CHEM 150 Assignment #2 (Due Oct. 17th, in-class) Answer each of the following questions, showing all of your work. ___________________________________________________________________________________________ 1) Draw Lewis structures for each of the following molecules/polyatomic ions. Indicate the VSEPR molecular geometry in each case. a. PCl3 b. ClO2c. CO a b trigonal pyramid angular (or bent) c linear 2) Arrange the following two-atom bonds in order of increasing polarity (lowest polarity highest polarity). B-F, C-P, S-O Answer: determine the bond polarity order by the difference in the electronegativity for the two elements in each bond. C-P < S-O < B-F 3) Which of the following molecules/polyatomic ions are polar? (Answers highlighted) a. PCl3 b. NH4+ c. ClO2d. I2 e. CO32f. H2CO 4) Indicate the formula weights for each of the following substances: a. Sodium nitrate: NaNO3 : 22.99g/mol Na + 14.01 g/mol N + 3 x 16.00 g/mol O = 85.00 g/mol b. K2CO3: 2 x 39.10 g/mol K + 12.01 g/mol C + 3 x 16.00 g/mol O = 138.21 g/mol c. Br2: 2 x 79.90 g/mol Br = 159.80 g/mol 5) Complete the Lewis structure for the amino acid shown below. What are the local molecular geometries around the atoms indicated? (i.e. a and b) H H H O N C C O H a) b) Answer: Local molecular geometries: a) Trigonal pyramid b) Trigonal planar H
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