It is assumed that the internal parts of the filter will have an approximate life span of 1 year. This means that in a worst case scenario, the village will have to re-purchase the filter system once a year along with approximately $100 in freight transporting the parts from Australia to Devikulam. This brings the annual cost to $219.52. 21 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.6.2 Solar Still The design cost has been evaluated using the average price of the materials. A number of suppliers were contacted for the pricing of each individual component of the system. Table 12 Cost of Single Solar Still Module Component Number Description Copper pipe (water flow) Type L used in residential and commercial water supply and pressure applications. 1 2 Copper pipe (gas flow) 3 Wood for the frame Specifications Ø = 14.13mm (conforms to $22.00/m standard 1 1/8 inches) 5 6 7 Total Cost($) Quantity 4m 88.00 4m 32.00 $25.00/m2 2m2 50.00 4.60/each 2 9.20 4.8/each 1 4.8 $16.50/each 1 16.50 Ø = 19.1mm (conforms to $8.00/m standard ¾ inches) 2 part system 98.5% Reflective surface reflectivity, 10 year guarantee Copper elbows (water Short elbow to fit 3 flow) inch pipe T-junction to fit 3 T-junction inch pipe Regulator: 2Kg/h LPG, 2.8 kPa, Max inlet Pressure 1750 kPa. Inlet Fitting: CGA-510 Gas regulator and POL with soft bull fittings/hose nose (7/8" - 14T-LH) Hose: Quality 1.8 meter 8mm1/4"BSPF, Max WP 7kPa, AS/NZS 1869 4 Unit Cost TOTAL $200.5 It can be assumed that in a worst case scenario the still will have to be replaced between 10 years. This means that the still will cost the village approximately $30.05 per year in replacement parts and $100 in freight from Australia to Devikulam. 22 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.6.3 Conclusions The initial cost of the water treatment system is approximately $320.02. There is also an additional freight cost of approximately $250, giving a complete initial cost, including transport, of $570.02. Additionally, there will be an annual cost of $149.57 in maintenance. In small villages such as Devikulam, each person has an average income of $500 a year (Sanford, 2003). The module produces water for 20 people with a combined income of $10 000. This indicates that it is feasible for the village to be able to easily afford the costs of the system annually. 9.0 Feasibility 9.1 Assumptions and Details for Calculations Each person in the village has been allocated 20L of purified water for drinking, cleaning and cooking as per a recommendation by the UN (UN 2010). Design specifications stipulated that the system must be able to purify water for 10 persons. The village contains 320 persons therefore 16 modules are needed. The design proposed consists of two parts; Part A: A gravity fed sand filter flowing into a ceramic candle filter (see engineering drawings for details). Part B: A solar distillation unit. Each module must be portable as per design requirements. 9.1.1 Water Filter System The sand within the filter system makes the weight of the filter unit a key concern. It was concluded that each module will contain 13kg of sand and have a total weight of 15kg. This weight is deemed as acceptable for each module maintaining the portability of the system. The system will be contained within a PVC pipe with a diameter of 250mm and a height of 550mm, allowing the system to be robust. 9.1.2 Water Still System The energy available to the system is controlled through the size of the concave mirror. It was decided that the mirror would have a length of 4000mm and a radius of 500mm, with an angle of curvature of 180 degrees. Another controlling factor is the volume of water which the copper pipe can hold. The allocated pipe was 4m long with a radius of 14.13mm. This has a resulting volume of 2.129L. There are also known efficiencies within the still involving solar radiation absorption. The assumed efficiency of the reflective surface is 95%. There is also an assumed radiation absorption efficiency for the copper piping of 64%. The flow rate of the still is the main effecting factor as it has to be steady enough to allow the water to evaporate within the time it is in the pipe. The minimum flow rate for the piping is 1L/2.34mins. This flow rate uses all 7.8hrs of sunlight to process 200L, however there is 32.5 MJ of excess energy at this flow rate. 23 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Using this excess energy a maximum flow rate was calculated and was found to be 1L/1.54mins. This produces 304L of water in 7.8hrs and would give the village the ability to produce more water if necessary. The excess energy also allows for an output efficiency of less than 100% e.g. 80% efficiency It was also calculated that to produce enough biogas to distil the 200L of water in the case of rain, the approximate waste from fifteen cows would be needed. This would then have to be stored in a digester with a volume of 20m3 and then further transferred into a gas storage container which can hold the 3.4 m3 of gas required for distillation. It should also be noted, however, that Devikulam only receives at most ten days of rain, thus meaning the biogas use will be infrequent. 