TABLE II. O R G A N I C DERIVATIVES OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.* )**
No
Name
•c
Melting
point
n
•c
o
-169 15T
-185 25T
Bromine addition product
D;°
x-Bromo-
BP.'C
0 384"
05139
dldl-
131 36
141 99
-10371
-47 70
-36'"
-345
-690
-136
-14035
1 3467
0 5942s
telradi-
6 1-Butene
-626
-18535
1 3465
05951
d,-
7 1,3-Butadiene
-441
-10892
1 4292 '
0650 '
06255 '
1
2
3
4
5
Erhene(Ethylene)
Propene (Propylene)
Cyclopropene
Allene
2-Methylpropene
Boiling
point
8
9
10
11
s
-105 55
lrani-2-Buteae.
Cyclobutene
as 2-Butene
1,2-Butadiene
(Methylallene)
12 3-Methyl-l-butene
13 1,4-Pentadiene
088
24
372
1085
-13891
-136 19
2006
2597
14 1-Pentene
MP/C
"B
D;°
983
-555
1 53868
1 52004
2 1792
1 93268
107
149
1 6200
1 5080
2703
1 7595
1663
1 5150
1 7951
1 5110
1 7852
1 5110
1 6070
1 7852
25085
1 50932
I 6776
telradi-
161 0
1 4208'
diletra-
161 0
975
-16849
-14828
1 3643
1 38876
06272
0 66706
dilelra
61 2"
2997
-16522
1 37148
0 64050
di-
68"
1 5012"
1 592'»
15 2-Methyl-l-butene
31 16
-13756
1 3778
06504
di-
474 48"
1 5088
1 6711
16 3-Methylcyclobutene
17 2-Methvl-l,3butadiene (Isoprene)
32
3407
-14595
1 4005
1 42194
0 68095
ditetra-
18 /rans-2-Pentene
19 m-2-Pentene
20 1-Methyl-l-oclobutene
21 2-Methvl-2-butene
3635
3694
37 1
-14024
-151 39
1 3793
1 3830
1 4088
06482
06556
07244
didi-
90-6"
155
60' 2
91 0™
92 4™
38 57
-13377
1 3874
06623
1 410
0680
tetra-
1 4398 ' » 5 07983"
-889
1 4309
06803
tetra-
25 3,3-Dimethyl-l-butene 41 24
-1152
1 3760
06529
di-
26 1, lrart?-3-Pentadiene
27 l,«s-3-Pentadiene
-8747
1 43008
- 140 82 1 43634
0 67603
069102
etraeira-
41 1
4203
4407
-2
855 60,
eth
Mercaptosuccmic
acid adduct.
1073 6
Mercaptosuccmic
acid adduct.
1223-6
Maleicanh adduct.
63-4, Igr
1 5096
1 5096
1 6809
1 6817
Nitrosochlonde, 74,
Mercaptosuccmic
acid adduct.
1537-40
-85
24 1,3-Penladiene
(Piperylene)
2,4 Dmitrophenylsulfenyl chloride.
86 7
2.4-Dimtrophenylsulfenyl chloride.
775 85
118 Igr
0 6042
0733°
06306'
0652 s
22 3-Methvl-l,2-bula40
diene(l 1 Dimethylallene)
23 Cyclopentadiene
4083 '
Miscellaneous
* Derivative data given in order m p , crystal color, solvent from which crystallized
**T = triple point, S = at saturation pressure
12
150 2 1
1 594"
2 305"
Dimer 32, Maleic
anh adduct, 164
5 Benzoqumone
adduct, 75 6
Maleic anh adduct.
61, pet eth , Oxid
byKMnO,-*
HCOOH +
CH,COOH
1145,al
953
56'"
13IJ
13I J
1 5109
115,al
115, al
1 5615
TABLE II. ORGANIC DERIVATIVES OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
Boiling
No
Name
point
•c
Melting
point
Bromine addition product
"8
•c
DP
x Bromo
B P 'C
M P 'C
n
b°
D;°
28 Cyclopentene
4424
-13508
1 42246
077199
dl-
71 5"
29 1,2-Pentadiene
(Ethylallene)
30 2,3-Pentadiene ( l 3Dimethylallene)
31 4-Methyl-l-pentene
4486
-13726
1 42091
0 69257
letra-
94 6" '
4827
-12526
1 42842
0 69502
5388
-15363
1 3828
06642
di
87"
1 4980
1 5689
54 14
-1530
1 3842
1 405
06675
0695
di
99"'
1 5060
1 6016
5567
56
-15727
1 3904
1 405
06779
0694
di-
80'
1 5105
1 6033
563
-13443
1 3880
06690
di
72 3'"
1 5060
1 5983
58 55
-14081
1 3889
06686
di-
78"
1 5070
1 5996
5946
-1408
1 4042
06923
lelra-
607
6349
-13572
-13982
1 3920
1 38788
06817
067317
di
di-
87 8'°
89 90'"
2-Ethyl-l-butene
/ranj-13-Hexadiene
3-Methylcyclopentene
m-3-Hexene
3-Hexene (cis-lrans
mixture)
46 rrani-3-Hexene
47 2-Methyl-2-pentene
64 6
645 55
-131 53
1
1
1
1
1
06894
06925"
07622
06796
06816
dilelra-
87 2 '
di
di-
6708
6729
-11343
-1357
1 3943
1 4004
06772
06863
48 3-Methyl-/ra/)i-2pentene
49 rro«5-2-Hexene
50 2-Hcxene (cis-trans
mixture)
51 2,3-Hexadiene
52 2,3-Dimelhyl-Mbutadiene
53 c«-2-Hexene
54 4-Methyl-l,2-pentadiene(l-Isopropylallene)
55 3-Methyl-cw-2pentene
6763
-13484
1 4016
6787
-13297
32 3-Methyl-l-pentene
33 3-Methyl-l,4-pen(adiene
34 2,3-Dimethyl-l-butene
35 2-Methyl-l,4-pen(adicne
36 4-Methyl-m-2pentene
37 4-Methyl-/ra«i-2pentene
38 1,5-Hexadiene
(Biallyl)
39 2-Methyl-l-pentene
40 1-Hexene
41
42
43
44
45
55
650
6644
-13782
66 6-67
679 8 1
68
6878
-7601
1 5MO"
1 8713"
52
1 SII2
1 6045
80 1 I J
80 \"
1 5045
1 5045
1 6027
1 6027
didi-
80 I 1 3
71-2"
1 5045
1 5063
1 6027
1 5849
06942
di-
72 4"
1 5085
1 3935
1 3928
06784
06813
didi-
90'"
9016
1 5025
1 5025
1 395
I 4394
0680
07267
-141 14
1 3977
1 424
06869
0708
7045
-13845
1 4045
06986
MercaptosucciTiic
acid adduct,
152 1 6
1 5812
1 5812
Maleic anh adduct.
