C1 – The Developing Atomic Model What is our world made of?? What are mountains made of? What is water made of? Thinking about the world… • Is really hard Aluminum Foil 1. 2. 3. 4. Grab a piece of aluminum foil Tear it in half Tear it in half again Repeat until you cannot tear it anymore What do you have left? Balloon 1. Fill a balloon with a scent 2. Fill with air, and tie off end 3. Smell the balloon Can you smell the scent? How? Mass of Volleyball 1. 2. 3. 4. 5. Weigh the volleyball on the scale Record the mass Fill with air Record the mass Compare the two masses (deflated vs. inflated) What can you conclude about the air that was added to the balloon? Ice, Water, Steam 1. Turn on the hotplate 2. Place Ice cube onto hotplate 3. Observe the changes of state Has whatever makes up ice changed when it becomes water, then again to steam Ancient Greek Philosophers • The ancient Greek philosophers wondered why matter behaves as it does • Performed thought experiments in their minds Leucippus 500 BCE • Was an atomist, believing the world consisted of two fundamental principles, atoms and void (empty space) • These atoms were indestructible and existed in infinite shapes and sizes Leucippus cont. • The atoms moved through out the void bouncing off one another • Occasionally they became “hooked” on one another to form cluster • These clusters of different atoms are what is responsible for visible matter Empedocles 450 BCE • All matter is composed of the four ultimate elements • Fire • Air • Water • Earth • Combine to produce all known structures Empedocles cont. • Identified the ultimate elements as indestructible and unchangeable • Stated nothing new comes into being: all changes are attributed to rearrangement of element within matter • Believed to be the TRUTH for 2000 years Democritus 400 BCE • Tiny particles existed (atomos) that could not be broken down further • Material matched the shape of the atom • Iron atoms; solid and strong with hooks to lock them • Water atoms; smooth and slippery • Air atoms; light and whirling Democritus cont. • Each atom was visibly different with regard to shape, size, and arrangement • Connections between atoms were explained by mechanical linkages • Hook and eyes • Balls and sockets Alchemy 500-1600 AD • First people to perform experimentation • Practiced throughout the old world by people who were part • • • • Philosopher Mystic Magician Chemist Alchemy cont. 1. Attempted to change base metals in gold • Discovered new elements and properties by accident 2. Investigated the preparation of the “elixir of life” 3. Attempted to develop a “universal solvent” 4. Developed the technique of distillation Antoine- Laurent de Lavoisier • Discovered that, although matter may change its form or shape, its mass always remain the same • Identified 23 elements; pure substance that cannot broken down into simpler substances Antoine- Laurent de Lavoisier cont. • Element - pure substance that cannot be chemically broken down into simpler substances • Identified 23 elements. He based his investigations on careful measurement and observations of designed experimentation • How does this differ from alchemy? • Recognized mixtures exist and identified air as a mixture of oxygen and some other gas In a group of 4… • Try to brainstorm a “model” that explain what everything around us is made of… • Some ideas to think about • How is pure gold different/same than plastic • How is ice different/same than water Atoms • Smallest particle of any type of matter • All matter is made of atoms • Building blocks • Different atoms exist for each element • Gold, Silver, Copper John Dalton • English chemist (early 1800) • Atom is a solid, indivisible, indestructible sphere • Atoms are the smallest unit that exist • All atoms have similar characteristics Dalton’s Billiard Ball Model Dalton’s “billiard ball” model 1. All elements are composed of atoms. Atoms are indivisible and indestructible particles 2. Atoms of the same element are exactly alike. They all have the same mass and chemically behave the same way 3. Each element is characterized by the mass of its atoms. Different elements have atoms that differ in mass and chemical properties from the atom of every other element. Atoms of different element are different 1. The joining of atoms of two or more elements forms compounds 2. Atoms are neither created nor destroyed in a chemical change J.J. Thomson • A British Physicist began experimenting with a Crookes Tube • When a magnet was brought nearby the tube; the beam would move • He made a significant conclusion… J.J. Thomson • Presence of very light negative particle called electrons • disproved Dalton’s theory that the atom was indivisible “Plum Pudding” Thomson’s “plum pudding” model 1. Electrons have small mass and a negative charge 2. An atom is a sphere of positive electricity 3. Negative electrons are embedded in the positive sphere, so that the resulting atom has a neutral charge Earnest Rutherford • Tested Thomson’s model using gold foil and alpha particle radiation • Shooting a “laser” beam through gold foil to a detector • While the majority the laser beam passed through the gold foil, a small amount was blocked. • What conclusion can you draw from his observation • Rutherford proposed the presence of a dense positively charged core called nucleus Rutherford’s “Nuclear” model 1. Nucleus is a very tiny, dense, and positively charged core of an atom 2. All of the atom’s positively charged particles, called protons, are contained in the nucleus 3. The nucleus is surrounded by mostly empty spaces 4. Rapidly moving, negatively charged electrons are scattered outside the nucleus around the atom’s edge in what is referred to as an electron cloud Niels Bohr • Proposed a theory of the hydrogen atom (the most simple of all atoms) consisting of one heavy proton in the center with one lighter electron in orbit around the proton Bohr’s “planetary model” 1. Electron move around the nucleus in nearly circular paths called orbits 2. Each electron in an orbit has a definite amount of energy. Electrons can move within these energy levels without loss of energy 3. The further the electron is from the nucleus, the greater it energy 1. Electrons cannot exist between these orbits, unless energy is added 2. Each orbit is located at a certain distance from the nucleus 3. Electrons are stable when they are at lower energy level, closer to the nucleus Dalton’s Model Thompson’s Model Rutherford’s Model Bohr Model? Bohr’s Model Search for the Atom History of the Atomic Model Quantum Model of the Atom • Electrons do not move about the atom’s nucleus in a definite path like planets around the Sun • It is impossible to determine the exact location of an electron • The probable location of an electron is based on it energy • Energy levels are divided into four sublevels, and each sublevel is made up of several pairs of electrons called orbitals • The quantum model of the atom show how electrons move randomly in electron clouds called orbital Assignment • Write a short letter pretending to be Thomson, Rutherford, or Bohr to an earlier scientist explaining how you revised their atomic model and what you discovered. Give reference to the experiment that lead to your discovery. • J.J. Thomson writing to John Dalton • Earnest Rutherford writing to J.J. Thomson • Niels Bohr writing to Earnest Rutherford What are we learning today? • John Dalton • Model • J.J. Thompson • Model, Experiment • Earnest Rutherford • Model, Experiment • Niels Bohr • Model Periodic table of the elements Atoms & Elements What do we know about the atom or any elements? Atom • Building blocks of matter • Smallest unit of an element • properties of the element • Electrically neutral Just How Small is an Atom? How Small? Very Small Nucleus • Core of the atom • Consists of • neutrons • protons • Mass of an atom Subatomic particles • Atom is composed of particles that are smaller than the atom • Electron • Proton • Neutron Neutron • No electrical charge • 1 Mass Unit Proton • Positive electrical charge • 1 Mass Unit • Each element has a different number of protons Electron • Negative electrical charge • Located in the outer shell • Size too small to be currently measured • Mass of 1/1837 Mass Unit Review Subatomic Particle Symbol and Charge Mass Location Proton P+ 1 amu Nucleus Neutron N 1 amu Nucleus Electron E- 1/1837 amu Electron shell Periodic table of the elements Overview of the atom Static Electricity Demo • Electroscope • Glass Rod • Fur
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