9.2 Removal Efficiency 9.2.1 Sand Filter A rapid type sand filter is utilised as the first stage of filtration, it is expected to remove the larger organic particles and 80% of the turbidity. A rapid type system was determined as the most viable method for the first stage filtration. Details on the efficiency of the system are detailed in the following table. Table 13 Removal Efficiency - Sand Filter Problem Expected Improvement Turbidity Organic Material Water Colour Bacteria and Coliforms Reduction of turbidity by up to 80% Reduction in organic material by 5% Removal of water colour by up to 10% 90 % removal of coliforms, 50-90 % removal of cryptosporidium and Giardia cysts, Table: (ITACA, 2011) 24 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 9.2.2 Ceramic Water Filter Candle A Doulton 5" Super Sterasyl Ceramic Filter Candle type water filter is utilised as the second stage of filtration, the ceramic candle is expected to remove particles/organic materials/bacteria that passed through the sand filter. Removal efficiencies are detailed in the following specifications as retrieved from the manufacturer. Table 14 Removal Efficiency - Ceramic Water Filter Problem Expected Improvement The Doulton 5" Candle is NSF Certified Standard 42 & 53 for the reduction of: Turbidity Reduction of turbidity by up to 99.69% Particulates (rust, sand, sediment, algae) Reduction up to 99.99% Taste and Odour Removal of up to 99.99% Bacteria and Coliforms Removal up to 99.99% Guinea Worm 100% Removal Table: (DoultonUSA 2011) First stage: The first stage consists of Doulton supercarb ceramic which provides genuine sub-micron filtration. The cartridge reduces fine particulate matter, bacteria, cysts and turbidity. Second stage: The incorporation of silver locked within the ceramic structure gives enhanced bacteriostatic and self sterilizing properties, preventing the growth of bacteria. Third stage: An inner core of activated carbon block removes chlorine and organic compounds. It is expected that once the water has passed though the filter stage of the purification process the only impurity left within the water will be salt. (DoultonUSA 2011) 9.2.3 Solar Distillation Unit The design of the solar still unit has moved away from the conventional solar still to a unique module, yet it still works on the same principle of boiling water, collecting the vapour and condensing it. Solar stills are proven to be effective in the purification of water. Solar distillation removes all salts as well as biological contaminants (for example, cryptosporidium, E. coli, etc.) It is expected that all salts will be removed. Note: Turbidity, organic material, water colour, bacteria and coliforms will have been removed by the filter system. In the event of a partial failure of the filter system the below details the expected removal of particles left in the water after partial filtration. 25 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Table 15 Removal Efficiency - Solar Still Problem Expected Improvement Salt Turbidity Organic Material Water Colour Bacteria and Coliforms Reduction of salt by 100% Reduction of turbidity by 100% Reduction in organic material by 100% Removal of water colour by up to 90% 90 % removal of coliforms, 50-90 % removal of cryptosporidium and Giardia cysts, The primary disadvantage of distillation is that any material that has a lower boiling point than the water will boil off along with the water; this may include oils, herbicides/pesticides. This will not be a concern in the system as the pre-filtration will remove these impurities. After passing through the solar still all impurities are expected to have been removed. 9.2.4 Overall Removal Expectation It is expected that after passing through both systems the water quality will be clean of all impurities and be within the acceptable range for drinking water. 26 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 10.0 Failure Modes and Effects Analysis 10.1 Functional Block Diagram Water Treatment Module Ceramic Filter Ceramic Filter PVC End Caps/ Coupling Caps PVC Piping Figure 10 Functional Block Diagram of Water Treatment System 10.2 Risk Priority Rating Scale Severity (Sev) 1 2 3 4 Negligible Marginal Critical Catastrophic Probability (Prob) 1 2 3 4 Improbable Remote Occasional Expected Detection Probability (Det) 1 2 3 4 Certain Likely Possible Impossible 27 Mesh Membrane Water Filter System Water Distillation System Sand Filter Solar Distillation Sand Reflective Surface Biogas Distillation Copper Piping Gas Hose Gas Regulator FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 10.3 FMEA Analysis Chart Item Failure Mode Causes (Failure Mechanism) Decomposition of Material PVC Piping Fracture/Leak Long Term Exposure Temperatures to Decomposition of Material PVC End Caps/ Coupling Fracture/Leak Caps Stress Fractures Long Term Exposure Temperatures Sand Excess Particle Build Lack of Maintenance Up Mesh Membrane Fracture Ceramic Filter Excess Particle Build Lack of Maintenance Up Fracture 28 to Term Exposure Leakage of Water Reduction of Gravitational Pressure Reduction of Production Rate Disenables the Filtration System Reduces Effectiveness/Efficiency of Filtration System Leakage of Water Reduction of Gravitational Pressure High Reduction of Production Rate Disenables the Filtration System Reduces Effectiveness/Efficiency of Filtration System Leakage of Water Reduction of Gravitational Pressure Reduction of Production Rate Disenables the Filtration System Reduces Effectiveness/Efficiency of Filtration System Leakage of Water Collapse of Filter System Leakage of Water Reduction of Gravitational Pressure High Reduction of Production Rate Disenables the Filtration System Reduces Effectiveness/Efficiency of Filtration System Disenables the Filtration System Reduces Effectiveness/Efficiency of Filtration System Stress fractures Long Effects to Collapse of Sand Support Spread of Sand through System Disenables the Filtration System Reduces Effectiveness/Efficiency of Filtration System High Disenables the Filtration System Risk Priority Rating Se Pro De RP v b t N 1 8 1 8 2 4 2 16 3 24 2 1 1 2 3 Recommended Improvement Risk Priority Rating Se Pro De RP v b t N 1 1 2 3 3 2 6 6 12 18 16 The use of UPVC to resist 