78-9
90'
6
1 5025
di-
72-415
1 5085
13
2,4-Dimtrophenylsulfenyl chloride
61 2 Mercaptosuccmic acid adduct, 94 5 5 7
19
ditetradi-
'Derivative data given in order m p , crystal color, solvent from which crystallized
Mercaptosuccmic
acid adduct
1026 9
Oil HNO 3 -»succmicac 185
1 5581
1 5774
6884
70
Mercaptosuccmic
acidadduct
142 8 3 1 Pseudomtrosite 69 70
Perbenzoic acid
oxid —epoxycyclopentane
b p 102 3
2 3469 \:
1 5015
1 5024
3969
4060"
4207
3947
3942
Miscellaneous
47, Igr
138, bz
1 5812
TABLE I I . O R G A N I C D E R I V A T I V E S O F A L K E N E S , C Y C L O A L K E N E S ,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point,
•c
Melting
point,
•c
Bromine addition product
"B
Miscellaneous
Di»
i-Bromo- B P . ' C
56 2-Methyl-2,3-pentadiene (Tnmethyl
allene)
57 1,4-Hexadiene
72
1 425
0711
723 25
1 4402"
07057'"
tetra2 forms
58 4,4-Dimethyl-lpentene
7249
1 3918
06827
di
59 1, (m and/or [rans)-3~
hexadiene
60 2,3-Dimethvl-2-burene
61 2-Ethyl-l,3-butadiene
62 4-Methylcyclopentene
63 1-Melhylcyclopentene
64 2-Methyl-l.k« and/or
ira/M)-3-pentadiene
65 1,2-Hexadiene
(«-Propylallene)
66 2-Methyl-l,(c« and/or
(rani )-3-pentadiene
67 4-,V1ethyl-l,3-pentadiene
68 4,4-l)imcthyl-/rani-2pentene
69 3.3-Dimethyl-lpentene
70 233-Tnmethyl-lbutene
71 3-Methyl-M-pentadiene
72 trans-l ,3,5-Hexatriene
73
1 438
0705
1 4122
1 445
1 4306
1 4330
1 446
07080
0717
07796
07802
76
1 4282
07149
76
1 446
0719
763
1 451
0719
73 as- 1 3,5-H exatnene
74 3-Methyl-l.2-pentadiene
75 2,4-Hexadiene
76 3-Methyl-l,5-hexadiene
77 4,4-Dimethyl-l,2pentadiene (lenButylallene)
78 1 3-C'yclohexadiene
7321
75
752
758
76
-1366
-7428
-127
77-8'
telra-
1303
di-
7754
-1343
1 3984
06974
di-
92893"
95 3 6'°
7787
-10985
1 4029
07050
di-
98-9"
780 3
1 4494
07499
785,
77 85
785
79 70
1 4884 "" 0 74229 ii
1 4577
1425
07179
0715
1 4493
07152
1 5850
2 1873
1 5538
1 5109
1 5615
1 534 '"
1 622 '"
38-9
78
hexa-
2,5-rfitetra-
1 5080
85"
182
-1048
1 4740
08413
68, iso-
di-
Maleicanh adduct.
145-6, heptane,
Benzoqumone
adduct, 196 7, Igr
— m 108
tetra-
1 , irans2,as-3,
trans-4.
92,l,as2, irans3, trans4, 156
2
forms
8042
Maleicanh adduct,
95 6, Igr , S02
adduct, 43-3 5
07103
menzes
79 4,4-Dimethyl-Oi-2pentene
Mercaptosuccmic
acidadduct, 1190
5
07184
80-3
80 3 1'57
1 5129
.
