JOURNAL OF PETROLOGY VOLUME 37 NUMBER 3 B\GES 583-607 1996 W. P. MEURER* AND A. E. BOUDREAU DEPARTMENT OF GEOLOGY, DUKE UNIVERSITY, BOX 90227, DURJ1AM, NC 27708-0227, USA Petrology and Mineral Compositions of the Middle Banded Series of the Stillwater Complex, Montana The two olivine-beating zones of the Middle Banded series of (1974), McCallum et al. (1980), Segerstrom & the Stillwater Complex are characterized by an increase in the Carlson (1982) and Raedeke & McCallum (1984). number of cumulus minerals with height In each, anorthosite The Stillwater Complex is one of the most intenand anorthositic troctolite dominate the lower part whereas oli- sively studied layered intrusions in the world. Much vine gabbro and gabbronorite form much of the upper portions. of this interest results from the occurrence of a Electron microprobe analyses of cumulus minerals indicate little variety of magmatic ore deposits in the lower third of or no variation of average mineral compositions with height. In the complex (including Pt and Pd deposits, Cu—Ni addition, no significant lateral variations in cumulus mineral sulfides and chrome ore). compositions occur along 8 km of section. Plagioclase from The igneous stratigraphy of the Stillwater throughout these zones shows the complex, reverse and oscillatoryComplex can be divided into three series (Fig. 2): (1) zpnation patterns also seen in plagioclasefrom the thick ( >500 the Basal series, which includes mafic dikes and m) anorthosites that sandwich the zones. The data suggest that gabbroic rocks that make up the lowermost 100 m of the entire Middle Banded series is genetically related and the complex (Zientek et al., 1985); (2) the Ultramafic therefore requires models for the origin of the thick anorthosites series, composed of olivine, olivine-orthopyroxene to also explain the olivine-bearing rocks between them. However, and orthopyroxene cumulates with cumulus textural features such as discordant troctolites, pegmatoids, chromite present locally (Raedeke & McCallum, slump structures and variably developed mineral laminations, 1984); (3) the Banded series, which is composed of and chemical features such as zpnation in clinopyroxene pro- rocks with cumulus plagioclase and is subdivided duced by intergranular exchange with orthopyroxene and large into the Lower, Middle and Upper Banded series. within-sample variations in the mg-number of olivine in lowAlthough there is general agreement about the three olivine troctolites, indicate that significant modification of these major series divisions, subdivisions within the rocks by postcumulus processes has taken place, thereby obscurBanded series are not standardized. In this paper we ing evidence of their genesis. use the stratigraphic nomenclature of McCallum et al. (1980). The Lower Banded series has received KEY WORDS: Stillwater Complex; Middle Banded series; layered inconsiderable attention from geologists because it trusions; mineral chemistry; postcumulus processes hosts an economically significant platiniferous horizon known as the J-M Reef. Olivine is present in the Lower Banded series associated with the J - M INTRODUCTION Reef in Olivine-Bearing zone I and again just below The Stillwater Complex is a layered ultramafic to the base of the Middle Banded series after being mafic pluton of Late Archean age located in absent throughout most of the upper part of the southwest Montana (Fig. 1). The complex is exposed Ultramafic series and the lower part of the Lower for ~ 4 8 km along strike with an exposed thickness of Banded series (Fig. 2). The Middle Banded series is >6-5 km (Page & Zientek, 1985). Results of large- the main subject of this paper and is discussed in scale mapping of the complex have been reported by detail below. The Upper Banded series contains a Hess (1960), Jackson (1961), Page & Nokleberg relatively thin olivine-bearing zone that is overlain 'Corresponding author. Telephone: (919) 681-8169. Rix (919) 684-5833. e-mail: [email protected] edu © Oxford Univenity Press 1996 JOURNAL OF PETROLOGY VOLUME 37 NUMBER 3 JUNE 1996 | | || Pifcmolc Cover G^ibroic - (LBS. UBS) Anocthoritk - (MBS) Ultnmaflc - (UMS) USGS