Acids and Bases Review Guide Answers 1. What are 3 properties of acids? What are 3 properties of bases? See notes…any are GOOD 2. What is the purpose of an indicator? Give an example. To identify a substance as an acid or base. Ex: Phenolphthalein turns pink in a base, litmus paper changes color according to the type of substance (red is acid/blue is base) 3. What does a neutralization reaction produce? Acid + Base Salt + H2O 4. What is an Arrhenius acid? What is an Arrhenius base? Arrhenius acid – produces H+ ions when put in water Arrhenius base – produces OH- ions when put in water 5. Are the following acidic, basic, or neutral? a) pH = 4 acidic b) pOH = 9 acidic (pH = 5) c) pH = 10 basic d) pOH = 2 basic (pH = 12) 6. If the H+ concentration is 8.6 x 10-3 M, what is the pH of the solution? pH = - log [H+] pH = - log (8.6 x 10-3) pH = 2.1 7. If the [OH-] in a solution is 5.2 x 10-5 M, what is the pH? pOH = - log [OH-] pH + pOH = 14 -5 pOH = - log (5.2 x 10 ) pH + 4.284 = 14 pOH = 4.284 pH = 9.7 8. If the pH is 2.5, what is the [H+]? pH = - log [H+] 2.5 = - log [H+] 10-2.5 = [H+] [H+] = 3.2 X 10-3 M 9. If the pOH is 2.5, what is the [OH-]? pOH = - log [OH-] 2.5 = - log [OH-] 10-2.5 = [OH-] [OH-] = 3.2 X 10-3 M 10. If the OH concentration is 6.5 x 10-5 M, what is the [H+]? pOH = - log [OH-] pH + pOH = 14 pOH = - log (6.5 x 10-5) pH + 4.187 = 14 pOH = 4.187 pH = 9.813 pH = - log [H+] 9.813 = - log [H+] 10-9.813 = [H+] [H+] = 1.5 x 10-10 M 11. What are the strong acids? HCl, HBr, HI, HNO3, H2SO4, HClO3, HClO4 12. What are the strong bases? All the group 1A metal bonded to hydroxide Group 2A metal (from calcium down) bonded to hydroxide 13. What is the difference between strong acids/bases and weak acids/bases? Strong acids/bases complete dissociate into their ions and weak acids/bases only partially dissociate. 14. What is the purpose of a titration? To determine the volume or molarity of an acid or a base that is unknown. 15. It takes 12.8 mL of 0.25M NaOH to turn 22.0 mL of HCl pink. What is the molarity of the HCl? 1) NaOH + HCl NaCl + H2O 2) M 0.25 x mol => 0.0032 mol NaOH 0.0128 L 3) 0.0032 mol NaOH x 1 mol HCl = 0.0032 mol HCl 1 mol NaOH 4) M mol L mol L M 0.0032 = 0.15 M HCl 0.0220 16. A 25mL sample of H2SO4 was exactly neutralized by 32 mL of 1.3 M KOH. What is the molarity of the H2SO4? 1) H2SO4 + 2KOH 2H2O + K2SO4 2) M 3) 0.0416 mol KOH x 4) M mol L mol L 1.3 M x mol => 0.0416 mol KOH 0.032 L 1 mol H 2 SO4 = 0.0208 mol H2SO4 2 mol KOH 0.0208 = 0.83 M H2SO4 0.025 17. How much 2.0 M NaOH is necessary to exactly neutralize 30 mL of 1.8 M HNO3? 