06889
1 4116
1 4970
0719
1 3982
80-1
DJ°
173 4 121
di
-11524
-79
"B
a) 63 4 b)
fp <-50
7675
794
81 6765
MP/C
-13546
1 4024
06996
di-
'Derivative data given in order m p , crystal color, solvent from which crystallized
14
928
30"
1 5080
1 5538
TABLE II. ORGANIC D E R I V A T I V E S OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p. )* (Continued)
No
Boiling
point
°C
Name
80 3,4-Dimethyl-lpentene
81 Cyclohexene
82 2,4-Dimethyl-2pentene
83 3-Methyl-l-hexene
84 23-Dimethyl-lpentene
85 3-Ethyl-l-pentene
86 5-Methyl-l-hexene
87 5-Methvl-(rans-2hexene
88 2-Methyl-3-hexene
89 2,4-Dimethyl-2,3pentadiene (Tetramethylallene)
90 4-Methyl-l-hexene
Melting
point
•c
81
Bromine addition product
"S
DJ°
x-Bromo-
1 3995
0701
BP "C
M P 'C
"*D
D;°
8297
-10351
1 44654
081096
dl-
101 3' 3
1 5445"
83-4
-1277
1 4016522
0 695822
dl-
88"
1 5092022 s 1 5431 2!S
840
8426
1 397
1 4033
0695
07051
dl-
-1348
84 0- 2 6
725-
1 5028
1 5028
1 5248
1 5245
-1274
1 3980
di-
1 3966
06962
06920
di-
1 5006
1 4970
1 5251
1 5072
860
1 400
0700
di-
30"
935 1 S
1426
36""
87 8 1 U
1 4960
1 5027
860
865
1 399
1 40039
0694
07006
di-
96"
1 5060
1 5310
1 4000
06985
di-
947-
1 4980
1 5027
85 13
85 31
8673
-141 45
di-
1 7759"
Miscellaneous
Mercaptosuccmic
acid adduct, 1 50 5
1 5,KMnO,
oxid — • adipicac ,
154, 2,4-Dimtrophenylsulfenyl
chloride, 117 8
HBr — cyclohexyl bromide,
bp 165
57"
91 3,4-Dime(hyl-2pentene
92 4-Methyl-c/5-2hexene
93 4-Methyl-(ranj-2hexene
94 3,3-Dimethylcyclopentene
95 2-Ethyl-3-methyl-lbutene
96 5-Methyl-ns-2-hexene
97 5-Methyl-l,4-hexadiene
98 2-Methyl-l-hexene
870
1 407
0713
di-
655 60
1 5104
1 5400
8737
1 4024
06996
di-
91 2"
1 5045
1 5382
1 4023
06975
di-
91 2"
1 5045
1 5382
88
1 423
0771
89
1 410
0715
di-
725
35J
1 5062
1 5261
91
91-25
1 400
1 4390
0700
07258
di\,2-di-
89 90"
101 4"
1 4990
1 5233"
1 5152
1 566"
- 102 84 1 4034
07030
di-
1005
1 5000
1 5066
876
920
-1265
1 5 23
99 1,3-Dimethylcyclopentene
100 2-Methyl-l,5-hexadiene
101 2,4-Dimethyl-l,3pentadiene
102 1,4-Dimethylcyclopentene
103 3-Methyl-(ranj-3hexene
104 1-Heptene
0766
92
1 428
92 5™ 9
1423/6' 7 3 07289" 5
1 4412
07368
932
1 4283
0779
93 5
1 4107
07099
1 39980
0 69698
93
9364
-114
-11903
Nitrosochlonde,
75 6
di-
'Derivative data given in order m p , crystal color, solvent from which crystallized
15
106 2' 3
1 4990
1 5208
Mercaptosuccmic
acid adduct
103 4- 9
TABLE n. O R G A N I C DERIVATIVES OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Boiling
point
Name
•c
Melting
point
•c
nf?
D;°
Bromine addition product
Miscellaneous
x Bromo
BP.'C
940
1 410
07120
di-
94
9535
1 405
1 4123
0708
07132
di-
1 4106
1 4043
07082
06981
didi-
95 75
1 4059
07030
di-
96
1 4282"
07225'"
105 3-MethyI-//-an?-2hexene
106 2-Ethyl-t-pentene
107 3-Methyl-c«-3hexenc
108 2-Methyl-2-hexene
109 trans-3-Heptene
9541
9567
110 ra-3-Heptene
1 1 1 5-Me«hyl-l,2-hexadiene(Isobutylallene)
112 3-Ethyl-2-pentene
113 2,3-Dimethyl-2pentene
114 tranS'2-Heptene
115 3-Ethylcyclopentene
116 cu-2-Heptene
117 5-Methyl-l ,3-cyclohexadiene
118 2,2-Dimethyl-rran.r3-hexene
119 1,4-Heptadiene
120 2,4,4-Tnmethyl1-pentene
121 3,3-Dimethyl-l,5hexadiene
122 3,4-Dimethyl-1,5hexadiene
123 2,5-Dimethyl-3-hexene
124 5,5-Dimelhyl-lhexene
125 4-Methylcyclohexene
126 3-Methylcyclohexene
127 2-Isopropyl-3methyl-1-butene
128 3,4,4-Tnmethyl-lpentene
129 3,5-Dimethyl-l-hexene
130 3,3-Dimethyl-l-hexene
31 5,5-Dimetliy\-trans-2hexene
32 2,4,4-Trimethyl-2pentene
33 3,3,4-Tnmethyl-lpentene
34 2,2-Dime«hyl-c«-3hexene
35 1,2-Heptadiene (nButylallene)
-13035
-13663
D°»
650
5 1'
77 8 4
1 5040
1 5240
1 4990
1 4929
730 l»
1055
652'
105 565 2 3
1 4990
1 5010
1 5116
1 5153
1 5010
1 5153
1 4148
07204
di-
76 0- 4s
1 5090
-1183
1 4208
07277
di-
97 9"
1 51722
1 S426
1 54722
-10948
1 4045
1 4319
1 406
1 4662 ""
07012
07830
0708
08252
di-
96 2 "
1 5000
1 5129
di-
96 2 "
1 5000
1 5129
\ 4063
07039
di-
96570 8
1 5032
1 4856
1 4202
1 4086
07106
07150
di-
1 5734
2091
101 6
1 4160
07249
101 8
1 4211
07304
102
1025
1 406
1 4049
0710
0709
di-
109"
1 5058
1 5034
1 4414
1 4444
1 4085
07947
08010
0722
di-
13040
104
1 412
0719
104
104
104 1
I 404
1 4070
1 4055
0708
07140
07066
1 4160
07218
1 4144
0729
1 4099
07128
1 432"
0 7306"1
2,1-dt-
108IO' 2 ,
1403
1 520018
1 5595"
1 5718
20675
1 4448
07976
1 440
1 413
1 4410
1 4113
0798
0722
07982
07169
92 34
1 5113
1 5148
9601
975
9795
98 1
985
1005
1 5 762
1009
101
101 44
10274
1040
104
10491
-9348
-1155
-10633
105
1054
-1374
105 5 60
letra-
36 1,2-Dimethylcyclopentene
37 4-Ethylcyclopentene
38 4,4-Dimethyl-2-hexene
39 1-Ethylcyclopentene
40 5,5-Dimethyl-cw-2hexene
"B
M P.'C
1058
106
106
1063
1069
-904
-1184
di-
)envative data given in order m p , crystal color, solvent from which crystallized
16
1 6501?
