M INERALOGICAL AND G EOCHEMICAL A NALYSIS OF
S TRONTIUM AND B ARIUM S OURCES IN THE P OINT
P LEASANT F ORMATION
Senior Research Thesis
Submitted in partial fulfillment of the requirements for graduation
With Research Distinction in Earth Sciences in the undergraduate colleges of
The Ohio State University
By
Matthew Gordon Edgin
The Ohio State University
2016
TABLE OF CONTENTS
Abstract…………………………………………………………………………….ii
Acknowledgements………………………………………………………………...iii
List of Figures……………………………………………………………………...iv
List of Tables……………………………………………………………………......v
Introduction………………………………………………………………………..1
Geologic Setting………………………….………………………………………...3
Methods
Leica DMS 1000 Microscope……………………...…….…………………..4
FEI Quanta 250 FEG SEM………………………….……………………...4
ICP-MS-LA……...…………..……………..……………………………….5
Data interpretation………....……………………...………………………...5
Results
Leica images prior to SEM and ICP-MS-LA…..………….………………….8
SEM and EDXS………………………………………………………..…...9
Barite Estimation Calculation……………………………………...13
Induced Coupled Plasma Mass Spectrometry………………...……………14
Carbonate Shell Site A……………………………………………..15
Carbonate Shell Edge Site A……………………………………….18
Short Axis Carbonate Shell Site C………………………………….20
Bowtie Carbonate Short Axis Site D……………………………….23
Molar Sr/Ca vs Mg/Ca……………………………………………25
Discussion
Barium……. …………………….………………………………………..27
Barium Mobilization……....……………………………………………….27
Strontium…………………………………………………………………28
Carbonate Crystal Structure Effects on Strontium Accommodation…...........29
Magnesium’s Influence on Strontium Incorporation into Calcite…………..30
Conclusions……………………………………………………………………….32
Recommendations for Future Work…………………………………………….…33
References Cited….……….…………………………………………………….....34
Appendices.………………….…………………………………………………....36
i
ABSTRACT
Analysis of trace elements in rocks from the Utica-Point Pleasant gas shale play is important
because elevated concentrations of trace elements in flowback fluids derived from hydraulic
fracturing may be an environmental hazard. Previous reports show high levels of barium and
strontium associated with flowback fluids, with no clear explanation as to their origin. The goal of
this study is to determine potential sources of Sr and Ba from Utica-Point Pleasant mudrocks that
could be released into hydraulic fracturing fluids with which they interact. Polished sections of core
were analyzed to determine the concentrations and distribution of trace elements across selected
mineralogical/textural regions of the samples.
Samples provided by Chesapeake Energy were observed with light and scanning electron
microscopy (SEM) to identify areas of interest for analysis by inductively coupled plasma mass
spectrometry laser ablation (ICP-MS-LA). SEM backscattered electron images and QEMSCAN
mineral mapping helped determine the spatial distribution of the sulfide, sulfate, and carbonate
minerals of interest. Energy dispersive spectroscopy was used to obtain semi-quantitative spot
chemical analyses of minerals. SEM images show significant quantities of carbonates (CaCO3), barite
(BaSO4) and celestite (SrSO4) which may be the sources of high levels of Ba and Sr in flowback
fluids previously reported.
Analysis from ICP-MS-LA line profiles across a pyrite/carbonate mineral assemblage and
surrounding silt and clay-size carbonate/silicate matrix show major elements Mg, Ca, Sr, Ba, Al, Na,
Ti, Fe, S, Si and trace elements Mo, Mn, Ni, Zn, La, Ce, U, Th, Rb. Barium concentrations were low
in the pyrite and carbonate shells but ranged from 50 to 500 ppm in aluminosilicate clays in the
matrix and up to 500,000 ppm in barite. Strontium concentrations ranged from 100 to 500 ppm in
the pyrite but range 4000-6000 ppm in the carbonate shells and finer-grained clay-carbonate matrix.
ii
ACKNOWLEDGEMENTS
I would like to thank the following individuals and organizations who made my entire
project possible: Steve Chipera and Chesapeake Energy for providing the samples and well data for
this study, everyone associated with the Subsurface Energy Materials Characterization and Analysis
Lab (SEMCAL), Dr. Dave Cole, Dr. Julie Sheets, Dr. Susan Welch, Alex Swift, Derek Foley, and
Edwin Buchwalter for use of their facilities, knowledge, guidance, and collaboration. I would also
like to thank Dr. John Olesik for his expertise and guidance with inductive coupled plasma mass
spectrometry laser ablation (ICP-MS-LA).
Appreciation goes to the entire faculty, students, and staff of The Ohio State University’s
School of Earth Sciences for being a truly special place to spend time pursuing my second bachelor’s
degree. I would like to thank all the professors that have imparted their knowledge in the classes I
have taken and contributed to my overall understanding of the Earth Sciences: Dr. Panero, Dr.
Barton, Dr. Krissek, Dr. Cox, Dr. Royce, Dr. Lyons, Dr. Cook, Dr. Carey, Dr. Wilkins, Dr. Wilson,
and Dale Gnidovec. I also would like to thank the School of Earth Sciences for maintaining their
Field Geology program. Particularly, I want to thank Dr. Kelley, Dr. Wilson, Dr. Judge, Dr. Millan,
and Dr. Darrah, the states of Utah & Nevada, and my TA’s Trish Hall & Will Blocher for their hard
work, time, and commitment. Likewise, I would like to recognize my roommates Alex Grady, Sam
Perry, and Murvin Morrow for making field camp one of the best experiences in my life.
In addition, I would like to thank Mario Gutierrez, John Daniele, Lienne Sethna, Drew
Sabula, Laura Miller, Abbie Bowman, Megan Mave, Ken Peterman, and Myles Moore for satiating
all the great clichés about geologists. Special thanks to my undergraduate advisor, Dr. Anne Carey
for her help, support, and patience. The utmost appreciation goes to my research advisor, Dr. Dave
Cole, for his wealth of knowledge, top-notch facilities, and advice. Lastly, I would like to thank my
parents and the rest of my family for being incredibly supportive of my decision to pursue a second
bachelor’s degree.
iii
LIST
OF
FIGURES
1.
Leica Images……………………………………………………………………………...8-9
2.
SEM Images…………………………………………………………………………...10-11
3.
Laser Ablation Graphs………………………………………………………………....15-25
4.
Laser Ablation Site E SEM images..…………………………………………………....36-38
5.
Laser Ablation Site E Graphs………………………………………………………….86-87
iv
LIST
OF
TABLES
1.
Chesapeake Mineralogical and Petrophysical Data……………………………..…………...7
2.
EDX Carbonate Analysis………………………………………………………………….12
3.
Barite Estimation Calculation……………………………………………………………...13
4.
Calculations of barium in bulk mineralogy…………………………...……………………27
5.
Sr/Ca ratios relation with Kd……………………………………………………………...29
6.
Laser ablation raw data………………………………………………………………...39-85
v
INTRODUCTION
Since the shale gas boom began, there has been immense concern about the fluids and
chemicals associated with hydraulic fracturing. Flowback water is defined as water that has returned
to the surface when pressure is released on a hydraulically fractured well. Most of the flowback water
returns to the surface within the first few days to weeks after the wells are hydraulically fractured.
The remainder of the returns overtime during the production phase, when hydrocarbons are
extracted from the wellsite. The water quality of the flowback waters can be affected by the
chemistry of fluids in contact with the formation, fluids within the formation water, the formation
itself, the amount of time the fluid was retained in the well, and the initial quality of the fluids used
in the process (Vazquez et al., 2014). Although the interactions with dissolved substances in the
subsurface is still being studied, it is important to note that when flowback waters return to the
surface, an immense amount of water-rock interaction has taken place. These interactions have the
potential to mobilize many different types of chemical compounds, which is why understanding the
trace element composition of the Utica/Point Pleasant formation is important.
Monitoring of trace element concentrations has been used to assess the potential
environmental impact of flowback water and design strategies for how to process and dispose of the
fluids. Trace elements are defined as elements with concentrations less than 0.1% in the Earth's
crust (Harris et al., 2013). They are utilized to identify associations among trace elements themselves,
and to identify paleoceanographic conditions and depositional processes (Harris et al., 2013). They
can also be used to investigate the composition of the fluids associated with gas shale systems and
detect substances potentially harmful to human health and the environment. The trace element
composition of the Utica/Point Pleasant formations are of particular interest because these organic
carbon rich formations are a major source of hydrocarbons. Previous studies have examined
flowback waters to measure trace elements compositions and have shown high concentrations of
total dissolved salts (TDS), Cl, Br, Na, Ca, Sr, Ba, Ra, and other elements. The levels of TDS, Cl and
other elements are as much as 5-10 times the concentration of seawater (Haluszczak et al., 2013).
Concentrations of 226Ra, 228Ra, and Ba have been found to be significantly higher than what is
allowed for drinking water limits (Haluszczak et al., 2013).
Flowback waters from wellsites located in or near the Appalachian Basin have been shown
to contain elevated levels of barium and strontium levels as high as 3g/L (Rozell and Reaven, 2012).
The levels deviate from normal water near wellsites which have Sr/Ca ratios of about 1/100 mg/L
and Sr/Mg ratios of about 1/50 mg/L for water (Rozell and Reaven, 2012). Barium in high
concentrations is poisonous to humans and other lifeforms. It has required standards in drinking
water because high levels have been associated with gastroenteritis and muscular paralysis
(Kravchenko et al., 2014). In barite, radium, which is harmful to humans, can incorporate itself into
the crystal (Dresel and Rose, 2010). Barium is likely to be found in the form of barite a reasonably
insoluble sulfate mineral and from contamination with salts associated with hydraulic fracturing
(Dresel and Rose, 2010). Strontium is commonly found in the minerals celestite (SrSO4) as an
endmember of the barite-celestite solid solution series and strontianite (SrCO3) as an endmember of
the aragonite (CaCO3) group. Strontium also can precipitate as celestite with sulfate like barium from
hydraulic fracturing fluids (Dresel and Rose, 2010). Elevated levels of strontium although unusual,
are not harmful to humans unless strontium is in the form of 90Sr. This isotope of strontium is a
fission product of 237Pb linked to nuclear reactions and not involved with the drilling process.
1
However, the high mobility and presence of strontium is still of interest to scientists because it has
potential application as a tracer and source rock indicator (continental vs oceanic).
Like in the Appalachian Basin, Ohio has a high concentration of oil and gas wells located in
the eastern part of the state (Figure 1). The trace element concentration of the flowback water
associated with hydraulic fracturing and local groundwater wells need to be monitored. The purpose
of this study is to determine concentrations and distribution of Ba and Sr levels across selected
mineralogical and textural regions of an organic rich sample. The objective is to determine whether
these elements originated in the formation itself or from the muds or fluids associated with hydraulic
fracturing.
Figure 1: Map of oil and gas production wells in the Utica/Point Pleasant formations with
the oil, wet gas, and dry gas windows outlined (Figure from Hammes, 2015)
2
GEOLOGIC SETTING
The Point Pleasant formation formed during the Middle Ordovician when much of what is
now the Ohio Valley was covered by a shallow and expansive epeiric sea. The rocks that represent
this formation can be described as carbonate sediments that were deposited in a shallow platform
with some shale indicative of an influx of silliclastic sediment (Drozd and Cole, 1994). The
formation exists between two carbonate platforms: The Trenton Platform to the northeast and
Lexington platform to the southwest. Both platforms are suggestive of deposition in a subtidal
environment that was oxygenated (Drozd and Cole, 1994).
The transition between two carbonate dominated platform systems to a clastic dominated
system suggest that there was a collapse of a widespread carbonate platform. The lower gradational
contact of the Trenton/Lexington Limestone through Utica Shale create a transgressive systems
tract (TST) (McClain, 2012). The TST occurs because of a rapid sea level rise overcoming the rate of
sedimentation to produce retrogradational onlapping or patterns where rock facies are more distal
when traced upward vertically. The thickness of the unit varies from 40 feet to over 100 feet
(Wickstrom, 2013). Variable thickness causes the formation to form limestone interbeds that range
from regular to irregular and contrast with black shale and gray limestone in core samples (Patchen
et al., 2004). This has caused geologists to label the unit as transitional, from a shallow sea to a deep
ocean environment.
3
METHODS
All research and analyses were conducted in the Subsurface Energy Materials
Characterization and Analysis Lab (SEMCAL) and the Trace Element Research Lab (TERL) at The
Ohio State University School of Earth Sciences. The sample chosen was JP 10,930 of the Point
Pleasant formation and was supplied by Steve Chipera and Chesapeake Energy. The Point Pleasant
tends to be the preferred formation target for hydraulic fracturing compared to the Utica. This
sample was is located in Washington County Pennsylvania at a depth of 10,930 ft. below the surface.
The sample has an average Ro maturity of 2.59 which indicates it was located in the gas window in
terms of thermal maturity (Table 1). The sample was examined under light and scanning electron
microscopy (SEM) to determine the spatial distribution of carbonate, sulfide, and sulfate minerals of
interest and select specific areas for elemental analysis. SEM backscattered electron images (BSE)
were analyzed using grayscale percentage to determine microscale mineralogy for barite using
ImageJ. Induced coupled plasma mass spectrometry laser ablation (ICP-MS-LA) was used to
determine concentrations and distributions of trace elements across selected mineralogical and
textural regions in the sample.
Leica DMS 1000 Microscope
The Leica DMS1000 digital light microscope allowed for low magnification (up to 300x),
high resolution images. Image capturing hardware and image processing software platform allowed
further sample interpretation, measurement, and image presentation. This image analysis was used to
identify key areas of interest for SEM analysis. The high resolution images allow a more macro-scale
form of image analysis compared to the SEM that aided in correlating images between the SEM and
Laser Ablation Microscope for ICP-MS-LA.
FEI Quanta 250 FEG SEM
Analysis of mineralogical, grain, and pore characteristics was performed using a FEI Quanta
250 Field Emission Gun SEM. Prior to analysis, the sample was carbon coated with an SPI carbon
coater. Carbon was chosen over gold-palladium because the coating doesn’t overlap with the energy
range of most elements of interest during energy dispersive X-ray micro analysis. Both secondary
and backscattered electron images were acquired. A backscattered electron (BSE) detector acquires
signals from electrons that interact deeply with the sample and deflect into the BSE. Higher-atomic
mass elements scatter electrons more strongly, and are therefore brighter than lower atomic mass
elements. The atomic mass contrast helps indicate chemistry of the rock. A secondary electron (SE)
detector allow the user to produce images that show enhanced topography. This detector operates
by using low energy electrons that only interact with the surface of the material.
Images acquired were then analyzed to determine mineral distribution and association which
are important parts of microtextures for the sample. Micro-scale analysis is important because it can
tell us a great deal about porosity, permeability, and diagenesis. Spot micro analysis was performed
using a Bruker energy dispersive X-ray spectrometry (EDXS). Mineral mapping is also available
using to Quantitative Evaluation of Minerals by SCANning electron microscopy (QEMSCAN),
which identifies minerals based upon EDXS spectra and BSE grayscale intensities, as compared a list
of standards obtained under similar experimental conditions.
The entire sample was mapped in a grid pattern with a 400 μm scale with backscattered
electrons. These images were taken by Alex Swift. I used the information available to estimate the
4
amount of barite present. Backscattered electron images were analyzed for microscale bulk
mineralogy using ImageJ. Calculation of known minerals with grayscale threshold allowed for
determination of bulk mineralogy using scales from the SEM image as a known measurement. This
method was used to estimate the amount of barite, carbonate, and aluminosilicate clay. Barite was
identified with BSE because its heavy molecular weight allows it to displays a nice bright image. The
SEM was preferred for this reason to identify areas of interest for ICP-MS-LA without causing
severe damage to the sample.
ICP-MS-LA
Concentrations and distributions of trace elements across selected mineralogical and textural
regions of the sample were analyzed using ICP-MS-LA. This method by firing a focused argon laser
beam at the sample to generate fine particles from a Photon Machine Analyte G2 Laser Ablater. The
particles are then transported to an Element 2 high resolution mass spectrometer. The ICP source
converts the atoms of the elements in the sample to ions which are then separated and detected by
the mass spectrometer by their mass to charge ratio. This method allows the collection of highly
sensitive chemical analysis including: bulk analysis, local inclusion and defect analysis, depth
profiling, & elemental/isotope mapping with a solid sample (Almirall et al., 2012).
The main advantage to using this approach is that it allows chemical analysis down to parts
per billion (ppb). Since the samples are in solid form the results have a lesser chance for
contamination, sample loss, and preparation related hazards compared to dissolution methods with
ICP-MS. This approach allows samples to be performed without the need for a complex vacuum
system and results are available within seconds.
Disadvantages with this approach compared with dissolution methods include having a
sample that could be less representative of the bulk. However, multiple sampling locations were
utilized to increase sample size representation. Detection limits are higher than dissolution methods
due to a smaller mass entering the ICP-MS. This can complicate things because when using ICPMS-LA matrix matched standard reference materials are often unavailable. This is important because
“accurate quantification of the ablated mass is directly correlated to the ablation rate, which is
inherent to the respective sample matrix” (Almirall et al., 2012 pg. 23). However, applications of
NIST series glass standards for quantification have yielded successful results for accuracy when
using the preferred concentration numbers from Pearce et al. (1997). A final issue with laser ablation
is fractionation which is affected by laser irradiance, wavelength, thickness, and the pulse interval
(Almirall et al., 2012). This was reduced using higher laser irradiances and shorter pulse durations
with a 10 by 10 μm beam.
Data Interpretation
Major elements Mg, Ca, Sr, Ba, Al, Na, Ti, Fe, S, Si and minor elements Mo, Mn, Ni, Zn, La,
Ce, U, Th, and Rb were profiled for analysis. Other elements besides barium and strontium were
analyzed to observe geochemical relationships among elements in mineralogical/rock textural
features. Data were collected using rapid peak-hopping between selected mineralogical and textural
features for periods of 60-200 seconds. Two glass reference materials NIST-610 & NIST-612 were
used for calibration using preferred concentrations reported by Pearce et al. (1997). The major
cations Na, Ca, Al, and Si were measured as oxides and then calculated to ppm as the element. The
NIST concentrations were compared to Bruker EDXS spot chemical analysis for major cations.
5
Results were given in counts per second and then calculated to ppm using the average signal
background to calibrate sensitivity values.
Equations Used
𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆 =
𝐴𝐴𝐴𝐴𝐴𝐴. 𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵𝐵 𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆
(𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃, 1997)𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃𝑃 𝐴𝐴𝐴𝐴𝐴𝐴.
𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒𝑒(𝑝𝑝𝑝𝑝𝑝𝑝) =
𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆 𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆ℎ
𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆
For Oxides (Si, Na, Mg, & Al)
𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶(𝑝𝑝𝑝𝑝𝑝𝑝) = �(𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜 𝑤𝑤𝑤𝑤%)𝑥𝑥 �
AW=atomic weight of element
MW=molecular weight of oxide
𝐴𝐴𝐴𝐴
𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆 𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆ℎ
� 𝑥𝑥10,000� 𝑥𝑥 �
�
𝑀𝑀𝑀𝑀 𝑂𝑂𝑂𝑂𝑂𝑂𝑂𝑂𝑂𝑂
𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆
6
RESULTS
Important properties of bulk samples were measured by Chesapeake Energy (Table 1) and
made available for analysis. Although the sample of interest is classified as a shale, about half of the
sample is composed of carbonate minerals, and about 20% is clay (Table 1). Other than calcite,
minerals that make up a large portion of the non-clay minerals are quartz (SiO2) (14.8%) organic
carbon (4.1%), plagioclase (NaAlSi3O8) (3.9%), and dolomite (CaMg(CO3)2) (2.9%). The majority of
the clay fraction is illite (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2,(H2O)] and micas (17.1%) with a small
percentage of illite/smectite (4.3%) and chlorite(Mg,Fe)3(Si,Al)4O10(OH)2·(Mg,Fe)3(OH)6) (0.3%).
Table 1: Mineralogical and petrophysical data for sample JP 27P 10930 from Chesapeake
Energy
WEIGHT PERCENT
Raw Data NORMALIZED to sum 100%
WELL NAME
STATE
COUNTY
SAMPLE ID
OSU ID
USANS priority
SAMPLE DEPTH
JP
Penn
Washington
73
27
1
10930.68
2.49
2.468
2.622
2.648
7.4
Average Ro (Maturity)
Bulk Density g/cc
A-R Grain Density g/cc
DRY Grain Density g/cc
Porosity % of BV
NON-CLAY FRACTION
14.8
1.0
3.9
4.1
0.9
1.2
Quartz
K-Feldspar
Plagioclase
Organic Carbon (TOC)
Apatite
Pyrite
Marcasite
Calcite
Dolomite
TOTAL
49.5
2.8
78.2
7
CLAY FRACTION
Mixed-Layer ILLITE/SMECTITE (Includes
R3)
TOTAL
4.3
17.1
0.3
21.8
GRAND TOTAL
100.0
Illite + Mica
Chlorite
23.6
27.9
1.02
n/a
% Expandable Layers in I/S
% I/S to Illite in <1.0um Fraction
% Expandable I/S Layers in sample
% Fe in the Dolomite/Ankerite
Leica images prior to SEM and ICP-MS-LA
Leica DMS1000 microscope was used to observe mineralogical and textural features at a
lower magnification than an SEM (less than 300x). JP 10930 is a sample that is carbonate rich and
there are numerous carbonate structures present. The size variation of the carbonate shells range
from as long as 5mm or more (Figure 2) to less than 1mm. There were carbonate shells present with
pyrite (FeS2) replacement on parts of the shells (Figure 3A). Closer observation of the pyrite
structures shows two different mineralogical structures: tiny circular structures which appear
framboidal (Figure 3B) and block shaped structures which seem to be replacing the carbonate
structures (Figure 3A). The carbonates also have assemblages where they form an ellipsoid shape
and possess a finer dark texture (Figure 3C). The dark texture could be micritic cement,
disarticulated carbonate debris, multiple carbonate shells together or another mineralogical feature.
The most surprising result was the presence of a darker outer layer on the underside of the larger
hook carbonates (Figure 3B). This could possibly indicate a chemical change in mineralogical
composition.
8
Figure 2: Chesapeake sample 10930 27P with Leica DMS 1000 depicting multiple pyrite and
carbonate rich areas (Scale bars = 5mm)
Darker outer layer
Figure 3A: Bowtie carbonate with
pyrite replacement
Figure 3B: Hook shaped carbonate
depicting both replacement and
framboidal pyrite
Finer dark matrix
SEM and EDXS
Figure 3C: Carbonate mass with finer dark matrix of
either micritic cement, disarticulated carbonate
debris, multiple carbonate shells together or another
mineralogical feature
Samples were analyzed to determine physical and chemical characteristics at a smaller scale
than what was possible with the Leica DMS1000. BSE images suggest that the sample is
mineralogically and texturally heterogeneous. This is much more noticeable in SEM images than in
the Leica images. For example, when comparing Figure 4A to Figure 4B the pyrite structures vary
more considerably in the SEM image (Figure 4A) than what was evident from the Leica (Figure 4B).
There are both framboidal and massive pyrite textures present with each other indicating two
9
different mechanisms of formation. The framboidal pyrite formations are often mixed with clay
matrix, Ca-phosphates, or quartz (Figure 4A and 4C).
Framboidal Pyrite
Ca-Phosphate
Figure 4A rotated 180°
Pyritohedrons
Figure 4A: Carbonate, framboidal
pyrite, pyritohedron, and Caphosphate assemblage with closeup
of the heterogeneous matrix
Figure 4B: Insert shows area of image 4A on
the Leica DMS1000
Figure 4C: Carbonate, framboidal pyrite, and
pyritohedron assemblage from figure 4 with Ca
and S map post laser ablation
SEM images also reveal the presence of barite in multiple areas throughout the sample. Most
barite was found as grain aggregates (Figure 5) or associated with pyrite, but is also barite present in
a barite/Ca-phosphate assemblage in one particular area (Figure 6A). Analysis with EDXS also
confirms the presence of strontium in barite in Figure 5. EDXS analysis with strontium however can
be difficult to determine due to silicon and strontium sharing very similar peaks. To confirm
strontium presence from silicon with EDXS results laser ablation was used. The presence of
strontium with barite indicates that the barite minerals could contain celestite in the form of a
barite/celestite solid solution (Figure 5). Strontium was found in some of the carbonate shells
10
sampled with EDXS. This is not unexpected because strontium can substitute for calcium in the
calcite crystal structure due to the similarity in ionic radii (within the 15% size difference), thus
satisfying Goldschmidt’s replacement rule to form strontianite. The highest concentration sampled
had an overall weight percent SrCO3 of .93%mol SrCO3 and the highest weight percent MgCO3 was
6.47% mol MgCO3 (Table 2). Weight percent values and elemental ratios were calculated
stoichiometrically based on EDXS observed weight percent.
Figure 5: Diagenetic barite replacement
texture present as indicated from
energy dispersive x-ray spectrometry
(EDXS)
Figure 6A: Closeup of barite and Caphosphate assemblage
11
Figure 6B: Ca & Ba map of figure 6a
this is Ba and P
Table 2: Bruker Spot analysis of four carbonate from Sites D, C, A, & B in that order
bowtie (Matt Edgin)
Element
Ca
Mg
Sr
C
O
atm
atm
O2
wt %
weight
prop.
Factor
44.01
40.078
1.098
0.781
0.975
7.724
25.311
24.305
87.62
12.0107
15.994
0.032
0.011
0.643
1.583
smaller shell 011
Element
Ca
Mg
Sr
C
O
atm
atm
O2
weight
prop.
Factor
41.356
40.078
1.032
0
11.294
40.28
24.305
87.62
12.0107
15.994
0.017
0.000
0.940
2.518
hook middle009
Element
Ca
Mg
Sr
C
O
calcite003
Element
Ca
Mg
Sr
C
O
0.061
0.021
1.219
1.896
3.000
total cations
2.164
wt %
0.415
0.305
10.64
30.28
24.305
87.62
12.0107
15.994
0.077
0.003
0.886
1.893
basis of 3
oxygens
1.229
0.020
0.000
1.120
1.191
3.000
total cations
1.250
atm
atm
O2
wt %
weight
prop.
Factor
44.538
40.078
1.111
1.875
basis of 3
oxygens
2.082
basis of 3
oxygens
1.761
0.122
0.006
1.404
1.585
3.000
total cations
1.889
atm
atm
O2
basis of 3
wt %
weight
prop.
Factor oxygens
41.168
40.078
1.027
1.273
1.18
24.305
0.049
0.060
0.338
87.62
0.004
0.005
9.813
12.0107
0.817
1.013
38.717
15.994
2.421
1.239
3.000
total cations
1.338
12
Mg/Ca
Sr/Ca
0.018
0.022
%MgCO3 %SrCO3
2.815
0.975
Mg/Ca
Sr/Ca
0.010
0.000
%MgCO3 %SrCO3
1.628
0.000
Mg/Ca
Sr/Ca
0.042
0.007
%MgCO3 %SrCO3
6.472
0.292
Mg/Ca
Sr/Ca
0.029
0.008
%MgCO3 %SrCO3
4.497
0.357
Multiple EDXS measurements were taken at laser ablation sites to calculate the weight
percent of the major cations. This was done to help calibrate the ICP-MS-LA calculations since the
areas examined with the EDXS were good representations for standard reference material. This
allowed for more accurate calculations.
Barite Estimation Calculation
Analysis of BSE images with ImageJ was done by selecting 10 BSE images using grayscale
values to identify barite. Results revealed that barite represented less than one percent of the total
mineralogy of the sample (table 3). Calculations were done by converting the images to 8-bit and
using the scale from the BSE SEM image as a known measurement. With the adjust threshold
feature on ImageJ, images that were known to contain barite, carbonate shells, and clay from EDXS
had grayscale values that could be quantified. This was done by adjusting the threshold value specific
to each mineral which highlighted them and allowed the same values to be used for other images
(200-240 for barite). Using the values for the grayscale threshold and the SEM scale ten images were
selected at random that contained representations of all three mineralogical features present. The
mineralogical features were highlighted with the adjust threshold feature to get an approximate area
and then divided over the total area of the image to get a percentage.
13
Table 3: Microscale bulk analysis barite with ImageJ
IMAGE
BARITE AREA
NUMBER
(μm )
IMAGE AREA
(μm )
BARITE % CALCITE
%
CLAY %
1
18,800
1,300,000
1.45
45.29
36.99
2
61.9
9,080
0.682
57.69
22.06
3
2,470
949,000
0.260
37.36
22.15
4
212
1,161,563
0.018
57.69
22.17
5
1,170
1,190,000
0.098
31.97
23.48
6
502
1,190,000
0.042
48.23
26.54
7
1,567
1,190,000
0.132
50.32
26.47
8
1,010
1,190,000
0.085
33.04
20.00
9
2,620
1,170,000
0.224
51.97
23.48
10
987
1,180,000
0.084
38.08
21.53
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
29,401
10,529,643
0.280
45.16
24.49
2
2
Induced Coupled Plasma Mass Spectrometry Laser Ablation
Laser ablation sites were chosen based on SEM analysis of potential strontium and barium
sources. Dresel and Rose, 2010 list typical concentrations of 580ppm Ba and 300 ppm Sr for shale’s
and 600ppm Sr and 10 ppm Ba for limestones for the Marcellus Formation. Several ablation lines
where done to analyze chemical concentrations across specific mineralogical and textural features.
Site A and B (Figure 7) show four ablation lines were done along the long axis of fossil carbonates
across the center, edge, and surrounding matrix. These sites were selected to observe concentrations
at specific sites within the shells. Sites C, D, and E (Figure 7, 8, and 9) had vertical ablation lines that
were drawn across the short axis of the carbonate shells to observe differences in trace elemental
compositions from the middle to the edge. It should be noted that because the NIST glass standards
for Ca, Na, Al, and Si were measured in oxides (CaO, Na2O, Al2O3, & SiO2) their concentrations
had to be calculated from weight percent to ppm from the mass spectrometer calculations. The
unavailability of matrix matched standard reference materials made calibration of the major cations
from Bruker EDXS necessary to improve the accuracy.
14
Figure 7: Leica image of the hook fossil carbonate assemblage with laser ablation sites
outlined A. Lengthwise carbonate traverse B. Lengthwise carbonate traverse bulge C. Hook
carbonate vertical slice
Laser Ablation Site
Figure 9: Leica image of carbonate
and pyrite assemblage with laser
ablation site E outlined
Figure 8: SEM image of bowtie
carbonate with laser ablation site
D outlined
Carbonate Shell Site A Center
The bright green areas as indicated from Figure 10 show a large carbonate shell that is
greater than 5mm long (Figure 7). The carbonate shell, although fairly uniform does contain some
grains of Si (Figure 10 blue) which could indicate quartz (SiO2), albite (NaAlSi3O8), or clay as well as
S(Figure 10 fuchsia) which probably correlates with pyrite. These color changes on the carbonate
structure (green Figure 10) from green to cyan and fuchsia indicate avenues for mineral replacement
from fluids. Overall, the large Ca signature (Figure 10 green) suggests that the structure is largely
calcite. It should also be noted here that there are red regions signifying higher concentration of Mg
(Figure 10 red) which are probably either dolomite or high-Mg calcite. This could be from further
alteration during diagenesis from dolomitization.
15
Transect
1
2
3
4
Figure 10: Stitched image of Ca, Si, Mg, & S maps of Site A post laser ablation
The long axis laser ablation lines in the carbonate shells were fairly uniform for Ca, Mg, and
Sr throughout and had clear drops where inclusions are shown to occur from SEM images. Barium
showed highest concentrations in the inclusion areas (350 ppm) as compared to the carbonate and
pyrite areas (cyan spots in Figure 10 and Figure 11). These areas could be secondary albite or quartz.
Strontium was fairly uniform with concentrations ranging between 3200-3600ppm (Figure 12). The
strontium spike at about 1000 μm appears to occur right around a fracture or inclusion which
represent a change in mineralogy. Sodium was fairly uniform with its concentrations slowly
decreasing with distance from 1560ppm to about 1480ppm with the exception of a spike around
1000 μm which could indicate a mineralogical change.
All measurements were done along Transect 1 as indicated in Figure 10. Strontium has a
strong correlation with calcium and magnesium in the carbonate shells (Figures 11 and 12). When
comparing barium to calcium and sodium concentrations, there appears to be an inverse correlation.
The barium spikes seem to occur where the silicon spots in Figure 10 are highlighted. The inverse
correlations in these areas could be related to a change in mineralogy from carbonate to illite or
albite. Overall, the inverse correlation appears to be stronger with calcium than sodium because
spikes with barium do not always align with decreases in sodium (Figure 10). Areas where both
barium and sodium spike together could be related to mineralogy because both can be present in
feldspar or illite. This indicates a mineralogical change and/or geochemical relationship between
barium and both calcium and sodium. The position-timing of the barium spikes with the SEM image
may be slightly off due to the mass spectrometer calculating the peak hop slightly later than when
the sample was ablated.
16
Barite Signals from inclusions
Figure 11: Lengthwise carbonate shell traverse ICP-MS-LA for Na & Ba
Mineralogical Change
Figure 12: Lengthwise carbonate shell traverse ICP-MS-LA for Sr
17
Mineralogical Change
2
2
1
1
0
Concentration Ca (ppm)
4
3
Concentration Mg (ppm)
4
3
0
Figure 13: Lengthwise carbonate shell traverse ICP-MS-LA for Ca & Mg
Carbonate Shell Edge Site A
The next set of measurements targeted the edge of the carbonate shell and there is a clear
change in mineralogy from the edge to the center of the shell. Although, for the edge and matrix
laser ablation lines there is a large proportion of carbonate present it is more diverse mineralogically
than the center of the carbonate shell. Spikes in sodium that correlate with barium indicate a feldspar
presence whereas spikes in barium and decreases in sodium could indicate aluminosilicate clays.
There is also more magnesium present here as indicated from magnesium spikes and EDXS which
indicates dolomite, dolomite cements or high-Mg calcite (Figure 14). All measurements for calcium,
magnesium, barium and sodium were made along Transect 3 while strontium was measured along
transect 2 and 3.
Barium concentrations seem to show an inverse correlation with calcium and sodium but it
is not consistent throughout the run. This could be due to feldspar presence causing a spike in both
sodium and barium or aluminosilicate clays containing both calcium and barium. The magnesium
concentrations have lower concentrations in the carbonate shell in Figure 11 (approx. 17,000 ppm)
avg.) compared to outside it in Figure 12 (up to 75,000 ppm). When comparing Figure 12 with
Figure 10 the spikes seem to correlate with the red Mg grains from the SEM EDXS elemental image
which suggests high-Mg calcite, dolomite, or dolomite cement as the calcium signal also increases
slightly with the magnesium during the spikes.