8 decomposition 8 16 24 2 1 1 1 3 2 16 2 12 1 1 2 3 8 8 16 The use of UPVC to resist 24 decomposition 1 1 2 3 6 6 12 18 16 4 8 8 8 Reinforcing the PVC with 16 a stainless steel frame to 24 support it 2 1 3 1 1 2 3 16 18 Using sand with different particle size in order of biggest at the top to 12 smallest at the bottom 12 Using a stainless steel 12 support 18 Using a larger ceramic filter bulb to lengthen the 12 time before needed maintenance 24 2 3 2 1 3 1 1 2 3 4 4 2 2 2 2 4 2 2 3 2 3 2 3 3 3 2 3 2 2 2 3 4 2 3 3 2 3 2 1 2 3 2 12 2 6 6 6 12 18 12 9 1 2 3 3 3 2 12 6 6 12 18 3 1 2 1 3 4 2 6 6 6 9 6 24 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Temperatures Decomposition of Material Copper Piping Leakage Lack of Maintenance Long Term Exposure Temperatures Gas Hose Leakage Decomposition of Material Gas Regulator Non-Regulation Stuck Regulator to Decomposition of Material Reflective Surface Loss of Reflectivity Long Term Exposure Temperatures 29 to Reduces Effectiveness/Efficiency of Filtration System Leakage of Water Leakage of Gas Reduction of Production Rate Disenables the Distillation System Reduces Effectiveness/Efficiency of Distillation System Leakage of Water Leakage of Gas Reduction of Production Rate Disenables the Distillation System Reduces Effectiveness/Efficiency of Distillation System Leakage of Water Leakage of Gas High Reduction of Production Rate Disenables the Distillation System Reduces Effectiveness/Efficiency of Distillation System Leakage of Gas Reduces Effectiveness/Efficiency of Distillation System Reduction of Production Rate Free Flowing Gas Uneven Heating Reduces Effectiveness/Efficiency of Distillation System Uncontrolled Heating Reduction of Production Rate Disenables the Distillation System Reduces Effectiveness/ Efficiency of Distillation System Reduction of Production Rate High Disenables the Distillation System Reduces Effectiveness/ Efficiency of Distillation System 2 1 3 2 3 2 1 3 2 3 2 1 3 2 3 4 2 4 2 3 2 2 3 2 2 3 2 2 2 2 3 2 2 3 2 16 8 8 16 Coating the copper with a 24 protective layer to prevent in 16 oxidation/tarnishing high temperature 6 18 12 18 12 8 24 16 24 Regular inspections to insure coating is intact and copper is not oxidising/decomposing 16 24 4 2 1 1 4 4 2 2 Replacing the hose after 16 specific periods of time 16 3 2 Regular testing of the regulator 2 2 16 24 2 1 3 2 3 2 1 3 2 3 2 1 3 2 3 3 1 3 2 2 2 2 3 2 2 3 2 2 2 2 3 Replacing the reflective 16 surface after a certain 16 period of time 24 2 2 3 16 2 16 6 18 12 18 12 1 6 4 6 4 1 18 12 18 12 18 3 2 1 1 3 3 2 2 12 12 3 2 2 2 12 18 12 12 18 12 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 10.4 FMEA Conclusions The main outcomes of the FMEA analysis was to highlight the biggest hazards that the system causes and demonstrate how they are controlled and the risk reduced. The highest risk priority rating of the original system was 24. This rating generally occurred when leakage, caused by high temperature exposure or decomposition of the material forced the failure of the filtration system or distillation system. These hazards can be controlled by using heat resistant materials (i.e. UPVC piping instead of PVC piping), replacing materials after a certain period of time, providing maintenance to the vulnerable areas or coating the materials in exposure resistant paint. These precautions reduced the original risk priority rating to a maximum of 18 for everything except for the risk of the ceramic filter fracturing. This specific risk is difficult to control as it mostly happens spontaneously, without warning, and it is not necessarily dependant on age. 11.0 Conclusions After extensive research on water purification and treatment methods, a conclusion was reached on the basis of the criteria which were prescribed. These were: • • • • Water purification ability; Cost effectiveness; Sustainability and; Modular design. Of the potential methods explored; filtration/adsorption, reverse osmosis, solar distillation and biogas, a solar distiller and filter (with option of biogas addition) were deemed the most suitable, for the Devikulam community. The primary reason a dual solar distillation and filtration system was selected over the other water treatment methods was that it did not have to rely on a reticulated power source and could remove: • • • Salinity; Turbidity and; Bacteria. Furthermore, this treatment process is also cost-effective as the materials required are common place and/or can be simply substituted for another material with similar properties making it also economically acceptable. Additionally, this procedure is environmentally sustainable as it relies on solar energy, gravity and biogas rather than power from nonrenewable sources. In a basic design form this water treatment system has no moving parts and is simple to understand, and thus, can be mechanically maintained simply. Community understanding regarding this process would be of a relatively high level as this type of method has been used in history (boiling of water) and therefore, the perceptions of it being beneficial would already exist. Through a Triple Bottom Line Assessment, the environmental, social and economic impacts were evaluated and the total life cycle of the system determined. From an environmental perspective, the energy required for the production of specific components in the treatment 30 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 system was of an elevated level due to the requisite of using hydrocarbons. These elements included the PVC piping for the filter and the ceramic candle filter. As part of the environmental division, the resources themselves and their possible impacts were established. From a resources angle the PVC and