topographic base Contour Interval 250 ft Fig. 1. General location map with detail map of the Banded series. Locationj of the Picket Pin Mountain (PPM), Eastern Contact Mountain (ECM), Central Contact Mountain (CCM) and Western Contact Mountain (WCM) sections, in the Middle Banded series, are indicated on the detailed topographic map. The Camp Lake section ij located on the southwest corner of Camp Lake. throughout both zones. Despite the relatively constant average An content, individual grains are often complexly zoned over 10% mole fraction An, and variations of up to 20% are found within a standard thin-section. In comparison with the thick anorthosites, relatively little work has been done on OB-III and OBIV. McCallum et al. (1980) measured a stratigraphic section through OB-III and OB-IV in the Contact Mountain area. Foose (1985) mapped a portion of the Contact Mountain area including OB-III and OB-IV, at 1:5000. This map provides a sense of the lateral continuity of the units but does not express the small-scale complexities present in OB-III and OB-IV. The Middle Banded series differs from the Lower Banded series and Upper Banded series in several by a thick plagioclase-orthopyroxene—augite cumulate. The Middle Banded series contains two thick anorthosite zones, AN-I and AN-II, that sandwich two olivine-bearing zones, OB-III and OB-IV (Fig. 2). The thick anorthosites have been described by Hess (1960), McCallum et al. (1980), Scheidle (1983), Salpas et al. (1983, 1984), Salpas (1985), Czamanske & Bohlen (1990), Boudreau & McCallum (1992), Haskin & Salpas (1992) and Loferski & Arculus (1993). In summary, AN-I and AN-II are very similar both chemically and texturally. They both contain an average of 90% plagioclase by volume, have plagioclase grains up to three times more coarse grained than plagioclase in most other rocks in the complex, and have an average An content of 78 that remains approximately constant 584 MIDDLE BANDED SERIES, STILLWATER COMPLEX the mg-number [Mg/(Mg + Fe)] of cumulus mafic minerals with height in the Lower Banded series and Upper Banded series, but no such trends have been discerned in the Middle Banded series. To characterize and understand the internal complexities of OB-III and OB-IV, the relationships between the two thick anorthosites and OB-III and OB-IV, and the relationship between the Middle Banded series and the rest of the Stillwater Complex, we have undertaken a detailed study of the olivine-bearing zones of the Middle Banded series. | MEURER AND BOUDREAU Meters Gabbronorile-lll 6000- 4000- Banded series 5000- Middle Banded series o. Olivinc-bcaring V V Anorthositc II (AN-II) Olivine-bearing IV (OB-IV) Olivine-besring III (OB-III) GEOLOGY AND STRATIGRAPHY OF THE MIDDLE BANDED SERIES Anorthosite I (AN-I) Lower Banded series Olivinc-bcanng II / 3000- Gabbronoritc II Nome II Terminology and petrography N Olivinc-beanng I \ Gabbrooonle I Norite I 2000- 1000- o- Ultramafic senes Bronzitite zone Peridotitc zone Basal scries Fig. 2. Subdivisions of the Stillwater Complex used in thii paper and their approximate thicknejies [after McCallum et al. (1980)]. The nomenclature for cumulus rocks has been a source of confusion and controversy (Irvine, 1982). A system for naming cumulates on the basis of their cumulus mineralogy is inherently a genetic classification but provides valuable information about the rock modes and texture. In this paper we follow the lead of McCallum et al. (1980) and name cumulates based on their cumulus mineralogy (Table 1), ignoring the cumulus mineral proportions in applying rock names. Determining whether or not a mineral is a cumulus phase can be complicated by a number of factors (McBirney & Noyes, 1979). We have ignored chemical considerations and characterize minerals as cumulus or postcumulus on the basis of grain morphology. Cumulus minerals (1) are assumed to be primocrysts (i.e. thefirstminerals to crystallize), (2) are equant and usually euhedral-subhedral, (3) typically have at least one boundary in common with another grain of the same mineral (not always true for olivine in plagioclase-rich troctolites), and (4) are found throughout