The strontium does not vary much but its average concentration (4000ppm) is
approximately 800ppm more on the edge than in the middle of the shell (3200ppm) (Figure 15 and
16). It should be noted that for the strontium laser line there was an error and data were not
recorded for the entire line. The strontium was also collected on two different lines with minor
elements (Mn, Mo, U, Th, Ce, La, Ni, Zn, & Rb) and also major cations (Ca, Al, Mg, Na, Ba, and
Ti). This means that for that particular line strontium concentration relationships with major cannot
18
be constrained. Barium concentrations average 150 ppm, and are higher on the edge and in the
matrix (Figure 17) than in the carbonate shells (Figure 13; approximately 70ppm avg.). The calcium
concentrations seem to be higher in the middle structure (400,000 ppm) than on the edge and within
the matrix (300,000 ppm).
4
3
2
1
0
4
3
2
1
0
Figure 14: Lengthwise carbonate shell traverse edge ICP-MS-LA for Ca & Mg
Possible Mineralogical Change
Figure 15: Lengthwise carbonate shell traverse edge ICP-MS-LA for Sr
19
Concentration Ca (ppm)
Concentration Mg (ppm)
Magnesium spikes from High-Mg
Calcite, Dolomite, or Dolomite Cement
Carbonate rich areas
Figure 16: Lengthwise carbonate shell traverse edge ICP-MS-LA for Al & Sr
Figure 17: Lengthwise carbonate shell traverse edge ICP-MS-LA for Na & Ba
Short Axis Carbonate Shell Site C
The bright green areas indicated from Figure 18 show the same carbonate shell as in Figure
10. The difference for site C is that the carbonate structure was ablated along the short axis to see
chemical changes from the edge vs the middle. From the SEM EDXS images this area has S signals
from EDXS (Figure 18 fuchsia) which probably correlate with pyrite. There are two different
structures present: pyritohedron and framboidal. Overall, the bright solid Ca signal (Figure 18 green)
suggests that the structure is largely calcite. The elemental maps also show areas of Mg (Figure 18
red) which are probably dolomite, dolomite cement, or high-Mg calcite. Both the magnesium and
sulfur signals indicate alteration during diagenesis (secondary).
20
Clay Matrix
Transect
1
2
3
Pyritohedron
Structure
Framboidal
Pyrite +
Mg-Grains
Dolomite Grain
Figure 18: Stitched image of Ca, Mg, & S maps of Site C post laser ablation
Short axis laser ablation lines were taken across the hook carbonate structure (site C). All
laser ablation measurements were made along Transect 2. The strontium and calcium signals show a
strong correlation with each other (Ca in Figure 19 with Sr in Figure 20). This is due to the bright
green areas in Figure 18 being carbonates as indicated by EDXS. Spikes correlated with areas that
were carbonate rich while drops correlated outside the carbonate rich areas in the clay matrix. The
aluminum signals were used to differentiate between the carbonate and the clay or feldspar in the
fine-grained matrix and seem to show an almost uniform inverse correlation with calcium to signify
this mineralogical change.
Strontium and calcium concentrations are highest in the carbonate structures (green in
EDXS elemental map image Figure 18) (4,000-6,000ppm) with the highest numbers being located in
the center of the shells. Barium had higher concentrations in the clay matrix (120-300ppm) than in
the carbonates (100-200ppm) (Figure 21). Sodium was fairly uniform throughout the run (around
1750ppm) with only a few areas that showed only slight spikes. The concentrations of magnesium
stayed between 11,000 and 40,000ppm relatively consistently throughout the line. It is only at about
500 μm that we see a big spike and there is also a slight increase with the Ca signal with it.
Barium has an almost inverse correlation with strontium, calcium, and sodium. This is due to
mineralogical changes from carbonates to clay matrix for strontium and calcium and albite and
aluminosilicate clays with sodium. The spike in Mg at about 500μm (110,000ppm) shows a clear
mineralogical change to dolomite or dolomite cement as indicated by rhombohedral grain shape in
Figure 19. The spike in magnesium at 500 μm correlates with an increase in Calcium.
21
11
4
8.25
3
5.5
2
2.75
1
0
0
Concentration Ca (ppm)
Concentration Mg (ppm)
Rhombohedral grain
10000
2
8000
1.6
6000
1.2
4000
.8
2000
.4
0
0
Figure 20: Hook carbonate vertical Slice with Clay Matrix Al & Sr
22
Concentration Al (ppm)
Concentration Sr (ppm)
Figure 19: Hook carbonate vertical Slice with Clay Matrix Ca & Mg
Figure 21: Hook carbonate vertical Slice with Clay Matrix Ba & Na
Bowtie Carbonate Short Axis Site D
The bright green areas as indicated from Figure 22 show the bowtie carbonate shell as well
as an additional pyrite-carbonate assemblage (refer to Figure 8). At this site the carbonate structure
was ablated along the short axis to observe chemical changes from the edge vs the middle. However,
the pyrite structures here are much larger than those present from Figure 18. From the SEM EDXS
images this area has S signals from EDXS (Figure 22 fuchsia. There appears to be two different
structures present: pyritohedron and framboidal. Overall, there is a bright solid Ca signal (Figure 22
green) around the pyrite areas which suggests calcite. There are also small fuchsia spots that show S
signatures from EDXS which could indicate pyrite, barite, or celestite. There are also more red
regions indicating Mg (Figure 22 red) which are probably dolomite, dolomite cement, or high-Mg
calcite.
Barite
Transect
1
2
Clay Matrix
Pyritohedron
Pyrite
Framboidal pyrite
23
Figure 22: Stitched image of Ca, Si, Mg, & S maps of Site D post laser ablation
Short axis laser ablation lines were taken across the bowtie carbonate structure (site D) as
well as across the hook carbonate (Site C). In site D there are carbonates with two different pyrite
structures: framboidal pyrite and pyritohedron (Figure 19). Data shows similar trends to the long
axis laser ablation lines across the carbonate shells.
15
12.5
10
6
Pyrite
Concentration Ca (ppm)
Concentration Mg (ppm)
All laser ablation measurements were done with Transect 1 (Figure 22). Calcium was highest
in the carbonate shells (300,000-400,000 ppm) while magnesium was highest in the clay matrix
(Figure 23). Strontium was typically highest in the carbonate shells (3000–4000 ppm) with the
exception of a small piece of barite (3000 ppm) (Figure 22 circle). Barite identification was
confirmed by observing peaks for both strontium and barium at the same time and a sulfur peak
from the EDXS map (Figure 24 & 25). Barium shows a correlation with strontium and no
correlation with sodium in the clay matrix (Figures 24 and 25). This could be due to most sodium
existing in albite and therefore means the barium in the matrix area must be in the clays. This
correlation is suggestive of a relationship with aluminosilicate clays versus carbonates and the
presence of barium and strontium.
5
Pyrite
4
7.5
3
5
2
2.5
1
0
0
Barite
Framboidal pyrite
Pyritohedron
Pyrite
Clay Matrix
Figure 23: Bowtie carbonate vertical slice with clay matrix Ca & Mg
24
4000
3000
2
Pyrite
Pyrite
Concentration Al (ppm)
Concentration Sr (ppm)
5000
1.6
Barite
1.2
2000
.8
1000
.4
0
0
Barite
Framboidal pyrite
Pyritohedron
Pyrite
Clay Matrix
Figure 24: Bowtie carbonate vertical slice with clay matrix Al & Sr
Pyrite
Pyrite
Barite
Barite
Framboidal pyrite
Pyritohedron
Pyrite
Clay Matrix
Figure 25: Bowtie carbonate vertical slice with clay matrix Na & Ba
Molar Sr/Ca vs Mg/Ca
The relationship between strontium and magnesium exhibits an interesting correlation for all
areas interrogated. The strontium concentrations are higher when the magnesium ratio is less than
0.0425 mol Mg/Ca (Figure 26). However, once the Mg/Ca ratios exceed 0.0425 mol Mg/Ca the
25
Sr/Ca ratios decrease from 0.007 to 0.005 (Figure 26). This could be due to magnesium’s smaller
ionic size causing a deformation in the calcite crystal structure that enables larger elements like
strontium to fit. Therefore, magnesium had a positive influence on strontium accommodation in the
carbonate structure to a certain extent. The decrease after .0425 Mg/Ca could be the point where
magnesium alters the crystal structure to something less accommodating to strontium like dolomite.
Ratio Trend
Figure 26: Molar Sr/Ca vs Mg/Ca
26
DISCUSSION
Barium
Results indicate that, other than barite (up to 500,000 ppm), barium is most concentrated in
the clay matrix (approx. 150-600 ppm). Barium concentrations are as much as 70-400 ppm greater in
the clay matrix areas than over the pyrite areas and carbonate shells. This is due to the high surface
area to volume ratio of the clay matrix, and to barium’s ability to be absorbed during authenigenic
diagenesis of aluminosilicate clays. The concentrations observed for source rock’s potential for
barium are within Dresel and Rose’s values for shale’s (580ppm Ba) and well above the values for
limestone (10 ppm Ba) (Dresel and Rose, 2010). Although there is barite in the sample, it than 1%
(by volume) from ImageJ analysis suggests that the clay matrix (21.8% Table 1) would be a better
source despite having lower concentrations of barite (0.025–0.05weight percent clay versus 60
weight percent in barite) (Table 2). Using the values from Table 2 the total percent of barium in the
sample should be 1.36 percent or 0.034g/cc of the sample. The highest amount of barium coming
from the clay matrix (67.6%) over barite and the carbonates (Table 4). This means the barium in
flowback water should be related to dissolution mechanics of the clay matrix.
Table 4: Calculations of barium in bulk mineralogy from Table 1 and Table 3 data
bulk density 2.468 g/cc
sample
wt % ba
percent from
table 2
den. mineral-x
sample
den. Ba
in
sample
% in
mineral
from total
barite
60
0.0279
0.000689
0.000413 0.957
calcite
.8
45.16
1.11
0.009
20.7
clay
5.6
24.49
0.604
0.034
78.4
Total
total in
rock
1.72 g/cc
0.04g/cc
Barium Mobilization
One mechanism for barium mobility could be a result of the leaching of salts involved in the
drilling process. Laser ablation results exhibited an inverse correlation between barium with calcium
and sodium in the clay matrix (Figures 11, 13, 14, 16, 19, 21, 23, and 25). These elemental
differences are directly related to changes in mineralogy. Most likely the barium decreases and
associated sodium increases are related to sodium from albite whereas the opposite is true for the
aluminosilicate clays. The higher values of barium and overall greater volume of the clay matrix
27
versus barite suggest mobilization might be related to higher overall abundance of barium liberated
from aluminosilicate clays (Table 4). This hypothesis has been supported in previous studies which
show that under high ionic strength conditions a large inflow of Na+ and Ca2+ will be preferentially
accommodated in the in the clay structure (Renock et al., 2016). In fact, when using fluids that are
identical to the ionic strength of hydraulic fracturing fluids “between 5 and 25% of the total Ba in
the rock can be leached from shales over a contact time of 7 days” (Renock et al., 2016 pg. 81).
Therefore, barium in my sample can have as much as 0.026 g/cc or up to 435ppm using Dresel and
Rose (2010) values. Therefore, barium in flowback waters from the Utica/Point Pleasant formation
could be a result of the high ionic strength of the reactive fluids if fluids can access pores within the
clay matrix. Another factor to consider as a barium source is flowback fluids interacting with brines
and formation waters in the subsurface. However, the bulk of barium should still be from
aluminosilicate clays as indicated from laser ablation results and barium calculations from Table 2
and 4.
Strontium
Results from this study indicate that, strontium concentrations are highest in the carbonate
structures and more on the outer edge (800ppm more) than the middle of the carbonate (Figures 11
and 12). Strontium was also present in high concentrations in barite (3000ppm), which is likely due
to the mineral being a barite/celestite solid solution. This was also observed in barite with EDXS
analysis of barite. Strontium concentrations were typically 4,000 ppm more in the carbonate shells
compared to pyrite rich areas. Although strontianite (SrCO3) and celestite (SrSO4) are present from
SEM/EDXS analysis, they are not present in significant quantities to explain high strontium
presence in flowback waters from hydraulic fracturing. Because the bulk mineralogy of the sample is
49.5% calcite and 21.8% clay by weight, calcite dissolution could be a key reason behind the high
strontium levels from flowback waters (Table 1).
Using molar Sr/Ca values from Figure 26 and the molar Sr/Ca ratio of the seawater they
formed in was calculated. This was done using Kd or the ratio of the measured difference in molar
Sr/Ca. Using proposed Kd values from Banner (1995) Kd values for calcite (.14) and high-Mg calcite
(0.146) resulted in the molar Sr/Ca aq values range from 0.089-0.023 with an average of 0.039 mol
Sr/Ca for low-Mg calcite and 0.085-0.022 with a 0.03 average mol Sr/Ca for high-Mg calcite. Kd
values greater than 1 indicate that the mineral phase favors incorporation of the trace element
(Banner, 1995). With the Kd values being well below this and the Sr/Ca ratios of the seawater values
being significantly higher, strontium is going to favor being in a liquid phase over a solid unless the
water is enriched in strontium (Banner, 1995). Therefore, strontium is susceptible to being
mobilized, especially, in an acidic environment (Stewart et al., 2015).
28
Table 5: Sr/Ca ratios relation with Kd
Kd Low-Mg calcite
Kd High-Mg
Calcite
Sr/Ca
calcite
Molar Sr/Ca aq
Low-Mg calcite
Molar Sr/Ca aq HighMg calcite
0.14 (Banner,
1995)
0.146 (Banner
1995)
Max
Max
Max
0.013
0.089
0.085
Min
Min
Min
0.003
0.023
0.022
Avg.
Avg.
Avg.
0.005
0.039
0.037
The presence of the strontium ions in clays and carbonates can be explained by the ionic size
and charge. The Sr2+ ion is approximately 1.18 Å which is within the 15% size difference required
for Goldschmidt’s replacement for calcium and potassium. The clay matrix can contain strontium
for the same reason as it can for barium, in that the matrix has a high surface area to volume ratio.
This allows the sorption of strontium ions on folia rather than incorporation into the crystal
structure. Unlike barium, strontium is much more soluble, making it more mobile.
Carbonate Crystal Structure Effects on Strontium Accommodation
Upon closer examination of carbonates as a key source of strontium, the crystal structure of
CaCO3 needs to be taken into consideration. Aragonite (CaCO3) with its orthorhombic crystal
structure and nine coordination number (CN Ca with respect to O = 9) is well known as a favorable
polymorph of CaCO3 and can accommodate strontium. Its crystal structure has more space to
accommodate larger elements like strontium than does calcite (CN Ca with respect to O = 6 and
hexagonal crystal structure). In fact, strontianite is a member of the aragonite group. Aragonite’s
larger overall crystal structure as indicated by its coordination number creates Sr-O bond distances
that are 3.0% shorter than for calcite (Finch and Allison, 2007). This results in strontium
incorporation in aragonite causing only a small 2% dilation of the Ca-site versus a 6.5% dilation in
calcite, indicating a higher Sr preference for aragonite than calcite (Finch and Allison, 2007). This
would make aragonite based carbonates an effective sink for strontium to accumulate, and would
explain the high strontium levels in flowback waters from the Utica/Point Pleasant formation.
Aragonite although favored biogenically, is naturally unstable under normal temperature and
pressure conditions and will recrystallize to calcite unless it is in a high pressure system. The
recrystallization process during diagenesis could force strontium into a calcite crystal structure that
would be ideal to mobilize strontium, once fluids are introduced via hydraulic fracturing (Stewart et
al., 2015).
According to Adabi (2004), Stanley and Hardie (1998), and Banner (1995), an aragonite
based sea was not present during the late Ordovician when the Point Pleasant was formed. Laser
ablation results support this, as strontium concentrations only reach as high as 4000 ppm which is
29
not a high enough value for a recrystallized calcite based carbonate from aragonite (7000–9000ppm)
(Figure 12) (Swart, 2009; Banner, 1995). Previous studies using sea level height, Mg/Ca ratios, and
paleotemperatures argue that calcite seas were present (Stanley and Hardie, 1998; Adabi, 2004).
Seafloor spreading in the late Ordovician created lower levels of magnesium and an increase of
calcium in the seawater. Aragonite seas show a strong correlation with magnesium levels and an
inverse correlation with sea level (Stanley and Hardie, 1999; Adabi, 2004). Therefore, the conditions
present during the creation of the Point Pleasant Formation prohibited the production of aragonite.
Magnesium’s Influence on Strontium incorporation with Calcite
Although previous research and laser ablation results favor calcite over aragonite crystal
structure, calcite structure’s is affected by many factors that cannot be ignored. One clear influence
is the magnesium concentration relative to strontium. Examination of data in Figure 26, reveals an
interesting relationship between Mg/Ca molar ratios with Sr/Ca. The Sr/Ca ratios increase with
Mg/Ca ratios until the Mg/Ca ratios reach 0.0425Mol. At this point, the Sr/Ca ratios drop and level
out between 0.006 to 0.004 mol. A definite effect can be seen between the amount of magnesium
incorporated into the crystal structure and the amount of strontium that the calcite contains. Since
larger coordination numbers of calcite (CN Ca with O=6 vs 7 or 8) do not correlate with generating
better fits with strontium, the amount of magnesium incorporation into the crystal structure is a
significant factor (Finch and Allison, 2007).
Evaluation of geochemical relationships with strontium and magnesium in calcite show a
complex relationship with regard to each element’s size. Previous studies with inorganic calcite
conclude that “the incorporation of small magnesium ions (0.65Å) causes a deformation in the
crystal lattice where cations larger than calcium (0.97Å), like strontium (1.13Å) are more easily
accommodated” (Wienbauer & Velimirov, 1995 pg. 101). Essentially, the smaller magnesium ions
incorporated into the calcite crystal structure cause the structure to shrink in some areas to
accommodate the magnesium, which in turn can cause other areas to expand. This distortion allows
for larger areas such as the Ca-site to accommodate larger ions like Sr2+ (Allison and Finch 2007). In
addition to the Ca-site in calcite, magnesium has more than one site it can occupy in the crystal
structure. It is magnesium’s incorporation into these other sites such as the nano-domains based on
Transmission Electron Microscopy (TEM) studies that allow this process to occur (Allison and
Finch 2007). It should be noted that magnesium’s relationship with strontium concentrations is not
always preserved for biogenic calcite. In Wienbauer and Velimirov’s study, they claim that high
mineralization rates could have been the cause for this distortion, as higher rates reduce strontium
levels in carbonates. However, there is still debate among scientists over how much crystallization
rates influence strontium levels.
Laser ablation results support magnesium influence on crystal structure as strontium levels
reach as high as 4000ppm. This values is within those reported for source rock values containing
high-Mg calcite from Swart (Swart, 2015). EDXS analysis did show some carbonate shells reaching
as high as 6.47%mol MgCO3, but it was not present in sufficient quantities to suggest high-Mg
calcite as a factor for strontium levels (Table 2).
Despite high-Mg calcite’s presence from laser ablation its relationship is more complex than
simple positive correlations of strontium with magnesium in calcite. It is possible that the
magnesium content in the carbonates could be higher due to alteration from diagenesis. However,
more magnesium is not necessarily a good thing for strontium accommodation. When observing
30
Figure 26 it is clear that once the molar Mg/Ca ratio exceeds 0.0425, the strontium levels drop. This
could be due to magnesium either distorting the crystal structure too much or recrystallization to
dolomite. In SEM/EDXS elemental maps (Figures 10, 13, and 15), magnesium signals were
commonly present, indicating dolomitization could have occurred on a large scale. Dolomitization
further reduces strontium levels in carbonates because strontium does not fit ideally into the
dolomite crystal structure (Allison and Finch, 2007). Therefore, further research needs to be done
into magnesium’s influence on the calcite crystal structure to understand how this geochemical
relationship between strontium and magnesium works.
31
CONCLUSIONS
The high levels of barium and strontium from fluids associated with hydraulic fracturing are
supported by the mineralogical and textural features of sample JP 73 Point Pleasant Formation.
Laser ablation results show barium is concentrated in the aluminosilicate clays of the formation due
to the high surface area to volume ratio. Based on results reported by Renock et al. (2016), waterrock interactions could cause Ba2+ in the clays to exchange with Na+ and Ca2+ ions during the
hydraulic fracturing process due to high ionic strength conditions. The replacement of barium for
sodium and calcium was noted from laser ablation results showing inverse correlation of barium
with sodium and calcium.
Laser ablation results show that the highest strontium levels are concentrated in the
carbonates. The concentrations of strontium in the carbonate structures are indicative of high-Mg
calcite. Research on Ordovician rocks suggests that oceans during that time in geological history had
high sea levels, high sea floor spreading rates, and lower magnesium levels than present day, in the
seawater to support calcite over aragonite seas. Mineralogy of the samples being predominatly calcite
(49.5%) had higher magnesium concentrations which lead to a scenario of elevated strontium
concentrations. However, influences from other processes like water-rock interactions with
subsurface brines enriched in strontium cannot be ruled out. Data are lacking on indigenous basinal
fluids in the Pt. Pleasant Formation from eastern Ohio and western Pennsylvania. The high mobility
and concentrations of strontium from flowback waters show promise for strontium application as a
fluid flow tracer (Haeri-Ardakani et al., 2013).
32
RECOMMENDATIONS
FOR
FUTURE WORK
Additional analysis of core samples of the Utica/Point Pleasant formations from wells at
different depths, and levels of thermal maturity across the basin must be examined. This should be
done so that the results from my study can be compared with other areas to ensure that data analysis
from this study is a good bulk representation of the formation as a whole. In addition, other regions
should be observed within samples for elemental analysis such as different shell types, grains,
dolomite, and micritic carbonate among other areas.
Isotope analysis of the formation could yield more useful information with δD, TOC,
C/12C, δ18O, δ11B, and 87Sr/86Sr. Carbon isotopes can tell us sources and sinks for methane while
TOC can tell us source rock quality. Strontium isotopic composition of the subsurface brines could
help to identify source of strontium, constrains in water-rock interactions, and may be used to trace
the fluid migration pathways. Hydrogen and oxygen data could provide information on the origin
and chemical evolution of subsurface water. Boron can help distinguish between marine and nonmarine solute sources which might be useful for source indication. Isotopic evidence could reveal
some interesting results and have not been done extensively in the Utica/Point Pleasant formations.
13
33
REFERENCES CITED
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19, p. 133-141, doi: 10.1007/BF03178476.
Almirall, J., Naes, B., and Cahoon, E., 2012, Elemental Analysis of Glass by SEM-EDS, XRF, LIBS
and LA-ICP-MS
Banner, J.L., 1995, Application of the trace element and isotope geochemistry of strontium to
studies of carbonate diagenesis: Sedimentology, v. 42, p. 805.
Dresel, P. E., and Rose, A. W., 2010, Chemistry and origin of oil and gas well brines in western
Pennsylvania: Pennsylvania Geological Survey, 4th ser., Open-File Report OFOG 10–01.0
Drozd, R.J., and Cole, G.A., 1994, Point Pleasant-Brassfield (!) Petroleum, Appalachian Basin,
U.S.A.: Chapter 24: Part V. Case Studies-- Western Hemisphere, in Memoir 60: The Petroleum
System--From Source to Trap: Houston, TX, AAPG, p. 387-388-398.
Finch, A.A., and Allison, N., 2007, Coordination of Sr and Mg in calcite and aragonite: Mineralogical
Magazine, v. 71, p. 539-552, doi: 10.1180/minmag.2007.071.5.539.
Haeri-Ardakani, O., Al-Aasm, I., and Conglio, M., 2013, Fracture mineralization and fluid flow
evolution: an example from Ordovician-Devonian carbonates, southwestern Ontario, Canada:
Geofluids, v. 13, p. 1-20, doi: 10.1111/gfl.12003.
Haluszczak, L.O., Rose, A.W., and Kump, L.R., 2013, Applied Geochemistry Geochemical
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10.1016/j.apgeochem.2012.10.002.
Hammes, U., 2015, EMD Shale Gas and Liquids Committee 2015 EMD Shale Gas and Liquids
Committee Mid-Year Report: p. 1-138.
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Upper Devonian Woodford Shale , Permian Basin , west Texas : Insights into metal abundance and
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health impacts of barium from natural and anthropogenic exposure: Environmental Geochemistry
and Health, v. 36, p. 797-814, doi: 10.1007/s10653-014-9622-7.
McClain, T., 2012, Sequence Stratigraphic Interpretation of the Utica Shale and Associated Late
Ordovician Strata, Eastern Ohio and Western Pennsylvania *: v. 50613, p. 1-4.
Patchen, D.G., Laughrey, C., Kostelnik, J., Drahovzal, J., John, B., Lake, P.D., Bocan, J., Wickstrom,
L., Smith, T., and Lee, K., 2004, Creating a Geologic Play Book for Trenton-Black River
Appalachian Basin Exploration: .
Pearce, N.J.G., Perkins, W.T., Westgate, J.A., Gorton, M.P., Jackson, S.E., Neal, C.R., and Chenery,
S.P., 1997, A Compilation of New and Published Major and Trace Element Data for NIST SRM
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10.1111/j.1751-908X.1997.tb00538.x.
34
Renock, D., Landis, J.D., and Sharma, M., 2016, Reductive weathering of black shale and release of
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10.1016/j.apgeochem.2015.11.001.
Rozell, D.J., and Reaven, S.J., 2012, Water pollution risk associated with natural gas extraction from
the Marcellus Shale: Risk Analysis: An Official Publication of the Society for Risk Analysis, v. 32, p.
1382-1393, doi: 10.1111/j.1539-6924.2011.01757.x.
Stanley, S.M., and Hardie, L.A., 1998, Secular oscillations in the carbonate mineralogy of reefbuilding and sediment-producing organisms driven by tectonically forced shifts in seawater
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http://dx.doi.org.proxy.lib.ohio-state.edu/10.1016/S0031-0182(98)00109-6.
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the calcite sclerites of Mediterranean gorgonians (Coelenterata: Octocorallia): Estuarine, Coastal and
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Wickstrom, L.H., 2013, Geology and Activity of the Utica-Point Pleasant of Ohio, Search and
Discovery, p. 1-49.