copper piping are both non-renewable, conversely though, both can be recycled. Taken as a whole, this system is environmentally sound as once it is in operation; there is negligible impact as it is self sustaining. This water treatment system is completely socially viable as it would be integrated into the community of Devikulam with ease. The positive influences are that it: • • • • Creates employment and builds community ownership; Respects the established customs of the people and does not impose Western values, or push capitalist motives upon the community; Forms an awareness of the health risks associated with water that is contaminated and; Produces the opportunity for the community to increase their knowledge base. As this design has been evaluated as being socially viable, it can be inferred that the imperativeness of this system will be understood by the people and therefore, they will actively maintain it to ensure their own well being which is the first step for improved quality of life. Finally, it is also essential to appraise the economic viability of the given system to ensure that it will work in a developing country. The initial outlay is the largest determining factor to be considered. For this design the cost was at an acceptable level for the work it is to undertake. Furthermore, there are no operational costs associated with the chosen design’s energy sources as they are unlimited (being biogas and the sun). Although, there are costs allied with the filter system including the ceramic candle filter, which has a limited operational life span in comparison to other components in the system. 12.0 Recommendations It is recommended that a two part system be installed to meet the demands, and requirements, of the Devikulam community for treated water. The first part consisting of a rapid gravity fed sand filter with an addition of a ceramic candle filter and the second part consisting of a solar distillation unit with the capacity for a biogas heating system to be attached. The first part of the system consists of PVC pipe with a diameter of 250mm and a height of 550mm, split into modules so that the sand and ceramic candle filter are separate identities joined together. It was deemed that 13kg of sand will make up the first section of the first part of the system which was determined as an acceptable weight, with a total weight of 15kg. The second part of the water treatment system entails a concave mirror of length 4000mm and radius of 500mm with an angle of curvature for the mirror being 180°. The copper pipe running the length of the concave mirror (4000mm) needs a radius of 14.13mm (this is a basic component description). 31 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Calculations were undertaken to determine the production volume of purified water from the still using solar energy. To get the required 200L of treated water, 7.8hrs of the day is needed and the system requires a flow rate of approximately 1L/2.34mins. The approximate maximum that this system is capable of is 304L of water in 7.8hrs of the day, which would give Devikulam the ability to produce more water than they would generally require. For the situation when biogas is used, it was assumed that the biogas will supply the equivalent energy as the solar radiation or more (supported by the highly exothermic combustion of methane that makes up a proportion of the biogas). This gives the Devikulam community the alternative to use biogas when it is necessary. 32 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 13.0 2011 References APEC Water Systems n.d., Different Water Filtration Methods Explained, viewed 20 March 2011, <http://www.freedrinkingwater.com/water-education/quality-water-filtrationmethod.htm#Anchor-Ultraviolet-35326>. APEC, 2011, Water Education, Retrieved 14 March <http://www.freedrinkingwater.com/water-education/quality-water-filtrationmethod.htm> 2011 Brissaud, F 2006, “Low Technology Systems for Waste Water treatments: perspectives”, Water Science and Technology, Mexico. Camco, 2010, Biogas Digesters, viewed 14 <http://igadrhep.energyprojects.net/Links/Profiles/Biogas/Biogas.htm> May 2011 Cartwright, P.S 2006, “Water Purification”, ASHRAE Journal, vol.41, no. 5, pp. 66. Engineers Without Borders 2011, “2011 EWB Challenge”, viewed 7 March 2011, <http://www.ewb.com.au/2011EWBchallenge.htm>. ITDG, 2008, Solar Distillation, viewed 15 <http://www.itdg.org.pe/fichastecnicas/pdf/solar_distillation.pdf> April 2011 Jian, L 2009, “Socioeconomic Barriers to Biogas Development”, Human Organisation, vol.68, iss.4, pp415-430. Kostoff, R, Rushenberg, R, Solka, J, Wyatt, J 2007, “Technological Forecasting and Social Change”, vol. 75, issue. 2, pp. 256-275. Kucera, J 2010, “Reverse Osmosis: Design, Processes and Applications for Engineers”, Wiley, viewed 6 March 2011, <http://www.wiley.com/Reverseosmosis.html>. LCA, 2011, LCA Calculator, Retrieved 20 March 2011 <www.lcacalculator.com> LeChevallier, M. W., & Au, K.-K., 2004, Water Treatment and Pathogen Control: Process Efficiency in Achieving Safe Drinking Water. London: IWA & WHO. Lof, GO 1961, ‘Fundamental Problems in Solar Distillation’, Proceedings of the National Academy of Sciences, vol. 47, no. 8, pp. 1279-90, viewed 20 March 2011, <http://www.ncbi.nlm.nih.gov/pmc/articles/PMC223133/ >. McIlvaine, R 2008, “Reverse Osmosis”, Chemical Engineering Journal, vol. 115, no. 8, pp. 20. MREC, 2006, Anaerobic Digestion and <http://www.mrec.org/anaerobicdigestion.html> 33 Biogas, viewed 29 April 2011 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Qiblaway, H, Banat, F, 2007, “Solar Thermal Desalination Technologies”, Desalination, vol.220, iss.1-3, pp.633-644. Stanford, 2003, India, viewed 25 <http://cee45q.stanford.edu/2003/briefing_book/india.html> April 2011 Suthar, S 2009, “Contaminated drinking water and rural health perspectives in Rajasthem: an overview of recent case studies”, Springer Science and Business Media, India, viewed 15 March 2011. ITACA, 2005, An Introduction to Slow Sand Filtration, Retrieved 12 March 2011 <http://itacanet.org/eng/water/Section%206%20Water%20treatment/ssfintro.pdf> UN, 2010, Statistics, viewed 5 April 2011 <http://www.unwater.org/statistics_san.html> Wotton, R.S 2002, “Water purification using sand”, Hydrobiologia , vol. 469, no. 1-3, pp. 193-201. 