TABLE II. O R G A N I C D E R I V A T I V E S OF ALKENES,CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p. )* (Continued)
No
Name
141 2-Methyl-2,4hexadiene
142 2-Methyl-13-cyclohexadiene
143 3-Melhvl-2,4hexadiene
144 4,4-Dimethyl-l-hexene
145 3-Ethyl-4-methyl-lpentene
146 2,4-Heptadiene
147 2,4-Dimelhyl-/ranv-3hexene
148 Quadricyclene (Quadncyclo[2,2,l,0">.
O 3 '] heptane)
149 23,4-Trimethyl-lpentene
150 4-Methyl-13hexadiene
151 23,3-Trimethyl-lpentene
152 4,5-Dimcthyl-lhexene
153 1,5,5-Trimethylcyclopentene (Isolaurolene)
154 2,4-Dimethyl-cw-3hexene
155 3,3-Dimethyl-2-ethyl-
Boiling
point
•c
Bromine addition product
b°
•c
x-Bromo-
1 426621
07439
107 8
1 4662 '»
08272!!
IS
107 8
1 46I46
1072
1075
1 4102
1 4097
07198
07200
107 5 8 0
1076
1 4578
1 4126
07384
07145
108"° si d
1 4804
108
1 415
0729
108 10
1 4523
07558
1 4174
07352
109
1 414
0728
109'"
1 4324
07824
109
1 4140
07178
1 4159
0728
1 415
0730
1 413
1 4503
0725
08102
103
1 4105
07195
103
105
106
II
0715
07214
07213
12
1 407
1 4113
1 4118
1 406
1 4110
1 4105
1 418
12
12
1 413
1 4232
0724
07395
12
12
12
122
125
1 416
1 402
1 410
4140
423022 5
0725
0706
1083
11 2
11 6
125
-69
-121
4142
Miscellaneous
D;»
n
107
110
1-butene
156 3-Ethyl-2-methyl-l110
pentene
157 4,5-I)ime(hyl-2-hexene 10
158 1-Methylcyclohexene
100
159 2-EthyM-methyl-lpentene
160 3-Ethyl-l-hexene
161 2,3-Dirnethyl-l-hexene
162 2,4-Dimethyl-2-hexene
163 3-Methyl-l-heptene
164 2,4-Dimethyl-l-hexene
165 2,5-Dimethyl-l-hexene
166 3-EthyI-3-methyl-lpentene
167 3,4-Dimethyl-l-hexene
168 3,4,4-Trimethyl-2pentene
169 3,S-Dimethyl-2-hexene
170 2-Methyl-3-heptene
171 5-Methyl-3-heptene
172 2,5-Dimethyl-2-hexene
173 3-Methyl-l,5heptadiene
174 2-Ethyl-3-methyl-lpentene
Melting
point
BP 'C
M P 'C
"5
D;°
1 5003
1 4689
07625"
di-
224 5
Reduces Tollen's
reagent on warming
d,-
100 2"
di-
8813
2,4-Dimtrophenylsulfenyl chloride.
139 40
0711
0720
07172
07305
0713
0720
0729
* Derivative data given in order m p , crystal color, solvent from which crystallized
17
1 4740
3980
TABLE II. O R G A N I C DERIVATIVES OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point
•c
4-Methyl-l-heplene
6- \lelhyl-3-heptene
4-Ethyl-l-hexene
4-Ethyl-2-hexene
2-Isopropyi-l-pentene
5-Methyl-l-heptene
4-Methyl-2-heptene
2,3-Dimethyl-3-hexene
4-Methyl-2-octene
2.4-Dimethyl-2,4hexadiene
185 6-Methyl-2,4heptadiene
186 3-Ethyl-4-methyltrans-2-pentene
187 Cycloheptene
(Suberene)
1128
113"'
113
113
113
1133
1135 4 1
114
114
114-5
11438
188 1 -Methyl- 1,4-cyclohexadiene
189 3-Ethyl-4-methyl-cw2-pentene
1145-48
175
176
177
178
179
180
181
182
183
184
Bromine addition product
Melting
point
"D
•c
410
4114
412
412
414
4094
4096
416
410025
4545716 -,
Df
x-Bromo- B P . ' C
0717
07256
0726
0725
0725
07164
07154
0728
07188"
07635' 6 5
1 4397"
0704 1 25
1143
1 4210
07350
-56
1 4580
08254
di-
<-70
T4703
0848
tetra-
1 424
0739
115
191 1,3,5-Cycloheptatriene
(Tropihdene)
192 3,4-Dimethyl-2-hexene
193 3-Ethyl-3-hexene
194 6-Methyl-l,3heptadiene
195 2,5-Dimethyl-I,3hexadiene
196 2,3,4-Trimethyl-2pentene
197 4,4-Dimethvlcyclohexene
198 6-Melhyl-2-heptene
199 2-n-Propyl-l-pentene
200 5-Methyl-2-heptene
201 3,3-Dimethylcyclohexene
202 2-Methyl-l-heplene
203 2,5-Dimethyl-l,5hexadiene
115 5
204 2-Ethyl-l-hexene
205 rf/-l,2,3-Trimethylcyclopentene
(Laurolene)
206 4-Methyl-3-heptene
207 3-Ethyl-2-hexene
208 3-Methyl-3-heptene
209 1-Octene
-7949
116
116
116 8
1 418
1 418
0737
0729
074(22
1 45024
07412
1163
-1133
1 4275
07434
11698
-805
1 4420
07996
1 412
1 4136
1 414
1 445
0718
07240
0723
0804
1 41195
1 45054
0 72025
07637
120
1 4157
07270
120 I7"
1 4421
07950
1204
121
121
121 28
1
1
1
1
-8738
solid at
-80, hq
at -23
-101 76
Miscellaneous
unstable
Nitrosochlonde,
118 Oxid —
pimelicac , 105
171
Maleic anh adduct.