35
APPENDICES
SEM Images of Laser Ablation sites
Site E
Figure 1: SEM images of Laser Ablation Site E
36
Figure 2: Elemental maps of laser ablation site E
Site B
Figure 3: SEM BSE image of Site B
37
Figure 4: Elemental maps of laser ablation site B
Other Mineralogical Images
Figure 5: SEM image and Elemental map of a Sphalerite mineral
Figure 6: SEM Images of Pyrite framboidal structures
38
Figure 7: SEM Image of pyritohedron structure from bowtie carbonate
Figure 8: SEM images of Ca-phosphate structures with different textures
Laser Ablation Raw Data
39
Zn64(LR) Rb85(LR)
Sr88(LR)
Mo98(LR) La139(LR) Ce140(LR) Th232(LR) U238(LR)
511,686 413,373 1,454,630 1,578,339 323,729 1,317,153 1,702,166 1,335,839 2,275,608
Mn55(LR) Ni58(LR)
1,092,207
Na23(LR)
121,763
Mg24(LR) Ca43(LR) Sr88(LR) Ba138(LR) Al27(LR)
Ave net signal
861,030 565,677 1,983,331 2,089,212 452,513 1,621,539 2,039,395 1,743,885 2,955,042
75,818 356,626 325,537 2,224,106 51,901,429
NIST 610 End
1,714,247
388,392
227,869 130,332 605,362 547,681 4,075,508 88,951,114
138,730
Ave net signal
230,714
NIST 610
133,123
115,718
63,635
198,410
327,288
52,654 4,435,973 118,242,940
236,832
44,426 131,214
91,706
Ave net signal
95,761
NIST 612
Table 1: NIST 610 and 612 standard data from Sites A, B, C, & D
40
Bowtie Carbonate
bowtie carbonate major
Ave blank
21,292
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
um/s
0.95
1.83
2.71
3.59
4.47
5.35
6.23
7.11
7.98
8.86
9.74
10.62
11.50
12.38
13.26
14.14
15.01
15.89
16.77
17.65
18.53
19.41
20.29
21.16
22.04
22.92
23.80
24.68
25.56
26.44
27.32
28.19
29.07
29.95
30.83
31.71
32.59
33.47
34.35
35.22
36.10
36.98
37.86
38.74
39.62
40.49
41.37
42.25
43.13
44.01
44.89
45.77
46.65
47.53
48.40
49.28
50.16
51.04
51.92
52.80
53.68
54.56
55.43
56.31
57.19
58.07
58.95
59.83
60.71
61.58
62.46
63.34
64.22
65.10
65.98
66.86
67.74
68.61
69.49
4,157
45,682
7,579
13,047
44,199,386
3,253
Mg24(LR)
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
10 Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
22477
21201
21838
22476
21681
20402
21360
20724
20883
21999
21681
22158
20561
21361
21679
20563
20563
21520
20883
19926
20722
21201
20722
20084
1368054
4129041
4965909
3447494
5145243
4426888
3533116
2876600
3306544
5335109
5148271
3196069
3700673
4901120
6526856
5947339
4549141
3014802
3458991
3991576
2687154
3599750
3692711
3070434
2511165
1362636
1531789
2560107
3883035
3567877
3621092
2811035
2099993
816754
413235
194982
95338
64088
41449
73654
56276
2172388
6619168
6780620
3884179
2832402
2773413
2263416
3070764
3620659
3861031
3485281
11368019
21116688
24611188
4455
4261
4517
4455
4262
4326
4262
4006
4326
4134
4070
3816
4261
4006
4070
4135
4070
3752
3943
3879
4006
4070
3879
4261
237971
364375
310630
610173
827126
286049
187726
124938
176455
291460
148752
284140
263952
215427
434231
454546
225553
119079
158306
346098
243766
399208
265924
206576
243512
138693
88896
187282
284519
479570
534143
422514
302599
103923
49668
35787
27126
18654
8528
10504
16426
312028
679906
604570
217020
202182
252998
187536
258475
366159
218802
196449
171805
295538
284010
49160
48520
48010
47247
47056
46546
46865
47438
46039
45528
45783
44889
44444
43808
45401
44191
44318
43999
43174
43872
43365
43555
43299
44001
1744631
1737502
1878165
3813641
5166992
1516972
938955
632526
1359367
1566333
1000279
1785579
1461448
1062747
1879246
3115662
1145273
882592
1430045
1905294
1492838
3026198
1240409
1357898
1297211
1064591
1370891
1316378
1763601
3044945
4290086
2846673
2365688
907432
546372
447473
298593
171424
76476
63104
297830
2495165
4297717
2687650
1242965
1154952
1323838
1192586
1430109
2720185
1475146
1117698
1008432
1417816
1619250
41
7892
8083
7447
7828
7828
7574
7574
7383
7510
7256
7638
7892
7638
7256
7765
7956
7002
7765
7892
7320
7129
7129
7638
7321
213708
351894
306427
134873
189637
331197
335977
403666
333044
362400
393984
427927
346159
259113
219887
278471
341385
352723
327886
290250
338966
246694
316422
244847
215109
325341
430539
412895
271911
192948
251280
193584
122771
66033
30139
14007
18401
8784
8083
8657
36613
124938
210460
142132
280254
292862
190975
250578
231920
535354
388827
226635
432195
296046
479821
16418
13708
14186
13547
12910
12751
13709
13390
13229
13070
13390
12115
12433
14027
12913
12272
12910
13709
12911
12274
13388
12433
13229
12911
6251800
16474648
15401185
5978525
2150830
17888972
23180482
21012698
23006082
17941374
22328326
18013616
19880628
16931098
13403884
16489707
20885714
23141004
26070690
15659427
18095322
11098788
11155361
18865876
13551981
12094819
16333317
21302584
16410444
13610233
6795298
2468748
445284
318379
166123
27740
21520
23274
18650
19608
18811
29492
412283
3489084
14891825
17220170
17255478
25333716
21722404
14444328
18480852
19364450
15392333
15314291
9531075
44558972
45378668
45282820
45024580
44910212
44708544
44688396
44463936
44361984
44268780
44078100
44036584
43835528
43763896
43550628
43571996
43528244
43435040
43374600
43331460
43155840
43173744
43088480
42929952
43956612
46070164
44892912
44119412
44482864
44851604
46233168
44391696
44472484
44910620
45572808
46272440
44805208
44724824
49132224
45296660
44753924
44659296
46637316
45067516
50152576
46426488
44639556
44548796
47342240
51995472
46582984
45884776
44384164
43662148
43338580
43444400
43472280
44556732
44646272
45091736
44962920
43103132
42838176
43216280
42316604
42895968
43599876
43719940
46236420
45206100
47167028
59966160
51502392
46763688
47320464
48248832
43905736
43333088
42908588
3186
2866
3343
3343
3502
3025
3661
2865
2549
3661
3345
3025
3184
3345
3343
2865
3824
3184
2865
2547
3663
3345
3186
3025
35708
80667
85292
41129
30927
110480
146356
91670
214432
109206
126106
91670
91670
106497
65522
74769
150660
199444
122598
56276
68233
345006
102033
93585
60102
58508
53088
88321
65840
63290
32204
9563
8286
4779
4460
4302
3025
3504
3665
3186
3824
3983
4460
21840
425035
182226
84972
93263
93104
65684
80351
104424
1277662
244243
85770
70.37
71.25
72.13
73.01
73.89
74.76
75.64
76.52
77.40
78.28
79.16
80.04
80.92
81.79
82.67
83.55
84.43
85.31
86.19
87.07
87.94
88.82
89.70
90.58
91.46
92.34
93.22
94.10
94.97
95.85
96.73
97.61
98.49
99.37
100.25
101.13
102.00
102.88
103.76
104.64
105.52
106.40
107.28
108.15
109.03
109.91
110.79
111.67
112.55
113.43
114.31
115.18
116.06
116.94
117.82
118.70
119.58
120.46
121.33
122.21
123.09
123.97
124.85
125.73
126.61
127.49
128.37
129.24
130.12
131.00
131.88
132.76
133.64
134.52
135.39
136.27
137.15
138.03
138.91
139.79
140.67
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1108
1117
1125
1134
1143
1152
1161
1169
1178
1187
1196
1205
1213
1222
1231
1240
1248
1257
1266
1275
1284
1292
1301
1310
1319
1328
1336
1345
1354
1363
1372
1380
1389
1398
1407
5275102
4456498
3534859
2238856
3251523
3643566
3551749
3669118
4703597
17878900
12243679
4249436
4267065
2987533
4982647
30310512
40363412
11803967
4010426
3949859
7669441
2588495
3427067
3555578
9096094
13917111
6347013
6964228
3139776
2780090
3160024
3121766
2634715
2576844
2746780
2033181
2204732
2499362
2757489
1919666
2854100
2062040
3005237
2387742
3096927
2187536
2255581
1718163
2489785
3366501
4871841
6527186
3062955
3397725
3944085
6034360
6085998
25292812
48899828
63495868
6969265
1347183
345481
187487
72379
58827
34754
20086
22636
26143
19608
20720
19445
20084
20245
20563
20084
19286
20404
22953
19447
260067
600182
452571
243764
379022
492880
373797
391693
285921
291905
285854
289485
414169
235742
278598
438434
413086
335589
256375
323236
235931
115130
202564
227464
272485
198107
90295
152639
82335
78705
200463
316996
213580
247076
219375
139776
62657
25596
29735
17317
19420
13242
12032
11841
8275
10248
25787
83036
195940
226763
260195
194730
226507
186899
199508
428562
278789
295918
412261
366475
42978
11905
6684
4582
4453
3881
3943
3943
3816
3816
3816
3943
3817
3816
4135
4070
3816
3752
3752
3498
3752
2590301
4843071
4668087
3850169
3395945
2663739
1514422
3045238
1750094
1555223
1322877
2111682
2296409
1239455
1795442
1379488
1258228
1383571
2280307
1691314
1381721
717156
1140815
1176923
1297217
849231
504661
855279
393159
476893
1036572
2168865
1505442
890879
1494110
929537
537075
290377
356478
244402
255417
176582
180468
179322
133025
191230
232430
852220
1429149
875336
1176160
875721
2378177
3647305
1883393
4134968
2227066
938052
863113
463842
105133
52978
45210
42024
40307
39288
39352
39350
39350
37697
38905
39417
38142
38841
39034
39034
39225
37568
38396
38142
38396
341640
260194
589991
880052
331134
179511
216065
259812
350810
343807
414169
387300
405000
410094
233895
135510
314257
379721
450660
271722
205939
247394
236058
235996
199190
126529
137990
204920
202564
311202
391881
282290
333297
351254
416019
165822
133024
158369
116024
94882
174991
106979
102140
83864
86155
105133
80169
141941
276814
312217
283501
278980
2481021
3308834
620039
3037772
1843519
326168
120351
48331
14962
8720
8657
7892
6874
7512
6747
6429
6493
6493
6175
6429
6493
6493
6175
6684
5919
6493
6493
6557
6364
Table 2: Bowtie carbonate raw data Major elements Site D
42
16660545
9889184
13627022
10892134
12203641
9600774
14168891
17078228
14197737
14555338
19098780
18976478
15942902
18939948
15133379
8882164
9482642
19461010
14439241
17458368
20073342
20863024
18572122
17139482
12793384
13809256
24203374
18256596
22938112
29765742
26482066
19654946
22839008
19345320
18768092
9867410
15344918
17273894
19396704
13566022
21273382
15191886
21404232
17827008
10895238
14767079
15367608
11063227
15415430
21413694
22068558
18074972
18831484
30178338
25281416
13015860
14267182
13462136
6782401
3440638
622567
162139
71421
32043
36188
21201
17693
22956
17374
19606
19288
16738
16099
18331
16895
17056
16258
16418
19606
16417
17375
45619816
42882944
43638540
44291980
43774680
45887012
45734184
47056936
55463520
45290552
44004636
44337360
42969432
43763488
44379688
42677208
42153804
43268780
43675780
43901260
44995888
54466776
52078092
47027832
43874396
52348136
81925032
57388220
59456188
58539624
46044112
44171912
45237032
44006876
45332068
48178624
49531288
47670280
48221564
46548388
49878868
46451928
47052048
45300320
44852012
46273052
46303576
47242320
48048384
44521324
44319044
43465568
43190432
43079528
43156448
43591940
44740492
42494872
41323320
41352216
40845504
40549616
40539848
40433824
40391696
40342856
40391496
40268988
40284452
40394140
40294424
40278144
40180056
40260848
40315588
40152788
40203460
40219740
40205496
40131016
40040864
51174
58190
101874
70465
54840
65524
77001
54522
73494
116381
82104
123876
83378
49738
53565
28217
47187
102671
79076
78915
81945
88801
126587
95017
101713
287769
113035
64567
96613
478130
144919
109208
112714
82422
63451
40493
32734
9243
14984
6692
8447
4940
6851
8925
7331
8129
10838
13070
66160
105699
127701
111119
181589
405747
1057005
300525
88642
68711
47028
44636
6852
3663
3345
3983
3186
3024
3343
3504
3504
2708
3504
3663
2865
2706
3822
3024
3663
3822
4302
3186
2708
bowtie carbonate minor
61,752
Ave blank
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
um/s
0.90
1.73
2.55
3.38
4.20
5.03
5.86
6.68
7.51
8.34
9.16
9.99
10.81
11.64
12.47
13.29
14.12
14.94
15.77
16.59
17.42
18.25
19.07
19.90
20.72
21.55
22.38
23.20
24.03
24.85
25.68
26.51
27.33
28.16
28.98
29.81
30.64
31.46
32.29
33.11
33.94
34.76
35.59
36.42
37.24
38.07
38.90
39.72
40.55
41.37
42.20
43.02
43.85
44.68
45.50
46.33
47.15
47.98
48.81
49.63
50.46
51.28
52.11
52.94
53.76
54.59
55.41
56.24
57.06
57.89
58.72
59.54
60.37
31,500
Mn55(LR) Ni58(LR)
Low
Low
30,131
52,735
134,022
Zn64(LR) Rb85(LR) Sr88(LR)
Low
Low
Low
10 Intensity Intensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
513
521
529
538
546
554
562
571
579
587
595
604
63301
66712
62296
65208
60892
62297
66412
65709
61294
59085
57781
61896
62296
60591
64003
55172
61895
60188
60691
59286
60088
64204
56576
65106
56074
68720
1019668
912976
792060
892852
393194
506712
618616
928352
967984
645672
584504
648232
777224
772360
841808
657484
644932
778184
2012840
2707808
990804
708120
795984
947652
833904
1399016
1830928
1832397
4317872
5828448
2200128
2171312
1145360
781892
1594568
2291672
1345408
477048
336583
168045
114702
133287
79862
102551
312209
267921
113502
33599
31694
30990
31592
33700
30691
28985
34603
28182
31993
32998
31192
32095
34101
26576
32596
31693
29787
33398
32094
29988
29687
33900
28483
30992
39317
808732
437922
249084
448414
206645
173674
224041
182022
220873
224347
336329
334434
265380
205468
268397
387111
163322
235304
1084572
1529040
453062
230195
378596
499962
209865
235504
354291
336650
509544
417350
570008
779060
447926
232086
417046
1452768
4201488
7854848
8336844
10983680
8639514
10575040
10312320
10607808
8902016
8801344
10702272
31793
32496
28683
27981
29084
31393
28484
32596
30390
32495
29887
30089
28182
29988
28784
31392
31091
32396
31693
31794
32194
31191
30289
30489
31092
40020
163223
160910
82170
89299
81871
261784
400603
175254
85012
63703
58283
64003
66211
60892
72936
65409
88596
65209
74241
87092
83777
73438
118420
97631
69924
67616
58082
69322
81769
61594
102150
134186
93615
67316
81268
76148
89501
122037
193819
126252
112894
77653
78658
81969
79460
81970
71831
58985
52062
51057
54871
58082
53366
51961
53767
52161
51660
50656
48148
52461
53567
53566
51459
52563
50355
54069
51459
51660
52663
49753
51659
54270
126869
421488
544688
440660
587798
281583
367366
437540
342198
389240
491882
581750
475158
472222
358208
489262
711574
616830
492082
397802
434890
607100
480580
680444
583960
446694
460722
518858
652186
305938
335240
415844
398908
552452
531740
394386
315906
164330
90805
55072
60994
60792
66112
65914
56177
50154
97204
49954
43
144688
140018
138467
138984
136915
136393
138472
133796
133279
134314
134319
130171
135876
129649
134314
130171
129654
128097
125496
130166
131205
128097
131205
130688
127057
792471
6782754
4161678
3077044
3079924
1411606
456116
1592712
9163557
1768106
3078998
4363031
5499428
4170656
10851060
9131649
3183397
4627256
11009700
6164204
6015377
4895500
4481048
4191765
5520808
6093401
6057531
5590518
2762393
4775021
3345066
3956851
2929198
2865135
4237820
3520035
4346814
4803576
4087892
6262024
2511235
2406970
1812111
551824
2453641
7093330
3930211
1139437
658
751
57
665
-
Mo98(LR La139(LR)Ce140(LR) Th232(LR U238(LR)
Low
Low
Low
Low
Low
Intensity Intensity Intensity
[cps]
[cps]
[cps]
601
1402
1000
401
600
1102
500
500
901
300
1302
400
1201
200
400
901
500
600
500
300
901
800
600
300
500
1101
10327
4913
3006
2305
2004
2103
5313
2104
1904
1703
2104
1804
3508
1602
1903
2304
1403
10428
24872
19354
4411
3507
3608
1401
1502
2705
2305
3708
1503
2304
3708
3908
2405
3709
6216
5312
15043
43330
75646
52060
32696
9124
6215
7218
11632
5113
2203
1301
1603
1202
902
800
600
1202
801
1101
600
900
600
801
701
500
701
300
601
1101
400
1302
400
1001
800
1101
13437
33198
20859
93216
42127
20559
68319
110693
64404
79260
36108
32695
97832
53465
94429
75445
35505
34001
71028
26477
32495
40221
95123
54571
84379
53165
68420
40623
28582
42731
33900
17750
33098
34102
38214
47244
34904
28984
11932
13738
6216
4409
3307
3107
3207
7319
4411
3607
0
100
0
0
0
100
0
0
100
0
100
200
0
200
0
100
0
200
0
100
0
0
100
0
100
91517
155804
116970
200512
117213
78358
143127
218464
151669
171260
98235
108376
219517
153980
279711
168248
91106
120326
173676
64512
108577
159303
237213
150764
280821
152571
151164
103756
233620
98636
113297
57079
130776
131592
106468
138808
96628
75546
58586
41424
21460
18151
9224
6617
22363
43130
16445
9525
Intensity Intensity
[cps]
[cps]
500
300
1301
400
300
1501
200
600
300
701
901
700
1301
801
600
600
400
400
1301
801
1001
300
200
701
500
12233
18652
38215
23166
19153
10829
10730
10829
12534
12132
16045
26276
21561
23868
14540
20057
15844
39321
21663
9725
9425
37211
32395
19154
68768
26376
17047
14540
14038
11230
11933
11331
13338
28884
22364
18351
14038
6818
1803
1503
1101
1301
901
200
1302
701
2605
801
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
28484
18251
54371
21562
17750
5915
13236
7820
8121
9825
11431
24671
23370
24169
18854
20257
37312
39619
12634
6016
11431
21866
18853
12734
38716
24771
13637
12534
11531
12735
12433
13137
15744
77554
25374
12835
9425
4110
3007
801
1604
1503
100
902
100
200
2305
0
61.19
62.02
62.85
63.67
64.50
65.32
66.15
66.98
67.80
68.63
69.45
70.28
71.11
71.93
72.76
73.58
74.41
75.24
76.06
76.89
77.71
78.54
79.37
80.19
81.02
81.84
82.67
83.50
84.32
85.15
85.97
86.80
87.63
88.45
89.28
90.10
90.93
91.75
92.58
93.41
94.23
95.06
95.88
96.71
97.54
98.36
99.19
100.01
100.84
101.67
102.49
103.32
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
302337
1142888
4667936
4064400
2153304
1597216
1274800
700712
904484
860124
1116076
1458472
751720
802148
1099304
543764
894600
999204
1616944
1166888
1437624
757084
602948
854452
833248
960732
887692
723824
700376
430076
600844
873552
439038
409194
671300
721152
979676
1583392
2183968
1017332
783824
621884
542500
407820
303928
645300
1549352
1160956
633160
1013238
805076
1266724
7192192
1513632
794184
714828
1319448
1031484
464284
337466
210866
262374
394026
1363576
563334
265024
409643
480478
292810
401056
291556
240434
806760
399340
224166
298512
546644
530646
217015
259594
2904720
5641440
2399544
451046
279992
154586
104561
216883
226762
378068
490944
213881
181211
215796
155587
117715
173370
484272
497036
223638
272937
1176812
800836
3277408
128012
69223
110253
96225
109782
91207
105563
83275
83178
80766
79763
119122
73438
62598
64404
91608
91007
78257
63300
63802
96535
63200
195706
68519
75347
85486
68921
73441
121732
167446
134293
92410
96631
85785
90206
302585
293624
108977
93717
87391
104165
88997
96230
69824
89903
92310
87993
82874
113800
352976
280981
363460
50556
56377
115104
394682
328512
301922
386112
537498
503696
525696
520044
449916
613556
445614
457784
494116
531270
431260
342084
483006
509558
451328
479614
437416
559740
384232
301641
414242
280572
208862
296478
431272
381788
205843
194982
522802
480174
473764
390248
454454
707932
577402
427430
340980
531466
414970
435400
361526
423298
525082
438628
302346
8163826
15425262
9281985
4812572
7324966
9087877
5628997
3924052
4755436
6314659
4219046
4921225
3330137
5275533
5134623
5147700
5067281
6751871
16525077
6279681
5223599
5512908
5495916
4809118
3784725
7958247
8634658
6546258
6727377
10338058
8528725
4156547
3183107
2082828
4458674
3645742
4596414
7337719
9775978
5787048
5276057
4300718
3088478
1415873
1448027
2069366
3372699
1866871
4173175
4789619
7194851
6133280
Table 3: Bowtie carbonate raw data minor elements
44
2003
7218
3608
10829
21260
6517
3508
1903
4309
3709
4209
11131
2404
1503
6316
4310
3007
5613
1504
2706
5513
8823
3407
2505
8020
3106
1603
6517
36307
41525
11430
4610
2806
1101
2205
3508
2205
6315
4309
2806
2605
3307
2806
1903
1302
1201
4811
2004
901
5613
26677
47143
25474
60491
45137
52864
26477
27579
110487
152816
143531
60691
64805
30188
89865
34101
38013
39016
47847
48650
95636
111690
60492
228993
75449
64103
25875
50254
59391
48749
159407
345006
162320
45839
23669
24972
38214
53065
47545
43532
32596
37813
36911
49554
41928
18353
19956
25072
19957
22364
28383
41324
82885
33399
77955
3809
154682
6616
132277 11631
204587 15442
74141
6015
96529
8724
281793 19856
223133 23065
479694 14441
133585 12434
162218 21461
118720 19355
143329 14239
118319 14942
101046 16246
155306 23969
158403 22765
139917 13637
245260 19255
230579 24068
176791 25276
571814 28082
171765 20860
172794 18352
89805
7519
200348 10629
165733
9727
188673 34702
598016 114199
1281048 252410
573776 67315
178904 23768
104561 14039
116713
7921
182225 15644
170563 18853
124445 26076
101650 13536
110689 12735
147077 14439
142825 19455
121234 44937
119528 77352
91649 15042
99150 14238
67415 11933
60591
9826
96631 15242
96427
7419
148051 14439
208661 18852
93917
7119
4911
5112
22064
10930
4911
9125
14640
18953
14740
9325
12234
15844
22163
15744
28785
17448
13236
11631
10728
13738
14139
15243
10829
14340
9627
8823
10429
28283
40923
64003
27180
10028
8723
7519
9625
14339
26077
15744
12335
10228
19556
67114
188757
28383
11933
11733
11732
13337
6517
14340
22163
9726
Left Hook Carbonate
Left hook carbonate major
Ave blank
20,873
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
um/s
0.95
1.83
2.71
3.59
4.47
5.35
6.23
7.11
7.98
8.86
9.74
10.62
11.50
12.38
13.26
14.14
15.01
15.89
16.77
17.65
18.53
19.41
20.29
21.16
22.04
22.92
23.80
24.68
25.56
26.44
27.32
28.19
29.07
29.95
30.83
31.71
32.59
33.47
34.35
35.22
36.10
36.98
37.86
38.74
39.62
40.49
41.37
42.25
43.13
44.01
44.89
45.77
46.65
47.53
48.40
49.28
50.16
3,809
37,639
6,375
17,416
38,314,798
3,616
Mg24(LR)
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
10 Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
21921
21619
21921
20562
21317
21317
22679
20713
19804
21467
21165
20259
20862
21922
19653
19956
21014
20410
20108
20561
21165
20410
20107
20108
995524
3236490
3151220
3054141
3907695
2941200
3136841
3787649
4114977
3412807
4266651
23304364
32122340
21038736
7018855
3565663
1896696
1809279
2411704
2832794
2582859
2539916
3006216
2508168
2130286
710505
1706627
11757126
30802220
24542844
10124394
5244341
5032041
3920
4165
4041
3801
3800
3922
3862
3922
4041
3800
3862
3801
3619
3981
3560
3558
3741
3860
3679
3739
3558
3800
3679
3498
116076
246348
273525
358559
358439
252688
415270
346239
304990
303661
323593
309883
321720
290678
188489
146816
168800
330054
419136
267908
211922
285423
251541
177195
136308
69510
130629
260600
273585
318216
292850
358017
361037
40402
40221
39312
39737
39616
38589
37985
37744
37502
37080
38288
37080
37563
36537
36295
36960
36960
36656
35752
36356
35931
35628
35569
36536
1072356
1330482
1213258
1518964
1733852
1469876
2439375
1917793
1380010
1616080
1812722
984306
927829
1120365
866832
779141
1378129
1647605
1697134
1522414
1005681
1739660
1428749
978320
498070
405662
1448127
1376440
1079419
1336700
1597907
2083833
1397754
45
6520
6942
6640
6821
6761
6701
6098
6279
6339
6339
6399
6520
6098
6640
6158
6399
6098
5977
6339
6339
6218
6037
6037
5977
196762
289711
202318
171880
243087
194105
228892
202501
224001
225389
201775
87871
159379
187643
144462
143253
172847
260963
209687
252025
270203
235113
211558
179489
110761
110336
461167
201653
117342
219774
230947
237832
195313
19047
18444
18444
17537
17839
18140
17837
17084
17687
17387
17385
17688
17536
16933
16631
17084
17234
17234
17385
17687
16780
16782
17233
17537
4051492
14128565
9951756
9947702
12458488
12263124
7946582
7112726
11540724
11676210
9162627
8170848
3930807
9983794
9613909
10311122
8779715
7133907
8826276
11337254
17073744
13406070
11268932
14021546
20380510
12300180
14113897
10676422
4859981
8702177
10511648
8406549
8422038
37381592
39337840
39106048
39060884
38897992
38721204
38704220
38587840
38392524
38273252
38177908
38070216
38100904
37931640
37912728
38099744
37948432
37842476
37804840
37726676
37711620
37666844
37536956
37463036
37953836
39250216
39152172
39282256
39010512
39109712
38255108
38647480
38628756
39206792
39481240
38246232
37673792
38454864
38793772
38907640
40076064
38937556
38135064
38832760
38624124
39063200
38424948
44487272
54657020
45353648
39133260
38896448
37645228
38195472
38546924
38108236
38106884
3777
3928
3474
3174
3472
3626
3472
2568
4231
3928
3323
3626
4229
3777
3172
3929
4229
3476
3928
4079
4382
3323
3779
4382
27667
48232
68945
83613
50500
67434
84370
67735
258255
128521
42486
30087
37344
153319
45509
41881
69249
42332
113098
556579
752842
167078
74994
60026
48684
30238
145002
102515
32204
62597
61991
42032
32052
51.04
51.92
52.80
53.68
54.56
55.43
56.31
57.19
58.07
58.95
59.83
60.71
61.58
62.46
63.34
64.22
65.10
65.98
66.86
67.74
68.61
69.49
70.37
71.25
72.13
73.01
73.89
74.76
75.64
76.52
77.40
78.28
79.16
80.04
80.92
81.79
82.67
83.55
84.43
85.31
86.19
87.07
87.94
88.82
89.70
90.58
91.46
92.34
93.22
94.10
94.97
95.85
96.73
97.61
98.49
99.37
100.25
101.13
102.00
102.88
103.76
104.64
105.52
106.40
107.28
108.15
109.03
109.91
110.79
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1108
2744183
2450678
2757644
2572268
2472463
2873625
2384009
4039526
9240164
11599445
6116942
4188945
3854934
3813632
11443501
6283091
3292604
2412295
3049774
3679666
2075703
1580978
1812777
2419858
2090829
2931972
3435798
2547612
2525538
2017200
1657647
1502819
1657490
1735348
1720848
2028539
3518185
3011343
2031410
1602437
1712362
1536226
1539241
1529266
1601243
1927986
2599650
4310510
5825078
6696618
7292795
6992366
6592591
7233833
5081039
2231285
2128790
3116600
2903709
2050456
2154049
2687332
6991136
7745959
22769176
31823770
38359328
52176584
47201432
285604
211982
168739
173512
206124
230827
187160
217781
190845
166263
322865
423965
311635
307345
241273
233120
216089
188370
213553
327337
168620
112632
121148
121329
157568
80504
163666
239944
344006
286689
268994
430429
512620
562327
608288
622241
626948
653103
693690
703591
702019
715611
666327
731551
718026
709510
684689
726663
692538
662222
663187
655639
678648
657874
485627
324076
418285
578816
546748
304929
392502
439787
488287
339294
273283
283490
310729
328123
325464
1095975
1337611
783860
888997
1287594
956279
953504
1028871
628037
926626
1851558
2371970
1680451
1795690
1116445
982611
1003624
1009607
1649306
1340928
602009
393345
679432
728053
594880
402827
1039016
1311640
2376011
1385318
1439611
2637032
3272158
3535398
4273213
4387252
4572990
5760302
6006426
6598139
6183720
6437250
5997644
6605280
6678572
6972511
6163431
5348947
5171532
5018507
5181761
4919015
4917640
4221972
2998122
2403863
3029654
4766304
3344497
2378375
3084152
3749797
4849439
2359232
1575194
949512
888880
948245
958818
46
170309
220922
211983
197608
266458
216873
275217
210292
140899
229194
165962
153218
229920
172544
207695
234631
245137
202923
173570
146574
164329
216751
266337
211318
407115
406511
289589
269960
152675
65284
39132
36777
28564
59727
28443
38650
54171
38226
20953
18418
19083
20894
20470
18718
20894
33395
74766
111121
215062
241092
194529
176892
160888
142951
80262
35207
52419
47650
119034
109071
143857
205340
86361
68483
34422
36355
45595
34784
33394
10316767
14976752
14509740
14098505
13194493
12959612
12908757
14255993
11265844
12579354
9133387
7214147
11784194
15124445
13784542
13680033
15714542
15032577
12562563
9039638
9993250
15894418
16935172
15402751
15958977
25397738
20005512
13739139
8567125
2875423
1008371
1421162
992195
872589
1212046
1208560
536166
457540
284111
120961
69097
45358
151202
65620
46870
74843
223176
110226
34775
19954
22828
20862
22074
21468
782778
2121372
1652189
647907
2918812
10798832
7823255
7691677
4714966
5134234
2810116
1912413
1425396
1298685
1790395
39536436
43956520
38627408
38561592
40387180
38755364
37943220
37946696
43571872
45308100
38598648
38837196
41437100
40124508
37795384
37654300
40942056
38878884
38434408
37678040
38035476
38510640
38182736
38655392
42154480
40629396
39947912
39799304
37850196
37214452
36651088
36495336
36476616
36236908
36224556
36423344
36592220
36440524
36084632
35962848
36023644
35944320
35985428
35869436
35940652
36002800
36098720
36491860
36841576
36953516
36762640
36820732
37076072
37369240
38083920
38131204
36765920
36590872
36800276
38522028
37030716
36832892
36433576
37366344
38964384
36665560
36146392
35924440
36175340
44300
139256
104478
100701
94954
68643
72726
65014
52314
63201
47021
47021
56246
41729
114761
106595
74843
107504
110830
60932
111584
80137
80893
192027
92836
93290
270655
128368
61840
31902
25398
12093
18594
7406
9220
5743
5894
5743
4382
4382
4683
4231
4231
4380
3928
4836
9220
4836
3777
3928
4837
3626
3476
4080
4080
4231
4986
4986
21922
73785
30539
67888
18444
15419
9826
11186
7102
8314
7557
111.67
112.55
113.43
114.31
115.18
116.06
116.94
117.82
118.70
119.58
120.46
121.33
122.21
123.09
123.97
124.85
125.73
126.61
127.49
128.37
129.24
130.12
131.00
131.88
132.76
133.64
134.52
135.39
136.27
137.15
138.03
138.91
139.79
140.67
141.54
142.42
143.30
144.18
145.06
145.94
146.82
147.70
148.57
149.45
150.33
151.21
152.09
152.97
153.85
154.73
155.60
156.48
157.36
158.24
159.12
160.00
160.88
161.76
162.63
163.51
164.39
165.27
166.15
167.03
167.91
168.79
169.66
170.54
1117
1125
1134
1143
1152
1161
1169
1178
1187
1196
1205
1213
1222
1231
1240
1248
1257
1266
1275
1284
1292
1301
1310
1319
1328
1336
1345
1354
1363
1372
1380
1389
1398
1407
1415
1424
1433
1442
1451
1459
1468
1477
1486
1495
1503
1512
1521
1530
1538
1547
1556
1565
1574
1582
1591
1600
1609
1618
1626
1635
1644
1653
1661
1670
1679
1688
1697
1705
35708088
17196396
6980883
6087437
6577657
7560582
6408155
6635847
6580649
6716907
5744380
6493075
4756099
7293132
4811563
3518957
3025420
2317496
3189180
2162662
2086004
2477614
5674176
5255656
2481377
3653892
2897352
2850490
3170278
2263203
2959209
2690348
2454176
2648949
2470822
2770660
2404129
2468096
2878438
3545724
3363037
2832770
3928250
2709105
1632684
2208306
3020571
2726801
2751300
3073959
5312687
6198147
7829721
7031810
7577663
6755434
7190312
7211011
6537417
6952777
6605763
6063216
6747883
6430205
6237447
5768239
4689997
4735521
286872
194408
291460
547592
601641
655214
686317
683781
652560
691637
668018
672367
510931
507674
373176
305472
325706
189395
221706
133589
116741
150560
272558
235777
148628
116801
239462
294058
300521
297200
484116
610646
668380
673094
399323
308553
303963
298226
264828
347144
209747
193864
286991
239703
175081
294058
353065
335307
220136
331324
579060
615172
627494
655515
687466
676957
688914
667475
659140
668082
640781
686438
658356
678953
672852
613484
458993
399204
1178530
821773
2100142
3668810
4159319
4619817
4600469
4393645
4549493
4233672
4553160
4404574
2943431
2736402
1969264
1776239
1717115
997777
1400903
608050
762836
1009245
1557498
987322
538171
688193
1197740
1654553
1180460
1602738
2552075
3893944
4564523
4304117
2487457
2063405
1479466
2020059
1522354
2077428
1016368
1411047
1846914
1157940
1039866
1876636
2538541
1935380
1820032
2299318
3544457
3996427
4048151
4237243
4283876
4395237
4483052
4663749
4785556
5420478
5458812
5751159
5579703
4788933
4561024
3991192
3140967
1952593
47
25545
34363
222610
118490
94273
96869
86181
88474
74522
59908
74162
136549
145971
156721
167773
145668
133046
172967
219290
213248
230101
244837
163545
146394
177133
393464
176470
186678
197668
140475
52481
39132
52419
104359
186254
226416
186254
259151
137514
197427
323108
274915
171517
277753
178403
157566
149896
206184
252265
168920
107077
120001
124711
86179
118793
202318
98861
244294
139509
145067
188490
141683
179187
135221
89983
94636
