Teacher Notes – Flame Test Lab Preparation: Prepare 0.5 M stock solution of NaCl, KCl, LiCl, BaCl2, CuCl2, SrCl2, CaCl2 Select at least one of the solutions to prepare double the amount of stock. Label this solution(s) “Unknown”. *This test can be done using cotton Q-tips also. Heat the Q-tip until no color is imparted to the flame. Recommend to the students that they try sodium last as it can overwhelm the other colors. Wet the tip in water before dipping in the salt. Then introduce it to the flame. Pre lab Exercise: 1. Why do we expect different metals to produce different color flames when burned? Explanation of the Bohr model – different elements have did stable orbits around their nuclei, this results in different wavelengths when electrons fall from higher energy orbits to lower energy orbits. 2. The metal ions being tested are Na+, K+, Li+, Ba2+, Cu2+, Sr2+, and Ca2+. How many electrons are in each ion? Na – 10; K – 18; Li – 2; Ba – 2; Cu – 27; Sr – 36; Ca - 18 3. Classify the following processes as physical or chemical changes: a. Dissolving the ionic compounds in water physical b. Flame testing the solutions chemical DATA TABLE Metal Flame Color Na Yellow K Pale purple Li Carmine red Ba Pale green Cu Green www.njctl.org Chemistry Atomic Structure Sr Crimson red Ca Brick red/red orange Unknown Analysis Questions 1. What is the identity of the metal in the unknown? Various 2. Estimate the wavelength for each of the tested metal ions. Calculate the approximate energy being emitted by each. Na – about 3.4 x 10-19 J; K – about 5 x 10-19J; Li – about 3 x 10-19 J; Ba – about 3.5 x 1019 J; Cu – about 3.8 x 10-19 J; Sr – about 2.8 x 10-19 J; Ca – about 3.2 x 10-19 J 3. Some commercially available fireplace logs burn with a red and/or green flame. On the basis of your data, what elements could be responsible for these colored flames? Red – lithium; strontium; and calcium Green – Barium; copper 4. Aerial fireworks contain gunpowder and chemicals that produce colors. What elements would you include to produce the following colors? a. Crimson red Strontium b. Yellow Sodium www.njctl.org Chemistry Atomic Structure
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