34 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 14.0 Appendix 14.1 Decision Making Matrix Table 16 Decision Making Matrix Weighting 0.5 0.2 0.2 0.1 Purification Cost Effective Sustainability Modular Total Solar Still Score Total 5 2.5 1 0.2 3 0.6 2 0.2 3.5 Parabolic Mirror Score Total 5 2.5 2 0.4 4 0.8 4 0.4 4.1 Note: Benchmark is if nothing was implemented to purify the water Rating Scale (score): 1. Much Worse 2. Worse 3. Same 4. Better 5. Much Better 14.2 Sensitivity Analysis Table 17 Sensitivity Analysis Weighting 0.4 0.2 0.3 0.1 Purification Cost Effective Sustainability Modular Total 14.3 Solar Still Score Total 5 2.0 1 0.2 3 0.9 2 0.2 3.3 Parabolic Mirror Score Total 5 2.0 2 0.4 4 1.2 4 0.4 4.0 Pairwise Comparison Table 18 Pairwise Comparison Purification Purification Cost Effective Sustainability Modular 0 0 0 Cost Effective 1 1 0 Sustainability Modular 1 0 0 1 1 0 - Note : the design must remain modular as prescribed by project brief. 35 Score (weight) 3 (0.5) 1 (0.2) 1 (0.2) 0 (0.1) Scores normalised up to 1 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 14.4 Life Cycle Analysis of Filter Figure 11 Sources of Carbon Emissions (LCA, 2011) Figure 12 Major Impacting Sources (LCA, 2011) 36 FINAL REPORT- WATER PURIFICATION - DEVIKULAM Table 19 Carbon Emissions Produced through Manufacture and Disposal (LCA, 2011) 37 2011 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Table 20 Carbon Emissions Produced through Transport (LCA, 2011) 14.5 Life Cycle Analysis of Still Figure 13 Sources of Carbon Emissions (LCA, 2011) Figure 14 Major Impacting Sources (LCA, 2011) 38 FINAL REPORT- WATER PURIFICATION - DEVIKULAM Table 21 Carbon Emissions Produced through Manufacture and Disposal (LCA, 2011) 39 2011 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Table 22 Carbon Emissions Produced through Transport (LCA, 2011) 14.6 The Ceramic Water Filter (Doultonusa, (D 2011) Doulton Water Filter Ceramic Candle & Cartridge Technologies, taking the mysteries out of the drinking water filtration Ceramics, cs, a natural water filter Sterasyl micro micro-filter Doulton mines only the finest and purest kieselguhr or diatom earth often described as a silica-like silica sediment resulting from kiesel algae (one celled algae) deposited on the bottom of geological lakes and nd lagoons millions of years ago. This is the same material used in making the finest bone china (like of Royal Doulton) and numerous other applications. The filter elements are produced using the latest ceramic techniques to provide a hollow porous ceramic ic which is fired at a temperature in excess of 1000°C. The chemically inert ceramic filter can be stored for eternity without losing its effectiveness. Doulton ceramic filter particles from the water but leaves oxygen and mineral contents unchanged, which gives water it's spring-like spring freshness and taste (not "pure" but wholesome). Pathogens of the most varied diseases which are reliably filtered from the water include; cholera, typhus, cryptosporidium, amoebic dysentery, ecoli, colibacillose or bilharzia, anthrax spores among others. Ceramic filtration technology is often called "dead-end "dead end filtration” and "depth filtration". filtration" 40 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 There are several mechanisms by which the ceramic element filters out particles as a deadend filtration. a) Direct interception or sieving (fig. 1): Particle of 0.5 µm and larger "runs into" a pore that is smaller than the particle of topmost layer of the ceramic and are captured as with absolute pore rated synthetic dead-end membranes. b) Bridging (fig. 2): Smaller than 0.5 µm particles may be too small to be intercepted however two particles hitting the obstruction at the same time will form a bridge across the pore adhering to each other. Bridged particles may not plug the pore creating even smaller pore gradually forming a "filter cake". This "cake" creates a finer filtration for subsequent interception at the cost of decreased flow rate and eventually no flow rate. Mechanical regeneration of the filter "cake" is simple. The topmost blocked layer can be removed with stiff brush or nylon scouring pad. This can be repeated many times before the filter has to be changed. c) Inertial impaction (fig. 3): Particles flowing through the filter hits none porous surface barrier it become captured while the water flows around the barrier. Inertial impaction is more prevalent with smaller particles in range of 0.1 to 0.4 µm size as these particles are easily affected by molecular bombardment. Unlike with synthetic membranes, all of the above methods of capture are dependable under variable operating conditions e.g. pressure surging, pulsing etc. with Doulton ceramics. Ceramic depth filtration will filter out considerably smaller particles than equivalent pore size membrane for the following reasons: a) Particles intercepted within the ceramic depth are much smaller than the pores measured by porometry. This is because particle laden water has to navigate through intricate maze of labyrinths. The path through the filter