1042-50,00,
>-80
119 22
119 23
D?
1 5243
116 8
117
1177
118
119
ng
97
di-
114 6
M P 'C
Mercaptosuccimc
acid adduct.
101 9-27
41712 25 0741 1 25
424
0737
418
0728
071492
40870
di-
240 2,
1185 1 5
* Derivative data given in order m p , crystal color, solvent from which crystallized
18
1 4970
1 4580
Mercaptosuccimc
acid adduct,
96 1-6
TABLE I I . O R G A N I C D E R I V A T I V E S O F A L K E N E S , C Y C L O A L K E N E S ,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point
•c
Melting
point
•c
210 trans-4-Octene
121 4"9
fp - 9 4
211 1 ,3-Cycloheptadiene
(Hydrotropilidene)
121 52
-11042
212 3-Methyl-2-heptene
213 m-4-Octene
121 6
12i 7^9
fp
-118
Bromine addition product
"D
1 41157
Dj°
x Bromo
071467
BP
C
M F C
103»
di
(meso)
Miscellaneous
"i>
D{°
1 4967"
1 4525
H, — Cyclo
heptane b p
118 20
0 8929?
1 4183
1 41361
07296
0 72048
di (dl) 840
1 4981
1 4569
1 5060
1 387
84"
214 2,3-Dimethyl-2-hexene 121 8
215 3,4-Dimethy\-trans-3- 122
hexene
122 4
216 6-Methyl-l-heptene
113 5
122 3 74 '
217 c«-3-Octene
1224'"
218 frans-3-Octene
1 4268
1 430
07408
0747
1 4070
07125
1 41246
1 41241
071888
071630
1 4138
1 4132
07241
07199
1 4150
1 4432
07243
07432
128
1 446
0802
128
1 448
08051
1289
1 412
0722
1295
305 36"
131 2
1 4623
08320
1 4621
07551
132 4
71 3
132 5
1 4410
07832
1 4649
07667
1 4761
1 449
1 454
0810
0815
1 4487
07728
1 4542'
1 4796 I J
07427'
0 7646 "
1 451
1 44406
0814
08035
1 4575
1 4588
0823
08250
1 445
0802
1 4810 JU
08948
219 2-Methyl-2-heptene
220 (rans-2-Octene
123 5
1250
221 m-2-Octene
222 2-Methyl-l,3-heptadiene
223 1 ,4-Dmiethy Icyclohexene
224 1 ,5-Dimethylcyclohexene
225 2,6-Dimethyl 2heptene
226 4-Vmylcyclohexene
12564
127 8 '
227 4-Methyl-2,4-heptadiene
228 3,4-Dimethyl-2,4hexadiene
229 3-Methyl-2,4-heptadiene
230 Bicyclo[4,2,0]oct-7-ene 1325
231 4-Ethylcyclohexene
133
232 1 ,6-Dimethylcyclo133
hexene
233 3.5-Dimethy 1-2,4133 44 •
heptadiene
234 2,4-Octadiene
1335 40
235 2,5-Dimethyl-2,41336 28'
hexadiene
134
236 3-Ethylcyclohexene
237 1,2,3,3-Tetramethyl134 5
cyclopentene
(Campholene)
238 1-Ethylcyclohexene
36
239 1 ,2-Dimethylcyclo37
hexene
240 1,3-Dimethylcyclo137
hexene
241 Bicyclo[4,2,OJoct-2-ene 37 9
-115 1
f p -126
fp
-1104
-877
-1002
146 8
di
85 7'
Mercaptosuccmic
acid adduct
1429 3 5
Nitrosochlonde
83 4
Nitrosochlonde
118 9
aft
di
695 70
eth
HBr^Dihydro
bromide b p
109 1 1 "
di
74"
tetra
101
Oxid in air —»-poly
menc peroxide 59
di
142 3
acet
Nitrosochlonde
58 60
'Derivative data given in order m p crystal color solvent from which crystallized
19
TABLE I I . O R G A N I C D E R I V A T I V E S O F A L K E N E S , C Y C L O A L K E N E S ,
DIENES A N D POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point,
°C
Melting
point
•c
Bromine addition product
"5
Df
x Bromo
243 1-Mcthylcycloheptene
1375 85
1 4581
08243"
244 2-Methyl-4-octene
245 a-Fenchene(l,55-Tnmethylbicyclo[2,2,l]
hept-2-ene)
246 1,5,5-Tnmethylcyclohexene (o-Cyclogeraniolene)
247 2,6-l)lmethyl-2,4heptadiene
248 1 ,4,4-Tnmethylcyclohexene (Pulenene)
249 1 ,5,6-Tnmethylcyclohexene
250 23-Dimethyl-2-norbornene (Santene
2,3-Dimethylbicyclo
[2,2,l]-hept-2-ene)
138"J
139 40
1 4181
1 44862
07392
08433
139-41 "
1 44612"
07981"
139 437 '
1 4587"
0 74820
1395-405
1 444" '
08032""-
140
1 4572
083U,
140-1,
35'
1 46699
08640
251 2,6-Dimethyl-Uheptadiene (Isogeraniolene)
252 Cyclooctatetraene
140-2.31
1 4606"
07923"
1 5290
09206
253 7-Methyl-3-octene
254 2,6-Dimethyl-l,5heptadiene
(Geraniolene)
255 1,8-Nonadiene '
256 1,3.5-Trimethylcyclohexene (Tetrahydromesitylene)
257 3-Methyl-2-octene
258 Cydooctene
14! 74.