141985
178465
1823199
504412
192934
122321
35833
26459
18897
18444
18896
19956
18293
301047
3177854
5512418
7266933
10698521
8435644
11812758
12775152
15535149
16049301
14799530
11131999
9150082
13634485
16653294
10712465
9386700
11146522
9788284
3666083
574872
178267
579863
7598555
13014231
11858740
11953358
11180876
8024168
14944955
17112538
12336512
10677484
16184594
10897166
7079940
10331531
14457920
10817071
1429171
299531
117029
53524
44149
25096
35229
27516
19502
19351
19956
24642
19200
19048
18142
46870
641707
7714837
37625544
36617312
36368340
36803748
37010260
37304004
37205188
37177592
37458600
37293968
37386996
37240120
36989028
36686212
36917620
39490696
39825744
40771828
38014244
37613768
37616856
38405840
37074336
38141048
39302136
37355152
36855860
36525248
39161632
37030524
36694124
35993728
36113968
36239996
36909704
40684016
39870520
37148256
36506916
36517724
37190520
37862352
40244744
37929520
47522392
42408084
37390468
37667232
38086428
36934024
36183448
35868280
35931388
35931584
35925212
35915564
35847820
35744564
36010712
35825240
35656172
35710212
35620852
36041592
36252928
36465228
36879984
41183112
6346
4382
4229
3626
3474
3777
3926
3626
3777
4534
3777
12699
20257
25550
101758
130034
41579
285168
111435
88604
106596
83917
28575
41578
80286
84974
55186
38706
32204
44604
48182
5894
4532
9068
43241
61840
113855
197317
82102
87090
119750
762067
353059
764485
640042
128824
47626
39763
58512
24342
8011
4988
4836
4231
3474
4229
4080
3476
4231
4231
3625
3779
3777
4231
3626
3474
7708
105841
171.42
172.30
173.18
174.06
174.93
175.81
176.69
177.57
178.45
179.33
180.21
181.09
181.96
182.84
183.72
184.60
185.48
186.36
187.24
188.12
188.99
189.87
190.75
191.63
192.51
193.39
194.27
195.15
196.02
196.90
197.78
198.66
199.54
200.42
201.30
202.18
1714
1723
1732
1741
1749
1758
1767
1776
1784
1793
1802
1811
1820
1828
1837
1846
1855
1864
1872
1881
1890
1899
1908
1916
1925
1934
1943
1951
1960
1969
1978
1987
1995
2004
2013
2022
2450690
3849940
2969932
3001536
19034914
25335978
7734475
4065087
7429294
10254186
5987029
3335088
3235416
3394955
5515289
7504033
2381898
289402
147422
69349
26911
25248
21619
22678
19047
19048
18745
18442
18748
18293
18291
18897
19956
17385
18140
19502
235477
236684
71807
145606
219954
265131
285180
187886
307829
327578
221768
232034
235354
362486
556169
609376
142891
21678
16986
5553
4466
3800
3619
3558
3438
3498
3558
3317
3558
3317
3317
3197
3438
3498
3317
3438
1026272
983824
781496
763197
832050
1314240
1577009
1170985
1889132
1577853
1154496
1155274
1276671
2512510
3395268
3285717
520838
110339
53930
40099
33335
34241
33397
30435
31221
30919
29710
30919
30434
30678
30797
30435
30135
30376
30316
30134
Table 4: Left hook carbonate major elements
48
223940
222552
562269
416116
269898
205338
314653
307708
284153
214156
303419
277389
215788
138663
101278
52479
12317
6701
5494
5434
5675
4950
5069
5615
5012
5252
5133
5312
5133
5494
5555
5010
5374
5010
4950
4830
10829037
9993878
25575780
19629452
12167299
8325682
11106282
15650660
12264812
8993076
19494062
14904811
12298828
7292360
1770594
403258
82403
49894
29027
23433
20862
18594
19954
17688
20107
17688
18293
17536
16780
17537
17537
17233
17537
17233
17688
17991
40877784
36533164
37122392
36911828
38158800
36920512
38078512
37745976
37744044
36555164
37161572
38413368
36991924
37336624
36589328
36156040
35382112
34794232
34652572
34711436
34760264
34639640
34640220
34644656
34632692
34608376
34608180
34538700
34678048
34644464
34556844
34623236
34630760
34718000
34528664
34449344
70609
94801
72879
139862
45360
54126
109619
555973
250393
104178
159518
75296
44149
25853
7254
5289
4836
4079
3625
4383
4383
3174
3929
4079
3928
3929
3777
4383
3626
3625
3777
3777
3476
3777
4079
3777
Left hook carbonate minor
Ave blank
51,720
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
um/s
0.90
1.73
2.55
3.38
4.20
5.03
5.86
6.68
7.51
8.34
9.16
9.99
10.81
11.64
12.47
13.29
14.12
14.94
15.77
16.59
17.42
18.25
19.07
19.90
20.72
21.55
22.38
23.20
24.03
24.85
25.68
26.51
27.33
28.16
28.98
29.81
30.64
31.46
32.29
33.11
33.94
34.76
35.59
36.42
37.24
38.07
38.90
39.72
40.55
41.37
42.20
43.02
43.85
44.68
45.50
46.33
47.15
47.98
48.81
49.63
50.46
Mn55(LR) Ni58(LR)
Low
Low
10 Intensity
[cps]
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
27,259
59287
48951
48850
51058
48047
54469
51960
50356
54669
51960
52562
53667
51860
47545
56777
51660
50255
48949
53768
53967
50155
50254
50656
47645
50054
68034
660518
379264
549718
643230
1131136
1657752
979260
775308
728720
603262
1300968
816864
500000
619016
943188
920020
802096
930680
1022698
997676
735320
646324
838932
1024892
1554752
677656
443665
341608
1575432
1653888
1091024
770124
515600
682588
637322
28,449
41,873
128,371
Zn64(LR) Rb85(LR) Sr88(LR)
Low
Low
Low
Intensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
33399
27479
25474
28885
28182
25374
26176
32997
25274
27680
25373
27680
25372
26777
25574
27080
27580
28884
27580
26677
27480
27480
27279
25373
31191
31693
163348
149858
154587
124042
332016
279584
184428
171574
149764
168150
554406
238028
172772
159509
147247
146749
155787
165940
185337
354014
398912
260661
170254
206544
261761
163222
144835
103162
93817
156791
132480
165936
132580
154078
155995
33700
31894
29887
30790
27479
28884
27079
25774
29586
31391
31693
30991
28383
28181
28383
24470
26677
26978
29286
26477
31694
26175
29286
29686
28082
30489
94419
86689
66010
58282
67415
54871
50254
48047
49954
67114
100643
70226
56878
62197
58684
79260
74140
60892
61193
67415
61595
60993
46241
48147
53867
62697
163288
73438
85482
104259
65810
61494
54268
49853
53065
45238
45337
42628
45739
42728
46542
39619
42830
43632
42931
41626
39418
42427
43532
39619
39117
39319
39017
43833
43130
42228
42628
41024
41024
43732
86890
433896
589644
491410
400934
472628
467876
468490
313588
394088
538150
581444
635092
495830
374520
283400
415370
375734
471814
513688
416248
438648
469102
559656
354374
387342
457450
307758
159003
280296
341580
292648
369188
366880
393568
333022
49
137283.3
130624.8
132446.3
133049.4
131837.1
128821.5
127000
129412.5
128815.4
132440.2
127000
128212.3
127603.2
127597.1
127609.2
126396.9
122766.1
127000
124581.5
120956.7
125793.8
121553.8
123369.2
123375.3
125190.7
2659341
3368145
4572978
3337947
5345955
8286469
5666610
4088512
5578810
3749218
3410515
4090296
2809146
4214915
5089531
7878887
7364784
5077999
5869709
3188165
4993077
6648480
4878240
2914016
3142074
3492391
14263786
41828120
57145368
66017160
24053660
11306326
6931137
5226199
4464114
3322218
520
801
67
607
7
Mo98(LR La139(LR)Ce140(LR) Th232(LR U238(LR)
Low
Low
Low
Low
Low
Intensity Intensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
800
400
500
601
401
600
200
701
700
1001
801
600
0
500
400
500
200
600
902
701
400
401
900
801
1001
901
2104
1902
1602
2605
2104
2806
801
1501
2204
2104
3208
1803
1904
2002
1001
2505
1402
2104
2505
7219
6417
3106
3005
2204
3007
2805
2204
2304
4611
1302
1401
3608
2204
1002
1503
1000
801
500
400
1001
902
901
400
601
400
400
901
901
901
1302
1002
801
1201
701
1101
700
601
801
1302
1301
11031
46040
62198
54871
48347
114803
74042
39919
36509
30390
28382
33599
34401
39519
51661
79976
41925
52964
68119
101688
188851
189153
108986
70426
32296
29586
30790
35505
27982
70025
94131
49052
39518
34102
32495
35807
100
100
100
100
0
200
0
0
0
200
100
0
100
0
100
200
0
0
0
200
0
0
100
0
100
50156
161116
161716
166840
150363
359724
161116
151466
112398
107279
92110
92114
103863
108681
150461
134993
154689
182227
162119
208102
851424
585480
377924
203829
112695
96025
102151
75347
83977
264716
271408
186350
145749
98234
76250
125861
300
901
300
601
700
500
400
300
800
1001
601
501
601
500
901
800
500
400
801
1001
300
200
501
600
400
8422
13036
18953
17048
14941
32195
19957
11130
8823
12835
14439
14941
13136
14640
16144
12032
14440
15442
16346
27481
102150
89699
35305
21160
12333
12534
12836
9124
19055
24069
25474
17550
16446
11229
11431
13236
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0
19756
18853
16345
32194
17047
25374
21762
10929
12133
9826
12134
26279
16545
12234
24270
25580
14540
10027
13236
28885
75948
47445
20559
20758
9625
11933
13337
7720
7920
38523
23667
21762
12535
9926
7821
15042
51.28
52.11
52.94
53.76
54.59
55.41
56.24
57.06
57.89
58.72
59.54
60.37
61.19
62.02
62.85
63.67
64.50
65.32
66.15
66.98
67.80
68.63
69.45
70.28
71.11
71.93
72.76
73.58
74.41
75.24
76.06
76.89
77.71
78.54
79.37
80.19
81.02
81.84
82.67
83.50
84.32
85.15
85.97
86.80
87.63
88.45
89.28
90.10
90.93
91.75
92.58
93.41
94.23
95.06
95.88
96.71
97.54
98.36
99.19
100.01
100.84
101.67
102.49
103.32
104.1439972
104.9700012
105.7949982
106.6210022
107.4469986
108.2730026
109.098999
109.9250031
110.7509995
513
521
529
538
546
554
562
571
579
587
595
604
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
1041
1050
1058
1066
1074
1083
1091
1099
1108
531724
137102
663480
247175
569424
187544
470620
208854
450546
128562
466464
140315
780156
167053
1375628
343204
1444328
531298
717344
170056
960484
123743
1161828
176201
648316
191164
664282
215497
511242
157399
418258
169855
427041
167345
465566
135895
705332
151968
643322
143839
497534
155188
709896
164026
654704
147548
466966
187653
495720
160207
455074
142224
561342
124744
629056
828876
545420 1828912
641904
585166
967416
192590
364858
92513
322948
45037
633888
94637
826248
86789
823292
122138
1095568
215679
1303304
96827
1060888
52463
551262
34803
236811
29888
135391
32195
193173
30891
311370
30188
338660
28482
368174
35806
571746
41123
741832
52262
1083316
64205
1262528
84078
1305496
969344
957588 3727328
486786 7111322
187241 13677234
74441 9737791
60491 9710843
81468 10109887
127958 8969337
285712 7102979
538106 5091860
843064 2703088
1023436
567242
1327544
231483
1554568
277337
41927
94720
45639
93816
42528
99639
41926
95422
42929
87492
41023
93516
40822
96126
41524
93313
43130
98034
55875
77151
66313
57982
54068
49552
60390
65911
65208
55371
58083
55072
52362
86334
53667
55372
55673
52062
69629
50456
54770
58785
52262
57680
46742
52964
62599
271780
144950
53666
46442
151474
45639
51560
43631
49351
51761
43332
44434
36609
32195
29386
36207
40422
48248
41123
43531
43932
41124
39518
40722
48048
60994
68319
66311
72033
72836
75646
68119
73437
79969
52965
53466
50956
7519
6716
10227
9726
8925
9425
8221
9123
7619
310703
477978
414434
488468
379782
499162
596484
548708
479292
477876
265596
476902
445196
438528
438934
477354
386012
408880
508884
348536
378648
453964
548338
680068
635292
424108
365258
303118
357826
376640
257637
96728
83676
147648
159108
246369
293254
218082
62899
43031
42929
45237
42328
37913
39519
41124
39117
42427
41525
40823
44235
40322
37512
42529
39618
48851
40421
39819
41123
42529
53767
54670
47946
69323
8622
9025
11833
10629
10127
10227
8321
12534
9926
50
2474272
4756375
3415992
3152228
4002651
2480340
3215187
4737744
5237432
4119592
6510561
6880960
4161703
4439070
2881936
1548318
1701842
7689913
4577912
5733802
3332519
4337578
4854216
3744272
3662986
3541164
7092605
1113765
2822906
3327561
7162182
14165910
14517170
11365046
13195120
8674771
4987868
10183211
11414647
11804797
6020297
3316174
8795782
14948526
17415644
17282474
20700312
21918432
23965004
26352896
24069126
14501538
6917265
2153735
443315
258240
858228.8
2570459
4285083
11334745
15137858
21314824
18804762
18190926
78765
84029
80081
88612
80743
84677
78117
85987
81397
2104
2405
1903
1804
1803
1402
3007
5714
4411
2806
2305
2304
2806
1703
1202
1602
2706
2406
2103
2806
901
2305
1101
1803
2004
2606
2906
6215
8724
3609
1502
801
701
901
1502
1001
1101
1001
801
200
200
600
300
1101
500
300
400
500
100
700
800
701
500
601
400
601
700
1001
802
901
300
600
8924
16145
200
200
701
500
800
400
500
1302
600
31392
27379
17048
35806
43835
50555
55172
37110
55574
59989
72333
62898
69227
32295
24370
16746
62498
105966
52362
84480
50756
71330
36710
38415
180206
61896
69370
26075
34603
34203
15142
12534
18753
44134
69022
44636
36708
43833
32195
22365
4912
2706
3407
6315
9424
8723
10327
14941
26678
26375
22866
9625
4209
1803
1001
1603
2905
4511
14741
23768
25875
53667
68419
55072
4210
3608
3909
2205
3709
3307
3608
2304
3507
89098
81869
76453
128561
97129
151169
98636
119429
164327
188548
224150
205138
165435
78857
54469
72334
213286
278899
346509
209558
121138
261710
137504
174533
408808
181234
101548
76550
90204
81368
67215
43131
59185
169264
218712
101146
111789
108878
73939
40521
14941
7922
11530
13738
17047
16547
13036
28884
35505
46543
31090
16245
10628
4210
500
600
3308
13137
41526
71130
83879
139011
149960
151367
801
500
1202
500
900
1502
1302
801
701
14140
12132
7018
13036
11832
10728
11431
11231
24169
12835
19454
21962
218124
70025
20057
15041
21059
18853
15444
19355
13536
17048
14941
13638
33398
13738
9726
14039
11731
7821
4310
1603
2506
14039
14240
11531
6817
5414
1703
700
1002
300
1001
400
1201
601
1202
601
1201
901
400
1101
400
801
700
601
901
801
1703
2204
1702
1903
2304
3106
100
100
100
0
100
400
501
0
501
86795
23067
12835
13236
10628
10828
13438
17149
27984
16044
13636
23669
279775
81567
19255
13437
30594
14641
17248
15142
19155
17248
16546
16546
23568
22665
14941
11130
13537
7721
4109
1101
2605
9225
11130
6416
8321
6215
4209
701
0
0
0
300
300
801
700
1202
1001
2204
1403
100
0
100
0
0
200
200
100
1904
601
901
1802
1603
1101
1502
700
1403
1503
2003
1702
1101
801
111.5770035
112.4029999
113.2289963
114.0550003
114.8809967
115.7070007
116.5329971
117.3590012
118.1839981
119.0100021
119.8359985
120.6620026
121.487999
122.314003
123.1399994
123.9660034
1116
1124
1132
1141
1149
1157
1165
1174
1182
1190
1198
1207
1215
1223
1231
1240
43131
41927
43832
40822
42429
42528
44335
46341
44334
45639
40020
40521
39518
41325
41525
40924
87088
100042
96426
95723
93816
94318
97530
90503
95924
91707
88797
95624
91206
99440
90905
93114
9224
10829
10227
9625
10528
9525
8924
8423
8423
8923
11230
9726
8221
10227
9926
10127
11532
10429
11130
10529
9826
9425
9526
9426
10629
9927
10829
11531
10027
11732
10628
9926
83361
83368
83361
82707
78772
80743
83368
85987
76801
82707
85332
83361
84023
82707
84023
84023
Table 5: Left hook carbonate raw data minor elements
51
701
100
901
902
501
500
100
1602
1302
701
700
1201
601
801
400
902
4511
2705
4310
3507
3407
4711
2304
3810
3006
3508
4712
3207
2805
3709
3808
2906
500
800
1202
1402
1201
900
1703
1402
1502
701
1202
700
1302
1602
1001
1202
300
300
500
600
0
0
200
100
500
400
300
600
400
300
200
400
1603
1503
1202
1502
2104
800
1703
2304
1702
1703
1202
400
800
1703
800
1101
Left Hook Carbonate down 30
left hook carbonate major down 30 um
Ave blank
18,486
3,473
28,996
4,998
17,321
32,838,573
3,343
Trace for Mass: Distance (um) Mg24(LR)
Resolution:
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
Time
[sec]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
0.953999996
1.832999945
2.711999893
3.589999914
4.468999863
5.34800005
6.225999832
7.105000019
7.984000206
8.862999916
9.741000175
10.61999989
11.4989996
12.37699986
13.25599957
14.13500023
15.01299953
15.8920002
16.77099991
17.64900017
18.52799988
19.40699959
20.2859993
21.16399956
22.04299927
22.92200089
23.79999924
24.67900085
25.55800056
26.43600082
27.31500053
28.19400024
29.0720005
29.95100021
30.82999992
um/s
10 Intensity
[cps]
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
18506
18060
18506
18949
19541
17322
17914
18653
18357
18506
18803
18504
18358
17322
19247
18653
18506
18653
18358
17766
16729
18357
17469
17617
1072611
6525839
6948160
6909651
4879319
5357749
6355007
6694191
6111433
4462054
4453643
3544
3544
3721
3721
3663
3426
3721
3662
3071
3603
3485
3426
3545
3426
3248
3485
3308
3308
3485
3308
3367
3189
3367
3248
240708
507205
474201
531630
478699
687644
640867
566705
592367
449894
382828
30930
30870
30397
29982
30219
29330
29627
30041
29271
28741
28208
29035
27913
28267
28799
28384
28740
28385
28858
28148
27321
28031
27262
27913
2004747
2874029
2954224
3350734
3713236
3766770
3718268
3013841
2550224
2740299
2176784
52
5381
5262
5262
5025
5026
4788
4967
4908
4848
4967
4908
5085
5202
5026
4788
5322
5025
5085
4433
4907
4554
4433
4849
4670
62453
88061
83507
102017
71324
92675
131885
112310
145487
275841
139041
20727
17174
17469
17617
17322
16433
18506
17914
17323
16877
17765
16877
17026
16582
17172
17322
16728
18357
16582
16729
17172
17320
17174
16580
32573
205667
2972935
465675
92393
44418
36275
306502
1446925
2388641
2495851
32101650
33496092
33379668
33246044
33174224
33153056
33037388
33025672
32958954
32889968
32828732
32764472
32687360
32715144
32584544
32544100
32473224
32495716
32363036
32368518
32323348
32278364
32164776
32133968
32195394
33114690
41441084
34548256
33080480
32943456
33082182
32799628
33003936
32929280
33693408
4291
2513
2958
3699
3403
2810
3848
3401
3107
2958
3846
3254
2958
2959
3699
2811
3553
3846
2810
2810
3403
3551
2958
3402
4291
3403
3107
3699
3550
3254
2958
6512
8142
25317
12137
31.70899963
32.5870018
33.4659996
34.34500122
35.22299957
36.10200119
36.98099899
37.85900116
38.73799896
39.61700058
40.49499893
41.37400055
42.25299835
43.13199997
44.00999832
44.88899994
45.76800156
46.64599991
47.52500153
48.40399933
49.2820015
50.1609993
51.04000092
51.91799927
52.79700089
53.67599869
54.55500031
55.43299866
56.31200027
57.19100189
58.06900024
58.94800186
59.82699966
60.70500183
61.58399963
62.46300125
63.3409996
64.22000122
65.09899902
65.97799683
66.85600281
67.73500061
68.61399841
69.49199677
70.3710022
71.25
72.12799835
73.00700378
73.88600159
74.76499939
75.64299774
76.52200317
77.40100098
78.27899933
79.15799713
80.03700256
80.91500092
81.79399872
82.67299652
83.5510025
84.43000031
85.30899811
86.18800354
87.06600189
87.94499969
88.8239975
89.70200348
90.58100128
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
4458085
2104810
2498828
4207684
3844166
13283629
18867586
16238974
5886500
5773360
9447874
5727622
3928861
3538104
2011669
1605520
1324630
764629
516168
717695
1625949
2703303
3528347
2892114
3114626
4574462
3176240
1491659
985546
2087487
2705074
1729882
2310631
4894273
4216283
2981522
2868997
3077924
3975355
3903228
3908308
2424776
1497122
2887034
4434554
6357535
1820956
938317
1091865
2917711
5399943
5768327
5179049
5976653
5608457
6418393
5199745
3303590
1443824
3094804
4574745
6619229
6713564
5799867
6336296
7124497
6814253
6579114
404711
213740
325459
374072
385077
384072
571372
476035
446876
439543
408786
475683
411509
388092
357635
335159
215218
116332
46247
113729
164059
148564
231779
299259
254074
408200
284947
79191
98589
197121
180207
324278
524945
503183
483193
422453
420144
556469
561082
599411
469768
391642
168731
396250
425885
437060
199014
95749
167667
381290
539022
564750
566288
538313
548661
496854
403170
360649
207708
310852
460599
549376
558536
561971
612242
595681
565045
560019
1998120
1128555
1747990
2246643
2042783
1825545
2052292
2672354
2250541
2342277
2022843
2551051
2276989
1694604
1423081
1621213
1064082
463437
345214
891690
1050066
1231636
1206505
1023045
1637354
2690368
1581109
506018
756015
1286582
718227
2616268
3760486
3460236
3155757
2700267
3395066
4998129
5146895
3643046
2334587
1349685
888247
1897879
2455051
2772358
1292908
971826
1441598
2791294
3295038
3351868
3278016
3081362
3084090
3107644
2145445
1681427
1467384
2197137
3248473
3653394
3487641
3904693
3262518
3523645
3426594
3279953
53
83446
67479
115799
85815
127215
98884
59376
133307
86228
98825
100127
121300
75464
49559
102592
95100
33234
26019
42166
28266
96281
117159
148860
174822
119643
72566
47844
64639
95040
136263
148208
149865
107578
87173
134843
135551
1000062
140107
211552
140343
113255
65173
64580
114911
89776
118462
196590
154360
95692
82147
96814
141288
133363
111659
93267
97109
124671
50032
271463
179791
136501
158264
110122
189728
121772
139633
167429
116863
1865383
2772453
1921362
2648516
3036911
2109394
543709
665422
2402875
2676630
3586370
3202133
1327595
590206
743898
1320779
1574866
911659
1140875
741973
2123451
7276146
6427229
9878416
8095106
2951767
5857890
13430293
13403738
7617881
5354323
4566595
942017
485519
2037290
4151267
5249641
1656307
1382080
900556
659947
4852221
10515960
7783209
3068309
1869966
4795048
11571052
10631392
4422388
1100004
720802
508617
1052771
1027156
133114
61742
276446
829329
723025
955339
337006
57893
35091
22800
19985
18506
16433
33559216
37224684
34364168
33416524
33952336
32601932
32506110
32716088
32653340
32537106
32650128
32864454
32498550
32227902
32121116
32171768
32172904
32381936
32254552
32079726
32787908
33254740
32779404
32942512
32639356
32536350
41404984
57614760
58549552
47341856
36436744
34249068
32755780
32399136
32675264
33001856
40401964
35450540
33282712
33233948
32530302
41037192
57409884
50260392
37677528
34475112
40233752
48035104
47485304
37660140
32776192
32398758
31992786
32093144
32238108
31982580
31953664
31809078
32551470
32453946
32932872
32431456
31955364
32105240
32075380
31938164
32013198
32010552
21172
95650
15398
11694
29463
11991
7697
7697
58039
22058
15396
113518
6069
5475
5920
7105
7844
10953
6808
6364
19395
36422
44269
32130
28130
10215
7548
8732
17469
18653
31092
30202
6807
10805
20282
58780
19395
12286
29759
6661
7845
10856
4142
15099
11548
6808
6956
33756
59225
35386
10807
9917
4883
4143
4289
4291
3105
5327
58484
8882
5031
4289
3994
2808
3551
3699
3402
3697
91.45999908
92.33799744
93.21700287
94.09600067
94.97399902
95.85299683
96.73200226
97.61100006
98.48899841
99.36799622
100.2470016
101.125
102.0039978
102.8830032
103.7610016
104.6399994
105.5189972
106.3970032
107.276001
108.1549988
109.0339966
109.9120026
110.7910004
111.6699982
112.5479965
113.427002
114.3059998
115.1839981
116.0630035
116.9420013
117.8199997
118.6989975
119.5780029
120.4570007
121.3349991
122.2139969
123.0930023
123.9710007
124.8499985
125.7289963
126.6070023
127.4860001
128.3650055
129.2429962
130.121994
131.0010071
131.8800049
132.7579956
133.6369934
134.5160065
135.3939972
136.272995
137.1519928
138.0299988
138.9089966
139.7879944
140.6660004
141.5449982
142.423996
143.3029938
144.1809998
145.0599976
145.9389954
146.8170013
147.6959991
148.5749969
149.4530029
150.3320007
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1108
1117
1125
1134
1143
1152
1161
1169
1178
1187
1196
1205
1213
1222
1231
1240
1248
1257
1266
1275
1284
1292
1301
1310
1319
1328
1336
1345
1354
1363
1372
1380
1389
1398
1407
1415
1424
1433
1442
1451
1459
1468
1477
1486
1495
1503
4679593
2892976
4964463
5805962
6207374
6268020
7695891
6355291
6268776
5884751
5621049
5962950
5342369
2902910
1905652
944681
1158647
1090093
1210315
1350547
3731652
6076185
5055396
5440200
4235514
1364155
1782902
2881565
5767004
5262067
5203761
5173261
6404100
6292377
5501365
8454159
8617172
11713464
9850774
6780375
4411449
2572255
2115158
2090293
624261
1126960
924104
1158942
1460551
4388486
4567374
2810666
770698
314942
534530
1777557
1640461
633292
525054
784766
1685768
3001084
3486011
1607888
795132
757964
1444120
4838306
342137
273297
427536
479230
502471
524239
567470
628564
600116
565754
523170
487272
442266
232903
196706
207885
405536
264720
181979
173286
359053
467754
433749
461367
286663
190084
233731
277318
454270
467639
492534
470061
487803
510043
512586
485382
479700
476688
555288
519266
423459
244671
226398
199367
72033
97050
97997
157080
238344
406665
471543
239645
93976
74340
178313
382828
214863
75640
74045
87114
193809
310378
349117
128455
117812
81199
186416
262177
1588964
1806911
2918420
2679583
3147653
3296940
3807382
3746524
3529552
3056248
2820506
2754841
2234996
1208041
1222062
2332697
2548984
2000530
948993
1184268
2534006
2883904
2935359
2703338
1324140
1087034
1300722
1750365
2693404
2836524
2829377
3115854
2918266
3049562
3044885
2810808
2981487
2746028
3136077
2960425
2215234
1309061
1242167
1103890
555226
493659
700954
1004588
2038093
3172046
2371312
1104303
537011
593495
2187203
2998107
1119801
528674
473256
596983
1540013
2392421
1986414
817759
698647
897957
1189359
1299416
54
42048
48967
71147
73335
67656
76053
85339
78302
84039
130468
90308
86465
107224
44825
25014
46956
67714
71263
29212
58312
101722
97465
96223
52752
64108
82915
49618
72625
113610
84276
120650
132241
205991
133719
103439
90428
249225
105272
102375
110299
72329
36666
47727
30574
40806
24481
50209
155308
143596
142769
99061
37611
17385
20994
57189
70789
26966
21289
48849
37493
39919
45775
47785
35186
75878
88533
86109
70791
18950
24281
71219
188492
71219
23688
27982
17617
25169
363809
1390231
1046847
1026559
1094529
181828
864569
997247
1557986
1029235
303395
400968
1133911
1800520
1100748
538231
946164
641729
515876
694445
378616
1031450
1214172
749674
703919
1232386
1137467
1483951
541045
618931
466715
213811
1699825
887671
483297
1240519
1164417
513357
814673
219586
265487
1176856
1150945
421848
209072
877013
1009833
222697
171611
1680435
2774378
790540
200929
175017
148513
269338
2047354
4156465
4772888
32026996
31718358
32028128
31925692
32370976
32354344
32562620
32357744
32199552
32465476
34930412
34143228
32539184
32894504
31915864
32036256
31744628
34345268
33867664
32312764
32488912
32607414
32065552
32300478
32154948
32273452
32154004
32035312
32379292
32021136
32150034
32055344
32169124
32180652
32072544
32637844
32325992
31787720
32471712
32191424
31812480
36502704
34207112
32791688
31577552
31421440
31567724
33244722
31855950
32342248
31928716
31614030
31425976
30922856
31647104
33171200
31376456
31298400
32391008
32863508
32530680
31561866
31685850
31497416
31050054
31381938
33981256
34414820
3700
3253
3403
3402
4143
3402
3403
3846
3996
3403
3402
4440
8732
5326
6364
6513
5178
8585
5178
4143
4883
13028
11399
5032
7697
7104
7253
4439
4142
4734
10955
5475
5029
12731
9621
9623
6364
5031
3699
6067
4735
3550
2810
4142
5474
7993
14955
4734
4883
4291
7844
7697
4586
3402
6215
5327
3848
3846
14656
26352
7253
3699
3996
3550
5031
17766
16580
19691
151.2109985
152.0890045
152.9680023
153.8470001
154.7259979
155.6040039
156.4830017
157.3619995
158.2400055
159.1190033
159.9980011
160.8760071
161.7550049
162.6340027
163.5119934
164.3910065
165.2700043
166.1490021
167.0269928
167.9060059
168.7850037
169.6629944
170.5420074
171.4210052
172.298996
173.1779938
174.0570068
174.9349976
175.8139954
176.6929932
177.5720062
178.4499969
179.3289948
180.2079926
181.0859985
181.9649963
182.8439941
183.7220001
184.6009979
185.4799957
186.3580017
187.2369995
188.1159973
188.9949951
189.8730011
190.7519989
191.6309967
192.5090027
193.3880005
194.2669983
195.1450043
196.0240021
196.9029999
197.7810059
198.6600037
199.5390015
200.4179993
201.2960052
202.1750031
1512
1521
1530
1538
1547
1556
1565
1574
1582
1591
1600
1609
1618
1626
1635
1644
1653
1661
1670
1679
1688
1697
1705
1714
1723
1732
1741
1749
1758
1767
1776
1784
1793
1802
1811
1820
1828
1837
1846
1855
1864
1872
1881
1890
1899
1908
1916
1925
1934
1943
1951
1960
1969
1978
1987
1995
2004
2013
2022
14735574
22485992
20932316
22708634
16274790
6227314
1007016
742268
726130
186568
43529
759594
3132699
5789188
5331832
3034395
1138211
1484991
687928
148808
33017
25319
19542
102314
18655
16877
17320
17618
18061
18506
17322
17468
17765
18210
17322
16876
17617
17320
17025
17174
17322
16433
16729
17915
17172
17468
17617
18061
17320
17617
17174
16580
17174
17320
16877
17469
17174
17322
17912
273592
374549
412933
408966
291453
180680
173285
165539
103142
21643
7389
103613
330369
560964
469352
228170
123665
170150
53582
9874
4610
3839
3544
3662
3130
3367
3189
3189
3189
3544
3426
3189
3426
3308
3248
3248
3012
3367
3248
3367
3189
3189
3367
3130
3248
3426
3071
3130
3426
3189
3012
3248
3367
3308
3308
3426
3485
3248
3367
1289831
2371253
2561931
1644501
1084258
1097446
1674446
1122524
639626
149629
90605
921437
2556615
3709539
2607232
1180482
976439
819711
230181
57722
33177
30159
26848
25485
25900
25428
25604
25725
25249
25959
25428
25252
26079
24245
25547
25664
25545
24304
25428
24895
25251
25902
25310
25367
25369
25131
25426
25190
25902
24542
24659
25133
25013
25487
25013
25959
24659
24836
25074
53700
81260
70791
52870
41574
38618
29037
27144
22411
10289
8455
100956
541978
141998
87175
37493
26966
30515
14309
6680
4967
4552
4139
4078
4433
4551
4433
4433
4195
4255
4374
4316
4254
4315
4018
4315
4255
4552
4255
4075
4492
4611
4195
4195
4196
4492
4255
4255
4077
4196
4315
4255
4313
4551
4075
4077
4433
4315
4136
Table 6: Left hook carbonate down 30 raw data major elements
55
4543229
1523925
246979
86618
143921
431178
383649
579394
3375540
10978207
13082013
11946690
4830911
986137
285922
105719
139628
44419
32721
66333
18504
17323
16433
15398
16582
16137
16137
16728
15990
17322
15545
15842
15545
16729
15841
15990
16877
16137
15990
16137
16580
15841
14952
15841
15841
16434
16433
16729
16433
15545
14803
15988
16879
15396
16433
16285
15101
15990
16136
40550896
35318996
31618756
31216564
31109022
31307472
31201064
31234896
37403668
48899216
56888244
56725704
44362648
33911136
32411610
31691708
31327696
31425596
31583790
31719304
30875228
33153624
30721004
30685852
31920588
30667140
30683584
30707396
30717414
30673756
30676212
30707964
30634632
30642570
30638980
30607984
30599668
30572452
30662982
30625938
30585304
30620836
30573584
30561868
30597966
30603258
30634254
30676590
30529360
30475304
30536730
30525390
30472660
30502900
30544100
30466422
30508758
30484188
30524634
7251
6513
6363
3846
6364
5772
5178
6216
11251
4882
3699
3107
3848
4289
5624
3254
7253
4289
3699
3551
3697
3550
3256
3402
3550
3699
3105
3700
3551
3699
3107
3553
3994
3108
3105
3551
3550
3107
3551
3550
3253
3550
3403
3699
3402
3402
3402
4142
3254
2810
3699
3697
3551
3403
3256
4291
3254
2958
3402
left hook carbonate minor left side
Ave blank
49,425
27,908
30,309
42,167
136,175
767
914
53
727
-
Trace for Mass: Distance (um) Mn55(LR) Ni58(LR) Zn64(LR) Rb85(LR) Sr88(LR)
Low
Low
Low
Low
Resolution:
Low
Mo98(LR)La139(LR)Ce140(LR) Th232(LR U238(LR)
Low
Low
Low
Low
Low
Time
[sec]
Intensity Intensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
um/s
0.90
1.73
2.55
3.38
4.20
5.03
5.86
6.68
7.51
8.34
9.16
9.99
10.81
11.64
12.47
13.29
14.12
14.94
15.77
16.59
17.42
18.25
19.07
19.90
20.72
21.55
22.38
23.20
24.03
24.85
25.68
26.51
27.33
28.16
28.98
29.81
30.64
31.46
32.29
33.11
33.94
34.76
35.59
36.42
37.24
38.07
38.90
39.72
40.55
41.37
42.20
43.02
43.85
44.68
45.50
46.33
47.15
47.98
48.81
49.63
50.46
10 Intensity Intensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
52061
53164
53265
51058
51660
47645
49452
46943
52160
52864
48849
46841
50956
49852
48347
48950
43933
51860
49353
50355