twists and turns trough sharp angles due to complicated 41 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 ceramic structure and so the particles that may have penetrated the topmost layer become trapped within the structure. To appreciate the distance and how difficult a path the water has to follow, consider that the wall thickness of the ceramic is 1000-2000 1 2000 times greater than the pore size of the ceramic filter and the pores are sharp and jagged rather than smooth and round. b) Small particles can combine with other particles to form a cluster of particles large enough to become trapped as a group or individual in dead end cavities. c) Weak Van der Waals forces (adsorption fig. 4) attract the small particles to the ceramic, causing them to be adsorbed onto the wall of the ceramic. Depth filtration is very dependable as pressure surges are not affecting affecting adsorption because the pressure is stabilized (drops by 50%) on the surface of the ceramic. Doulton ceramic depth filtration captures particles as small as 0.05 µm with greater than 90% efficiency. Given favourable conditions, the accumulated bacteria could could proliferate and grow unless prevented by some means. To prevent this Doulton elements (except the Standard, Ceracarb and Ceramet) are manufactured with a small amount (about 0.07%) of pure silver (Ag) through-out through the porous ceramic shell. Silver is a recognized bactericide, so when the bacteria comes into contact with the silver impregnated ceramic, their growth is inhibited. This selfself-sterilizing effect is known as the bacteriostatic effect. effect Silver, a nature's water purifier (I.E. click refresh button to see silver animation) Free silver ions (Ag+) have concentrations. They have a studies describe silver ions depend a toxic effect on micro-organisms micro organisms even in relatively low highly fungicidal, bactericidal and algaecidel effect. Medical a catalyst that disable the enzymes that microorganisms on to "breathe". In the presence of air (oxygen in water), metallic silver forms silver oxide, which also has a bactericidal effect due to its adequate solubility. The destruction of viruses, bacteria, moulds, spores and fungi through contact with silver objects is termed the spores oligodynamic effect. effect. To primitive life forms, oligodynamic silver is as toxic as the most powerful chemical disinfectants. This, coupled with its relative harmlessness to animate life (i.e. mammals), gives oligodynamic silver great potential as a mammals), disinfectant. 42 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 The best and most environmentally-friendly silver based disinfectants are capable of rendering stored water potable for long period of time as in space stations. The silver leach rate from the Doulton ceramic is very low and always well below the national recommended limits or equivalent to having a meal using silver cutlery. Do Doulton ceramic filter removes viruses? Due to their tiny size viruses theoretically cannot be removed with a 0.2 micron or higher rated absolute filter (or any mechanical filter for that matter). If virus is a concern simply add a commercially available disinfectant such as silver (e.g. Katadyn's Micropur®) or iodine tablets. Doulton Supersterasyl candle will remove the unpleasant taste and odours of the iodine. Physically viruses have electrical surface charge that attaches them to other larger particles (free ride). The tight pore-structure of any absolute sub-micron water filter (e.g. Doulton, Katadyn etc.) can remove "free ride" viruses however due to many variables no device should be relied upon viral control. Activated carbon as another natural absorber Doulton uses high quality carbon blends obtained from different raw materials such as lignite, bituminous coal and coconut shells. Active carbon is used for water treatment due to its adsorbing effect with respect to organic and health endangering chemicals. Activated carbon surfaces are both hydrophobic and oleophilic; that is, they “hate” water but “love” oil. When flow conditions are suitable, dissolved chemicals in water flowing through the carbon media “stick” to the carbon surface in a thin film while the water passes on. This process is call adsorption. Substances affecting taste and odours such as chlorine, pesticides (lindane, DDT) and trihalogenmethanes (THM's) are removed by activated carbon. These substances are adsorbed on the large surface area of the active carbon. For visual purpose, one teaspoon of activated carbon have a surface area the size of a football field. Active carbon is available in granulate (GAC filters), powder (PAC filters) or extruded solid carbon block form 43 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 (CB filters). 14.7 Doulton Ceramic Candles and Cartridge Grades Sterasyl membrane: (candle and cartridge form): Used for microbiological removal. The only ceramic element in the world to meet the stringent NSF antimony and arsenic extraction test featuring: • • • • • • >99.99% E.coli removal Tested with live Cryptosporidium cyst to 100% removal far exceeding EPA three log cyst reduction requirements 100% efficiency at 0.9 µm absolute (0.5 µm absolute ANSI standard) > 98% efficiency at 0.2 µm > 90% efficiency at 0.05 µm < 0.07 NTU turbidity reduction Typical application: UV, RO and ozone pre-filter, point-of-use (POU) final polish filter, zero cyst tolerance in bottling water plants using our industrial multi cartridge filters and various other application requiring absolute filtration. Least expensive absolute filter on the market as it is cleanable and reusable for up 60 times. Backwash capable, selfsterilized, no bacteria grow through as encountered in