259 3,6-Dimethyl-2,4heptadiene
260 4-Nonene
261 1,4,5-Trimethylcyclohexene
14056
142 3,
42 2 5 '
141-2,
165 70
-468,
-7
-70
BP 'C
M P °C
<
D;°
Miscellaneous
Nitrosochlonde,
106, Nitrosate,
97 8
Nitrosochlonde,
131
Nitrosochlonde,
100 20, aq me , al
Nitrosate, 102 4
di-
120
05'"
1 5247"
1 5324" Nitrosochlonde,
118 22. et ac
Dichlonde 88 9,
Nitrosdte, 216d ,
Nitrosochlonde,
109 10 Nitrosite,
3 forms a) 122 4,
bl b ) ! 2 7 - 8 , g r n ,
c) 104, col
Mdleicdnh adduct,
167 8 Benzoqumoneddduct.
141, dl Acrylic ac
ddduct 112 3, Igr
AgNOiddduct,
173 4
1 4168
07278
1 44361" 0 7626"
141-4
142 5-3 5
1 4302
1 449135
07511
08025' 4i
143-5734
143845773
1 4247
1 4693
0 740925
144-6
1 4633514
0 7853°
144-6,
44 6' 2
144-6
1 42I2 18
0732' 8
1 4482
0805
Nitrosochlonde,
134
Br2 — » Bromocyclooctene, b p 7-823,
n2D° 1 5182, Dichlonde, b p
1304-06",mp
-5, rig" 1 5061,
D2° 1 1620
di-
'Derivative data given in order m p , crystal color, solvent from which crystallized
20
119
20"
1 4988"
1 410"
TABLE II. O R G A N I C D E R I V A T I V E S OF A L K E N E S , CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point,
•c
Melting
point,
°C
262 1-Vinylcyclohexene
145,
63 553
263 as- 1 ,4-Cy clooctadiene 145 |"8
264 1 ,3,5-Cyclooctatriene 145 6,
76"°
274 l-Ethyl-3-methylcyclohexene
275 2-Nonene
276 1,23-Trimethylcyclohexene
277 l-Ethyl-5-methylcyclohexene
278 /S-Fenchene (2,2 Dimethyl-5-methylenebicyclo[2,2,l]
heptane)
279 2,6-Dimethyl-2,5heptadiene
280 2,7-Nonadiene
281 Allylcyclohexane (3Cyclohexylpropene)
282 l-Ethylidene-4-melhylcyclohexane
283 4,5-Dimethyl-2,6octadiene
284 l-Ethylidene-3methylcyclohexane
285 3,6-Dimethyl-2,6octadiene
286 2,6-Dimethyl-2,7octadiene
Df
x-Bromo-
BP.'C
M P/C
<
Miscellaneous
D;°
1 4950"
50°/ 0 H 2 S0 4 —
d i m e r . b p 118-95
-53
139
1 5035"
08754
08971 2S
1 4330
07647
1 4865
08626
MS
1 45620 '
08217 2 0 3
Nitrosochlonde,
133 4,et ac
1 41572
1 4173
1 4905
07294
08818 24
148 51
1 46285!5
0 7640"
149
1 4543 '»
07521"
149, 153 4
1 453"
08169"
149 51
1 454
08296
265 4,4-Dimethyl-l,7145 8
octadiene
266 £-Fenchene (2,7,7-Tn- 1462
methylbicyclo[2,2,l]
68» 2
hept-2-ene)
267 1,6,6-Trimethylcyclo- 14627 2 767 ,
hexene
144 6
14687
268 1-Nonene
147 475"
269 3-Nonene
270 1 ,5-Cyclooctadiene
148 9
271 4-Methyl-3,5-octadiene
272 7-Methyl-2,4-octadiene
273 l-Ethyl-4-methylcyclohexene
Bromine addition product
"D
-81 37
2
tetra-
Maleicanh adduct.
