Chemical Solutions Whiteboard Review Warm Up 4/3/17 Write the molecular/ionic/net-ionic equations for reaction between: KCl(aq) and Pb(NO3)2 (aq) 2 KCl + Pb(NO3)2 PbCl2 + 2 KNO3 2K1+ + 2Cl1- + Pb2+ + 2NO31- PbCl2(s) + 2K1+ + 2NO31- Pb 2+ (aq) + 12Cl (aq) PbCl2 (s) Write the formula for determining concentration of a solution (molarity). Molarity (M) = moles solute liter (of solution) Write the formula for determining molarity (concentration) of a diluted solution: M1V1 = M2V2 -Identify the solute/solvent: Cup of coffee Solute: coffee beans(compounds such as caffeine) Solvent: water Paint thinner and oil-based paint Solute: paint Solvent: paint thinner Ethane(C2H6) dissolved in hexane(C6H14) Solute: ethane Solvent: hexane Can of Sprite Solute: CO2 OR sugar OR flavoring Solvent: water Polar (P) or Non Polar (NP)? Permanent ink Dish soap NP BOTH hydrogen chloride P fructose P olive oil NP Octane (C8H18) NP watercolor paint P ethanol P Name 2 types of glassware useful to make precise volume measurements when preparing a solution. Volumetric flask or grad. cylinder 85 g of LiCl is the maximum mass completely dissolved in 100 g of o water at 20 C. 1) How would you classify this solution? saturated 2) If additional solute is added at the same temperature, what would you observe? Extra solute accumulates at bottom of beaker How could you transform the previous solution into a supersaturated solution? Heat up the mixture until dissolved, then allow to cool 123g of NaNO3 is the maximum mass to completely dissolve in 100 g o of water at 60 C. If 80g of NaNO3 are dissolved in water at the same temperature, how would you classify the solution? unsaturated Describe the relationship between temperature and solubility of gases. As temp. increases the solubility of gases descreases. [Use solubility graphs]: What maximum mass of nitrogen gas is completely soluble in 100g of o water at 30 C? approx. 1.7mg 2mg of NO in 100g H2O at any temperature: sat'd or unsat'd? unsaturated 70g of KNO3 dissolved in 100g of o water at 70 C...what mass can be added to make a saturated solution? Approx. 55g additional KNO3 Identify the type of solution: saturated Determine molarity of an ethanol solution made by dissolving 2.30 g of C2H5OH in 150.mL of solution. 0.333M How many grams of silver nitrate are needed to prepare 250.mL of a 0.100M solution? 4.25g *How would you prepare this solution? Calculate the volume of a solution that has 0.500mol of KBr and a concentration of 0.625M. 0.800L Calculate the dilute concentration when 42mL of 18.0M H2SO4 are diluted with water to a final volume of 250.mL. 3.0M Calculate the new molarity when 150.mL of water is added to 125mL of 0.200M HBr. 0.091M Solubility Rules they're really great! They help predict precipitates...! (s) or (aq)?? Li2CO3 AgCl Na2SO4 (aq) (s) (aq)
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