50957
51459
45237
45538
50957
69047
599270
861588
1296792
1604920
1496488
1914784
2896512
1518488
779612
633670
1220148
1025208
524812
538920
306648
388456
258550
622676
1534416
1243460
812276
664336
1014236
1331488
814852
528240
492036
206748
471408
744832
830932
696780
643268
1455766
1316384
34302
28283
28283
30489
32797
24971
27380
26377
29085
27179
26276
30289
27881
27781
28885
26477
25072
27680
27080
28583
27379
28584
30490
27479
26677
37414
171469
210062
322454
388638
335540
628644
408916
650770
363142
200312
616400
514300
202021
121431
151573
146045
129566
150564
267595
224844
185638
175885
304028
252211
207777
156792
145244
87492
131476
208051
153074
159205
155487
575348
333430
32595
29887
28784
30290
30991
27379
30389
29988
29687
31593
26979
32496
33599
29386
29587
29487
32395
30388
27781
28784
32497
31593
29987
28885
31193
37612
69923
65911
73941
73741
58684
72133
66413
84178
69925
70227
132700
103263
66612
117487
51760
53433
94527
63100
52361
58183
53767
60391
85987
64306
52562
61795
70828
54471
67215
61093
53467
50254
62701
73739
57681
46240
43632
42528
46341
45137
41825
42127
41525
40622
42428
39418
41424
41826
38817
44535
43632
42730
40121
42228
38414
38415
42027
42930
41224
38416
102451
410220
561732
434392
306043
273328
256030
361356
472972
449240
479380
317914
379966
408084
382724
304532
458698
714476
466262
364760
532630
511254
392190
317922
349559
295268
435516
326286
245767
436910
370498
196993
282185
377052
307654
276867
56
148058
142140
139766
140947
145689
141543
137988
136806
140368
139766
140953
134432
129701
133257
130292
133257
127327
130292
128514
130883
132064
132660
127333
123777
128514
4943756
5814349
4562341
5419938
5559333
5265167
5364231
4391865
8780512
5369236
5166762
7147856
4157225
4429461
3431661
3323872
2584693
920395
3184083
3115777
3416376
3787431
4556389
4422564
3611310
3120118
2869587
924411
1474767
2348975
2923416
2632085
3141440
5720203
3978823
2068239
600
300
200
1001
700
1202
701
200
701
1201
801
400
500
1001
901
500
800
900
500
700
400
500
800
600
1101
1102
2305
2706
1602
2104
3307
2606
4109
3607
1703
1702
6517
5112
1602
1703
1603
3508
3207
2404
1402
3207
2906
1603
2405
2305
1904
2906
901
700
2606
1903
900
1602
2906
6416
5213
1402
701
801
1102
1301
1201
200
601
1001
1002
800
1101
901
901
1201
1602
200
600
1201
600
901
400
501
500
900
19153
26979
59103
45740
34100
29386
34603
60390
186153
88295
37312
24871
24771
30188
22565
23667
14240
10226
33901
20056
44936
45839
57179
22264
21662
29486
30088
73475
57681
47044
30289
22063
36609
33398
39419
24070
0
200
100
0
0
0
100
0
0
100
100
100
200
0
100
0
100
0
0
100
100
0
0
0
200
69728
118522
137200
176592
130574
114604
165451
206458
426456
312831
96225
111202
81972
73238
86389
77855
53066
46845
97832
102666
127057
220979
151267
97933
68720
96527
114704
98141
177232
151066
103858
120534
102955
104961
118922
65106
500
601
600
600
902
400
300
801
1101
1101
700
1001
900
400
700
500
700
800
500
400
600
1001
500
500
700
10027
12133
14339
15743
13136
11331
13337
14942
22866
12735
9926
17149
11030
8221
11631
8522
21361
14840
10930
9726
20860
26878
13638
8824
9424
13136
11532
14039
17551
14742
10026
6717
11731
20358
15242
7118
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
11532
12032
8221
10728
10327
9125
10829
16445
15443
8321
16349
9726
21165
24074
15344
9426
57882
39318
17047
14339
23870
21160
16446
10729
11633
10128
9225
12133
18152
25376
11832
6618
10829
25975
16948
6717
51.28
52.11
52.94
53.76
54.59
55.41
56.24
57.06
57.89
58.72
59.54
60.37
61.19
62.02
62.85
63.67
64.50
65.32
66.15
66.98
67.80
68.63
69.45
70.28
71.11
71.93
72.76
73.58
74.41
75.24
76.06
76.89
77.71
78.54
79.37
80.19
81.02
81.84
82.67
83.50
84.32
85.15
85.97
86.80
87.63
88.45
89.28
90.10
90.93
91.75
92.58
93.41
94.23
95.06
95.88
96.71
97.54
98.36
99.19
100.01
100.84
101.67
102.49
103.32
104.14
104.97
105.80
106.62
107.45
108.27
109.10
109.93
110.75
513
521
529
538
546
554
562
571
579
587
595
604
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
1041
1050
1058
1066
1074
1083
1091
1099
1108
787956
756876
828276
715184
656672
459368
576732
669156
1371952
1289176
690612
966056
810856
1623528
1662392
714488
733616
948052
1667912
1483016
898028
664012
784752
489788
724016
612842
320032
374732
364440
399270
835096
4358128
4936832
2515472
656322
1062384
1357776
1451760
748012
941860
1017160
1011976
966636
1179944
1157972
637316
370298
278262
278163
278764
265582
314726
263374
263368
400843
292693
194780
805392
2056576
2805424
1897640
1888832
3180448
4541280
3554336
2283760
1104540
943260
995392
1412600
1862632
1698776
1505828
138913
321748
385516
394368
373824
195593
147450
174579
127265
120228
160717
193375
222537
241048
185637
200212
215098
280978
415804
326736
161122
127988
110286
162519
179537
195310
92914
107273
146044
145740
176488
409588
436410
225349
73840
110587
151066
113497
91305
83677
76247
81167
76348
80464
75244
49252
34302
36007
31292
35805
68647
33701
30890
37311
114245
31191
131190
114000
834992
1065824
646572
538474
2233456
2717792
2881680
1903600
483812
162217
231182
1367832
2166392
2747280
1750768
52061
70828
65409
68218
61393
68821
59086
67317
45137
46542
109127
72233
75625
69121
57278
56978
55173
57681
58786
52864
43631
55172
45539
76865
54570
52161
47245
72937
50054
51861
51359
47445
50055
46341
43331
49251
46542
50957
165880
40723
42428
56379
46943
40923
41927
40019
39116
43431
39016
45137
42528
38717
39718
47344
38315
41424
33499
62001
281772
52663
63908
68123
78657
93815
177720
85282
67013
79698
66512
131574
139913
136903
104258
375330
443168
393470
533644
417954
398196
374620
343492
243151
243152
326499
457720
611060
378952
468512
449138
433304
355384
321856
384502
405684
321866
333130
440378
368198
209763
171060
293462
492986
668140
437516
210368
89699
83576
57681
127663
148756
229875
299798
157898
118519
105463
116014
133183
99842
62902
43031
38415
40020
40723
41424
42829
43230
36608
42127
42427
39518
38716
38917
50757
52964
68419
110184
242853
177491
230592
199404
198098
208761
201719
205940
196893
277555
57
2452027
3407203
2290592
2677817
3699610
5119124
3320896
2792593
3422767
2693085
3694740
3431111
3527338
7231911
5697246
4784416
4557701
4461626
7339774
4845981
3916742
4629248
5542520
5891969
8902116
18486846
18481932
11956943
5506988
1927853
1400738
2381968
4434389
11311319
11495500
11647125
12228111
18957030
9914656
6967485
8589176
10703590
10961338
12325871
13939837
15910304
15780555
15865322
15068025
17917484
15736802
16275735
17519450
14584846
9674816
4083747
4522038
19353316
13402585
32289704
34375696
25399804
13318074
7147254
4121665
4143440
7142830
11300074
15434780
11328463
6330150
7218401
7477103
2004
2905
1703
3206
2905
1903
1703
800
1001
1001
2707
3307
2906
2204
2605
1302
2103
4410
4411
2606
1301
1102
2104
1001
1301
1602
1602
1302
1502
1602
1803
1302
1804
701
400
2305
500
1402
1001
700
600
1301
3909
800
901
901
1402
8323
1001
800
600
500
300
900
3609
1002
1602
2907
4812
5814
7018
36911
103657
143733
83578
52562
12934
7118
15041
75646
144936
105770
51058
34001
45640
29888
50857
67452
40924
38918
53366
27380
25173
34402
40522
24570
76158
44134
79714
40522
72233
51659
43030
27680
24270
24471
27580
182021
42026
17649
24170
21662
18452
20258
13638
21160
14139
22665
35405
30389
30289
31292
41625
50054
49651
44536
55779
27179
12434
3909
3106
2404
3106
1502
2204
2405
1402
2405
3307
8522
20057
21661
20759
34000
33900
279199
184034
28283
37211
45237
35606
33600
87893
268702
276344
102451
92812
140416
108980
137403
97832
155597
161018
95924
96226
58785
112897
117018
173611
160623
140419
129968
124345
315614
161717
181375
81368
67315
69625
91610
345112
110486
43230
91209
74545
50656
40122
95000
55473
40822
58784
94720
89601
91608
94624
80063
92510
113999
84781
88595
60993
31392
7921
6616
5615
4010
3909
4411
28394
7119
16849
18152
49051
82974
42027
84079
115406
86587
295270
408176
86292
111997
105162
103456
91310
323868
956216
928960
315402
9626
12535
13336
16948
13235
17650
16847
10829
9325
8723
8422
12233
16346
11130
10127
13738
12233
31192
26878
17348
6617
6316
8021
9625
7520
4711
8723
15944
11230
11932
7219
3307
2606
600
2404
3608
4911
11932
6216
2906
4310
7218
3709
2003
800
901
1101
701
1302
500
600
600
200
701
1603
1202
1603
701
801
1703
1603
5313
20057
10128
6517
7920
8221
6516
3407
66010
193474
149657
43530
11231
11331
18351
30991
12534
10629
12333
10429
6918
5313
10829
18954
18051
22464
10829
17950
19455
56705
26979
16848
13036
5413
9726
9325
5212
11632
10328
13939
11732
13838
4912
2103
800
901
2204
2404
2105
6716
3207
3308
1903
7219
4510
2806
1101
300
200
0
100
0
0
100
0
100
0
500
400
100
1301
900
2004
1202
7218
5113
5213
10328
9326
4711
4611
27481
63903
62900
16446
111.58
112.40
113.23
114.06
114.88
115.71
116.53
117.36
118.18
119.01
119.84
120.66
121.49
122.31
123.14
123.97
124.79
125.62
126.44
127.27
128.10
128.92
129.75
130.57
131.40
132.23
133.05
133.88
134.70
135.53
136.35
137.18
138.01
138.83
139.66
140.49
141.31
142.14
142.96
143.79
144.62
145.44
146.27
147.09
147.92
148.74
149.57
150.40
151.22
152.05
152.87
153.70
154.53
155.35
156.18
157.00
157.83
158.66
159.48
160.31
161.13
161.96
162.79
163.61
164.44
165.26
166.09
166.91
167.74
168.57
169.39
170.22
1116
1124
1132
1141
1149
1157
1165
1174
1182
1190
1198
1207
1215
1223
1231
1240
1248
1256
1264
1273
1281
1289
1297
1306
1314
1322
1331
1339
1347
1355
1364
1372
1380
1388
1397
1405
1413
1421
1430
1438
1446
1454
1463
1471
1479
1487
1496
1504
1512
1520
1529
1537
1545
1554
1562
1570
1578
1587
1595
1603
1611
1620
1628
1636
1644
1653
1661
1669
1677
1686
1694
1702
1565760
1539648
498500
129568
93130
100151
195384
227761
385618
262365
325384
481108
1096668
1247880
819188
498946
377402
518172
766800
1053340
932284
865516
839976
976564
834060
589732
469420
492722
424730
480634
640336
700788
634386
517534
155184
104358
220924
546082
743246
391556
605692
805504
2706032
4263376
2299624
961080
633392
1005488
1596824
906992
470734
229370
638206
498642
864716
1327848
716012
298904
238122
230385
196303
153582
189456
165934
176790
273263
274350
259171
374342
333954
383596
528730
2881936
3733408
1005536
305127
101766
47344
29386
54491
33097
35305
26076
31493
51258
156193
136497
130872
173704
88996
93414
205847
959008
755628
247995
266290
197702
189253
136295
133784
118217
117513
160122
137904
167545
75445
58286
32896
28584
64806
124645
161926
132580
150662
297098
451538
310066
139309
117313
184127
203628
134086
109581
85685
156395
130471
97531
47947
39920
31091
32295
46748
35807
29386
28483
28783
31594
35405
28282
48064
32696
29386
28483
32997
126856
95021
77592
39217
35204
85552
41826
40822
39720
43130
41224
44134
77354
70728
82474
85484
80062
95625
79460
82372
94017
137361
58283
59488
52763
50656
53467
46843
46843
57982
62397
59387
52061
61798
46742
39618
46240
52161
53365
55272
52764
60692
55372
50254
174755
51458
48749
57279
52161
48649
46140
52362
44536
45840
43733
51073
50860
36709
37311
41425
39719
39419
41725
39719
56678
40723
39217
41123
72132
48147
45037
42328
261293
87291
47947
43633
39217
54773
41928
53869
38615
49956
51663
48248
122540
269328
368984
332920
268098
270816
274034
199405
294160
486458
312882
380376
314494
356492
436716
401658
378070
285200
308756
354780
311172
168155
77959
43331
79073
174078
349242
359810
406062
325374
185034
178501
318544
328394
427748
603164
359110
398626
436926
296981
372626
427008
179504
75345
43130
90788
38416
34601
36107
39518
41926
32897
38716
40221
142557
55777
37211
54389
38415
48350
58
3583480
1574848
1231353
1182189
950009
2165952
9693243
13248711
12726268
14156006
14802764
13210060
8988982
6070255
3466591
2302186
3324065
3285966
6372277
5774116
3902078
1041075
5367367
6339509
8093832
4491223
3191159
2203268
3252194
5087644
5901431
7185287
5554403
8204821
12691822
15838106
15768270
11012227
5188948
3338643
6474195
4543348
2860114
1290511
1086394
6597967
4851323
3365299
4225385
5845156
3086937
2318770
2887353
4595464
8139616
13295394
15148114
14045818
16623400
17866500
14967430
15307960
15968894
18206086
16174431
16783388
16162618
13423347
15573316
14788636
18265338
16114707
130068
103154
25875
5914
3509
1102
1001
802
901
1101
900
1101
1302
1903
1002
1001
901
1603
1502
1102
3607
1202
1001
2304
1201
1202
2104
800
2204
2103
1403
1202
1803
1201
501
300
901
500
1803
1603
1401
1402
2004
1402
2405
1603
2504
2504
1903
1803
1502
1403
1503
3106
2505
1803
300
900
300
601
601
400
1503
701
500
200
500
901
801
600
300
1101
30288
13538
5112
2405
1302
1001
1001
1001
701
300
3006
18252
43933
89038
64205
23367
35206
29988
21360
23868
29084
39720
43733
55172
48649
79511
40422
43232
51058
34302
41926
74642
46643
13838
5714
7720
16848
30088
30289
44233
44134
33198
24369
31292
53468
52764
26881
23769
54972
41425
12133
43833
32295
41725
34903
20959
7620
3808
1101
700
1301
1302
1903
1000
20265
1202
1703
601
901
1503
1702
3207
104561
36415
14942
8121
23471
2405
3107
4511
1503
7922
6016
43631
96328
137002
169865
124032
240865
111489
72634
108476
224549
103856
154183
105061
156196
147547
115006
103458
147849
113298
146447
221827
129566
115344
16948
22966
55673
132179
77653
159919
128762
108375
85183
118461
163736
150268
62899
69925
201955
101146
55272
123160
128271
121932
92812
52362
26777
8623
5011
1703
2004
1101
1703
1101
9527
1804
700
2305
2304
1101
600
10630
13337
2705
1201
801
901
701
901
1202
300
400
500
1903
3708
8623
12333
8824
11332
10227
7420
8221
10328
9023
10828
11131
15844
15142
13537
13036
12735
12936
18151
22865
12935
4711
1702
2004
1804
9125
8221
11130
10228
10828
5013
7019
81569
23468
12133
13236
10729
9324
6717
7118
12835
13236
6416
1703
1202
1101
100
400
400
1201
701
100
901
400
500
500
801
800
400
900
5814
17754
1603
100
700
100
1804
100
100
100
1303
3408
7720
11833
13737
8021
9726
7920
5614
13739
20059
13738
8722
11432
16547
24671
14942
29592
14943
13437
18251
22965
9826
4411
2204
1503
2605
9926
29592
13437
12835
12033
19957
19956
95726
22164
22668
15343
10830
16948
10729
7419
16546
18050
8522
3507
801
400
100
200
0
100
0
0
200
100
100
100
3208
100
1002
200
171.04
171.87
172.70
173.52
174.35
175.17
176.00
176.83
177.65
178.48
179.30
180.13
180.96
181.78
182.61
183.43
184.26
185.09
185.91
186.74
187.56
188.39
189.21
190.04
190.87
191.69
192.52
193.35
194.17
195.00
195.82
196.65
197.48
198.30
199.13
199.95
200.78
201.60
202.43
203.26
204.08
204.91
205.73
206.56
1710
1719
1727
1735
1743
1752
1760
1768
1777
1785
1793
1801
1810
1818
1826
1834
1843
1851
1859
1867
1876
1884
1892
1900
1909
1917
1925
1933
1942
1950
1958
1966
1975
1983
1991
2000
2008
2016
2024
2033
2041
2049
2057
2066
726524
917120
2299184
1396736
480626
520456
476348
1341576
567284
383084
599508
579458
538558
855572
1030620
1712736
674794
156601
65508
51459
46241
49852
46241
51258
45840
50054
45638
45839
50356
46040
46842
46341
45538
40823
46842
46241
47344
44235
49854
48950
48247
44334
45138
46341
33398 50756
76548 59186
671588 86587
390656 67516
167344 72236
137603 47846
162029 49653
319852 69927
168448 54971
156890 266513
225651 57782
179904 53165
136296 66011
113497 76952
149866 70127
132388 99444
53365 38616
29989 29185
28683 30289
27280 26877
27279 29687
27982 29487
23467 24370
28684 29587
26176 28985
28683 28984
24270 26074
25974 28182
27480 26978
27179 29085
26176 31391
24571 29988
28784 29987
27078 26978
23869 28483
24069 25474
23367 30690
27480 28383
27279 24871
25474 27982
25173 28283
28884 31894
28282 26076
27579 27581
53467
172874
301106
410016
398626
343510
317218
358822
467280
543884
488954
553204
547010
324966
318122
286612
102852
47043
40722
39720
38716
39117
38616
37713
34202
35305
37713
38215
33298
38415
33801
36609
36309
39819
34401
38013
38215
37813
35605
37913
36509
34503
35205
37512
13775170
11173916
4855044
4079653
2107327
3418013
5472275
6861620
4483453
3051405
4977439
2757652
3654953
5095960
5181860
4043490
819114
222093
152210
117853
120222
110157
115485
111333
110152
117263
110748
112526
108380
113111
108374
105415
109561
105421
114298
104234
113117
101865
107198
108970
108380
110157
107789
106602
200 13036
26275
1502 59993 123446
3207 134062
86389
2304 25373
54670
1803 27379
97633
1202 1730168 3718816
4209 1379144 2145536
2004 205137 357941
900 83579 212491
1403 44234 115806
1703 120629 283124
1703 54470 135092
1402 35004
90503
801 38416 121936
1001 66913 164026
1000 46140 146042
700
8823
19655
1302
2304
11029
801
1302
1000
600
901
600
701
900
400
300
800
0
400
901
200
900
600
200
500
801
0
501
1001
0
801
1101
0
300
1201
300
800
600
0
1202
701
100
400
701
0
1002
901
100
701
1602
0
1202
701
0
500
801
100
500
400
100
701
600
0
400
500
0
600
601
0
600
500
0
500
800
100
1001
500
0
701
200
0
800
1302
0
Table 7: Left hook carbonate down 30 raw data minor elements
Carbonate Traverse Center
59
1503
9726
8321
17047
14540
84591
33097
13738
16044
20559
17650
11531
23368
20056
20458
7720
3207
500
1001
400
800
400
600
500
901
700
600
500
701
600
600
701
701
100
100
300
600
1000
600
400
700
1001
500
501
4411
10828
9625
19054
9926
11430
18352
13637
27181
17651
12836
10628
9023
20458
12534
7118
801
0
100
100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
left hook traverse center major
Ave blank
17,976
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
um/s
0.95
1.83
2.71
3.59
4.47
5.35
6.23
7.11
7.98
8.86
9.74
10.62
11.50
12.38
13.26
14.14
15.01
15.89
16.77
17.65
18.53
19.41
20.29
21.16
22.04
22.92
23.80
24.68
25.56
26.44
27.32
28.19
29.07
29.95
30.83
31.71
32.59
33.47
34.35
35.22
36.10
36.98
37.86
38.74
39.62
40.49
41.37
42.25
43.13
44.01
44.89
45.77
46.65
47.53
48.40
49.28
50.16
3,278
28,402
5,000
17,924
32,673,604
3,487
Mg24(LR)
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
10 Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
17617
17618
18210
18949
17469
17617
17765
17469
18061
17468
18357
18506
17322
17765
19395
17468
18061
18803
18506
17914
18358
17912
18207
18506
3168254
7421369
8061795
8466113
7048141
8098957
7923731
7223438
6532502
7057874
7395712
6861078
7737070
7328381
6824176
6203665
7051023
6454894
6991913
6851486
7358715
8041808
7164140
7426991
8276641
7592083
7529902
6254105
4856969
6462643
6980668
7688615
6948467
3308
3012
3189
3426
3485
3308
3248
3130
3368
3189
3248
3367
3189
3130
3367
3071
3367
3308
3367
3308
3486
3248
3012
3485
271463
561259
600592
595917
605438
614841
600356
618452
630873
651099
617389
637497
651805
583735
643114
624483
610349
604670
579952
608754
589116
647904
572617
609755
612003
596688
614785
556053
469237
595563
601182
598817
634774
28917
28741
28799
27972
27972
28563
28799
28564
28740
28622
28445
28090
28620
28799
28090
28326
28031
28858
28740
28799
29390
28978
27795
28149
2556190
3775299
3908473
3859451
4141368
3894227
3869799
3752642
3570187
3815768
3842795
4310594
4032150
3872114
3965764
4210920
4013203
4093575
3740854
3759565
3801877
4009801
3960164
4029126
4283614
4107041
4551664
3901244
3093623
3840220
4377075
4100851
4231828
60
4729
4848
4967
4848
4907
5084
5085
5026
5202
4907
5026
4788
5381
4908
5026
4967
4848
4908
5025
5262
4907
4967
5203
4848
50860
55711
49561
57543
67538
70436
75225
82620
130704
188070
177840
114438
110002
112724
123429
131828
120826
92910
89540
78894
86758
78007
81437
91906
123901
108109
118106
173819
109884
90249
414823
299023
121416
18653
17617
18061
18653
18506
17617
17471
17765
17617
17912
18507
18652
17469
18358
17765
16877
17765
18061
17471
17320
16580
17765
17322
17025
19985
18803
18653
18800
17617
18653
19987
18803
18209
19096
18950
19098
17914
17766
18209
17766
18653
18209
18210
18357
18358
19246
17914
18210
18655
18061
18949
19690
19541
18063
18358
18504
18653
31160996
32632362
32568858
32713820
32740470
32667516
32656176
32671296
32699646
32707396
32669216
32620076
32709664
32680746
32627636
32658066
32608736
32612140
32595696
32642756
32629904
32570370
32576796
32554872
32788854
33027372
33033608
33139448
33124140
33225066
33035876
32975586
33136424
33034176
33147576
33023214
33213916
33180462
33180272
33143228
33341490
33048918
33001480
32925880
33092010
32985980
32900552
32966892
33044382
33096546
33077836
33551092
33427864
33247746
33083694
33250580
33094278
3846
2810
3699
3994
3403
3107
3994
3550
2958
3403
3846
3699
3254
3699
3550
2808
3550
4143
3403
3107
3697
3254
3253
3254
3699
3254
3551
3845
3403
3403
3553
3699
3256
3403
3551
3846
3551
3402
3697
3551
3254
3699
3551
2959
3256
3846
3551
3253
3699
3402
3254
3996
3996
3403
3107
3848
3403
51.04
51.92
52.80
53.68
54.56
55.43
56.31
57.19
58.07
58.95
59.83
60.71
61.58
62.46
63.34
64.22
65.10
65.98
66.86
67.74
68.61
69.49
70.37
71.25
72.13
73.01
73.89
74.76
75.64
76.52
77.40
78.28
79.16
80.04
80.92
81.79
82.67
83.55
84.43
85.31
86.19
87.07
87.94
88.82
89.70
90.58
91.46
92.34
93.22
94.10
94.97
95.85
96.73
97.61
98.49
99.37
100.25
101.13
102.00
102.88
103.76
104.64
105.52
106.40
107.28
108.15
109.03
109.91
110.79
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1108
7108196
7183276
6952011
6152139
5941593
7441781
7685827
7234448
5792496
7958459
7673353
7283942
7603659
7643231
7369961
7285761
7360605
7686536
8199340
7685969
7294928
7581310
7576821
7442962
7010813
6663242
8002733
7860983
8297242
7879079
7154123
8000276
7943717
8458412
8216208
7113960
8040296
6844210
7338634
7054283
7217036
6906273
7453357
7729533
7742196
8289871
7542636
7189513
7066474
7015869
6915983
7203688
7316379
6754600
6927937
7315907
7860227
7998716
8056739
7231565
5923095
1247489
941716
1675402
2500742
4870294
7047361
8592011
7199577
610467
617741
660794
565160
480769
603312
641750
653760
675646
641106
628980
598345
595743
603013
592964
616382
631818
615673
622117
636431
581488
576934
620463
631168
585392
621645
605497
626379
619518
631228
646188
622356
671381
597636
630516
584444
624666
594497
606799
612242
617091
598932
611061
620818
578945
581134
571315
572853
628803
647077
628921
664052
616615
571019
611176
638622
589473
627264
601714
607570
363846
254311
381820
290152
268210
442443
616379
632054
623479
4295332
4182169
4337668
3180504
3421963
4112546
4147771
4391439
4372633
4062532
4027118
4278251
3920474
3835991
3554913
3843481
4042828
4563949
3767077
3998177
3870437
3590055
4013557
3973513
4206431
3927467
3701140
4331337
4404149
3715551
3852836
3806602
3912678
3920593
4033780
4138840
3800412
3994988
3867436
3789474
4013439
3857041
3813311
4344779
3753044
4063429
3889597
4160906
4031536
4395502
4040655
4107443
3948376
3627005
3858081
3997208
4111152
3778772
4045994
3995885
1766748
3010144
4371854
2373911
2200693
3407481
4110278
4138604
4405779
61
95101
111069
108349
59613
71263
61150
152762
167371
183458
95633
71442
79603
103734
80256
100422
111600
95928
66593
87291
83625
67005
89896
247156
94094
88713
79309
84453
98943
70140
79544
65351
70909
67833
82383
116213
88298
97111
101841
112487
135791
93443
94803
80195
67184
93088
64344
74162
117515
116923
119346
105747
82856
54410
48021
57127
58135
71796
83033
242483
126680
36843
21525
22531
40450
62807
149688
184817
134251
114320
21319
19098
17914
17320
18060
17914
17914
17912
17767
17914
18506
17617
18210
17914
17469
17765
18357
17172
17765
18358
17617
17914
17471
16728
18506
16582
18061
18358
17174
17766
18209
17766
18061
17766
20284
19688
17912
17322
17618
17025
16286
17320
18063
16728
17765
17912
17766
17912
18358
17766
17025
17766
19246
17025
18652
18357
17617
17471
18949
18358
20874
51674
587539
715173
105868
32276
22650
18360
18653
33076512
32993352
33015464
33111100
32968026
32992974
32887890
32752376
32740092
32961788
32877872
32720058
32877496
32796224
32845932
32834214
33004880
32903388
32828922
32751432
32826654
32728752
32844988
32806808
32676588
32712498
32768064
32547124
32529736
32672996
32448088
32544288
32485888
32528980
32719680
32637088
32570180
32705316
32599288
32635196
32634440
32713632
32643702
32481918
32458860
32625936
32408964
32689062
32670728
32705694
33332040
32585680
32583978
32383072
32471144
32607980
32553928
32499684
32518016
32644836
32379858
32435424
33448086
34145120
32451112
32431644
34050052
32576228
32568858
2662
3105
4291
2958
3550
3848
3699
3107
3848
3846
3107
4538
3699
3699
3403
3553
3846
3254
3254
3846
3699
3105
3699
4142
3107
3550
4289
3697
3699
3105
3699
4143
3402
3254
3699
3402
3551
3697
3699
3550
3402
3846
3402
3105
3551
4291
3254
3403
4291
3551
3107
3105
3846
3254
3256
3846
3551
3994
3254
3996
3699
3699
3699
4143
3845
3401
3253
2959
3550
111.67
112.55
113.43
114.31
115.18
116.06
116.94
117.82
118.70
119.58
120.46
121.33
122.21
123.09
123.97
124.85
125.73
126.61
127.49
128.37
129.24
130.12
131.00
131.88
132.76
133.64
134.52
135.39
136.27
137.15
138.03
138.91
139.79
140.67
141.54
142.42
143.30
144.18
145.06
145.94
146.82
147.70
148.57
149.45
150.33
151.21
152.09
152.97
153.85
154.73
155.60
156.48
157.36
158.24
159.12
160.00
160.88
161.76
162.63
163.51
164.39
165.27
166.15
167.03
167.91
168.79
169.66
170.54
1117
1125
1134
1143
1152
1161
1169
1178
1187
1196
1205
1213
1222
1231
1240
1248
1257
1266
1275
1284
1292
1301
1310
1319
1328
1336
1345
1354
1363
1372
1380
1389
1398
1407
1415
1424
1433
1442
1451
1459
1468
1477
1486
1495
1503
1512
1521
1530
1538
1547
1556
1565
1574
1582
1591
1600
1609
1618
1626
1635
1644
1653
1661
1670
1679
1688
1697
1705
7286517
7741676
2859653
3799420
6486575
10130731
7251718
7472304
8695228
7282028
8467011
8477831
7051826
7105243
7574600
7819804
6835492
7109046
7687481
7659792
8480336
7640231
7807968
7680960
6948443
7612495
8083199
7897460
7729817
6993709
8298092
5017336
4809318
6220699
7058300
7067561
7557590
8242148
7205909
6955838
7782831
6768657
7837310
6604274
6864197
6646799
7546770
6736645
7754670
7185804
7323656
7562126
7001411
6603920
7636923
7623599
8065481
7734400
7566804
7837499
8225847
6885223
7544880
8265679
2136940
261933
78178
50490
649032
572082
286308
371946
561023
618157
710596
670026
641516
648790
657188
670318
605556
639981
644239
620050
605143
653408
615611
609814
614725
621293
656125
593611
608400
578234
619397
631050
615789
633770
620759
643823
553395
602423
636195
628331
664052
598758
630398
639033
655948
617862
635958
627976
632173
644180
625132
628508
583854
642169
635008
622649
606920
640158
638386
672450
587817
634243
630516
666889
591006
615733
640867
598401
124492
19040
7093
4788
4075832
3746240
1857232
2748875
3625942
4251272
11529945
5415016
4074415
4176971
3994019
3994421
4187957
3975662
3967465
4093598
3875303
3915868
3929287
3912631
4456880
3834834
3753446
3990901
3904669
3892715
3963472
3781796
4124453
4036709
4265990
5541362
4372562
3998980
3989152
4094425
3974009
3849174
4070706
4453620
4122988
4091756
4136832
4109923
4012683
3837480
4371759
4027590
3770881
4282929
3782410
3939115
3820824
4323115
4308988
4176522
4036190
4065957
3970607
3749855
4203573
4126177
4189067
3964488
522582
84985
45537
32467
62
123842
187836
56775
76706
88120
87411
91018
84867
68307
81497
83212
73453
57779
55296
70671
57957
61564
56716
79190
70081
139278
128752
71678
67125
79544
62630
63280
83920
93681
85577
111542
65232
82501
177309
176716
128811
122896
99947
98411
86819
74044
105035
130939
144423
221722
470950
160334
129402
81199
69844
74575
73333
68248
82441
77415
102550
113373
114556
78776
90308
278974
346811
116508
109353
14664
6621
5262
4728
17766
27686
123342
133853
29908
21171
19839
17765
17469
17618
18061
17617
17172
16877
17765
17322
18360
18060
17766
18952
17617
18209
17763
21319
17322
17469
18210
16877
16285
18063
17469
17914
131482
33313
19098
17025
17471
17174
16580
17765
17320
18209
16877
16728
16582
17766
18357
16877
17765
17025
16579
17766
17912
17468
17026
17469
17322
16728
17025
18653
17322
17025
17765
17912
16285
16580
16285
16434
32602688
32721570
32683960
32680936
32609116
32606280
32360580
32416524
32496472
32551280
32374376
32414256
32295564
32447332
32276664
32272696
32300856
32215616
32204088
32395924
32329016
32172148
32323724
32310684
32255118
32207490
32154948
32140584
32155136
32340356
32472656
32503276
32132268
32295942
32431076
32380992
32325616
32293484
32406696
32229414
32327694
32323348
32190668
32356612
32201632
32170636
32313520
32221854
32290272
32195772
32231304
32153058
32150600
32265702
32211648
32445064
32216372
32101650
32065362
31976154
31879386
32027562
31957064
32029264
31600988
31317112
31284604
31298778
3105
3697
3994
3550
3254
4291
3697
3256
3105
4143
4291
3107
3846
3699
3697
3254
3403
3846
3402
3108
3699
3994
3550
3105
3254
3846
3551
3254
3699
3994
3551
3105
3551
4143
2959
3254
3699
3697
3551
3403
3846
3697
3254
2959
3994
4142
3254
3254
4289
3699
2958
3996
3996
2959
3403
3550
3699
3846
3403
4143
3550
3254
3402
3550
3107
3402
3846
3699
171.42
172.30
173.18
174.06
174.93
175.81
176.69
177.57
178.45
179.33
180.21
181.09
181.96
182.84
183.72
184.60
185.48
186.36
187.24
188.12
188.99
189.87
190.75
191.63
192.51
193.39
194.27
195.15
196.02
196.90
197.78
198.66
199.54
200.42
201.30
202.18
1714
1723
1732
1741
1749
1758
1767
1776
1784
1793
1802
1811
1820
1828
1837
1846
1855
1864
1872
1881
1890
1899
1908
1916
1925
1934
1943
1951
1960
1969
1978
1987
1995
2004
2013
2022
21468
19541
17468
18358
18061
17469
17174
17765
17323
17471
17174
17172
17618
17617
18063
17322
16728
17025
17172
16877
17322
18210
16434
17025
16877
17914
16580
17617
16877
17320
17025
17174
16729
16582
17025
17322
3960
3721
3426
3071
3308
3130
3545
3130
3426
3130
3604
3308
3189
3485
3485
3189
3130
3248
3426
3012
3367
3071
3544
3248
3426
3603
3367
3367
3071
3071
3485
3248
3189
3071
3130
3544
28978
27677
28563
26909
26966
25547
26138
27381
26907
26494
26020
26729
26197
26020
25841
26137
26433
26789
26079
26317
26729
26435
25725
26492
25841
26019
26079
26494
25961
25428
25607
25664
26019
26612
26197
25666
4611
4787
4788
4670
4372
4669
4731
4849
4492
4728
4551
4613
4551
4374
4492
4315
4255
4552
4611
4315
4255
4551
4672
4787
4254
4313
4492
4434
4492
4492
4493
4372
4729
4493
4669
4552
16434
16433
16582
16433
15841
16284
17322
16284
16284
16433
16877
15545
17025
16580
16582
17025
15841
17172
16137
15841
16286
15990
15990
15693
15988
16582
16286
16433
17026
15841
16434
17174
16729
16285
15544
16728
31406508
31230172
31318434
31228092
31248692
31255308
31235084
31231684
31271184
31266270
31223368
31226012
31215240
31245480
31256064
31143420
31269104
31157406
31154004
31214106
31253228
31132836
31143988
31218076
31153816
31124898
31198986
31194260
31190292
31166288
31159108
31088800
31033232
31096360
31151548
31105432
3107
2810
3550
3254
3254
3253
3403
3846
3254
3848
3697
3551
3107
3846
3551
3254
3403
4142
3699
3107
4143
3846
3846
3254
3699
3402
3253
3402
3551
3108
3254
3994
3994
2959
3402
4291
