F eature A rticle Evaporative Cooling in Linear Paul T raps by Lohrasp S e if y a n d Robert T hompson ooling trapped ions is essential to high-precision studies in many fields including atomic and molecular spectroscopy[1], quantum informa tion [2], quantum computing[3], time standards[4] and antimatter physics[5,6]. Different temperature regimes are required for different fields and are attained by a range of methods, which include but are not limited to laser cooling[7], sympathetic cooling[8] and evaporative cool ing. This computational study explored the possibility of evaporative cooling of an ensemble of ions trapped in a Linear Paul Trap (LPT), and optimized its effectiveness by maximizing the temperature drop per particle evaporated. interact and equilibrate to achieve a typical Maxwell Boltzmann energy distribution such as that shown in Fig. 1, and ii) one of the highest energy particles must escape so that the average energy is lowered after the evaporation. As the temperature of the system is reduced, the evaporation events Calgary, AB T2N 1N4 become less frequent and the cooling rate is reduced. To counter this effect, the trap depth can be reduced to allow particles to continue escaping at similar rates and hence, for the system to reach lower temperatures. An example simulation where eva porative cooling is applied to a system to reduce its temperature is shown in Fig. 2. EVAPORATIVE COOLING LINEAR PAUL TRAPS By applying evaporative cooling to trapped neutral particles, the Bose-Einstein condensate state[9] was achieved for the first time. Later, applying the same cooling method was one of the key components in allowing the production and trapping of anti-hydrogen by the ALPHA group[10]. Evaporative cooling does not require any additional tools such as lasers, and so it is a non-invasive cooling method that can be applied to any type of trap without any extra cost. Linear Paul Traps (LPT) are widely used in many areas of physics such as mass spectrometry[11] and contain particles by electric quadrupole fields that have an oscillating saddle shape in the radial direction and a harmonic potential well in the axial direction. These oscillating fields and the ion-ion interactions cause the system to be non-conservative and can increase the energy of the system over time. Any cooling method applied to the trapped ensemble is required to compete with this heating and over come it. in the case of evaporative cooling, the system requires time to re equilibrate for the evaporations to reduce the average energy of the system. However, the longer the system is allowed to interact and equilibrate, the more the heating will take over. Therefore, there is a delicate balance C Evaporative cooling can be illustrated by the example of the cooling of hot coffee. Even when the temperature of the coffee is below its boiling point, there are particles that have high enough energy to overcome the surface tension of the liquid and evaporate. These particles have an energy higher than that of the average particle in the fluid. Hence, when they leave and the system is allowed to re-equilibrate, the average energy and temperature of the coffee will be reduced. in the case of a trapped ion ensemble, particles require suffcient energy to overcome the trapping potentials to evaporate. However, for evaporation to cool the system, two conditions must be met: i) The system needs to Summary Computational studies are used to demon strate and quantify the effectiveness of evaporative cooling of ions contained in a linear paul trap. Lohrasp Seify <lseify@ucalgary. ca > Fig. 1 The energy distribution of a sample ensemble before and after evaporative cooling. On the left, the particle(s) with the highest energy which are shown by the arrow have enough energy to evaporate. In the middle, the particles have escaped the trap, however the system has not re-equilibrated yet. On the right, the system after it re-equilibrates is shown. The new energy distribution will have a lower mean and so the temperature of the system is reduced. and Dr. Robert Thompson <rthompso@ ucalgary.ca > Department of Physics and Astronomy, University of Calgary, Calgary, AB T2N 1N4 La P hysique au Canada / Vol. 71, No. 3 (2015 ) · 147 E vaporative Cooling in L inear Paul T raps (S eify/T hompson) 0_ 5000 10 000 15 000 20 000 25 000 Radial Potential Reduction Rate Fig. 2 Temperature as particles are evaporated. After a drop in temperature due to the expansion of the system, as particles evaporate and leave the system, the temperature is further reduced to the point where the system reaches temperature of less than 20 K. Fig. 3 Temperature drop per particle as RPRR is varied for q = 0.64 and a = 5.95 x 10-3 . There is a clear increase at RPRR : 10000 s-1 . When the value of RPRR is too low, the system has too much time to interact, and so heating takes over, lowering the temperature lost per particle. As RPRR gets too large, particles are allowed to escape the system no matter their energy, and so evaporations might heat the ensemble. between how long the system is allowed to interact with itself, and the rate of evaporation. To be able to model the trap computationally, parameters a and q are defined [12], such that UD^C a/ — X2 (1) q- ^ (2) where Ω is the oscillation frequency of the fields, and UDC and UAC are the applied DC and AC potentials respectively that create the trapping fields. These parameters would control the trapping potential amplitudes and hence, could be reduced to allow for evaporations to occur even when the temperature of the system is lowered. in a lab setting, the values of the a and q parameters can be reduced by reducing the applied voltage responsible for creating the trapping fields. Hence, the rate of this reduction can be modeled by parameters RPRR and APRR which represent the Radial potential Reduction Rate and Axial potential Reduction Rate respectively. To allow the system to equilibrate, the potential amplitude follows a stepwise function where the potential is dropped and then kept constant to allow for the system to equilibrate with itself. shapes such as spherical, cigar shaped, or cylinder shaped systems and different interaction rates. From there, different RPRR and APRR parameters were randomly picked using a Monte-Carlo script. Then, simulations were run to evolve the system using these values and the temperature and the number of particles lost during the simulations were recorded at the end of each run. By keeping the initial trapping parameters a0 and q0 constant, and varying the RPRR and APRR, the optimum cooling parameters were determined. An example of such a run can be seen in Fig. 3, where a system of 256 particles at 900 K were modeled and a maximum in temperature drop per particle can be seen when the RPRR : 10000 s -1 for q = 0.64 and a = 5.95 x 10-3 . This would indicate that if the cooling parameters are set correctly, the temperature of the ensemble can be reduced by 850 K (almost 95% of the initial temperature) after only 20 particles evaporated (less than 10% of initial particles). This suggests that if tuned correctly, any study that makes use of LPT s can greatly reduce the temperature of the trapped system by sacrificing a very small portion of their sample, and allow for more precise experiments to be designed and performed. RESULTS This computational study was conducted by running simula tions that model and solve equations of motion of a trapped ensemble of ions inside an LPT using the RK4 integrating method. parameters a and q were picked systematically to represent different trapped systems with different general 148 · Physics in Canada / V ol. 71, No. 3 (2015) ACKNOWLEDGEMENTS The author would like to thank Dr. Michael Wieser for his support, Dr. Michael Cummings for providing the base code, WestGrid for providing the computation time and NSERC for providing the financial support. Evaporative C ooling in L inear Paul T raps (Seify/T hompson) REFERENCES 1. C.J. Campbell et al., “Multiply charged thorium crystals for nuclear laser spectroscopy”, Phys. 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