most all synthetic membranes. Available in candle and open both ends (DOE) cartridge style. Supersterasyl candle: Used in British Berkefeld gravity filters is a Sterasyl shell packed with granular activated carbon. Available in 2"x7", 2.75"x7" and 2"x10" candle style with long threaded end cap. Custom size and end caps configuration available with minimum kiln firing requirements of 2400 units for all grades of elements. Carbosyl elements: Sterasyl shell lined with fine activated carbon coating impregnated throughout the ceramic pore structure then re-fired in excess of 1000°C. Soon to introduce our inline filter fitted with Carbosyl candle as a replacement for the RO GAC final polish filter to control heterotrophic plate count (HPC)* bacteria commonly found in virtually all inexpensive RO systems. Available in 2" slimline and 2.75"x9.75" Imperial cartridge in case quantity by special order. 25 pcs. slimline and 9 pcs. per case Imperial size. • • Reduces HPC to meet TUV and Alpha Institute requirements. Test results of Carbosyl vs. RO GAC post filter>> Meets stringent European Union (EEC) stagnation requirements Supercarb ceramic elements: Used in all residential pressure filters is a Sterasyl shell with solid carbon block insert. Economical three stage filtration available in candle and cartridge style. Ultracarb ceramic elements: Used in all pressure filters is a Supercarb with ATS ion exchange medium incorporated into the carbon block for heavy metal reduction. Economical four stage filtration available in candle and cartridge style. 44 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Conclusion: Doulton ceramic filters are designed to convert raw water into high quality drinking water that will comply with the most stringent potable water standards all 100% naturally. * Heterotrophic (HPC) is a harmless bacteria commonly found in all waters. In absence of disinfectants this bacteria colonize the reverse osmosis holding tank. As the bacteria die it creates foul odor therefore all RO's have GAC final filter to remove the odor out of the water. It should be clearly understood that no GAC filter remove any bacteria. Calculations for Final Design • Assumptions: An overall system efficiency of 80%, filters are not clogged and are flowing at their maximum rate: • Calculations based on the following information: These rapid sand filters use coarser sand than slow sand filters and the effective size of the filter media is usually greater than 0.55 mm. The flow rates are normally between 4 and 21 m/h equating to 400 to 2100 l/h per m2 of filter. These filters do not remove disease causing entities as efficiently as slow sand filters and usually need a post filtration chlorination process. Flocculation and coagulation are sometimes used as pre-treatments. • Calculations: Each unit needs to produce 200L of water per day, so assuming 20% loss of water through the solar still. The filter system must output an amount of water equal to: Feedwater = 200 x 1.2 (80% efficient) Feedwater = 240L The solar still needs a minimum of 240L of feedwater. Therefore the water filter system must output 240L, the minimum feedwater into the water filter system is calculated by: Feedwater = 240 x 1.2 (80% efficient) Feedwater = 290L 290L = 0.29m3 of feedwater. Assuming only 7 hrs of operation for the water filter unit. (The unit is able to operate 24hrs if required) 0.29m3 = 0.0414m3/hr 7hrs So minimum required output = 0.0414m3/hr (Rapid filter minimum requirement = 5m3/hr/m2) Therefore 45 0.0414 x 5 = 0.207 m3/h/m2 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 =ට .ଶ గ = Pipe Diameter = 0.25m Standard size 250mm pipe diameter. A pipe diameter of 250mm is required to meet the minimum water requirement of 200L per day. The rate of flow through the sand filter is related to the surface area of sand, not the volume of sand, it is recommended that the sand be filled to 150mm height in the filter system. Manufacturer specifications place the ceramic candle filter at a flow rate of 2L/min this is equal to 120 L/hr. m3/hr = ଵଶ / ଵ 1 m3 = 1000L = 0.12m3/hr The ceramic filter flows faster according to manufacturer specifications then the rapid type sand filter therefore the restrictions placed on the system will come from the sand filter system. Weight of the filter unit: Using a pipe diameter of 250mm (.25m) and a sand depth in the unit of 150mm (0.15m) Assuming that sand has an average weight of 1800 kg/m3 So volume of sand in the unit (m3): = 0.00736 m3 So weight of sand in the unit (kg): = ሺߨ ݎଶ ሻ x H = ሺߨ0.125ଶ ሻ x 0.15 = 0.00736 × 1800 = 13.2 kg The overall weight of the system will be approx 18kg (±0.1 kg). Breakdown as follows: Pipe and lids – 3 kg Ceramic Filter – 1kg Sand Filter Unit – 13.2kg Miscellaneous – .7kg 14.8 Solar Still System How a simple solar still operates The incident solar radiation is transmitted and is absorbed as heat by a surface in contact with the water to be distilled. The water is heated and gives off water vapour. The vapour 46 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 condenses on a surface which is at a lower temperature because it is in contact with the ambient air, and runs down into a gutter from where it is fed to a storage tank. Design objectives for an efficient solar still For high efficiency the solar still should maintain: • a high feed water temperature • a large temperature difference between feed water and condensing surface • low vapour leakage. A high feed water temperature can be achieved if: • a high proportion of incoming radiation is absorbed by the feed water as heat. Hence low absorption glazing and a good radiation absorbing surface are required • heat losses from the floor and walls are kept low • the water is shallow so there is not so much to heat. A large temperature difference can be achieved if: • the condensing surface absorbs little or none of the incoming radiation • condensing water dissipates heat which must be removed rapidly from the condensing surface by, for example, a second flow of water or air, or by condensing at night. (ITDG, 2008) Calculations for Final Design • Copper Piping r1 = 0.0130175m r2 = 0.0142575m 2 Volume of pipe = πr h = π (0.0130175)2.4 = 0.0021294382m3 = 2.1294382 L = 2129.4382cm3 Density of copper = 8.94g/cm3 Mass of pipe = volume of copper . density = (πr2 2h – πr1 2h) . 