the rock. Postcumulus minerals (1) are anhedral and commonly subpoikilitic or poikilitic, (2) occur interstitial to ways. In both the Lower Banded series and Upper Banded series clinopyroxene appears after orthopyroxene in the stratigraphic sequence of cumulus minerals, whereas the sequence is clinopyroxene followed by orthopyroxene in the Middle Banded series. The mineral proportions in the Lower Banded series and Upper Banded series are approximately equal to those predicted for cotectic crystallization; Table 1: Cumulus mineralogy and rock names in contrast, the Middle Banded series contains on average 82% plagioclase by volume, well in excess of Cumulus mineral(s) Rock type the cotectic abundance of 60% (McCallum et al., 1980). Much of this plagioclase is concentrated in Plagioclase AnorthositB AN-I and AN-II and in anorthosites and olivine- Plagioclase + olivine Troctoltte poor troctolites in the lower portions of OB-III and Plagloclase+dinopyroxene Gabbfo OB-IV. Gabbros with approximately cotectic Plagioctasa+cllnopyroxene + oSvine Olivine gabfaro cumulus mineral proportions occur in the upper Plagioclase+orthopyroxene+clinopyroxene Gaboronorite portions OB-III and OB-IV. There is a systematic Plagioclase+orthopyroxene+clinopyroxene + olivine Olrvinegabbronorite decrease of both the An content of plagioclase and 585 JOURNAL OF PETROLOGY VOLUME 37 cumulus minerals, and (3) make up < 15-20% of the mode (in most instances much less). Based on these criteria, plagioclase and olivine occur as cumulus grains, quartz, apatite and ilmenite are postcumulus minerals, and clinopyroxene and orthopyroxene may be texturally of either type. Cumulus plagioclase occurs throughout OB-III and OB-IV and has an average maximum dimension that ranges from 3 to 15 mm. The habit of the plagioclase varies from blocky, nearly equant crystals to tabular, book-shaped crystals. In general, the higher the proportion of plagioclase in a rock, the larger the grain size and the more equant its crystal habit. The most notable exceptions to this general rule occur in thin (< 1—2 m) anorthositic layers located in sections dominated by more mafic rocks. Plagioclase found in rocks with 25-40% mafic minerals are typically 5-8 mm in the long dimension and tabular in habit. Rocks that are highly laminated contain plagioclase with the highest aspect ratios (Meurer, 1995). Cumulus plagioclase grains are almost always free of inclusions, although polymineralic inclusions of clinopyroxene—ilmenite—apatite are found in a few grains in ~30% of the samples examined. Loferski & Arculus (1993) reported that this type of inclusion is also found throughout the two thick anorthosites that sandwich OB-III and OB-IV. These inclusions have not been reported for rocks outside of the Middle Banded series. Olivine is the second most abundant cumulus mineral in OB-III and OB-IV. In layered rocks it generally occurs as 5—10 mm, subhedral, equant crystals. In discordant bodies, where the olivine is often much larger (>20 mm) it is 'ameboidal' in shape and often contains inclusions of rounded plagioclase. Throughout much of the section, the olivine abundance is relatively low (<10%). Thin layers that contain as much as 60-70% olivine occur sporadically throughout OB-III and OB-IV, but these layers cannot be correlated between sections and most persist for <50 m along strike. Olivine grains are generally partially altered along fractures to a fine-grained mixture of magnetite and a serpentinegroup mineral. This alteration rarely makes up >30 vol % of most grains. In some locations olivine is completely altered to medium-grained tremolite and talc mixture surrounded by fined-grained chlorite. The talc—tremolite—chlorite alteration assemblage represents a higher-temperature alteration than does the magnetite—serpentine alteration (Page, 1976). Samples in which the olivine is converted to talctremolite-chlorite are referred to as pervasively altered to distinguish them from the much more common magnetite-serpentine alteration. Both orthopyroxene and clinopyroxene occur as NUMBER 3 JUNE 1996 cumulus grains in the Middle Banded series. Clinopyroxene joins the cumulus