144-5, AgNO 3
adduct, 125-6, al
di-
lelra-
0738 2 '
08347' 2
1 452725
0812"
1505 3 5
1 46511
08599
di-
1506 1 0
1 4490
1 4358
1 4536"
07499
08196 13
di-
152-3
1 457 1 2 '
081 2 '
1529-38
1 43752S
0761 1 25
153
1458 4
0813511
153-5
1 44453
07767
1 4385"
07605"
55 67M
1 3980
184"
Nitrosochlonde,
2 forms a) 103-4,
pr , eth , b) 98 9,
cr , eth
1 420 '
1 463"
-725
1 4942
N-Bromosuccmimide — * bromocyclooctadiene,
b p 64", ng
1 5410, Df 1 3420
1494 9 9
1496
ISO 749
150
1506
151
141 520
-24 1
81-2
143 4"
[<*]g +625,
Nitrosochlonde,
120
1 537°
Nitrosochlonde,
2 forms a) 117-8,
least soluble, b)
1 1 3-4, more soluble
Nitrosochlonde,
114, acet
'Derivative data given in order m p , crystal color, solvent from which crystallized
21
TABLE II. O R G A N I C D E R I V A T I V E S OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point,
°C
Melting
point,
•c
Bromine addition product
"S
Df
x Bromo
287 a-Pinene
1560-63 -50
1 4560
08600
288 l-Ethylidenc-2methylcyclohexane
289 2,4-Dimcthyl-2,4octadiene
290 1,4,4-Trimethylcycloheptene (Eucarvene)
29! iS-Pinene (Nopmene,
Pseudopmene)
292 2,7-Dimethyl-2,6octadiene
293 3,7-Dimethyl-2,4octadiene
294 /-4-Carene (3,7,7-Tnmethylbicyclo[2,2, 1 ]
hept-2-ene)
295 Myrcene (2-Methyl-6methylene-2,7octadiene)
158
1 47
0823°
1 4558" •
0 78028 •
161-5720
1 4561
08185
163-4
1 4782
08694
1635 45
1 44814
07849
164-7,
58"
1655
1 456
07933
296 2,6-Dimethyl-2,6octadiene
297 /-3-Carene (3,7,7-Tnmethylbicyclo[2,2,ljhepi-3-ene)
298 3,8-o-Menthadiene
(m-3-Isopropenyl4-methylcyclohexene)
299 5-Decene
300 />-8-Men«hene(l-Iso
propenyl-4-methylcyclohexane)
301 (/-m-8-iV1enthene(lIsopropenyl-3methylcyclohexane)
302 /-m-8-Menthene(lIsopropenyl-3methylcyclohexane)
303 6,8-o-Menthadiene (3Isopropenyl-2methylcyclohexene)
304 5,8-o-Menthadicne (4Isopropenyl-3methylcyclohexene)
305 1-Decene
306 4-Decene
161 3
746
1 474
30
BP.'C
di-
MP.'C
"S
D?
169 70, al
Miscellaneous
Nitrosochlonde,
109, Hydrobromide, 89,
Nitrosobromide,
91 2d,Acid
KMnO 4 — pinonic
ac , 103-5
WD -22
tetra-
124-7
0 8552i»
k]3D° +62 2
Maleicanh adduct,
33-4, 1,4-Naphthoqumone
adduct, 81
Methiodide, 130d
7Q707
166
1 4722
07982
168, 56"
1 45245 ">
0775 2 '
168 9705,
123 4200
1 46930
0 8586i°
169-70
1 4749
08507
1 4260
07474
170
1 4523
08142
170
1 4546
08179
No +973
70-1
1 4574
08189
WD -»06
170 1
1 4758
08481
170-1
1 4778
084901?
1 42146
074081
1 4243
07404
170"°
7057
1706
-112 to
-111
-6631
WD" +769,
Nitrosochlonde,
100-1
di-
di-
'Derivative data given in order m p , crystal color, solvent from which crystallized
22
119'
145
160"
1 4912
1 489 1 24
1 3484
1 32428
Mercaptosuccmic
acid adduct,
935-8
TABLE I I . O R G A N I C D E R I V A T I V E S OF A L K E N E S , C Y C L O A L K E N E S ,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p.)* (Continued)
No
Name
Boiling
point
•c
Melting
point,
•c
Bromine addition product
"5
Df
Miscellaneous
x-Bromo-
BP.'C
M P,'C
172-4
1 4568
0819 21
172-6
1 5216
09068
173, 160-2
1 467
08345
173-5
1 4670
08214
173 5
48 755
1 477
08375
312 2,4-p-Menthadiene(2Isopropyl-5-methyl1 ,3-cyclohexadiene)
313 /-5-lsopropyl-2methyl-U-cyclohexadiene
314 1,5-p-Menthadiene
(5-Isopropyl-2methyl-l,3-cyclohexadiene)
174 6
1 484527
08441g
174-7
1 4732
08425
175 6
1 4777
0 84632S
315 rf-Silvestrene
175 8
1 4760
08479
tetra-
135
316 rf-Limonenc
176 6 4
1 4743
08411
letra-
104
317 Isocarvestrene (5-Isopropenyl-1-methylcyclohexene)
318 /-3~Isoproppnv|-lmethylcyclohexene
319 Dipentene (d 1Limonene)
320 3,8-m-Menthadiene
(l-Isopropenyl-5methylcyclohexene)
321 Menogerene (5-Isopropyhdene-2methyl-l,3-cyclohexadiene)
322 -y-Terpinene (1-Isopropyl-4-methyl- 1 ,4cyclohexadiene)
176 7765
1 4804
08496
letra-
137-8, me
al -chl
176-8
1 476 118
0 848"
1776-80
1 472720
,79730
1 4972
180 I789
183
307 p-Menthene(l-Isopropylidene-4methylcyclohexane)
308 I-Isopropenyl-1,4cyclohexadiene
309 o-Menthene(l-Isopropylidene-2methylcyclohexane)
310 m-Menthene ( 1 -Isopropylidene-3rnethylcyclohexane)
311 a-Terpinene ( 1 -Isopropyl-4-methyl1 ,3-cyclohexadiene)
323 d /-2,8-m-M enthadiene 184 7
(l-IsopropenyI-3methylcyclohexene)
"S
Df
Nitrosochloride,
101-3
letra-
113
Dihydrochlonde,
53-4, me al , Dihydrobromide,
58 9, me al , Dihydroiodide, 76,
me ai , Nitrosite,
155, Maleicanh
adduct, 62, 66-7
20
0 8402
tetra-
125,eth
1 5005
08672
di-
115
1 476514 5
0849
tetra-
129-30,
pet eth
1 503
086418
* Derivative data given in order m p , crystal color, solvent from which crystallized
23
[a]ff -11276,
Nitrosite, a 120-1,
0 105 6
[a]D +49 1, Nitrosite, a 11 3-4, ,8
105 Maleicanh
adduct, 126-7, pet
eth
Dihydrochlonde,
72, Nitrosochloride, 106-7
Nitrosochloride,
100-4, 2,4-Dimtrophenylsulfenyl
chloride, 195-6
Dihydrochlonde,
71 5, me al
[a]i> -68 2, Dihydrochlonde, 72
Dihydrochlonde,
50-l,al
[a]D + 1 7 5
[«)b 5 +36, Nitrosochloride, 111,
Nitrosate, 116d ,
ac a -me al
TABLE II. O R G A N I C D E R I V A T I V E S OF ALKENES, CYCLOALKENES,
DIENES AND POLYENES
a) Liquids 1) (Listed in order of increasing b.p. )* (Continued)
Name
Boiling
point,
Melting
point,
Bromine addition product
"D
Df
324 Menogene (3-Iso1846 7 6 4 5
propyhdene-6-methyl
cyclohexene
325 Terpinolene (4-Iso186
propylidene-l
methylcyclohexene)
1 5026
08624
1 4883
0 8633,'?