Table 7: Carbonate traverse center raw data major elements
left hook traverse minor center
Ave blank
45,961
25,280
27,609
30,962
122,001
722
772
43
672
-
Trace for Mass: Distance (um) Mn55(LR) Ni58(LR) Zn64(LR) Rb85(LR) Sr88(LR) Mo98(LR La139(LR)Ce140(LR) Th232(LR U238(LR)
Resolution:
Low
Low
Low
Low
Low
Low
Low
Low
Low
Low
Time
[sec]
um/s
10 Intensity Intensity IntensityIntensity Intensity IntensityIntensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
63
0.90
1.73
2.55
3.38
4.20
5.03
5.86
6.68
7.51
8.34
9.16
9.99
10.81
11.64
12.47
13.29
14.12
14.94
15.77
16.59
17.42
18.25
19.07
19.90
20.72
21.55
22.38
23.20
24.03
24.85
25.68
26.51
27.33
28.16
28.98
29.81
30.64
31.46
32.29
33.11
33.94
34.76
35.59
36.42
37.24
38.07
38.90
39.72
40.55
41.37
42.20
43.02
43.85
44.68
45.50
46.33
47.15
47.98
48.81
49.63
50.46
51.28
52.11
52.94
53.76
54.59
55.41
56.24
57.06
57.89
58.72
59.54
60.37
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
513
521
529
538
546
554
562
571
579
587
595
604
52261
51660
49150
42627
43833
49753
41624
46542
46341
44033
49351
47646
48650
48148
45638
46040
43231
45137
45639
40020
46742
42629
46341
45537
44233
47444
847244
826084
521462
223943
195791
170257
201113
194178
175887
184632
209862
216197
218911
237826
258739
450836
737248
972092
996860
442866
261460
185534
201516
261458
255222
171264
162016
179813
168951
164428
180306
170257
182516
149355
150360
157596
150962
133584
156489
168950
162318
170359
227860
191161
162921
163624
188148
30890
26877
23467
26075
24771
23669
26677
24169
26978
26075
24872
22664
29085
22966
24069
25073
26777
25474
24371
27078
23467
27782
22364
24570
26977
25975
44635
54570
37612
30088
26377
27178
29084
31793
30189
31492
32897
27679
27580
30088
32597
30389
55272
42226
36107
33198
28082
30088
109888
53669
31393
27981
29284
29284
27481
25774
24772
28985
28082
25875
28985
27480
34803
28283
23768
29186
28082
28584
29987
30289
28884
23165
52463
33600
27581
30189
27981
28081
29386
26277
28383
26978
26177
28383
29788
27179
27480
28282
24270
27881
24068
24170
26978
24570
27680
27681
28784
28181
25274
39518
39819
35305
33599
38214
39920
38715
42629
37411
34603
37813
35004
37511
36308
38314
35606
41324
39818
40221
43532
40120
38314
37112
45639
33800
33399
35204
38214
42228
55880
37512
39518
36006
36008
33198
34802
32996
31090
32295
61093
36107
40422
34602
38715
36207
32898
37311
35205
31994
33599
29286
30389
35004
29386
30189
32897
28783
29888
29989
30088
29386
36106
30691
31392
28383
29386
27882
27681
25674
31392
27380
28281
31492
29285
28182
31794
26277
29687
28884
25775
30288
30590
31894
24671
27881
27179
27781
28283
30489
32897
28483
27882
27180
30490
29686
28784
30388
26878
26878
26376
30991
26778
29285
28182
27178
26376
28082
28584
28182
28985
26677
27179
31193
26376
22966
25874
30990
29687
28984
28884
139181
132660
132666
124368
127923
123187
129701
124959
119040
123777
119040
122590
117269
121415
114888
122590
117263
112526
113701
117853
119625
116076
110152
111345
110748
512308
14316514
12747530
18521150
14822230
16155531
15498094
21118292
16621038
15684638
17356626
17547422
16660161
15519357
14967477
18297846
16468893
19754280
19151842
18164506
16478816
18159876
15920982
17687092
16561976
15842736
16723476
14491292
17685392
19341316
18572652
16927880
18513400
17566984
14490630
15478438
16693898
13616978
14707980
13724235
17957174
18629540
15939410
15374300
16692764
14420747
14862488
17920508
64
401
1101
901
400
601
1201
701
701
901
601
801
400
701
100
1001
1502
501
400
200
700
500
801
1302
1001
600
701
400
901
600
500
300
500
500
900
700
800
300
801
1302
500
500
1000
400
600
200
600
601
801
300
600
601
0
901
100
200
300
400
801
800
1202
901
701
400
600
0
801
901
1001
1002
500
200
500
500
1201
600
1202
801
500
1102
1102
1001
501
300
1502
300
1101
400
701
701
800
700
1002
902
801
1101
701
901
701
11331
80465
51459
17550
3006
2204
1602
400
1503
1101
1201
1201
2104
1602
2103
2105
6114
14641
12635
10929
4711
2003
901
1001
1201
1001
300
1303
1202
801
701
1002
1603
501
1403
500
1102
902
1201
1904
901
1302
800
1302
500
1302
1702
3006
0
0
0
0
100
0
0
0
200
0
0
100
0
0
200
0
0
100
0
100
0
100
100
0
0
43636
163626
102953
28182
4611
2405
802
3006
2304
701
902
1803
2805
3207
2906
6918
15944
46241
31794
23568
6918
1703
901
600
1903
902
100
400
701
901
1102
400
200
400
100
100
300
800
0
1101
1401
500
1101
2104
901
1302
3407
4209
901
401
701
1000
300
600
600
800
1200
100
500
1201
400
400
400
800
1101
400
400
400
801
1002
1000
901
1302
1803
2204
2404
400
800
1001
500
700
1101
300
1001
1502
801
900
400
300
200
1101
600
1201
701
200
801
600
300
500
801
600
501
600
1000
801
1402
400
800
700
200
401
701
901
300
601
901
1101
100
1101
800
1201
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
1201
300
100
100
0
0
0
0
0
100
0
0
401
100
200
800
3006
701
1001
0
0
100
100
0
0
100
0
100
0
0
200
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
100
61.19
62.02
62.85
63.67
64.50
65.32
66.15
66.98
67.80
68.63
69.45
70.28
71.11
71.93
72.76
73.58
74.41
75.24
76.06
76.89
77.71
78.54
79.37
80.19
81.02
81.84
82.67
83.50
84.32
85.15
85.97
86.80
87.63
88.45
89.28
90.10
90.93
91.75
92.58
93.41
94.23
95.06
95.88
96.71
97.54
98.36
99.19
100.01
100.84
101.67
102.49
103.32
104.14
104.97
105.80
106.62
107.45
108.27
109.10
109.93
110.75
111.58
112.40
113.23
114.06
114.88
115.71
116.53
117.36
118.18
119.01
119.84
120.66
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
1041
1050
1058
1066
1074
1083
1091
1099
1108
1116
1124
1132
1141
1149
1157
1165
1174
1182
1190
1198
1207
176085
163926
142425
153374
228018
211776
200210
207749
196390
172064
176587
204137
233291
273837
274438
170963
156690
169254
172467
159705
202025
237112
230274
298293
475436
540226
498034
583052
706384
427376
245771
194579
183022
164126
133483
131374
215901
174074
211877
192068
275543
250299
243683
220119
199105
209660
195182
179301
194276
194481
171763
141922
157193
169252
173773
239338
262662
276350
404804
249086
191364
209560
255928
366668
438026
215703
63401
44235
43632
44535
43230
44033
43231
62598
45140
32395
24972
29787
29185
26878
29586
26777
26276
31191
28383
31493
28884
27881
26677
25273
24671
27278
27078
27881
28483
29386
28182
35205
34201
29687
38114
36407
26677
28182
31091
29788
27179
29286
27380
29486
26477
30690
28182
30891
26678
29687
28283
25473
31393
27179
30590
29586
28684
26277
27782
27881
27580
29887
54067
34302
35606
102652
37813
30790
30790
28282
33800
41726
26778
23468
24872
21661
25975
24570
23568
24671
39317
40923
41826
35706
35605
39920
35004
36208
35205
35405
37612
59494
35807
42328
41124
36308
33399
39117
34702
39217
41324
35003
40120
37210
40723
37010
139884
35806
35506
33198
38515
46241
38717
38013
37210
39218
34803
34804
39718
35205
40020
41325
35204
34602
43633
36107
33799
36409
39117
37613
38515
37009
39519
37110
32798
46542
36007
39719
40120
39117
34803
38114
40221
43532
42227
31092
26678
22865
23567
23167
22364
26276
26376
26377
27681
27681
28785
28183
31895
25574
28884
25374
25474
29988
28283
24470
29988
26276
28282
28884
27680
27881
28082
27078
30088
29184
25775
32696
24872
28984
26477
27480
27380
27781
26978
30389
27981
23668
25774
25573
29587
29186
24872
25774
26175
23768
27581
26878
26376
30891
23968
29386
24270
29185
31393
24972
26176
30289
25473
23568
28383
28684
23567
27480
25775
24069
28083
24972
27179
26075
26175
27782
25774
25775
26275
30891
65
17506598
17706748
16609792
17392724
16386394
15499843
16423816
18532396
13870426
14659502
14863810
15508206
15791800
17316368
17141732
16969932
13512791
15174148
15807960
15601666
16822418
17035610
14786793
15173582
14346140
17314006
16575489
24844334
21918424
16320150
15364282
16005087
16259764
15098265
14630396
16285185
15264680
14568214
16417958
16441488
16671974
15102990
17892158
16600248
14642775
16807108
16789816
17384504
18329220
15781784
15929960
15615274
17834608
20821468
15762884
17974562
16416162
14946120
16460672
18808996
16723476
14498284
15145704
14044023
16410208
4328927
726717
235128
143912
117263
111339
108976
98900
400
700
500
1101
300
600
200
800
700
100
700
700
800
400
500
701
400
701
700
300
200
300
501
800
500
400
300
400
400
500
1001
901
701
200
501
300
700
400
800
700
1001
401
801
1001
300
500
600
300
600
901
200
500
901
801
801
500
701
801
1803
1001
1302
1001
500
200
1301
701
400
901
300
400
400
100
1001
2104
1101
700
1403
1401
1602
2104
2404
501
1402
600
700
1903
4411
1101
800
1203
1001
2706
1403
2806
3608
3007
6115
9425
9826
10328
20058
16948
6817
2405
2105
1702
1303
1102
500
1100
300
801
1803
801
1403
1803
900
1001
2505
1302
1101
1301
400
1001
1402
1903
1201
1201
1603
4410
3608
6115
1603
2104
3608
6317
8723
9023
2806
1102
701
500
1301
901
600
801
3608
2205
700
2104
3006
2104
3509
900
400
400
1402
2003
3207
6416
4410
1902
200
901
3407
2304
8924
6817
8523
28784
52262
33298
35906
42328
49854
13236
3608
4310
4712
1001
400
700
500
901
200
900
2205
1703
2103
2104
2205
1703
1704
3809
3006
1201
1000
3006
1602
1502
3107
6818
12433
8822
9425
2606
4411
12334
18351
23367
32897
5212
1602
300
300
0
200
100
200
801
601
900
300
1001
300
1102
700
800
400
800
400
601
1402
401
501
200
500
500
900
800
500
400
1603
800
701
701
1703
1502
500
500
300
600
801
500
300
901
901
1201
801
501
400
900
700
600
400
300
701
500
600
701
600
200
900
600
700
902
1000
501
700
600
300
200
600
700
300
100
600
900
800
400
801
1001
0
0
0
100
0
0
0
0
0
0
0
0
100
100
200
0
0
100
0
0
0
0
0
0
100
0
600
2004
1402
100
300
0
0
100
100
0
0
0
0
0
100
100
100
0
0
0
100
100
100
0
0
0
0
0
0
0
100
100
300
0
200
0
100
0
100
0
0
100
0
0
0
0
0
121.49
122.31
123.14
123.97
124.79
125.62
126.44
127.27
128.10
128.92
129.75
130.57
131.40
132.23
133.05
133.88
134.70
135.53
136.35
137.18
138.01
138.83
139.66
140.49
141.31
142.14
142.96
143.79
144.62
145.44
146.27
147.09
147.92
148.74
149.57
150.40
151.22
152.05
152.87
153.70
154.53
155.35
156.18
157.00
157.83
158.66
159.48
160.31
161.13
161.96
162.79
163.61
164.44
165.26
1215
1223
1231
1240
1248
1256
1264
1273
1281
1289
1297
1306
1314
1322
1331
1339
1347
1355
1364
1372
1380
1388
1397
1405
1413
1421
1430
1438
1446
1454
1463
1471
1479
1487
1496
1504
1512
1520
1529
1537
1545
1554
1562
1570
1578
1587
1595
1603
1611
1620
1628
1636
1644
1653
43833
41826
40020
47144
40722
39418
38616
39417
37512
41926
43229
45739
42729
44635
46642
44234
43029
41123
44535
47645
42829
42227
41926
46139
44636
41825
39518
40421
43732
43430
36006
36508
41725
43732
46441
38916
39417
39919
42829
42026
40421
45940
36608
43430
40221
42828
40823
42728
39819
42728
44735
43230
40922
44133
23066
24571
24872
27481
25473
22365
25976
22263
22264
24771
26075
23969
21561
26878
23868
22565
26376
23468
21762
25274
24471
22966
22363
25574
26177
22263
22765
25674
26978
25774
22966
26275
27179
23165
24570
23768
25173
23869
25173
25173
27279
28583
23768
26979
22666
25172
22765
22464
24270
23868
26376
25474
23167
27078
24671
22765
28082
22464
27178
27983
24571
23366
24571
26778
23567
23869
24069
24671
26377
26577
26375
26075
28683
25674
28583
25071
24370
23669
29687
24069
28382
23667
25173
24269
24971
26980
31393
26176
22565
25473
26076
26376
25072
24973
25774
28985
23868
24771
27380
26979
25574
22766
25474
26376
27981
25573
27180
28784
26577
30288
26879
32597
25874
25374
26878
25173
30892
27379
29084
27782
23768
26277
25875
30489
26175
23969
22664
27480
24772
22464
24471
22364
25875
25073
22364
25674
25774
26476
28181
24972
26377
26978
24471
26176
29386
26678
28684
25875
26276
21560
26177
23868
25976
26076
28383
26377
23568
23468
26175
27580
26477
26778
101269
104234
100081
99491
102456
103643
100081
98894
98900
101859
95345
101274
96526
98310
103040
100081
100081
99497
102456
97713
104228
99497
96526
100081
101263
97713
100678
103046
97128
96526
98900
101269
100678
99491
94163
102444
103637
100678
100081
95345
97122
94754
97719
99491
101865
92982
98304
99491
100081
97713
99491
100087
92976
101269
Table 8: Carbonate traverse center raw data minor elements
66
600
300
501
500
300
500
601
1202
500
500
300
800
800
500
500
601
601
1202
200
600
801
400
801
400
200
600
400
500
1201
901
901
600
400
901
701
300
200
1001
401
300
100
701
601
600
300
1202
700
700
1001
601
400
600
300
1302
600
300
901
900
501
501
1002
300
902
1202
600
600
901
700
800
1102
400
900
700
400
1402
600
400
501
1101
1001
601
1001
902
700
1201
1402
700
1202
601
501
1202
1502
1002
1101
601
601
701
1402
1002
701
800
1602
400
1001
801
500
500
901
100
0
0
100
100
0
200
100
0
0
0
100
0
0
100
300
100
200
0
0
0
0
200
100
200
0
0
100
0
0
100
100
100
0
0
0
100
0
0
100
0
0
0
0
0
200
100
0
0
300
0
0
100
0
300
300
901
901
501
400
300
200
800
400
0
400
400
300
500
400
300
500
500
400
300
700
400
1000
800
100
800
600
500
700
901
600
1402
500
501
200
701
700
400
200
800
700
400
1001
601
600
701
1402
500
400
800
701
200
400
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
200
0
0
0
0
0
0
0
100
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
100
0
Carbonate Traverse Down 30
Ave blank
222,993
4,252
25,307
14,635
167,118
3,852,310
1,990
Trace for Mass: Distance (um) Mg24(LR)
Resolution:
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
Time
[sec]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
um/s
0.954
1.833
2.712
3.590
4.469
5.348
6.226
7.105
7.984
8.863
9.741
10.620
11.499
12.377
13.256
14.135
15.013
15.892
16.771
17.649
18.528
19.407
20.286
21.164
22.043
22.922
23.800
24.679
25.558
26.436
27.315
28.194
29.072
29.951
30.830
31.708
32.587
33.466
34.345
35.223
36.102
36.981
37.859
38.738
39.617
40.495
41.374
42.253
43.131
44.010
44.889
45.768
46.646
47.525
48.404
49.282
50.161
10 Intensity
[cps]
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
268676
232571
225841
223216
227319
228468
225843
224692
222067
221247
222887
219276
219605
223214
221410
222394
220261
216978
219112
216323
218783
239956
658161
1054689
684581
594807
527845
526857
359281
1419238
1479450
1191747
1089819
1040253
1122625
726435
347791
315946
306430
341718
316276
315622
290672
313979
298057
296250
328586
361576
431989
433790
844770
1137906
1441517
1213895
1204049
1234904
1050099
4323
4323
4192
4125
4390
4521
3994
4519
4255
4193
4125
4321
4257
4192
4255
4454
3930
4059
3928
3995
4390
51067
213322
279602
180216
62210
22940
14158
34677
213845
264781
291794
323982
310283
308707
208078
203881
214371
212927
192802
178707
180938
171888
175888
161729
161007
195426
233579
197261
174970
80435
101347
96367
132489
218631
262490
276650
26415
25629
26351
25826
24384
26088
25762
25235
25695
25564
25498
25237
25040
25302
24385
25237
25040
24975
24713
25171
24844
856567
1659509
1857506
1192618
534353
176739
107118
433791
1606865
1848838
1918922
2221865
2642934
2153149
2113240
2383835
3212827
2807484
2212163
2197406
1972737
1977313
2272735
1990721
3247486
2812721
2674202
2211430
2323951
692545
838781
484007
708280
1360899
1921154
2042952
67
14483
15074
15534
14485
14614
15207
14747
14223
14945
15140
14681
14223
13961
14550
14878
14747
14487
14550
14485
14683
13896
29433
32184
32250
42414
34022
21173
20976
43789
62145
55720
44118
44445
53689
103251
150518
161467
187820
149534
139244
138062
137342
155698
184936
133671
228203
206372
181396
150321
133866
135966
130392
142192
84566
56835
51591
70012
221903
169544
163800
170364
169215
167246
169215
168561
162978
169381
169710
167575
162323
167575
166261
164129
165114
161831
165606
167903
161011
185139
190061
230273
326945
407366
509291
221574
181856
173977
186285
215995
227321
311515
884820
3191196
564933
392269
377333
372083
204014
355831
254891
338928
289688
300520
626317
654768
478601
1667227
6282015
7646122
8895763
4844583
1847430
587091
301011
4483300
3931870
3920871
3895600
3891358
3885754
3893793
3864751
3864437
3859645
3833745
3842073
3836705
3822223
3799597
3829791
3812874
3790562
3817012
3793679
3788781
3777259
6498062
4687196
4687039
4512735
5214979
4290141
3857864
4149017
4296400
4180730
4277859
4533947
4665513
4604967
4870823
4954754
4852151
4687537
4580351
4618113
4452163
4650953
4478587
4687170
4592293
4750544
5607268
5095747
4632359
4415553
4477434
4310986
4114240
4423567
4113088
2293
2131
1804
2131
2458
1966
2295
1969
2622
1638
1967
2131
1475
1638
1804
1967
1802
1967
2293
2296
1475
3115
3278
2131
14442
4100
4758
16409
2458
2622
2458
1638
2131
2951
3116
3278
3773
3607
2458
3278
3606
3115
3280
3445
3607
2293
4100
6562
5249
6563
30854
29703
26749
19364
25765
7547
2295
51.040
51.918
52.797
53.676
54.554
55.433
56.312
57.191
58.069
58.948
59.827
60.705
61.584
62.463
63.341
64.220
65.099
65.977
66.856
67.735
68.614
69.492
70.371
71.250
72.128
73.007
73.886
74.764
75.643
76.522
77.400
78.279
79.158
80.037
80.915
81.794
82.673
83.551
84.430
85.309
86.187
87.066
87.945
88.823
89.702
90.581
91.459
92.338
93.217
94.096
94.974
95.853
96.732
97.610
98.489
99.368
100.246
101.125
102.004
102.882
103.761
104.640
105.519
106.397
107.276
108.155
109.033
109.912
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1213889
1339451
1433988
1709245
1966603
449386
242745
221903
205488
209759
206639
208117
208117
204012
204505
204176
206639
208115
205652
206312
202863
206146
205161
202698
203848
205325
203027
201223
203027
202205
204341
202043
201221
202207
203356
202041
204177
202534
204177
200400
202207
198925
201221
206146
202041
199253
201552
202043
198104
203847
200894
197446
198760
198924
200730
198431
200894
200238
200894
200894
200730
194986
197940
203519
203685
196955
201385
199583
288648
170710
175561
196671
122983
24449
7143
5308
4125
4388
4059
3863
3928
4126
4255
3863
3928
4126
3928
3863
3666
4323
3863
4059
3666
4061
3799
3995
4257
4323
3732
4323
4192
3797
3799
4059
4650
4125
3928
4192
4192
3666
4190
4454
3930
3928
3928
4257
3928
3928
3928
3864
3601
4061
3928
3797
3928
3732
3930
3928
4257
4061
4192
3994
3666
3797
3535
4059
1912303
877412
754632
1026887
741319
75454
35005
27204
25237
24582
25368
23991
23860
23796
24056
24909
23795
23531
36383
24582
23729
23138
23991
24187
23338
23926
23795
23926
24253
23662
24713
23860
23991
22813
23664
24713
23927
22944
23664
23598
23269
23336
24646
24187
23335
23991
22944
23662
23204
24318
23074
22942
23074
23926
22615
23336
23402
23533
22351
24056
22813
23335
24056
24646
23924
23402
23007
22942
135177
133013
98596
93548
63261
22876
14550
14878
14094
13830
13568
14418
13632
13369
13567
13172
13500
13501
13960
13894
13369
13370
13501
13107
13239
12780
13827
12845
14092
13827
13172
14289
13960
13763
14223
13829
13698
13961
13830
13369
13892
13960
13567
13172
13763
13238
13958
13565
12845
13501
13763
13305
13698
13631
12714
13960
13434
13305
13108
13238
13698
12976
13634
13369
13501
13305
13434
13043
Table 9: Carbonate traverse down 30 raw data major elements
68
608264
3638937
5517864
2789859
5008831
1395264
314473
209101
166590
166261
158876
158876
157236
158876
155428
158711
160025
160845
159040
159369
159040
159205
156251
157398
154937
157564
158547
158053
154446
155758
154773
157398
156578
156742
156578
155922
155266
158384
154608
154115
155758
155100
157726
155757
155595
160027
154442
158547
156742
155264
159695
152310
154608
155102
151982
156742
157564
156578
154937
156742
152804
151653
154608
152804
157071
158711
153133
154444
3997705
4144958
4450697
4153888
4199035
3779380
3637941
3596578
3608664
3611649
3596893
3609554
3600520
3591485
3608533
3589678
3583917
3582633
3599865
3593606
3586719
3572761
3579831
3581455
3567183
3548131
3575563
3569304
3540105
3537971
3546835
3564381
3529748
3563883
3555870
3524026
3544871
3545028
3536334
3528124
3526985
3529420
3535496
3526776
3530101
3513682
3525833
3531096
3521538
3515489
3531070
3525348
3529761
3501020
3516811
3498441
3491357
3519731
3518959
3496110
3501531
3510081
3508732
3509557
3497105
3483134
3476260
3483501
4429
17230
21827
13292
63351
11321
3113
2460
2786
1802
1311
2458
2624
2295
1804
2295
1475
1311
2131
2133
1638
1804
2624
1638
1638
2458
2296
1147
1640
2295
1311
1640
2131
1967
1638
1804
2131
1638
2841
2131
1804
1311
1966
2295
1475
2131
2296
1638
1804
2460
2295
1804
1804
2458
1475
2295
2129
1967
1802
1804
2131
2129
1802
2295
1966
1473
2458
2624
traverse minor down 30 um
Ave blank
46,162
25,695
25,925
29,178
118,488
Trace for Mass: Distance (um) Mn55(LR) Ni58(LR) Zn64(LR) Rb85(LR) Sr88(LR)
Resolution:
Low
Low
Low
Low
Low
Time
[sec]
um/s
0.90
1.73
2.55
3.38
4.20
5.03
5.86
6.68
7.51
8.34
9.16
9.99
10.81
11.64
12.47
13.29
14.12
14.94
15.77
16.59
17.42
18.25
19.07
19.90
20.72
21.55
22.38
23.20
24.03
24.85
25.68
26.51
27.33
28.16
28.98
29.81
30.64
31.46
32.29
33.11
33.94
34.76
35.59
36.42
37.24
38.07
38.90
39.72
40.55
41.37
42.20
43.02
43.85
44.68
45.50
46.33
47.15
47.98
48.81
49.63
50.46
657
951
43
636
7
Mo98(LR La139(LR)Ce140(LR) Th232(LR U238(LR)
Low
Low
Low
Low
Low
10 Intensity Intensity Intensity Intensity Intensity Intensity Intensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
[cps]
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
50956
45739
45739
44535
51359
48047
45638
44435
45538
45739
48549
45639
46642
43731
47445
45638
43332
39920
43331
46541
45237
46642
44736
42427
43932
201221
503952
307656
255926
202219
185436
207701
191466
237219
217606
155383
117013
136500
187744
255634
346918
1036900
1140944
1073144
818448
549364
340782
319432
335138
419674
312688
342992
312482
286419
302218
292050
338670
296377
366674
320334
322054
32798
24170
25675
26576
25674
24671
27178
24671
28383
26476
27278
20157
25775
25573
23166
27480
26677
24571
25976
25775
24471
23868
21863
22063
26979
35105
36108
27078
29185
25272
25072
30289
28383
28282
27581
27580
24671
27981
24570
28283
30189
34000
44334
39317
31292
30790
28283
27981
29988
31894
28082
27379
25373
25875
26978
25473
29887
26778
27280
28182
24470
32797
25473
25473
27580
26777
27280
28784
25574
26777
25374
25474
24168
23368
25372
23768
25173
27479
27681
25374
27378
24169
25975
23667
26777
25975
35606
53065
38815
32796
34302
32496
34300
145521
32595
36508
33900
412520
245955
58713
166469
35907
40120
42528
41224
41123
39318
40421
36308
39016
43832
40422
38815
34603
34001
35605
37913
39919
34904
41225
39318
37712
34201
30288
30690
24670
27981
29586
31291
30892
29787
29988
26377
26578
29788
31493
28684
30890
30490
27882
27179
27279
29989
25675
28584
26676
29988
27881
25674
26677
27079
27981
25272
30088
28583
25775
29987
29085
27680
30890
26477
26978
24972
28984
32195
32094
28383
30690
29386
25875
30790
29888
27580
33499
28283
29686
28482
27078
25775
25173
25273
27179
28683
69
127923
126736
130292
124959
120818
120222
123187
122584
119637
122000
117263
116076
119625
116666
113117
111339
111339
110748
115485
111339
113707
108380
108970
107783
109567
9175525
19804554
14967997
13030605
8579750
7663525
7947167
13382476
16409074
12641548
5599409
2862488
5863560
6653013
11555366
13600912
14367496
16433456
18552524
17287452
16520396
17695976
15923912
13903029
15871842
13131342
16321851
15389703
15489212
15023610
15122079
14230094
13371230
15680007
19932508
12375673
700
501
600
1302
700
600
701
500
200
300
900
600
500
700
600
901
700
1000
500
900
1101
0
300
400
900
1603
701
500
200
200
800
802
600
500
500
700
600
400
200
1302
600
701
802
901
300
601
700
1001
500
500
701
500
901
400
1602
600
700
1301
300
1002
1001
700
1101
1002
500
1002
1603
700
700
1000
1001
700
901
1201
1202
1201
600
1001
1001
1102
1001
1401
1202
1201
500
1001
16346
9024
1803
1803
1301
1702
1302
1102
901
1001
1002
800
901
1202
1301
5413
26176
40522
32195
13738
3007
1602
1503
1602
2104
1201
1101
1201
1001
801
901
1100
600
1102
1202
1703
0
100
0
0
0
200
0
0
100
0
0
100
100
0
100
0
0
0
100
100
0
0
0
200
0
37010
17650
3507
5313
7118
6716
3808
6317
2707
6516
8120
4610
5414
5314
3007
8422
73339
119022
81167
25273
6817
2004
2204
3707
6516
4812
1702
1202
300
901
1202
600
1302
600
1301
4511
600
801
600
400
701
400
501
600
700
700
500
601
700
500
1202
801
600
701
801
901
200
300
601
100
800
0
1101
1002
1201
801
701
1302
701
600
501
801
1101
801
800
700
700
2605
3107
2806
1101
900
400
500
801
801
700
902
300
801
801
400
500
400
501
900
801
100
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
300
100
100
0
0
200
0
0
0
0
0
0
200
0
100
801
5614
2905
2304
901
100
100
0
0
0
0
0
0
0
0
0
100
100
0
100
0
51.28
52.11
52.94
53.76
54.59
55.41
56.24
57.06
57.89
58.72
59.54
60.37
61.19
62.02
62.85
63.67
64.50
65.32
66.15
66.98
67.80
68.63
69.45
70.28
71.11
71.93
72.76
73.58
74.41
75.24
76.06
76.89
77.71
78.54
79.37
80.19
81.02
81.84
82.67
83.50
84.32
85.15
85.97
86.80
87.63
88.45
89.28
90.10
90.93
91.75
92.58
93.41
94.23
95.06
95.88
96.71
97.54
98.36
99.19
100.01
100.84
101.67
102.49
103.32
104.14
104.97
105.80
106.62
107.45
108.27
109.10
109.93
110.75
513
521
529
538
546
554
562
571
579
587
595
604
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
1041
1050
1058
1066
1074
1083
1091
1099
1108
205141
161416
98233
82171
93816
93314
114500
141723
177390
232091
238725
259758
221425
204837
186238
230478
286713
281179
302326
272241
157997
219916
214795
247688
202222
79159
72734
80262
89206
68421
102753
183018
194378
123138
150989
129769
203027
315610
345730
499856
591932
752380
479382
265885
126853
77352
75445
91105
146445
262664
154985
126754
167247
230376
198298
273228
302130
368308
438324
426420
350344
258546
251798
184125
183523
223988
171163
237461
194481
258543
331119
556098
413324
27581
26076
24370
27580
26477
25272
26878
27381
30088
27079
28583
29887
26376
28683
25574
24772
31794
29787
29285
25876
27880
24671
31091
27780
26577
25473
25674
22564
92500
28984
26276
28383
25072
26677
25272
27278
28684
27178
30288
26778
26477
30991
26678
30490
30188
22867
24971
25373
26275
28583
27480
26075
26375
27580
26979
26077
29386
29786
35907
29686
39017
35003
27179
29787
30689
28884
25374
28783
25372
28483
28683
33399
33699
33801
30390
25294
120184
406005
205005
245451
33600
34490
173818
180076
80300
39819
31694
37813
48653
37311
36710
40420
32897
31793
50772
36809
36810
29687
100359
711301
483029
#######
200608
#######
684867
53681
206084
171047
33886
397692
317693
104720
35707
68420
41926
34201
34201
213409
296373
414581
126104
636162
336200
168379
278200
126648
188768
574324
82319
233805
41726
42829
41325
41124
37813
37813
37011
46141
128911
3181574
469503
346915
1267499
45739
73280
42227
24972
26777
25574
27981
25976
27480
29185
29786
31594
26978
31092
26176
27079
30891
28082
28684
27379
26376
30790
25775
27882
27782
23266
26979
26677
32396
27781
26276
29487
25675
29185
25774
25274
26576
26577
27179
27078
25574
25875
28984
26677
28487
25474
29587
27480
33399
27981
27380
26778
28383
28484
25674
27781
27580
30689
30390
25474
23669
31191
25674
28382
28283
25274
28082
24269
27681
22365
25673
23668
24069
25473
27279
25172
70
6603282
4488845
1759053
1558281
2083040
2387472
3271129
8264639
11762084
16415406
16502062
15218564
13492048
14911108
15184213
14802669
14591934
15510568
13604456
10748052
11215402
10962472
13372884
12149345
6443979
1403691
1199955
1291165
1226610
3788795
3385463
11188706
9834757
4202226
1563018
3592158
5785975
11001596
14136397
15513404
16130583
15592311
9630448
6320798
2410577
1725310
1413773
2085402
4267975
5989670
3258124
4448021
7213894
9967435
9229437
13503956
18509810
17384598
18430524
16568402
16270443
16307109
12777818
11901802
8496826
5631350
8258686
8437007
7441922
9550454
12251830
13176938
14207555
500
1101
1001
400
200
500
801
400
1001
901
1002
600
901
400
901
600
600
300
600
700
400
1101
901
500
300
1102
601
700
600
300
901
500
500
1000
601
500
500
700
600
801
801
601
1001
500
501
601
801
500
700
300
700
1001
300
600
600
1001
600
601
300
801
400
1101
100
701
600
901
801
300
600
600
500
300
900
1602
1702
1503
600
701
1301
901
1102
1803
1001
1602
1302
1402
1202
601
1402
2104
2104
2404
1702
1503
1301
1302
2004
1001
500
1802
1502
1803
800
1804
1101
701
1301
1302
1202
1603
2705
4009
7520
18653
14340
6315
2104
1402
600
800
901
2305
3608
1603
2305
1903
1201
1402
1803
2705
7319
9726
8823
3708
2605
1202
2203
2204
1702
1904
2105
2606
3708
6417
13336
10027
2705
5412
3708
7019
4411
6315
5815
5814
3709
5513
5814
3107
500
300
800
2404
1703
3809
7220
7319
4611
3207
4510
13236
4009
2706
3408
4310
5113
3508
1302
1904
2707
1803
4209
4410
5915
9024
11933
12935
39921
42528
11531
4411
3207
1001
1401
2806
8823
10829
3809
5915
4912
6617
6416
6718
11832
31894
43632
37311
21160
15142
11732
10730
9726
10930
9727
12333
12234
12936
22966
34101
31995
600
701
600
400
902
901
300
600
1001
701
700
500
1502
600
400
500
300
800
500
901
1302
701
300
600
801
501
600
700
600
400
700
1000
600
300
800
100
500
600
300
200
900
1202
900
1101
601
500
901
800
901
1102
600
800
901
300
701
901
300
801
801
1603
500
802
801
200
1202
500
1202
901
700
501
801
1001
0
0
100
0
0
200
0
0
0
0
0
0
200
0
0
0
0
0
0
0
0
0
0
100
100
100
0
0
902
0
0
100
100
0
501
200
0
300
200
300
0
1804
800
400
100
100
0
200
0
500
400
0
0
200
0
0
0
0
0
100
100
0
0
0
0
200
0
0
0
0
0
100
200
200
111.58
112.40
113.23
114.06
114.88
115.71
116.53
117.36
118.18
119.01
119.84
120.66
121.49
122.31
123.14
123.97
124.79
125.62
126.44
127.27
128.10
128.92
129.75
130.57
131.40
132.23
133.05
133.88
134.70
135.53
136.35
137.18
138.01
138.83
139.66
140.49
141.31
142.14
142.96
143.79
144.62
145.44
146.27
147.09
147.92
148.74
149.57
150.40
151.22
152.05
152.87
153.70
154.53
155.35
156.18
157.00
157.83
158.66
159.48
160.31
161.13
161.96
162.79
163.61
164.44
165.26
1116
1124
1132
1141
1149
1157
1165
1174
1182
1190
1198
1207
1215
1223
1231
1240
1248
1256
1264
1273
1281
1289
1297
1306
1314
1322
1331
1339
1347
1355
1364
1372
1380
1388
1397
1405
1413
1421
1430
1438
1446
1454
1463
1471
1479
1487
1496
1504
1512
1520
1529
1537
1545
1554
1562
1570
1578
1587
1595
1603
1611
1620
1628
1636
1644
1653
350362
341680
299606
265790
202021
77555
46040
47846
39017
43832
45638
40321
44434
46140
41023
46642
41725
39217
42930
46842
40019
40121
43432
43933
38615
37713
39418
41826
39417
38816
45639
43030
42227
37712
41725
44033
41726
43732
40922
40723
39618
42328
45538
41927
42328
41324
45638
45338
41725
42327
40422
43129
45538
42729
42328
40723
37512
36509
43231
44736
42629
40119
44535
44836
43230
44837
33599
32797
36108
27981
24169
28483
25374
23266
26377
22264
22364
24270
24270
21663
24771
22865
24269
25273
25874
23266
23568
23166
25574
20658
23968
22163
24971
23868
24871
21863
22364
26979
24269
24170
22966
25874
27279
24771
24171
25674
22263
20458
26076
26176
22865
23468
26476
25474
25975
22063
26577
21762
23969
27479
26777
21160
23267
24670
26076
26978
24069
23267
26677
24069
20057
23367
39417
48448
62608
38013
39718
29686
27380
27279
25374
26978
26677
26979
25473
27379
25674
24871
27078
23468
24069
27078
25073
27479
25673
27279
22364
26577
