1. What is the weight of a mole of carbon atoms if the gram molecular volume is defined as 33.6 liters? A) 8.00 g B) 12.0 g C) 18.0 g D) 24.0 g E) 36.0 g Explanation of the answer: In the problem # 1 above we are given 33.6 liters of carbon and asked to find the weight (mass) in grams. To answer this problem correctly, we will convert the given 33.6 L to moles by dividing it with 22.4 L because I mole of any gas at STP contains 22. 4 L. Then we will convert the calculated mole(s) into gram by multiplying it with 12, the atomic mass of carbon. By using the following dimensional analysis calculation ๐ ๐๐๐๐ 33.6 L x ๐๐.๐ ๐ณ ๐ฟ ๐๐ ๐ ๐๐ ๐ช ๐ ๐๐๐๐ = ๐๐. ๐ g we can say that 18.0 g of carbon occupy a volume of 33.6 liters or vice versa. The mass of one mole of a gas with a density at STP of 2.9 gโขLโ1 is close to 2. A) 2.9 g B) 24 g C) 44 g D) 64 g E) 76 g Explanation of the answer: In the problem # 2 above we are asked to find the mass in grams for the gas with ๐ density of 2.9 g.L-1, which can also be written as 2.9 ๐ฟ . The Density formula is given in Table T which is D= which can be rearranged for the calculation of mass as follow: ๐ ๐ , M= D*V We know that a mole of a gas at STP occupies 22.4 liters of volume. Therefore, the setup to solve the given problem will be ๐ M= 2.9 ๐ฟ X 22.4 ๐ฟ 1 ๐๐๐๐ = 64.96 ๐ 1 ๐๐๐๐ or Mass of 1 mole = 64.96 g 3. Seven grams of a gas occupies 11.2 liters at one atmosphere pressure and 546 K. The gas could be B) O2 C) CO D) NH3 E) N2 A) Ar 4. A 1.00 L sample of a gas, at standard conditions, has a mass of 1.96 g. The gas is most likely to be a. H2 B) N2 C) O2 D) CO2 E) Ar Explanation of the answer: To solve the problem # 4 first we will find the formula mass of each molecule. H2=1x2= 2 g/mole N2=14x2=28g/mole O2=16x2=32g/mole CO2=(1x12)+(16x2)=44g/mole Ar= 1x36=36g/mole Then we convert the given volume of 1.00 L into moles, 1 ๐๐๐๐ 1.00 L ๐ 22..4 ๐ฟ! =0.0446 moles We learned that the given mass in grams can be converted into mole by dividing it with GFM by using ๐๐๐ฃ๐๐ ๐๐๐ ๐ ๐๐ ๐๐๐๐๐ the following equation: moles= ๐บ๐น๐ ๐๐ ๐๐๐๐๐๐ข๐๐๐ ๐๐๐ ๐ ๐๐ . Rearranged equation for the calculation of GFM or MM will be ๐บ๐น๐ ๐๐ ๐๐๐๐๐๐ข๐๐๐ ๐๐๐ ๐ ๐๐ = ๐๐๐ฃ๐๐ ๐๐๐ ๐ ๐๐ ๐๐๐๐๐ ๐๐๐๐๐ . Now let us plugin the given above mass (1.96 g) and the calculated moles (0.0446) in the rearranged 1.96 ๐ ๐บ๐น๐ ๐๐ ๐๐๐๐๐๐ข๐๐๐ ๐๐๐ ๐ ๐๐ = 0.0446 ๐๐๐๐๐ = 44g/mole equation to calculate GFM or MM. 44 g/mole is the GFM or MM of CO2. Therefore, the answer is choice D. Hydrogen gas, H2(g), reduces hot iron oxide (MM = 232), to iron metal. 5. Fe3O4(s) + 4 H2 (g) ๏ฎ 3 Fe (s) + 4 H2O(g) How many moles of water are formed by passing dry H2 over 464 g of Fe3O4 until reduction is complete? A) 16 B) 2.0 C) 8.0 D) 4.0 E) 5.0 Explanation of the answer: To solve, mass-mole stoichiometry problem, the problem # 5, first we will convert the given grams (464g) of Fe3O4 to moles by dividing it with the gram formula mass (GFM) of 232 g/mole and then we will use the mole ratio given in the equation for water and Fe3O4 to calculate the moles of water formed ๐๐๐๐๐ ๐๐๐ ๐๐๐๐ ๐๐๐ ๐ ๐๐ Fe3O4๐ฟ ๐๐๐ ๐ ๐๐ ๐ ๐๐๐๐ ๐ฟ ๐๐๐๐ ๐๐๐๐ ๐ ๐๐๐๐๐ ๐๐ ๐๐๐๐๐ ๐ ๐๐๐๐ ๐๐ ๐ ๐๐๐๐ ๐ข๐ง ๐ญ๐ก๐ ๐๐ช๐ฎ๐๐ญ๐ข๐จ๐ง = 8.0 moles of water Answer 6. When 13.0 grams of acetylene, C2H2, is reacted, what mass of water, H2O, is produced? 2 C2H2(g) + 5 O2(g) ๏ฎ 4 CO2(g) + 2 H2O(l) A) 9.00 g B) 12.0 g C) 13.0 g D) 18.0 g E) 26.0 g Explanation of the answer: To solve, mass-mass stoichiometry problem, the problem # 5, first we will find the gram formula mass (GFM) for C2H2 and H2O. C2H2 = (12x2)+(1x2)=24+2=26g/mole H2O =(1x2)+(16x1)=2+16=18g/mole Now we will convert the 13.0 g of acetylene, C2H2, to moles and then use it along with the mole ratios given in the equation to solve the problem. 13.0 ๐ ๐๐ C2H2๐ = 1๐๐๐๐ ๐๐C2H2 ๐๐๐๐๐ข๐๐๐ 2 ๐๐๐๐๐ ๐๐ ๐ค๐๐ก๐๐ 18 ๐ ๐ ๐ 26 ๐ ๐๐C2H2 2 ๐๐๐๐ ๐๐ C2H2 in the equation 1 ๐๐๐๐ ๐๐ ๐ค๐๐ก๐๐ ๐๐๐๐ก๐๐๐๐ 9.00 g Answer
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