dl-
326 2-Undecene(2Hendecene)
327 5-Undecene (5Hendecene)
328 1-Undecene
(1-Undecene)
329 m-Cyclodecene
1 43325
077351?
telra2
forms
di-
145 6»
1 4289
07511
1 42609
0 75032
di-
186"
1 4854
08770
dt-
121
-3523
1 43002
0 75836
di-
-15
-2307
1 4336
07653
-1285
1 43631
07713
di-
0
1 5001"
09359!?
-373
1 4389
077641
di-
204-5'7
4 12
1 44120
078112
di-
225 7' 5
2997, 116' 11 2
314, 277'°° - 2 5
1 4432
07852
07953
di-
267-828
3142,128' 176
1 4449
07888
di-
No
330 1-Dodecene
331 1-Tridecene
332 1-Tetradecene
333 Cedrene
334 1-Pentadecene
335 1-Hexadecene
336 1-Heptadecene
337 2-MeIhyl-2-heptadecene
338 1-Octadecene
•c
•c
192 3,
78 5' 4
1922
19267
-49 19
194 574"
21336
88 7'°
23278
104 510
251 1,
1190'°
262-3,
124 612
268 17.
133 710
2844
1039'
r-Bromo
* Derivative data given in order m p , crystal color, solvent from which crystallized
24
B P 'C
M P "C
ng
D;°
Nitrosite, 155, me
al orchl , Maletc
anh adduct, 205 8
Maleicanh adduct.
182
69 70
a) 119,
ac a ,
b)122
1 4916
24, al
1 3122
O3 — » Sebacic acid.
1345
Mercaptosuccmtc
acid adduct,
1040 8
1 4897
135,ai
Miscellaneous
I 2235
!%HotKMnO4 —
n pentadecylic ac ,
52 3, Mercaptosuccimc acid adduct, 105 0 8
TABLE I I . O R G A N I C D E R I V A T I V E S O F A L K E N E S , C Y C L O A L K E N E S ,
DIENES AND POLYENES
a) Liquids 2) (B.p. at reduced pressure only. Listed alphabetically)
No
1
2
3
4
5
6
7
8
9
10
11
Name
Bicyclo[12,2,2joctadeca-14,16,18-triene
Bicycle [4,2,0)oct-3-ene
Butylcyclooctatetraene
Iranj-Cyclodecene
1,5,9,13-Cyclohexadecatetraene
Iran.t-Cyclononene
1 3-Cyclooctadecadiene
1 ,3-Cyclooctadiene
1 ,3,6-Cyclooctalriene
1 ,3-Cvclotetradecadiene
1 ,2-Dimethylcyclooctalef raene
Boiling
point, "C
1635 4 5 5 5
81"°
9g20
68-70'"
93 8°"
73 430
1153
482S
6860
106-83
10796
12 2,6-Dimethyl-2,5-octadiene
13 Ethylcyclooctatetraene
590-5"
813'
5-Methylcycloheptene
Methylcyclooctatetraene
7-Pentadecene
Propylcyclooctatetraene
69 7038
14
15
16
17
Melting
point, 'C
"£
1 5204"
1 4832
1 50832S
1 4822
1 5472
1 4799
1 4899
25
-57 to -55 1 4940
-62to-56
1 4982
1 5219"
D;°
Miscellaneous
Maleicanh adduct, 143 4
25
0 8876
08672
O, — Sebacic acid, 1 34 5
08615 Phenylazide adduct, 97 8 8 2
08814
0 869925
0 894025
0 872325 Nitrosochlonde, 109-10, Nitrosate, 21 Od
0 895025 Maleic anh adduct, 184 5-5 5, bz -Igr , AgNO 3
adduct, 1425 4 5, al
1 4500 0733
25
M
1 5187 0 8996 Maleic anh adduct, 97 8 5, bz -cyclohexane.
AgNO 3 adduct, 124-5 5, al
1 4201631 0760613'
1 524926 0 897825
1 4420 07765
1 5131 25 0 88702S
84 5<"
114 32
73"
*Derivative data given in order m p , crystal color, solvent from which crystallized
25