27079
25674
23969
28382
22364
26577
26777
26577
26176
26376
24671
23367
26578
29988
28584
30087
27178
23065
25875
24671
24470
24671
23668
27178
24571
23768
24570
22765
25474
25273
25172
21762
25173
26075
29186
25975
26276
23568
24169
27280
26877
24972
25374
24370
24169
26275
23969
26778
26878
27581
27079
29686
23969
24672
28784
28082
27279
26176
27781
28181
24972
27680
26075
28683
25876
25874
25675
25975
28282
26376
27380
27280
23869
28282
28283
25574
23868
25473
26777
21963
28684
29486
25875
26476
25774
22263
24571
27279
26979
26979
25975
26778
27279
27882
26677
26777
26677
25976
25073
26376
24670
26577
23267
26176
28683
24370
12342409
13785802
14616835
15276586
7581759
1324329
265332
142140
110748
103046
104818
100081
92970
90602
95351
94754
98900
97128
99491
97122
95941
98894
94754
98304
92386
98304
97128
100678
98900
96526
97128
94157
98894
94163
95345
97122
95935
97122
97122
96532
92976
92380
94754
98304
92380
97713
93567
95345
95345
91801
95345
93567
94754
95345
91204
95935
92970
94754
95345
95351
97122
95345
95935
90608
91204
94163
500
801
600
400
200
500
801
300
902
600
500
801
600
501
300
400
701
401
200
600
100
300
900
400
400
600
701
0
1001
801
701
901
1101
1001
800
801
500
300
1201
902
700
801
500
701
701
1202
300
600
801
700
200
600
800
900
701
400
300
701
600
500
600
401
500
800
200
700
Table 10: Carbonate traverse down 30 raw data minor elements
71
7520
6818
5714
5614
2304
1502
400
500
801
700
901
800
701
501
1102
1202
400
400
700
801
1101
1101
800
601
300
1302
1001
1202
1002
400
600
901
601
500
1000
1001
500
1401
900
500
1302
801
300
401
800
1202
700
601
901
1503
700
700
400
701
901
1000
801
601
1302
901
1002
1301
500
1402
1101
400
32697
26275
17449
19254
5513
1001
100
200
0
0
100
200
500
0
0
0
0
100
200
0
0
0
0
0
0
0
100
0
200
100
0
0
200
0
0
0
0
300
0
0
0
0
100
0
0
0
200
0
0
200
0
100
100
0
0
200
0
0
0
0
0
0
0
100
0
200
1000
1001
100
1001
800
800
700
800
700
600
500
700
500
701
700
100
500
300
1000
801
600
600
500
600
701
400
400
500
600
1000
800
701
100
600
400
200
400
1301
100
800
800
901
300
600
400
801
700
801
500
901
600
300
500
902
600
200
700
700
400
800
601
801
600
400
400
500
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Carbonate Traverse Down 60
left hook traverse major down 60 um
18,548
Ave blank
um/s
0.95
1.83
2.71
3.59
4.47
5.35
6.23
7.11
7.98
8.86
9.74
10.62
11.50
12.38
13.26
14.14
15.01
15.89
16.77
17.65
18.53
19.41
20.29
21.16
22.04
22.92
23.80
24.68
25.56
26.44
27.32
28.19
29.07
29.95
30.83
31.71
32.59
33.47
34.35
35.22
36.10
36.98
37.86
38.74
39.62
40.49
41.37
42.25
43.13
44.01
44.89
45.77
46.65
47.53
48.40
49.28
50.16
4,810
17,089
32,305,891
3,202
Mg24(LR)
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
10 Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
28,483
3,493
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
18950
18950
18506
19393
18652
18209
18803
18950
18653
18209
18801
17765
18950
18207
18061
18507
18507
17914
18210
18209
17914
17023
18061
18358
2384212
2668503
2547082
4173923
3160092
3924302
2630325
2271237
2998686
5249664
6092699
16284334
29361528
25828740
21172442
21225268
8876905
3231156
2503116
4224890
4404622
10717292
7756277
11098411
25177730
31107320
21951404
24041272
15848878
4327604
1719233
2064672
2743571
3426
3485
3662
3603
3721
3604
3367
3663
3544
3367
3485
3544
3367
3603
3248
3603
3189
3367
3248
3426
3426
3485
3248
3426
133719
176776
169027
162759
165833
189490
190141
155188
245440
305529
200432
248040
254667
326880
334509
330310
295890
208002
140461
108226
108938
153295
197475
199780
271583
213799
204040
245676
301864
264426
397259
369994
309019
30397
29273
29745
30042
29214
29155
28976
28149
28681
28505
28267
27913
28326
28561
27381
27911
27675
26847
26850
28622
26907
27144
26848
30221
996904
1085321
1185975
741651
1230399
1384342
1020677
1455300
1092774
1449104
1001039
974366
1102833
2329732
1753459
1986532
1909810
792152
653698
569363
504961
595090
1166284
810547
1140019
747380
690960
904646
1738729
1450587
1608431
1731630
1403036
72
4967
4849
4967
4790
5144
4907
4966
4670
4788
4669
4788
4670
4670
4848
4729
4908
4790
4848
4788
4670
4433
4848
4907
31402
251887
204217
222196
247095
211019
153297
152942
171690
134075
132595
155898
107104
144188
121949
125204
251532
318481
234440
200965
162463
149629
161456
178076
200138
143122
238165
158382
162699
312863
217644
167904
162404
169204
19838
16877
17025
17320
17469
16728
17025
18063
16580
17172
17618
17026
17025
16137
16433
17469
17174
17618
17172
16728
16137
16876
16731
17025
9851625
14437048
13090943
15399814
14502537
11593544
8476792
11596615
9015347
7058914
9951700
6823467
4305397
5236186
5375940
4098820
9773474
14042747
14648162
12247814
11401520
10720364
10343403
6604463
4110112
7606919
12947634
7996354
8805416
7006939
3056579
4732607
6982227
31528224
32961412
32862942
32741226
32584356
32597396
32501952
32459048
32353208
32342248
32196150
32119604
32219020
32066874
32064416
31999024
32037956
31896964
31870124
31761640
31760694
31795280
31602690
31650884
35639352
35553544
33428996
33655232
35788472
35468120
33109020
36501192
33370408
36521224
35312004
32442416
31967460
32188024
32074812
32169124
32838372
33115256
34117144
35182160
34523872
33312572
33270048
34007336
32483620
32731776
33131132
32422572
32532004
34414256
31845932
35385524
33177628
3848
3107
2662
3551
3550
2959
2810
3551
3402
2662
2810
3254
2959
2810
3551
3846
3105
2811
3256
3256
3107
3402
3402
2811
114603
177682
104386
97279
76402
43235
58487
88840
43974
28278
36275
45604
30055
67222
60263
33165
40421
39681
84545
110013
66185
44864
50934
22947
16877
42197
117121
45751
58930
62630
22650
30498
127042
51.04
51.92
52.80
53.68
54.56
55.43
56.31
57.19
58.07
58.95
59.83
60.71
61.58
62.46
63.34
64.22
65.10
65.98
66.86
67.74
68.61
69.49
70.37
71.25
72.13
73.01
73.89
74.76
75.64
76.52
77.40
78.28
79.16
80.04
80.92
81.79
82.67
83.55
84.43
85.31
86.19
87.07
87.94
88.82
89.70
90.58
91.46
92.34
93.22
94.10
94.97
95.85
96.73
97.61
98.49
99.37
100.25
101.13
102.00
102.88
103.76
104.64
105.52
106.40
107.28
108.15
109.03
109.91
110.79
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1108
2322160
3078940
7757741
14402934
17140694
11703542
3283875
2683316
3226443
4035505
2419744
2126120
1710332
5432002
3370792
2246064
1924752
1809846
1966504
1752113
1521113
1486627
2256418
3391534
2778962
2330311
2240146
3713000
2582047
2329413
1861662
2269607
1991091
2546929
1329367
1651854
1712730
2104799
3109145
3472828
14504522
24166012
10150009
3111531
1347730
1433606
2410719
3149874
2064672
2786663
3944714
3575419
2941691
2276422
3150760
3715339
3835590
4443272
11669285
11857813
8101910
2437675
2684332
2244883
5013757
3374772
3459492
3350675
2166413
172045
158855
240591
251649
278323
227048
189667
196175
268919
452200
387443
473850
461724
370114
298728
229174
127215
123190
162759
144365
156548
171512
256678
288379
286428
242424
148386
307005
326347
361595
307125
296597
254429
264306
285657
279507
187541
248872
389334
363016
306416
297547
221605
206939
129757
149334
198361
220954
240944
294589
338650
291631
183340
232725
257388
368754
375967
281873
302571
170624
230063
238875
195109
236036
340482
318895
379341
285245
312566
887018
757911
1177576
1248912
3291341
2166619
984548
941421
1936553
2715103
3221021
3804310
3735065
2889349
1764374
1378903
662451
574093
853013
903987
1076320
1187989
2428260
1982693
1788578
1036287
1062257
1874089
1663844
1541071
1506177
1420193
1269082
1598792
1775324
1603641
1070177
1698567
2195294
2316254
1489373
1078517
1098628
1071606
654472
1110038
1167884
921142
1029430
2135275
2041484
1482634
1119861
1501198
1531207
2124998
2077146
1498782
1198691
939531
1259207
1971861
748567
1080472
1727767
1969209
2013311
1432963
1686152
73
197239
186533
227698
280336
427779
268801
151935
177484
162993
219949
204808
130053
76529
149037
220423
222255
232017
181032
152350
136084
98882
164886
219596
197180
123309
131944
143300
167608
125616
139160
134841
143952
100480
88888
209126
223854
265312
159150
167196
184877
99240
150872
140284
126682
77771
107755
131470
172043
135435
151579
226220
217053
186711
159860
140522
126741
121595
156074
130231
262000
201024
251591
308723
205224
143419
122425
144186
196647
163113
9442346
11763218
10547476
9204253
8085893
10208126
13266194
13685915
10217340
4458794
3514136
4094095
2192010
2385546
6224077
9602003
13804276
11460771
10491721
9260575
7350021
7091044
7296062
7667163
6494584
9263930
12399109
8992998
7474194
5742836
6896587
7758686
7327365
5108080
4756587
6658210
9837403
7567088
5341306
5577178
4948020
4263037
7791124
9450236
13428166
11134084
8494180
9246967
9279191
8773238
5993686
9484209
13209541
9884180
8345012
4726985
5670331
5271399
4515659
2852258
6746166
10530702
11764919
12074785
6895287
6032927
6237260
9225043
10331543
32537296
32656932
34234328
32806052
33577928
32460372
34160428
33051752
32527468
32792068
33463396
32463396
32298020
32483240
35958196
33074622
33224876
32511402
33527466
33421248
33756536
34137748
34045516
33033042
32296698
33778456
38003932
37632544
33253228
32428242
33122440
33978800
33687736
32451678
34666000
34285736
32283656
31869748
32166476
32563944
32022836
31540508
32246046
33666760
47629512
48368692
34926632
32254172
31996376
32345460
32220532
32303692
32099760
31976720
31966516
32222232
32648804
33700024
31954796
31360770
34073864
34722512
32488156
32570936
33373808
34239240
31925312
31939676
31689630
169983
79511
57596
75810
79807
49453
100685
151178
55079
17174
15101
19098
7401
16284
58041
41753
47974
108089
50934
122797
39680
36273
32278
95206
139331
65149
38051
33165
47234
272002
559109
171907
92985
42938
26206
27687
37311
26058
16729
46493
23095
26650
29462
27984
21911
22355
49305
62484
59077
42642
30500
34941
96096
45012
61742
37903
34497
35830
48712
20284
41457
49453
51821
48418
29463
99649
34794
49750
90912
111.67
112.55
113.43
114.31
115.18
116.06
116.94
117.82
118.70
119.58
120.46
121.33
122.21
123.09
123.97
124.85
125.73
126.61
127.49
128.37
129.24
130.12
131.00
131.88
132.76
133.64
134.52
135.39
136.27
137.15
138.03
138.91
139.79
140.67
141.54
142.42
143.30
144.18
145.06
145.94
146.82
147.70
148.57
149.45
150.33
151.21
152.09
152.97
153.85
154.73
155.60
156.48
157.36
158.24
159.12
160.00
160.88
161.76
162.63
163.51
164.39
165.27
166.15
167.03
167.91
168.79
169.66
170.54
1117
1125
1134
1143
1152
1161
1169
1178
1187
1196
1205
1213
1222
1231
1240
1248
1257
1266
1275
1284
1292
1301
1310
1319
1328
1336
1345
1354
1363
1372
1380
1389
1398
1407
1415
1424
1433
1442
1451
1459
1468
1477
1486
1495
1503
1512
1521
1530
1538
1547
1556
1565
1574
1582
1591
1600
1609
1618
1626
1635
1644
1653
1661
1670
1679
1688
1697
1705
4666363
4719826
15836310
12266289
4512730
4512399
3204070
4968314
3705440
2636975
6456547
31115826
35543528
33298020
21494780
9816566
4557121
3267444
7100825
3449097
2465056
2652792
6072452
10390275
4734521
4154941
3285364
2558918
2187876
2627336
3403229
3110361
2313443
2453953
2333134
2661250
1927552
2681839
1635571
9736146
24213924
14270634
3166471
3749264
3941430
5432545
7257884
4668017
2374584
2204461
2743134
3154469
2331504
2140029
2760605
8166879
7362401
2533474
1683831
2273446
4790347
4046585
8680439
4052515
421996
102019
42642
37311
262592
233256
295534
272705
228052
336046
252535
347637
202503
175650
237514
309374
280925
221783
200374
209896
159210
163231
161814
177604
136795
150634
130348
139869
182217
277437
333801
167845
171393
152408
218707
162344
142651
214982
252005
200136
251769
177072
168615
188665
228999
267146
193632
177425
167844
185350
273238
297073
500643
565577
533701
369994
284535
213384
477752
205933
405895
346338
270991
357870
316175
191798
282582
221665
28208
7213
4137
3722
1302671
1334376
1310302
1150372
1417518
1725417
1490625
1502869
947339
1340093
1284574
986314
710894
782277
915699
1083726
825623
771746
877672
803920
1157879
885955
469001
1096338
1317324
1969971
1581056
990165
794577
899020
1107617
631697
640158
1115661
1791720
1225193
1674971
892753
821489
674695
928291
968690
1053439
864424
964668
1285519
1592514
2633018
3875941
3841756
3124914
1854929
1297467
1531432
2104102
1057408
2792286
2258172
2253742
2584044
1551956
941958
2022253
1098923
141644
59554
31225
27439
74
128634
116628
101841
178372
142472
175416
180560
205932
203922
309138
125971
95572
169325
172340
272114
246091
260405
177545
250054
262178
226161
179969
177368
272470
249520
229294
280336
235503
278974
206406
202029
243488
196529
246800
257981
173641
147382
152172
164296
157790
114026
120115
120826
165301
195642
195938
169797
154657
113137
120885
140756
152646
221902
206880
152349
104976
91020
110654
85636
105685
157495
136677
120767
30339
7271
4967
4492
4551
6999237
7167589
5333769
5846243
11287899
5790393
7214225
7396657
13440924
13227826
10726222
3083535
4822926
7459074
10121139
12714597
15562544
16682936
11844299
12196737
15148634
13681710
13770918
12347276
12375720
7421699
9891646
12763217
14781501
14523327
12402274
14148068
13760948
13234442
11305980
11124493
9734965
13014256
11345906
9540956
5599102
7111125
9969230
10981325
12822752
10413664
8827387
8888292
1697007
543712
2412207
5867552
7691024
11954770
5407219
5313310
4563500
6079114
7214366
6760270
8905208
11778480
7137491
4043041
516614
128818
55672
33462
31652208
32237920
32410288
31928336
34607412
32094280
32210514
32168744
32349428
33748784
32066308
31341114
31514048
33561864
32090120
32251716
34145684
32563756
33183864
32641812
34589456
33793012
33846876
34178572
32682258
32027562
32597964
32101084
32203520
32091822
32170068
32422950
33154002
32436180
32990140
34807184
38687168
34102784
43434280
36940808
33937596
31624236
32934384
33439960
32649750
34512724
35512912
31764096
31264948
31140774
31091824
31100896
31447332
32384204
31691898
31202200
32927202
33831756
39299336
33483428
32446196
32016222
31752188
32853304
30394602
30207870
30216752
30251528
71516
59965
60706
187752
103056
22503
42789
46490
58633
78326
277780
43529
29316
37164
104830
57004
113272
90764
82323
106311
313465
109422
136519
113270
57596
37754
57447
100538
70033
69294
111940
65001
52117
71221
50044
298063
104832
80251
260455
56115
73291
145896
247425
96834
107793
80843
50194
32870
10658
6067
12139
18357
26649
52266
31684
279112
95652
27687
53745
22949
59520
75957
30795
17617
5772
3699
3402
4143
171.42
172.30
173.18
174.06
174.93
175.81
176.69
177.57
178.45
179.33
180.21
181.09
181.96
182.84
183.72
184.60
185.48
186.36
187.24
188.12
188.99
189.87
190.75
191.63
192.51
193.39
194.27
195.15
196.02
196.90
197.78
198.66
199.54
200.42
201.30
202.18
1714
1723
1732
1741
1749
1758
1767
1776
1784
1793
1802
1811
1820
1828
1837
1846
1855
1864
1872
1881
1890
1899
1908
1916
1925
1934
1943
1951
1960
1969
1978
1987
1995
2004
2013
2022
22947
18506
17469
18653
17617
16728
17912
18357
17617
17618
18358
17765
18063
18061
17765
17023
17469
18357
17766
18063
17765
17174
17025
17766
16729
17469
17914
18358
18655
17912
17765
18209
17615
17322
18210
17469
3721
3662
3248
3367
3308
3071
3367
3248
2953
3367
3367
3426
3367
3308
3189
3485
3012
3248
3662
3308
3426
3130
3426
3426
3308
3426
3485
3248
3308
3308
3308
3130
3308
3248
3189
3189
26374
25251
25546
25072
25367
24836
25725
25487
24540
25487
25251
25310
25369
26373
25723
25428
25961
25251
25075
25487
25310
24600
25251
24895
25251
25133
25369
25487
25369
24481
25131
24778
25369
24778
25961
24718
4670
4374
4195
4255
4018
4254
4137
4315
4788
4137
4254
4552
4196
4255
4136
4315
4433
4195
4315
4196
4018
4254
4019
4254
4137
4374
4196
4077
4374
4255
4134
4255
4134
4255
4374
4136
19541
19395
18358
18801
19098
18358
18801
18210
17617
18507
17914
18061
18063
18653
17468
17025
18358
17914
17617
17617
17915
18801
17320
17766
18655
18061
18653
17914
17471
17766
18949
18950
17469
18209
18061
18061
30161188
30152116
30183678
30218264
30199744
30069144
30212216
30147390
30156272
30124710
30124520
30075192
30155328
30090500
30208816
30189536
30153628
30093336
30078784
30066308
30067632
30079540
30005262
30062340
29987874
29978236
29945348
29972754
29994868
30000726
30016224
29992220
29943270
29999970
29946104
30067064
3699
3253
3994
3994
2958
3403
3994
3551
3107
3403
3848
2958
3700
4145
3403
3551
3254
3994
3105
3403
3697
3403
2811
4291
3699
3846
3403
4143
3403
3105
3697
3699
3105
3403
3699
3402
Table 11: Carbonate traverse down 60 raw data major elements
traverse minor down 60 um
Ave blank
43,718
24,241 25,832
26,656
105,246
572
994
57
622
-
Trace for Mass: Distance (um) Mn55(LR) Ni58(LR) Zn64(LR) Rb85(LR) Sr88(LR)
Resolution:
Low
Low
Low
Low
Low
Mo98(LR)La139(LR)Ce140(LR) Th232(LR U238(LR)
Low
Low
Low
Low
Low
Time
[sec]
IntensityIntensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
um/s
10 Intensity Intensity IntensityIntensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
75
0.90200001
1.728000045
2.552999973
3.378999949
4.204999924
5.031000137
5.856999874
6.683000088
7.508999825
8.335000038
9.161000252
9.987000465
10.81299973
11.63899994
12.46500015
13.29100037
14.11699963
14.94299984
15.76799965
16.59399986
17.42000008
18.24600029
19.0720005
19.89800072
20.72400093
21.54999924
22.37599945
23.20199966
24.02799988
24.85400009
25.68000031
26.50600052
27.33200073
28.15800095
28.9829998
29.80900002
30.63500023
31.46100044
32.28699875
33.11299896
33.93899918
34.76499939
35.5909996
36.41699982
37.24300003
38.06900024
38.89500046
39.72100067
40.54700089
41.3730011
42.19800186
43.02399826
43.84999847
44.67599869
45.5019989
46.32799911
47.15399933
47.97999954
48.80599976
49.63199997
50.45800018
51.2840004
52.11000061
52.93600082
53.76200104
54.58800125
55.4129982
56.23899841
57.06499863
57.89099884
58.71699905
59.54299927
60.36899948
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
513
521
529
538
546
554
562
571
579
587
595
604
53266
42728
44033
39618
44936
46643
42427
42328
44033
44033
42929
41223
48047
43130
42428
45338
44936
47244
36710
45035
40622
43731
45638
41927
39118
45437
748140
570616
749384
735312
478088
476872
950748
1214408
905816
634568
836096
2301216
3758832
2968448
1830512
1005552
1225168
1981288
2496800
2075272
1262252
849992
701424
506526
538306
818280
506308
434990
550332
698494
667168
730072
870384
465668
258680
199610
916108
1342728
559500
669700
895192
748704
671492
455080
638804
663396
865268
28483
24772
25675
22665
22664
26376
25473
25474
24972
25073
23869
21561
24070
27480
22465
23166
24070
26677
21761
26376
26276
22364
24269
23066
24872
32797
123439
71736
84078
97931
111589
101146
96727
113597
110987
118819
130671
245061
337658
279265
138608
113497
131073
171462
164528
159808
116309
158304
138409
109279
92411
162020
110584
94619
99242
131375
173177
294065
186238
113902
76349
55874
141822
182014
155888
135093
103556
97933
123945
113901
108577
109881
152972
31091
25373
22866
28483
25173
24269
24370
24972
25674
25875
25875
24871
25875
29286
27982
26277
22664
26076
26176
27078
24370
21662
24972
27280
25573
30691
48448
41123
44635
54469
70828
56776
54871
59587
57580
63300
59988
53967
66919
69624
64204
64204
75748
76349
73338
85784
76550
87190
91006
86788
71531
84279
83676
65911
73135
67315
63200
70526
64504
51860
45839
35605
48248
54469
52864
45338
48549
49652
62400
45840
54369
52663
59789
27279
28584
27179
25874
23868
25172
28182
27279
25072
26677
24169
26678
30590
25373
28683
27681
27882
26577
30890
25072
27480
28884
24069
24269
24370
59692
137903
125548
263673
441954
412212
186739
139812
245562
280674
300302
235403
260157
814304
1215720
989632
1041028
890904
296997
160008
262867
251195
298190
363450
242951
224041
286013
316847
236819
248687
273839
266692
371298
386512
274537
113093
82170
152771
329698
312811
162624
139211
219314
301306
317329
254515
242121
264791
76
111339
107777
104824
110157
104818
106596
107187
103643
104234
107783
104234
103637
109561
103637
104824
100678
102456
98304
101269
103643
104824
107198
100087
107193
103637
909143
7138743
5679923
3986601
2643331
2797318
3735443
11943288
13942176
5319263
4965054
5181223
4850049
6905874
6481033
7812693
6131255
5540157
5589321
6459359
6162676
4694406
5979629
4214629
5129106
5449508
4920662
3669152
3726608
4782622
3991349
4748838
4056260
3865783
2221636
1213581
1843754
2971458
3869929
4401220
5988489
9359705
9879786
5864174
4030449
4825288
6937340
6908616
400
600
700
501
400
400
300
901
900
100
400
801
400
400
1302
700
500
400
601
900
700
300
901
500
600
1603
1903
1001
1402
1904
2906
1401
800
1202
1501
1502
1904
1001
500
901
1603
1202
1402
1001
901
1402
1502
2105
3207
900
1603
2103
1603
800
801
2505
2505
5412
2606
1703
1502
1903
1202
1402
1001
1202
1804
2204
1302
2003
1501
1101
1703
500
1201
1101
1502
1402
901
500
400
801
801
1502
1202
1502
400
1201
1101
701
1002
300
801
901
1000
500
1202
1201
9125
29686
25774
24770
21962
24070
41024
52362
47445
46140
38214
33700
23668
24470
24671
28484
35205
44535
37210
41726
43532
37914
35405
38315
24471
38816
50257
34402
20960
21060
40622
50153
50657
53969
31693
7720
14543
25574
59088
49555
35405
25374
31794
49653
38515
40722
54370
82573
200
100
100
200
0
0
100
100
200
100
0
0
0
0
0
100
0
100
100
200
0
0
100
0
100
63614
92311
89498
81267
58984
100545
128261
155391
150966
164132
114608
92512
76750
84183
73939
122940
91308
142425
111890
160610
142627
115104
106272
129767
98434
149763
145942
98037
57078
69322
159823
144835
168551
142423
93721
25875
32998
177855
150261
137408
88196
88496
72334
145742
123541
171379
160110
209062
500
800
701
901
801
901
200
200
901
801
600
800
700
100
700
500
600
700
700
600
501
801
300
600
1302
3708
3308
3708
7720
6517
9224
11231
9325
14640
14640
17349
6618
3106
4410
4812
6517
3407
3207
5212
5212
11029
8523
7821
11231
5713
13436
11832
12835
4210
4912
10829
20157
17048
9425
7720
2906
3508
6516
13136
13335
11331
3910
7318
11732
9425
12735
8823
7018
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3207
4912
6516
9325
10928
12635
9425
7419
10329
15744
12835
8723
5413
10929
7821
9225
9124
7721
2505
4210
9726
9726
12835
13436
5614
9526
11130
9325
4711
8522
10829
15342
18151
14038
6717
2204
3808
11532
16947
8623
12936
5915
6417
12033
13035
12132
5011
6818
61.19499969
62.02099991
62.84700012
63.67300034
64.49900055
65.32499695
66.15100098
66.97699738
67.8030014
68.62799835
69.45400238
70.27999878
71.10600281
71.93199921
72.75800323
73.58399963
74.41000366
75.23600006
76.06199646
76.88800049
77.71399689
78.54000092
79.36599731
80.19200134
81.01799774
81.84300232
82.66899872
83.49500275
84.32099915
85.14700317
85.97299957
86.7990036
87.625
88.4509964
89.27700043
90.10299683
90.92900085
91.75499725
92.58100128
93.40699768
94.23300171
95.05799866
95.88400269
96.70999908
97.53600311
98.36199951
99.18800354
100.0139999
100.8399963
101.6660004
102.4919968
103.3180008
104.1439972
104.9700012
105.7959976
106.6220016
107.447998
108.2730026
109.098999
109.9250031
110.7509995
111.5770035
112.4029999
113.2289963
114.0550003
114.8809967
115.7070007
116.5329971
117.3590012
118.1849976
119.0110016
119.836998
120.663002
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
1041
1050
1058
1066
1074
1083
1091
1099
1108
1116
1124
1132
1141
1149
1157
1165
1174
1182
1190
1198
1207
654180
512844
592362
606792
694264
830532
608408
677138
569060
532202
603956
483000
472538
460512
638656
435210
306248
245022
386924
253915
201214
478146
468586
675260
473736
450018
812836
655204
898936
845120
965388
762768
585118
506828
439528
368276
402948
471950
369218
258957
549430
472320
475556
505526
341686
477412
643742
877544
790020
1132848
787956
297390
517746
563364
646556
824868
1209076
920768
777532
535680
679030
1031552
1623064
539832
738352
631088
240054
100375
46843
43130
49251
40622
42929
168552
71230
65911
111890
88997
154782
67918
47645
47145
85385
62898
67014
110003
108576
155186
87189
99741
83577
79460
58584
61394
78658
62197
72132
65911
78355
90102
74140
75044
64003
64505
66813
69423
70326
99544
67115
54569
38014
64406
46943
59387
68318
74743
72836
70226
57380
60691
61896
146050
359858
281290
204245
251204
128873
114601
240539
539742
155889
76250
56677
90105
887968
1095064
303135
467212
257756
52463
29487
23167
24270
25573
25976
27981
43130
45739
40421
52061
45538
43732
38013
34903
40019
156028
43632
45639
48047
55072
55372
68419
62698
53165
57780
51358
48950
54269
147904
67220
45136
43030
48047
48046
51460
39819
52865
57379
45338
38315
40422
38214
43933
33800
32897
34703
43332
46140
48850
47747
46642
47746
47645
56476
52061
46140
43631
34602
40923
41223
53166
51058
58182
46842
45137
39518
35204
97224
41224
39518
45639
122396
230239
26075
26276
24671
26577
24370
23668
184228
205538
154882
204134
134288
118419
101347
93716
110285
110685
131474
165333
140321
143630
175584
251900
447998
415354
333226
175983
154083
202327
152878
197803
151667
236108
232889
209373
176900
140216
111690
108275
135693
141220
171664
144233
81569
42830
34904
61093
95421
149859
139711
167241
157222
101149
118819
101045
119325
85282
117214
83777
67415
97230
122538
113899
137310
108580
91306
65810
46040
35707
27079
24771
26778
21662
25775
28584
25073
24270
24170
23366
26678
77
4334904
5605929
4609096
6592060
7348391
8595720
9266150
7729202
6949766
6506727
7876670
3729537
4104466
5273053
3244492
5216164
1634082
1135400
2580559
4574137
1227201
2479255
3395539
7876468
11715826
5190129
8759772
7311040
8101769
10634321
12488789
7318175
6374710
4962715
6793983
4418986
7639144
5143328
3703502
3975946
9667822
6962193
8982461
6103401
5014206
5055656
5363088
9206379
8265821
6895901
3989201
1648479
3107680
3951092
6438073
9948344
9174344
12936483
10613626
6326657
5190129
3360597
4021566
6680323
4769014
5630806
812015
212619
155169
117263
98310
96532
97719
1402
1503
800
1101
900
2305
1302
900
1001
1002
2004
1001
1202
2003
2806
1403
1002
901
700
600
701
1503
901
1803
1402
1402
600
901
901
700
1302
1202
1101
1302
1000
1202
1202
801
2606
1201
500
901
901
1100
1302
200
1102
1904
4912
8923
6818
6617
7821
4309
7719
14841
9927
2505
1001
2204
16746
57782
39218
62097
72334
29386
4912
1503
400
701
701
1101
801
44938
34603
32396
33399
31796
42227
34302
26276
19355
25976
43430
27681
17650
27479
72737
100254
73841
63904
30389
16746
12033
24370
25273
139413
54067
28082
30790
27279
46643
38916
41123
28784
102151
45037
27881
16144
15644
10629
8021
11431
24270
55674
40722
32396
17349
16446
27178
55574
36008
34202
282060
204840
137214
33299
56777
140319
49151
31292
29587
27480
17248
12134
10428
13837
20257
15944
3307
800
500
1301
1001
800
1101
238300
99036
103456
96827
74944
124545
82873
62397
49252
104761
165033
88395
62598
109684
229319
189362
177312
136404
81074
39118
40120
77754
111314
536788
172166
86688
88695
84480
151570
126152
119723
76650
232889
115304
75446
56476
45739
21661
19655
29887
73542
167147
125676
85985
44435
84382
101347
128266
89097
69524
257733
289333
106569
64907
131085
471108
104862
65308
76048
64305
51760
30489
31793
66515
110685
47244
7520
2004
801
500
0
100
200
12735
6918
6517
7017
6115
9124
7519
4210
1803
3407
13237
4912
3709
4710
7620
9826
59287
16445
7820
3207
7320
6819
5814
42026
9826
9324
6316
4311
3207
7520
5715
4210
7920
11933
8923
3408
1703
1403
1301
2405
4111
7921
9927
8322
2505
2405
4009
5413
3006
3408
3709
3408
2404
1603
3307
7119
3909
3809
3408
2004
1201
1402
1202
901
1402
1202
500
800
1001
1002
500
500
400
11531
7319
5614
5414
5614
6616
3407
3408
2305
3508
3708
2805
4311
3507
10128
8221
136599
37310
10830
4812
5112
9225
3808
11832
5514
7519
5413
4911
3808
4811
6015
4411
7922
9626
6215
3509
2505
1502
900
1703
2305
2806
5714
14943
2806
4209
5313
1402
2605
1803
600
701
901
1703
1603
2906
1602
2806
4010
1503
400
701
900
601
300
500
0
0
0
0
0
0
0
121.487999
122.314003
123.1399994
123.9660034
124.7919998
125.6179962
126.4440002
127.2699966
128.095993
128.9219971
129.7480011
130.5740051
131.3999939
132.2259979
133.052002
133.8769989
134.7030029
135.529007
136.3549957
137.1809998
138.0070038
138.8329926
139.6589966
140.4850006
141.3110046
142.1369934
142.9629974
143.7890015
144.6150055
145.4409943
146.2669983
147.0919952
147.9179993
148.7440033
149.5700073
150.3959961
151.2220001
152.0480042
152.8739929
153.6999969
154.526001
155.352005
156.1779938
157.0039978
157.8300018
158.6560059
159.4819946
160.3070068
161.1329956
161.9589996
162.7850037
163.6109924
164.4369965
165.2630005
1215
1223
1231
1240
1248
1256
1264
1273
1281
1289
1297
1306
1314
1322
1331
1339
1347
1355
1364
1372
1380
1388
1397
1405
1413
1421
1430
1438
1446
1454
1463
1471
1479
1487
1496
1504
1512
1520
1529
1537
1545
1554
1562
1570
1578
1587
1595
1603
1611
1620
1628
1636
1644
1653
42627
40622
44234
40220
37914
42728
42026
42026
44635
45940
40220
42127
40020
39116
41525
39318
38213
42929
39217
39920
44936
41023
42128
41224
42929
38816
40421
41022
42427
42027
39117
47345
42026
45237
40822
39819
43934
44033
43130
40020
45037
41524
40421
42829
38415
40320
40120
43832
41526
40120
44836
42729
42128
47746
23367
25473
24872
26576
24572
26578
27981
23267
23267
22865
23266
24270
24269
24270
24772
21260
21863
22263
29184
22765
25473
23167
23367
24270
24872
23067
26075
25374
26476
24069
24670
25675
23267
23768
25674
25072
22765
21762
26377
23066
24771
25475
22966
22263
22464
21562
25775
24570
24872
25774
25273
26276
24471
23769
27580
25775
25474
22866
27280
24069
26678
24772
24470
26276
26476
22765
28784
26176
24169
23767
26677
27379
24671
26276
26577
24572
25473
25374
23868
24169
25274
26076
25273
24470
28283
24772
28082
23769
23567
22664
23368
26075
23267
22363
24270
25273
24771
25674
22565
27580
28484
24270
25473
25976
22965
28985
23366
25874
26778
24771
28985
23567
22966
25373
23367
26777
24269
27881
25974
24370
25575
27480
25875
24471
25173
25173
25272
26477
26878
26175
25674
26277
23668
25071
24370
25975
26476
24772
23969
24671
23467
25574
26176
24571
25173
26075
24972
22665
27882
24971
26075
23167
26578
23067
24070
23568
22966
24871
29185
24872
22464
23667
95935
97122
93573
95345
92976
96532
94163
94748
95935
97713
98900
90608
98310
95351
98900
93567
95339
90017
92386
97719
99497
94754
95351
95941
94754
96532
91789
94157
92386
94748
92386
95345
89427
91198
97122
95941
93567
94748
97713
91789
95941
88239
97122
92386
98304
94163
95345
96532
92386
92386
92386
93573
90011
95941
200
400
801
701
500
801
801
801
400
600
1001
902
700
800
600
700
500
100
500
1001
300
901
800
100
900
902
801
300
1001
700
900
701
801
801
400
1102
1102
700
200
400
901
600
400
300
400
801
200
701
901
800
400
500
500
801
Table 12: Carbonate traverse down 60 raw data minor elements
78
1202
300
801
1001
1101
1001
400
901
700
1101
901
1302
700
400
1302
701
901
1102
700