8.94 = ((π(0.0142575)2 . 4) – (π (0.0130175)2.4)) . 8.94 = 425.0072205 cm3 . 8.94 cm3/g = 3799.564552 g • Mirror r = 0.5m length = 4m Mirror = ½ cylinder Surface area of mirror = ½ surface area of cylinder = (2πr2 + 2πrh)/2 = 7.068583471m2 47 length = 4m FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 Solar energy for India = 5760 – 7920 MJ/m2/year Average =6840MJ/m2/year Solar energy per day =18.7269MJ/m2/day Efficiency of mirror = 0.95 Mirror reflection in one day = solar energy . surface area . efficiency = 18.7269 . 7.06858 . 0.95 = 125.754MJ/day reflected on to pipe Copper absorbs 0.64 of radiation on surface Radiation absorbs through copper = reflection . efficiency = 125.754 . 0.64 = 80.48253MJ/day is absorbed Using specific heat to find ΔT of the copper pipe due to absorbed radiation: Q = 80 482 530 J C = 0.385 M = 3799.564552 g Specific heat = Q = cmΔT = ΔT = Q/cm = 80 482 530J / 0.385 . 3799.564552 = 55018.31094 Using conduction to find the heat transfer to the water: k = 385 A = 6.41x10-4 ΔT =55018.31094 d=4 Conduction = Q/t = kAΔT/d = 385 . 6.41x10-4 . 55018.31094 / 4 = 3394.423 J/s is transferred to the water in the pipe • Water Need 200L of water through the system per day = 200L/day An average day (sunlight) in India = 7.8 hours Rate of water flow out of system = 200L/7.8hours = 25.64L/hr = 25.64L/3600s = 1L/140.4s = 1L/2.34mins Volume of water held within pipe = 2.129L Time water spends in pipe = volume of pipe . flow rate out of pipe = 2.129 . 140.4 = 298.9116s Using specific heat to find how much energy is needed to evaporate 1L of water: c = 4.186 ΔT (assume min 25°C, max 100°C) = 75 m = 1L . 1L/kg = 1kg = 1000g Q = cmΔT = 4.186 . 75 . 1000 = 313 950 J The 1L of water spend 298.9116s in the pipe There is 3394.423 J/s transferred to the water Amount of energy transferred to 1L during time in pipe = Q/t . day(7.8hours = 28080s) = 3394.423 . 298.9116 = 1 014 840.967 J/L Using specific heat to find how much energy is needed to evaporate 200L of water: c = 4.186 48 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 ΔT (assume min 25°C, max 100°C) = 75 m = 200L . 1L/kg = 200kg = 200 000g Q = cmΔT = 4.186 . 75 . 200, 000 = 62 790 000 J There is 3394.423 J/s transferred to the water Amount of energy transferred to 1L during time in pipe = Q/t . day(7.8hours = 28080s) = 3394.423 . 28080 = 95 315 397.84J The energy transferred to the water in the time it is in the pipe exceeds the energy needed, therefore it is feasible. This also allows for error and inefficiencies. It gives excess energy of +32 525 397.84J If there were no inefficiencies then all the energy may be used to create a higher output of water. Amount of energy transferred in a day (7.8 hours = 28 080s) = Q/t . time in day = 3394.423 . 28 080 = 95 315 397.84 J 1L of water needs 313 950J to evaporate it. Using this to find how many litres could be produced = energy produced in one day / energy needed for one litre = 95 315 397.84/313 950 = 303.6L Max flow rate = L/t = 303.6/28 080 = 1L/92.49s = 1L/1.54mins Therefore it may be possible for the village to produce more than the allocated 200L of water per day. • Biogas/Biodigester Table 23 Biodigester Relationship (Camco, 2010) Size of Family 6 8 Cows 6 9 Digester (m3) 8.4 10.8 Gas Storage (m3) 1.44 1.92 The biogas produced is approximately 50% methane, with the other 50% mostly comprising of carbon dioxide. Using the above table there is a relationship formed between the digester and the gas storage: Gas storage = g Digester =d Constant =k g/d =k 1.44/8.4 = 0.171 1.92/10.8 = 0.177 Therefore k is approximately equal to 0.17 d .k = g Using the above table there is a relationship formed between the digester and the number of cows needed to produce the waste: Digester =d Cows =c Constant =x d/c =x 49 FINAL REPORT- WATER PURIFICATION - DEVIKULAM 2011 8.4/6 =1.4 10.8/9 = 1.2 Therefore k is approximately equal to 1.3 d = c.x The combustion enthalpy of methane is as below: CH4 + O2 → CO2 + H2O ΔH = -891kJ/mol It is known that 62 790kJ is needed to evaporate 200L of water from earlier calculations Moles of methane needed to be combusted to evaporate water = 62790kJ / 891kJ/mol = 69.8 moles of methane Molar mass of methane = 12 + 4 . 1 = 16 g/mol Mass of methane needed to evaporate 200L of water = n . MM = 69.8 . 16 = 1116.77g 3 Density of methane = 0.668kg/m = 668 g/m3 Volume of methane needed = mass / density = 1116.77/668 = 1.67m3 Note that only 50% of biogas is methane. Assume other 50% is carbon dioxide If there is 69.8 moles of methane in the gas storage tank, then there must also be 69.8 moles of carbon dioxide due to the 50:50 ratio. Molar mass of carbon dioxide =12 + 16 . 2 = 44g/mol Mass of carbon dioxide resulting = n . MM = 69.8 . 44 = 3071.2g Density of carbon dioxide = 1.8 kg/m3 = 1800g/m3 Volume of carbon dioxide = mass/density = 3071.2 / 1800 = 1.7m3 Total volume of gases = 1.67 + 1.7 = 3.4 m3 The size of the digester =g/k = 3.4 / 0.17 = 20 m3 Number of cows needed to produce sufficient bio waste = d / x = 20 / 1.3 = 15.38 = 15 cows 50
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