assemblage before orthopyroxene, and occurs throughout most of OBIII but only in the upper half of OB-IV. Cumulus orthopyroxene is restricted to the upper 100 m of OB-III, and occurs only in the highest stratigraphic levels of OB-IV but is not present everywhere along strike in OB-IV. Postcumulus clinopyroxene and orthopyroxene occur throughout OB-III and OB-IV and are far more abundant than cumulus pyroxenes. Although coarse exsolution is present in some pyroxene grains, the majority of both cumulus and postcumulus pyroxene grains contain only fine-scale exsolution. Some inverted pigeonite is found as intercumulus grains in the anorthositic sections of OB-IV but the majority of the low-Ca pyroxene in OB-III and OB-IV crystallized as orthopyroxene. Field petrography and stratigraphy Methods Three complete stratigraphic sections through OBIII and OB-IV and a portion of a fourth were measured and sampled in the Contact Mountain and Picket Pin Mountain areas (Fig. 3). These sections are named, from east to west, (1) Picket Pin Mountain section, (2) Camp Lake section, (3) Eastern Contact Mountain section and (4) Western Contact Mountain section. The Camp Lake section is a partial section covering only the upper 75 m of OB-III and the lower 50 m of OB-IV. In addition to these sections, the measured section presented by McCallum et al. (1980) and Raedeke (1982) was studied and sampled. This section is referred to as the Central Contact Mountain section. The locations of the stratigraphic sections are shown in Fig. 1. The Eastern Contact Mountain section is the most complete overall but the Picket Pin Mountain section provides the most complete coverage of the upper portion of OB-IV. The lower portion of the Western Contact Mountain section is well exposed, but much of OB-IV in this section is not exposed. Exposure of the Central Contact Mountain section is generally good, although portions are covered and other portions contain fault repetition. OB-III and OB-IV were studied by dividing individual sections into layers that were used to construct stratigraphic columns. The sections were measured using a tape and compass. Samples were taken as close to the center-line of the section as possible, but 100-150 m on either side of each section were studied. Three criteria were used to define the layers used in constructing the stratigraphic columns: (1) layers must be laterally persistent for the entire width of the section studied (i.e. 586 MEURER AND BOUDREAU 90 70 50 30 MIDDLE BANDED SERIES, STILLWATER COMPLEX 10 onhopyroxene 900 m - clinopyroxene olivine plagioclase 90 70 50 30 10 700 m - 700 m - 700 m - 500 m - 500 m - 500 m - 300 m - 300 m - I 300 m - m 100 m - 100 m - 100 m - 90 70 50 30 10 •A Picket Pin Mountain Section 90 70 50 30 10 10 Western Contact Mountain Section Eastern Contact Mountain Section Fig. 3. Stratigraphic columni for Western Contact Mountain (WCM), Eaitem Contact Mountain (ECM) and Picket Pin Mountain (PPM) lections. Columni indicate the variation in relative proportion! of cumulus mineraU with height. Tick marks on the left side of the column indicate sample locations. Letters indicate locatiom of distinctive stratigraphic horizons: A, wispy-layered troctolite; B, homogeneous troctolite; C, disrupted zone; D, plagioclase clots; E, foliated zone; F, mafic layer, G, pervasively altered troctolite; H, AN-I.5; I,fine-scalelayering; J, Hesi' eggs; K, discordant troctolites. 200-300 m along strike); (2) layers must be at least half a meter thick to be depicted in the stratigraphic section; (3) layers can be either texturally or mineralogically distinct from the adjacent layers. To establish the extent of lateral continuity between the sections measured, marker units and layers were chosen that are easily correlated from section to section. In every section studied there are portions where exposure is poor, and these are described as 'covered'. Covered intervals may include portions of the stratigraphy used as marker units. A marker layer is described as 'not exposed' when it is anticipated to occur in a portion of the stratigraphy that is covered. A marker layer is 'absent' when the appro- priate