1) HNO3 + NaOH H2O + NaNO3 2) M mol L 1.8 x mol => 0.054 mol HNO3 0.03 L 3) 0.054 mol HNO3 x 4) M mol L 2.0 1 mol NaOH = 0.054 mol NaOH 1 mol HNO3 0.054 xL = 0.03 L NaOH 18. How much of 1.2 M H3PO4 is necessary to neutralize 34.0 mL of 0.8 M Ca(OH)2? 1) 2H3PO4 + 3Ca(OH)2 6H2O + Ca3(PO4)2 2) M 3) 0.0272 mol Ca(OH)2 x 4) M mol L mol L 0.8 1.2 x mol 0.034 L 2 mol H 3 PO4 3 mol Ca(OH) 2 = 0.0181 mol H3PO4 0.0181 = 0.02 L H3PO4 xL 19. What is a standard solution? The solution in a titration that you know the concentration and volume of. It is your “known” solution. 20. What is a binary acid and how can you identify one by its name? A binary acid is composed on ONLY 2 elements. You can identify it by name because it starts with the prefix, hydro 21. What is an oxyacid and how can you identify one by its name? An oxyacid is composed on 3 or more elements (one molecule is a polyatomic ion). By name it DOESN”T start with hydro. 22. If red litmus paper turns blue, is the substance an acid or base? Base 23. If blue litmus paper turns red, is the substance an acid or base? Acid 24. If blue litmus paper stays blue, and red stays red, what is the substance? Neutral Write out the formula or name for the following: 30. Carbonic acid__H2CO3____________ 25. HClO3__Chloric acid____________ 26. HBr__Hydrobromic acid_________ 31. Hydrobromic acid__HBr__________ 27. HNO2__Nitrous acid____________ 32. Dichromic acid____H2Cr2O7______ 28. H2SO3__Sulfous acid____________ 33. Hypoiodous acid___HIO_____________ 29. HI___Hydroiodic acid___________ 34. Bromous acid____HBrO2_________ 36. Hydrosufuric acid___H2S______ 35. Hydrochloric acid___HCl_________ 37. SAME QUESTION AS NUMBER 1 38. What is the pH scale used for? To determine how acidic and basic a solution is 39. Draw the pH scale and label where it is acidic, basic, and neutral. 7 0 Neutral Acidic 14 Basic 40. How many grams of NaOH must be dissolved in to a 2.0 L solution to make it have a concentration of 1.21M? M mol L 1.21 = 2.42𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 × 𝑚𝑜𝑙 1.21(2.0) = 𝑚𝑜𝑙 2.0 40.0𝑔 𝑁𝑎𝑂𝐻 1𝑚𝑜𝑙 𝑁𝑎𝑂𝐻 𝑚𝑜𝑙 = 2.42 = 96.8−→ 97𝑔 𝑁𝑎𝑂𝐻 41. What is the molality of a solution containing 58.4 g of NH3 dissolved in 658 g of solution? 58.4𝑔 𝑁𝐻3 × 𝑚= 1 𝑚𝑜𝑙 𝑁𝐻3 17𝑔 𝑁𝐻3 = 3.4353 𝑚𝑜𝑙 𝑁𝐻3 𝑚𝑜𝑙 3.4353 = = 5.2208−→ 5.22𝑚 𝑁𝐻3 𝑘𝑔 . 658 42. A gas mixture contains 42.84 g of steam (H2O), 3.58 g of hydrogen and 9.29 g of nitrogen. What is the mole fraction of steam? 42.84 𝑔 𝐻2 𝑂 × 1 𝑚𝑜𝑙 𝐻2 𝑂 18.0𝑔 𝐻2 𝑂 3.58 g H2 × 1 mol H2 9.29 𝑔 𝑁2 × 1 𝑚𝑜𝑙 𝑁2 2.0 g H2 28 𝑔 𝑁2 = 2.38 𝑚𝑜𝑙 𝐻2 𝑂 2.38 + 1.79 + .33179 = 4.50179 = 1.79 mol H2 𝑚𝑜𝑙𝑒 𝑓𝑟𝑎𝑐𝑡𝑖𝑜𝑛 = = .33179 𝑚𝑜𝑙 𝑁2 𝑚𝑜𝑙𝑒 𝑓𝑟𝑎𝑐𝑡𝑖𝑜𝑛 = 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 𝑡𝑜𝑡𝑎𝑙 𝑚𝑜𝑙𝑒𝑠 2.38 4.50179 𝑚𝑜𝑙𝑒 𝑓𝑟𝑎𝑐𝑡𝑖𝑜𝑛 = 0.529
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