801
1002
400
1002
901
1202
700
701
1101
1201
801
1000
1401
801
901
500
1001
400
300
700
300
801
400
400
1303
200
500
901
701
800
601
1202
1102
1101
501
0
200
0
0
0
100
100
300
100
0
0
0
100
100
0
0
200
0
0
0
0
0
0
0
300
0
100
0
100
0
0
100
200
0
500
0
0
0
200
0
100
0
0
0
0
100
0
100
0
0
400
300
0
0
800
500
1201
601
600
800
700
400
701
300
801
400
200
701
200
501
701
300
1001
700
400
700
700
1101
1001
500
200
800
600
400
600
100
800
601
1001
700
801
700
600
500
1302
601
500
400
200
600
200
700
700
1001
600
801
600
600
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
Carbonate Traverse Down 90
left hook traverse major down 90 um
Ave blank
18,960
Trace for Mass: Distance (um)
Resolution:
Time
[sec]
um/s
0.95
1.83
2.71
3.59
4.47
5.35
6.23
7.11
7.98
8.86
9.74
10.62
11.50
12.38
13.26
14.14
15.01
15.89
16.77
17.65
18.53
19.41
20.29
21.16
22.04
22.92
23.80
24.68
25.56
26.44
27.32
28.19
29.07
29.95
30.83
31.71
32.59
33.47
34.35
35.22
36.10
36.98
37.86
38.74
39.62
40.49
41.37
42.25
43.13
44.01
44.89
45.77
46.65
47.53
48.40
49.28
50.16
3,519
28,385
4,801
18,654
31,604,593
3,285
Mg24(LR)
Low
Ca43(LR)
Low
Sr88(LR)
Low
Ba138(LR)
Low
Al27(LR)
Low
Na23(LR)
Low
Ti47(LR)
Low
10 Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
Intensity
[cps]
10
18
27
36
45
53
62
71
80
89
97
106
115
124
133
141
150
159
168
176
185
194
203
212
220
229
238
247
256
264
273
282
291
300
308
317
326
335
343
352
361
370
379
387
396
405
414
423
431
440
449
458
466
475
484
493
502
19098
19542
19393
18504
19690
20282
19393
19246
18653
19393
17914
18358
18653
18950
19246
18506
18652
18801
18506
19247
18506
18506
18653
19096
1838870
2586170
1792216
2163601
2048666
1813242
1072315
2067483
4023503
3488645
2844108
2658297
5154881
10788923
12090992
24401600
21694082
7514829
2966261
1807620
2696191
3225380
2589135
1237714
2350605
2000423
2226515
2727861
2732172
2802941
2395894
2638145
2758243
3485
3603
3603
3603
3544
3781
3485
3486
3544
3721
3426
3722
3544
3367
3308
3367
3367
3603
3485
3248
3485
3544
3308
3426
116036
165480
160866
222849
285126
246564
137503
167489
162286
228820
347047
346399
341074
404535
375790
278264
279506
328712
282227
271343
314756
304348
146494
117337
207116
306003
533819
653287
574566
579297
570724
577764
558244
29686
29567
29985
29330
28740
28681
28208
28384
28031
28799
28563
28622
27500
27736
28917
28031
27854
27380
26966
27854
27145
27322
27145
28505
675994
992649
931673
1056460
1052612
710652
457879
995664
1044331
1114362
1643373
2087068
1542907
1440765
1621502
1068582
2552575
1852803
1626286
1370858
1602980
1973621
836095
861403
977626
2276328
3822053
3966661
4383666
4425908
3889904
3857136
3738491
79
5085
4966
5026
5023
4611
4788
4433
4967
4966
4729
4788
4790
4788
4849
4729
4790
4967
4907
4729
4788
4610
4552
4492
48732
241715
222432
207175
172104
109057
123250
158085
307126
281223
159684
149629
125616
85638
121951
159092
142887
193214
145904
214096
147915
188901
129047
116864
375120
170034
100008
114615
86109
67479
65173
59080
54290
90681
22060
18803
18653
18504
19542
18655
18358
18655
18653
18653
18357
18803
18801
18653
18950
18358
18210
18358
18507
18803
18950
18801
18652
18950
9366273
13087778
13227070
9847892
7585326
10398874
15066796
13898304
13977590
9693479
6041976
6402328
4177467
4118830
4113231
4356356
4388202
4629248
3974458
5356260
6677181
7415321
13407329
15114992
10423208
7168912
1201438
330639
200339
54488
151619
24725
26946
31292164
32348296
32192560
32112234
32055912
31900932
31864644
31767876
31619888
31615542
31493070
31473036
31411044
31389876
31342248
31234328
31183676
31209192
31150602
31123952
31124142
31092390
30967650
30993920
33054020
33357556
33781860
33169312
36754452
34852544
46469996
42967260
34114688
33834780
32331474
32554304
32406884
31779028
31606280
33960656
36632924
34793008
31752944
31499874
31587192
33462260
41460176
47420100
35505728
33744248
31613274
31416148
31317300
31462264
31560732
31448844
31491558
3699
3253
3256
2661
3550
3105
3254
3105
3402
3105
3402
3994
3550
2958
2958
3551
3402
2959
3107
3697
3253
3256
3846
3402
67073
199302
84250
56264
39532
201964
52709
75808
74772
83212
60854
70479
46639
27539
25020
341598
83510
180644
67665
47823
43678
67814
71368
32722
42642
19099
7399
4143
5772
3846
3996
2662
5624
51.04
51.92
52.80
53.68
54.56
55.43
56.31
57.19
58.07
58.95
59.83
60.71
61.58
62.46
63.34
64.22
65.10
65.98
66.86
67.74
68.61
69.49
70.37
71.25
72.13
73.01
73.89
74.76
75.64
76.52
77.40
78.28
79.16
80.04
80.92
81.79
82.67
83.55
84.43
85.31
86.19
87.07
87.94
88.82
89.70
90.58
91.46
92.34
93.22
94.10
94.97
95.85
96.73
97.61
98.49
99.37
100.25
101.13
102.00
102.88
103.76
104.64
105.52
106.40
107.28
108.15
109.03
109.91
110.79
510
519
528
537
546
554
563
572
581
589
598
607
616
625
633
642
651
660
669
677
686
695
704
713
721
730
739
748
756
765
774
783
792
800
809
818
827
836
844
853
862
871
879
888
897
906
915
923
932
941
950
959
967
976
985
994
1002
1011
1020
1029
1038
1046
1055
1064
1073
1082
1090
1099
1108
2596848
2900973
2336383
3784950
5585777
12351670
5515020
3203763
2722096
2259979
1812510
2047791
2240725
1658534
1836802
2610303
2959906
2304702
3031288
1997305
2592241
2806071
2470833
4480576
2873131
2288105
2949983
2975734
1658806
1995226
2175284
2391913
3350509
6572333
3657410
4569430
5866489
3805681
5341873
3513841
3852883
9886448
8412154
3853639
2569609
1859004
2250943
1037820
1610989
2050461
1694952
2030321
1753891
2619505
2403017
4014596
6178457
3584007
3229384
4106545
1991387
1843612
2936647
4699273
2810643
1824949
2758089
2278053
2216002
531450
538907
510161
473079
419615
383422
261704
270812
211196
339775
465451
271463
129283
256854
415710
373544
390459
300325
297189
223912
170744
210013
130584
215041
187126
261408
305234
325873
161043
212557
390044
266909
244731
270398
169975
165242
204808
299438
439249
318125
157673
259398
395073
219122
184818
155957
165006
245322
175355
199073
260048
440137
201793
196057
232665
204513
254370
268624
207057
414411
401337
208121
261588
287488
109471
277908
229589
237397
179259
3895763
3866657
3495177
3154174
2587009
2041413
1309587
1558760
1252397
2464749
3833487
1327099
852414
1931226
4217015
1844640
1882794
1452949
1492214
1057880
878561
976847
774463
944144
1589207
1532436
1696842
1929229
1035519
1522679
2011657
1432785
1203003
849638
1124417
962305
1001039
1833412
1904317
1266005
984365
796939
1162740
1382039
894053
746024
848578
670144
1359861
1776529
1754570
2060632
2113745
1165929
1592402
1076509
2281317
1116907
1051726
1440582
1204202
838936
1294095
968867
1207686
1681775
1724767
1472936
1071541
80
50741
57663
58370
93797
91727
271521
199072
159978
146968
118341
124019
594854
429901
198243
158679
159978
113554
114973
143359
159150
153413
164178
247512
203389
238933
190850
157317
131532
195997
158382
157969
143893
132123
195464
252359
236331
140285
136321
138806
119761
89363
104267
181625
178372
200728
176953
123724
111956
151463
185291
175122
133010
192566
197121
161576
125084
131768
154893
120530
113137
226871
211788
173167
170034
399921
184879
235622
413582
281635
55228
163171
545191
2148481
3184544
3733577
11193761
9158515
11536844
7409556
4942256
13376711
17542318
9034909
4808704
7872937
7508545
7366748
7155587
11097749
11388715
11486617
12098410
11169050
10856727
11605734
8681762
6529808
9659884
11134226
7704774
10126620
8835561
9043366
14195601
14307867
12146841
7778366
5288456
5681884
7546203
4804876
10283726
9510669
12924576
11571950
7077389
5471030
9427745
13068830
10410592
4853709
9117502
12217338
10805555
8126197
8290391
8630780
10593922
3202286
4953525
10660120
8481280
8948300
12659031
9382102
10229956
13041142
13337210
31441284
31504788
31897340
31722516
32595128
31427108
31971428
31595130
31743684
31222800
30864834
34074244
35743112
31380048
31044384
31597020
32480028
34902064
33655420
32111668
32703236
32128866
33465284
31868424
32067252
31990708
35483048
31755212
32696622
32718546
32259654
32081616
31704560
32215616
31883166
32022080
35416332
34032284
32304258
32519340
31247370
31034178
32389876
31893750
31925312
31735556
31391010
31507056
35014140
37638216
35022832
31722704
34633684
32940054
32492880
31037768
31185756
31659390
36942320
32348484
30863888
33573392
31935140
31879764
39258892
36931544
34135856
34999400
33040412
3846
4883
18358
11844
12731
21615
92691
42789
38642
92541
37016
55820
49156
25319
34054
63223
56560
31535
24282
80845
130596
110753
66628
57744
88247
100536
60409
62631
146292
74478
38348
55376
57449
111495
116826
133261
54487
73587
70627
43086
46491
54785
128226
114603
71960
85137
54042
33460
70775
186124
54634
24873
30352
78029
59966
46493
31832
41310
33314
11991
24133
64260
74183
37754
31387
31683
49156
214849
288291
111.67
112.55
113.43
114.31
115.18
116.06
116.94
117.82
118.70
119.58
120.46
121.33
122.21
123.09
123.97
124.85
125.73
126.61
127.49
128.37
129.24
130.12
131.00
131.88
132.76
133.64
134.52
135.39
136.27
137.15
138.03
138.91
139.79
140.67
141.54
142.42
143.30
144.18
145.06
145.94
146.82
147.70
148.57
149.45
150.33
151.21
152.09
152.97
153.85
154.73
155.60
156.48
157.36
158.24
159.12
160.00
160.88
161.76
162.63
163.51
164.39
165.27
166.15
167.03
167.91
168.79
169.66
170.54
1117
1125
1134
1143
1152
1161
1169
1178
1187
1196
1205
1213
1222
1231
1240
1248
1257
1266
1275
1284
1292
1301
1310
1319
1328
1336
1345
1354
1363
1372
1380
1389
1398
1407
1415
1424
1433
1442
1451
1459
1468
1477
1486
1495
1503
1512
1521
1530
1538
1547
1556
1565
1574
1582
1591
1600
1609
1618
1626
1635
1644
1653
1661
1670
1679
1688
1697
1705
2223266
5375916
2201496
2556851
388534
1898257
3837669
5521541
6179213
2935324
2285754
4537300
10933414
13205997
7222234
3192659
3544920
2948955
2666578
3494445
2283380
2820872
2112205
2321121
2297449
2644063
3629922
3310666
2594179
3029800
3346824
2529175
2419744
3821202
2477648
3338224
2594746
2269300
2696357
2735586
2597876
3200077
3441997
3254131
2771106
2948802
1772525
2255396
2211418
2700787
2678142
2428485
2404198
2361567
2594167
2860716
2505928
1459216
1993749
1985752
1730921
1592485
10522858
23212980
5130760
461829
149402
47823
251355
303578
272882
84040
34182
196232
252420
236036
305293
286840
240473
222079
185648
184643
228110
226986
252125
315998
302571
254431
192271
151046
191265
134902
213266
250173
284770
255671
177781
237101
248042
249995
213208
208476
194103
246621
168377
173818
225865
224919
210841
249994
297545
283115
216875
168849
226692
301803
271817
411156
484197
617980
546355
589766
545233
414409
401340
454802
364140
294530
456695
356098
380699
360001
87587
15374
5853
3841
1691231
2052363
1881082
788895
375553
1306634
1080649
963605
1109802
1223952
1190889
1215790
1051313
830770
1018486
1036175
1185568
1754700
1991741
1701585
1404394
1003761
655473
749923
1127367
1443671
1728854
2167098
943494
1447096
1179779
723427
1154637
1220810
1269371
1490318
1079698
1660666
1149132
944262
1103949
1195029
1701112
1515875
916172
1113824
1223119
1283269
1875388
2704059
3762754
4076683
4143613
3895054
3436351
2581622
3741208
4761808
2488410
2280521
4580037
3100888
2994079
1503099
229058
61447
34596
29627
81
232311
271522
293938
89539
79308
111895
187066
210310
172576
241656
232074
370703
235148
215454
208240
172220
230299
235445
250171
194341
271581
177427
214568
206996
292814
238756
320494
484020
269688
246267
194931
221369
212911
262827
222967
184700
314223
321677
199606
202147
227343
225214
247983
273947
287846
275188
188486
164474
331553
167373
77356
59850
85280
136439
159388
124315
68603
115209
143950
99712
102493
371001
133896
68132
14605
5440
4375
4018
11734490
9076016
8858666
15311740
16544398
12253012
7533871
9601247
8647270
11003911
9291051
11681665
10677460
9424060
11467244
11524795
10470884
8634843
9517615
9990871
10632715
12137060
12617309
13073886
12043080
9814912
9685069
10094962
13084895
13328894
10896748
9893110
11625437
14117828
12403786
12405676
14751356
13806922
14498757
13160354
12950138
11818123
9578189
9910404
13668433
12843117
8673635
6677016
9193149
5354347
1665190
271116
84545
2152112
821929
4467582
5938333
4175246
5939656
6055159
3560170
4772274
4257013
3903984
1056622
133704
46788
26649
32777324
32896206
35675264
55412912
57235248
45717776
38891476
32224688
32173092
32969916
33173658
32982390
32214104
32938352
32504788
34967080
33589648
31646348
32433156
32009608
35378344
41834960
39840064
33142096
32079916
32628016
32884300
33231304
31754268
31812102
31424274
31405940
32448088
31525956
32510080
31218452
31934952
33407262
31831758
31664492
31585302
31765986
31759560
31725162
31843098
32205600
31266460
32734988
31747464
31328452
30940244
31280634
30765798
30728188
31027374
34967080
36803592
37080288
32803784
32335444
30662604
30367576
30554118
30437128
29903202
29651454
29617244
29621970
101277
72256
40124
37162
39978
42938
53893
42345
42050
49453
41753
114900
91061
48563
66630
71813
64111
36127
45010
78029
55820
49158
47380
79362
58190
157100
943057
137406
126153
61742
46194
54488
66778
68554
72405
122750
131188
125709
81435
117418
74032
77735
62484
35681
62038
54044
35238
45305
114457
35091
9621
5327
4142
3699
5031
9029
7401
32424
31833
29463
22355
17617
44269
122897
19246
5770
3697
3107
171.42
172.30
173.18
174.06
174.93
175.81
176.69
177.57
178.45
179.33
180.21
181.09
181.96
182.84
183.72
184.60
185.48
186.36
187.24
188.12
188.99
189.87
190.75
191.63
192.51
193.39
194.27
195.15
196.02
196.90
197.78
198.66
199.54
200.42
201.30
202.18
1714
1723
1732
1741
1749
1758
1767
1776
1784
1793
1802
1811
1820
1828
1837
1846
1855
1864
1872
1881
1890
1899
1908
1916
1925
1934
1943
1951
1960
1969
1978
1987
1995
2004
2013
2022
24577
22947
21022
18950
17172
18209
18803
17617
17617
18061
17766
18210
17026
17468
17766
17617
18506
17469
18060
17617
18060
17766
17469
18506
18061
17469
18653
17026
17617
17320
17766
17914
17763
17468
17914
17174
3545
3545
3308
3071
3367
3485
3427
3308
3248
3367
3012
3308
3426
3189
3248
3367
3308
3248
3426
3367
3485
3367
2953
3308
3426
3189
3071
3248
3130
3189
3485
3248
3485
3130
3189
3308
26906
26552
25664
25428
24955
25013
24895
25487
24955
24659
24660
24540
24955
25190
25192
24363
24718
24836
24895
24895
25310
24837
24009
24837
25014
25249
25131
24186
23951
25133
24422
25311
24895
24245
25074
24896
4315
4670
4195
4019
4374
4374
4255
4196
4136
4077
4255
4195
4315
4552
3960
4255
3841
4136
4316
4315
4075
4198
4254
4077
4018
4078
4018
4195
3900
4257
4136
4433
4492
4374
4075
4196
23539
20579
18803
19839
19987
19246
19099
18803
19987
18804
18803
19395
19395
18358
19247
19541
18803
19691
18506
19838
18950
18358
19690
18803
18358
18209
18950
18358
19099
18357
19246
18949
17765
19247
17912
19098
29652400
29646162
29610630
29629152
29571884
29642760
29546370
29570752
29506680
29510648
29512160
29516696
29566026
29462076
29469068
29542024
29482300
29477764
29531816
29542780
29526336
29527848
29523690
29458484
29438828
29482866
29478708
29412368
29400462
29417094
29455650
29379104
29429380
29316546
29370222
29453572
3846
3256
3846
3253
3697
3848
3254
3253
3401
2958
3107
3551
3848
3254
3699
3996
4142
3254
3700
3551
3254
2959
3402
3403
2958
3254
3551
3107
3550
3996
3697
2808
3699
3699
3551
3253
Table 13: Carbonate traverse down 90 raw data major elements
traverse minor down 90 um
Ave blank
43,589
24,657
26,068
25,997
110,620
622
837
57
558
-
Trace for Mass: Distance (um) Mn55(LR) Ni58(LR) Zn64(LR) Rb85(LR) Sr88(LR)
Low
Low
Low
Resolution:
Low
Low
Mo98(LR)La139(LR)Ce140(LR) Th232(LR U238(LR)
Low
Low
Low
Low
Low
Time
[sec]
IntensityIntensity Intensity Intensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
um/s
10 Intensity Intensity IntensityIntensity Intensity
[cps]
[cps]
[cps]
[cps]
[cps]
82
0.90200001
1.728000045
2.553999901
3.378999949
4.204999924
5.031000137
5.856999874
6.683000088
7.508999825
8.335000038
9.161000252
9.987000465
10.81299973
11.63899994
12.46500015
13.29100037
14.11699963
14.94299984
15.76799965
16.59399986
17.42000008
18.24600029
19.0720005
19.89800072
20.72400093
21.54999924
22.37599945
23.20199966
24.02799988
24.85400009
25.68000031
26.50600052
27.33200073
28.15800095
28.9829998
29.80900002
30.63500023
31.46100044
32.28699875
33.11299896
33.93899918
34.76499939
35.5909996
36.41699982
37.24300003
38.06900024
38.89500046
39.72100067
40.54700089
41.3730011
42.19800186
43.02399826
43.84999847
44.67599869
45.5019989
46.32799911
47.15399933
47.97999954
48.80599976
49.63199997
50.45800018
51.2840004
52.11000061
52.93600082
53.76200104
54.58800125
55.4129982
56.23899841
57.06499863
57.89099884
58.71699905
59.54299927
60.36899948
9
17
26
34
42
50
59
67
75
83
92
100
108
116
125
133
141
149
158
166
174
182
191
199
207
215
224
232
240
249
257
265
273
282
290
298
306
315
323
331
339
348
356
364
372
381
389
397
405
414
422
430
438
447
455
463
472
480
488
496
505
513
521
529
538
546
554
562
571
579
587
595
604
52262
45539
43531
46041
46844
43932
47745
39317
41224
43631
41825
44936
44134
43933
41525
41825
43331
42428
43431
42729
42929
42930
46442
41324
45539
44234
438020
495324
572524
496836
354074
231080
329294
597796
487742
402334
248982
376534
521948
719264
450944
495160
606970
419262
470294
586454
648840
1300360
1117533
977600
1593344
982780
647184
525496
532750
733896
413444
374620
569242
536398
563034
625500
586846
621410
793756
905052
490786
412330
676094
524896
542342
620938
608816
28684
24771
22966
22866
26277
23266
26276
25574
24772
26175
21762
24770
25674
25373
23969
23969
24471
22464
22465
25473
25774
24370
22865
25272
27781
25072
97331
78356
64004
44134
37111
30189
41725
76750
182020
191161
119924
129163
114400
120526
133486
191768
109783
89200
125750
116008
182018
209177
163021
140115
627388
717060
183726
160711
181730
125651
107873
139216
380482
162217
115907
102954
139410
136398
210674
325164
160711
173876
242144
178503
195104
216399
238623
27982
25173
28583
28384
24570
30089
23669
25575
24068
27079
23667
27479
26076
25674
26276
26074
26276
25172
23568
24270
25173
26577
28383
23668
24270
26778
54771
43732
44134
41525
35305
37010
35506
49051
75144
62398
48750
171868
74447
67015
61996
195571
68619
67516
276201
71530
72634
78756
75847
64403
81468
76649
85383
74444
55071
59687
54470
51259
252841
52663
44335
40722
42628
42829
51759
123943
50154
62598
54469
41926
43130
50354
56075
26677
31192
24671
25072
25474
25674
24872
27179
25775
27881
29186
28182
23868
26577
24370
26577
23266
25574
23969
25775
25875
26077
28283
23065
26578
64910
241459
268695
131675
151566
68319
39919
38918
104359
324976
401132
346014
452778
353280
378048
325066
367976
296476
324276
335448
294073
373562
209161
180307
193877
222733
372416
495954
485746
325474
288025
266586
308967
346114
391864
306746
294090
343704
320645
358200
264980
314996
355378
338058
187041
195586
281580
505046
83
121409
110152
115485
117853
113122
113111
108970
113117
114304
109561
109561
111333
106011
108970
104824
111935
106011
109561
105415
105415
107789
104824
106602
100672
106005
783582
7122950
8424533
12372743
13586170
13096472
12525455
12632618
11319635
6769740
2402273
1063728
3280024
4362687
4496570
3189411
400191
3665017
7399917
1379340
7733313
7640836
6252097
8148546
5539590
3589552
4772163
2742248
3118358
4728166
5554403
3854537
2077122
677832
2360823
5861516
4888060
5029609
5268883
4387688
2061160
3669152
2072373
4585506
5878940
7852997
3341858
5086836
400
700
1000
1001
701
600
500
300
500
300
902
400
500
1201
601
601
601
601
801
701
500
801
501
800
801
1201
601
500
901
500
501
800
801
700
1302
1201
1704
1001
1001
1502
1804
2003
1303
1001
1302
700
2105
1001
1301
701
1603
1603
800
1001
1102
2003
2304
1101
1803
2103
1201
2104
2404
902
8622
4812
1301
1703
1803
2505
2103
3107
1704
1100
1101
801
501
800
1201
901
600
700
300
901
1001
1001
1202
1402
701
500
1002
700
1301
400
1101
500
600
900
20660
41224
41324
37211
32295
19755
14641
16144
16546
128763
59386
33801
30093
30590
39318
25875
29085
65910
75850
50655
41225
30088
42227
35605
74168
26677
27983
33800
23568
44035
38517
28683
28483
46040
34202
57280
66116
35707
40422
50355
35906
48951
25172
21461
23167
123520
84613
108217
100
100
0
100
0
200
100
100
0
0
0
0
0
100
100
100
0
200
200
100
0
0
0
0
100
80266
212879
151065
174782
126753
79962
49753
57279
78558
428860
172076
77353
108684
130881
145641
98536
98433
185736
187242
122538
122837
103857
122736
109480
134101
252926
105266
138107
77354
104058
98837
64706
70627
134890
192431
203859
141627
122152
152180
260476
161720
131979
97128
90008
75747
149567
127157
105063
600
801
901
300
1101
500
400
600
300
802
500
400
300
300
600
1001
701
701
400
901
701
800
600
1001
1000
6015
12033
12033
6818
6416
1704
801
1202
4311
72235
87995
16446
14540
17650
10828
14340
12735
9425
11631
24977
7921
7319
10729
6616
8724
10429
18652
29586
10429
12234
23668
8121
12233
16044
15342
11030
13438
12032
10529
18752
11331
14941
8121
7319
6817
12635
17148
15443
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
0
0
10931
9927
4210
2004
600
400
100
500
6517
197703
160509
30591
21562
33211
40833
28583
14540
9927
10126
7920
8422
6918
6215
5915
5313
14742
34401
42227
10027
11231
33801
13737
14139
15243
22264
11330
11933
14942
8121
14339
13939
10327
10930
8924
7219
14741
17047
17850
61.19499969
62.02099991
62.84700012
63.67300034
64.49900055
65.32499695
66.15100098
66.97699738
67.8030014
68.62799835
69.45400238
70.27999878
71.10600281
71.93199921
72.75800323
73.58399963
74.41000366
75.23600006
76.06199646
76.88800049
77.71399689
78.54000092
79.36599731
80.19200134
81.01799774
81.84300232
82.66899872
83.49500275
84.32099915
85.14700317
85.97299957
86.7990036
87.625
88.4509964
89.27700043
90.10299683
90.92900085
91.75499725
92.58100128
93.40699768
94.23300171
95.05799866
95.88400269
96.70999908
97.53600311
98.36199951
99.18800354
100.0139999
100.8399963
101.6660004
102.4919968
103.3180008
104.1439972
104.9700012
105.7959976
106.6220016
107.4469986
108.2730026
109.098999
109.9250031
110.7509995
111.5770035
112.4029999
113.2289963
114.0550003
114.8809967
115.7070007
116.5329971
117.3590012
118.1849976
119.0110016
119.836998
120.6620026
612
620
628
637
645
653
662
670
678
686
695
703
711
719
728
736
744
752
761
769
777
785
794
802
810
818
827
835
843
851
860
868
876
885
893
901
909
918
926
934
942
951
959
967
975
984
992
1000
1008
1017
1025
1033
1041
1050
1058
1066
1074
1083
1091
1099
1108
1116
1124
1132
1141
1149
1157
1165
1174
1182
1190
1198
1207
1590904
2121744
1491256
603646
348350
452190
1163580
2356336
3469744
4821792
2319440
740120
666204
590964
963672
730676
808748
894328
1463056
791252
703846
985216
2557552
3567072
4812387
2195880
955992
822736
602536
490808
354482
707600
2218080
2639840
1236632
776136
848388
861548
595880
890356
939440
676432
700180
598008
805688
1577856
3716896
4162048
3080752
1938280
987128
607708
359708
537500
690284
511554
987952
2142720
1948336
1069688
646544
785368
1042196
1905608
2467776
1139856
436016
74742
50255
44636
44434
48548
41826
370694
53967
308356
48147
231089
51760
114501
65920
132580
44334
128462
38816
404164
63401
437226
62798
367572
44836
365564
42127
248480
50154
173778
51961
293858
66915
174677 121057
193071
75444
147749
69524
145842 144693
190461 114501
471198 2862576
286817 5102048
384624 1776768
606592 601228
1543336 269911
2262560 204532
1228472 131675
627724
87392
233797
63903
249793
56778
146946
91670
116609
40924
78959
41826
136202
36911
204735
35204
257133
63309
227060 155501
221548
42227
142932
40923
180105
42328
167648
51458
247879
53466
170959
49755
270611
51459
185837
51861
128060
49754
106871
45839
161514
54670
334959
48749
420478
39518
292042
48047
271520
48048
136397
41625
85082
43330
65408 100500
126956 277916
275440
60792
122434
45437
173473
45939
218409 136561
150060
51358
171767
52764
123742 164363
110586
43531
121733
39920
500090
44735
849096
47546
331190
44937
94823
27982
27280
27078
27380
28884
24269
24972
27079
22665
23767
23468
25072
27379
468628
243653
281998
271818
279570
294864
291138
321654
238703
138307
236109
271117
293358
220418
291242
292850
238624
137502
283698
304228
296498
247072
354058
246166
228468
250290
227056
348438
356894
272935
213480
189252
122335
177200
224947
172877
195786
331328
237314
231887
275863
277359
291746
243551
260048
217506
136898
116710
261463
261052
266090
217805
171565
125548
211786
315702
227862
108977
73139
139109
227560
135193
171473
159608
125448
89599
37312
25473
24570
23969
24270
26276
24873
84
3155359
2884700
1929283
1174482
1567743
1944444
3797667
5114596
2833465
2591793
4008004
2905119
2824979
2100818
3533340
3246867
5929875
11188706
9349473
3687364
3745130
5109779
7934520
8074574
9287507
5692750
4603193
5616310
3733695
3054984
2412940
2782517
2418869
2756447
9197340
10137960
7442584
4629248
6104269
7614445
6295921
4859152
4071320
5804332
6582587
4077793
2932961
3660871
3019774
5854494
6061372
5755759
3371843
6172717
5515304
3562532
2059344
6756679
15887812
12569303
5169386
4366845
5079966
5864150
8877046
12711998
2883798
354765
419326
120812
104824
109561
100087
2606
1002
500
800
2305
1202
2305
2204
700
802
1703
1101
1502
1703
1201
1603
1604
8121
5613
5013
3608
4911
9926
13638
7720
2204
1101
1603
1202
2003
400
1001
801
1603
701
2105
1501
1101
1502
1402
1101
1502
1101
1402
1000
1301
700
1402
1602
701
901
701
1101
1502
1102
1100
901
801
500
1100
1402
1803
3307
12433
18552
10429
3007
500
400
600
300
500
300
16044
24475
10929
9025
11030
19253
53577
26181
15341
30489
34202
21863
43031
13136
21862
42637
39620
24570
31191
53568
33901
33097
27982
26076
96417
50154
41927
45739
50963
35807
23066
15744
16446
19956
24370
28783
46341
53366
71128
34000
29485
38816
33901
38715
49855
63332
20457
20257
16847
20358
18451
17549
11029
27380
22464
19154
55580
44434
40421
34503
26075
21462
28182
18150
28584
27179
5313
1302
801
1302
600
400
901
55775
44534
40724
26677
46246
90113
58683
54268
45437
67717
99037
69825
144339
55574
106897
115207
107171
58584
111198
141524
74341
102663
74843
73037
114104
146449
112493
152485
100141
116209
61093
54672
51359
65915
79061
101447
163325
151469
257078
109581
76750
134493
103858
120028
120427
88798
47545
71433
49050
59989
59086
52262
43133
93516
125753
45338
118923
142435
92410
98747
63903
68821
88097
39819
76750
65006
10829
1502
500
400
200
0
400
8623
5012
7518
4510
5815
7118
4711
4311
6417
5314
13337
8924
12634
4610
7219
7219
10228
6115
13236
31292
20359
9525
11231
9125
13236
14941
14539
13938
15844
10428
5615
4209
2606
6316
7921
7418
15643
12734
11632
11029
11331
11130
13236
13436
10728
5413
1703
2706
19355
7219
4009
12936
8422
7318
25172
8824
4811
3407
2504
5614
5815
5312
4210
5314
2705
4611
801
400
801
1001
501
801
601
8924
5112
9926
14841
19460
5112
5013
11130
9125
4310
11030
6617
6316
8021
11331
5715
6617
4110
8523
41126
14139
6216
14942
43355
11532
9425
10829
10829
19555
8924
4912
2605
2405
6116
7119
8622
15042
15242
9124
6116
11230
8723
16546
33199
14441
5613
2605
901
36007
8221
6617
12635
10327
33208
44836
10327
5613
1502
2706
5514
5513
5112
3909
7921
3508
4611
200
100
0
0
100
0
0
121.487999
122.314003
123.1399994
123.9660034
124.7919998
125.6179962
126.4440002
127.2699966
128.095993
128.9219971
129.7480011
130.5740051
131.3999939
132.2259979
133.052002
133.8769989
134.7030029
135.529007
136.3549957
137.1809998
138.0070038
138.8329926
139.6589966
140.4850006
141.3110046
142.1369934
142.9629974
143.7890015
144.6150055
145.4409943
146.2669983
147.0919952
147.9179993
148.7440033
149.5700073
150.3959961
151.2220001
152.0480042
152.8739929
153.6999969
154.526001
155.352005
156.1779938
157.0039978
157.8300018
158.6560059
159.4819946
160.3070068
161.1329956
161.9589996
162.7850037
163.6109924
164.4369965
165.2630005
1215
1223
1231
1240
1248
1256
1264
1273
1281
1289
1297
1306
1314
1322
1331
1339
1347
1355
1364
1372
1380
1388
1397
1405
1413
1421
1430
1438
1446
1454
1463
1471
1479
1487
1496
1504
1512
1520
1529
1537
1545
1554
1562
1570
1578
1587
1595
1603
1611
1620
1628
1636
1644
1653
42930
42728
43631
43732
40521
38515
42830
43230
40020
42929
39217
39618
41425
41325
46641
43330
36910
41123
41926
42930
41926
40923
46944
42127
37712
42528
39618
46842
40922
43431
40622
38615
38314
38415
40120
34301
44033
41825
38114
37812
40622
41926
41826
39819
42528
39719
41324
42427
40421
43029
43030
45037
40723
40923
20058
25875
23768
22464
21863
23266
27580
25674
23065
24370
23166
20357
25173
21362
24470
25574
22866
24068
25071
26076
26177
24271
23366
26678
24269
23468
24871
27178
24470
25874
22765
24469
23367
21763
25573
25373
24972
23869
24871
21962
26276
23367
21461
25073
21261
24471
21060
25774
23668
26376
21861
26578
24671
23367
25875
25072
26777
24672
25072
26677
27380
25173
26777
26276
21962
26778
25474
26979
26074
24470
25673
25473
26176
23567
24570
27179
21361
25072
24872
22163
25774
24271
26578
26076
21159
23969
27580
24671
24070
24370
25274
26075
23367
24671
27781
25574
24170
25674
24771
23869
25072
29084
25674
25574
24571
24170
27982
25775
25072
20558
24772
22263
22464
26878
23969
24871
25674
25474
24972
22464
24973
22163
22163
24470
24069
21561
23767
24170
23869
24772
24571
24170
25674
23968
21260
23468
23968
24270
22665
23568
22664
20859
22263
23367
24572
24670
21762
23767
23768
21261
26477
24872
26576
21161
25373
22764
21963
22866
24170
24270
21762
24471
97122
95345
95345
94157
98310
90608
92976
91198
95345
97122
91795
99491
96532
94754
93567
91204
93573
92970
96532
95351
93567
92386
93573
97122
94163
99491
93567
96526
95345
95345
94748
94169
95345
92970
96532
97122
96526
88830
94163
94754
92976
94748
92386
97122
93573
96532
95935
90017
94754
92380
97713
90011
95935
91789
300
600
400
701
300
700
400
700
1101
601
700
701
700
400
600
1302
701
300
400
500
1502
501
900
400
200
100
1302
200
700
801
500
400
801
701
200
701
800
701
800
700
300
700
901
700
400
100
801
1001
801
400
600
501
400
500
Table 14: Carbonate traverse down 90 raw data minor elements
85
701
601
501
800
601
802
700
701
801
1202
300
801
601
501
701
700
901
1002
1001
1102
700
700
1000
1202
700
1101
801
1000
1100
800
700
1202
300
400
800
900
700
901
701
1301
200
1102
1101
700
900
1102
1101
901
700
800
500
701
1302
901
0
0
0
100
0
100
0
200
100
0
0
0
200
0
0
0
100
100
0
200
100
0
0
0
100
0
100
0
0
0
100
0
100
100
100
0
0
0
0
0
0
0
0
0
300
0
100
0
0
0
0
100
0
0
0
600
601
900
400
1302
400
1101
200
400
500
601
901
1302
801
701
500
300
1001
500
600
200
501
400
900
200
500
400
400
700
1302
500
200
401
1102
500
600
800
100
500
500
200
501
901
801
1102
400
601
800
801
500
800
700
600
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
100
0
0
0
0
Laser Ablation Graphs
Site E
86
Figure 9: Laser ablation results site E
87