stratigraphic interval is exposed but the marker layer is missing. Olivine-Bearingzpru 111—petrography Wispy-layered and homogeneous troctolite. T h e base of OB-III is marked by two texturally distinctive and continuous troctolite layers. It is sharp but irregular and is denned by the first appearance of cumulus olivine above AN-I. In the lower troctolite layer, the olivine occurs in wispy, discontinuous layers and is termed the 'wispy-layered troctolite'. These olivine layers are no more than 2 cm in thickness and generally continue for <2~3 m along strike. They are 587 JOURNAL OF PETROLOGY VOLUME 37 similar in appearance to cross-bedded sedimentary rocks [also noted by Foose (1985) and McCallum et al. (1985)]. The wispy-layered troctolite is overlain by a 'homogeneous troctolite', which contains ^ 20% homogeneously distributed olivine. The contact between these two layers is sharp and easily recognized. The homogeneous troctolite is laminated, but the wispy-layered troctolite is not. The thickness of these two layers varies considerably along strike. In the Western Contact Mountain section the combined thickness of these layers is ~ 100 m, but thins to ~ 2 5 m at the Eastern Contact Mountain section. The upper contact of the homogeneous troctolite is sharp and regular but locally it is cut by discordant troctolites. Disrupted zone. Above the homogeneous troctolite clinopyroxene joins the cumulus assemblage within a zone of extensive layer disruption and discordant troctolites termed the 'disrupted zone'. The disrupted zone is 15 m thick at Western Contact Mountain, thickens to 30 m at Central Contact Mountain, but is absent at the Eastern Contact Mountain section. As noted above, the base of the disrupted zone is both sharp and regular; however, folding and stretching of layers becomes pronounced within 3 m above the top of the homogeneous troctolite [see McCallum et al. (1980), fig. 4b]. Abundant blocks of anorthosite are present in the disrupted zone. These blocks range in size from ~ 10 cm to nearly 1 m in long dimension and the mineral lamination in the host rock wraps around them. Small (1 m), discordant troctolites composed of 2530% ameboidal olivine and plagioclase are common in the disrupted zone. Discordant troctolites cut across the lamination of the host cumulates but also finger out laterally, parallel to the layering. Discordant bodies composed predominantly of anorthosite that have an outer zone of troctolite are also found in the disrupted zone. NUMBER 3 JUNE 1996 Opx Fig. 4. Thin-section sketch of plagioclase clot. [Note the blocky habit of the plagioclase in the clot (lower left) and how the tabular plagioclase of the host-rock wraps around the clot.] foliation defined by the lamination of platy minerals termed the 'foliated zone'. The plagioclase clots are present throughout most of the foliated zone but occur only sporadically below this zone. Cumulus orthopyroxene occurs locally immediately below the foliated zone but is prevalent in this zone. The plagioclase clots, cumulus orthopyroxene and strong foliation make the rocks of the foliated zone unique Plagioclase clots. Approximately 250 m above the in appearance, and it is readily identified in all strabase of OB-III, polycrystalline aggregates of plagio- tigraphic sections. Other features of the foliated zone clase, 15—35 cm in long dimension, give the olivine include the presence of fractures lined with horngabbro a distinct appearance. These 'plagioclase blende, plagioclase—quartz dikelets with hornblende clots' are often flattened in the plane of the mineral selvages, hornblende-bearing pegmatoids and myrlamination and the plagioclase in the clots is blocky, mekitic lenses. The top of the foliated zone is defined unlike the very tabular habit of the host rock plagi- by a pair of texturally distinct layers. The lower of oclase which wraps around the clots (Fig. 4). Most of the two is three to four times coarser grained than the clots examined are monomineralic, although one other cumulates of OB-III and is termed the 'coarsecontains interstitial quartz. The plagioclase clots grained layer'. The upper layer has ^ 8 0 % orthooccur over a stratigraphic interval of 75-100 m in all pyroxene + clinopyroxene and is called the 'mafic sections studied, are relatively uniform in size and layer'. The coarse-grained layer is a gabbronorite are homogeneously distributed within a given except at the Western Contact Mountain section where it is a olivine gabbronorite. An orthopyroutcrop but vary in abundance with height. Foliated zone and mafic layer. The plagioclase clots oxene-rich layer 2 cm thick is present half a meter first occur 30-50 m below a zone with a strong from the top of the coarse-grained layer and has a 588 MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX minimum lateral persistence of >2 - 5 km. The mafic layer marks the last occurrence of (1) cumulus orthopyroxene in OB-III, (2) plagioclase clots and (3) the well-developed foliation that defines the foliated zone. gabbro host. The lower portions of these bodies are pipe like but they become concordant with irregular lower contacts at the base of AN-II. The troctolite bodies (1) are composed of 10-15% ameboidal olivine, (2) may be zoned, containing up to 15% clinopyroxene at their outer margins, compared with 30—40% clinopyroxene in the host, and may have Olivine-Bearing zone IV—-petrography cores of anorthosite, and (3) are not continuous Pervasively altered troctolite and AN-I.5. The base of OB-along strike. IV is defined by a 100-125 m thick anorthosite termed 'AN-I.5'. As the name implies, this layer is Stratigraphy ofOlivine-Bearing zone III and Olivinevery similar to AN-I and AN-II both texturally and Bearing zone IV chemically (see below). Like the thicker anorthosites, AN-I.5 is three to four times coarser grained than An idealized stratigraphic section through OB-III most other rocks in OB-III and OB-IV and lacks and OB-IV is shown in Fig. 5. Much of the lower discernible mineral lamination. It is underlain by a portion of the idealized section is adopted from the troctolite that contains pervasively altered olivine. Eastern Contact Mountain section; this is reflected This type of alteration is observed in the discordant in the high abundance of anorthosite. The disrupted troctolites immediately below AN-I in OB-II (Hess, zone is a local feature and is therefore omitted from the section. Whereas the lower portions of OB-III in 1960) and AN-II in OB-IV but is otherwise rare. the Eastern Contact Mountain and Western Contact Fine-scale layering. The top of AN-I.5 is defined by the first appearance of cumulus olivine above the Mountain sections differ, the upper portions of OBbase of OB-IV. The next 100-150 m of section are III in all measured sections are similar. The composed of alternating anorthositic and troctolitic thickness of AN-I.5 differs slightly between the layers with troctolitic layers becoming more Eastern Contact Mountain and Western Contact dominant up-section. Three to five meters below the Mountain sections; however, the continuity of the level where abundant clinopyroxene joins the exposure at the Eastern Contact Mountain section is cumulus assemblage, there is a texturally distinctive better, so the Eastern Contact Mountain thickness is zone composed of fine-scale layering of clinopyrox- used in the idealized section. The upper half of OBene i olivine in a plagioclase-rich matrix. This zone IV is not continuously exposed at any of the sections. has been noted in the Western Contact Mountain, The upper part of OB-IV in the idealized section is Central Contact Mountain and Picket Pin Mountain based on a judicious mixture of observations from sections, but is not exposed at the Eastern Contact the measured sections, examination of float in Mountain section. In some locations a single layer covered areas, and on the section presented for may be defined by both olivine and clinopyroxene Central Contact Mountain by McCallum et al. (the two minerals do not occur together—they (1980). Cumulus orthopyroxene is present near the alternate along strike for sections of the layer). top of OB-IV at Central Contact Mountain but is Olivine layers are thinner than clinopyroxene layers not present at the top of OB-IV at Picket Pin Mountain. We have opted to include the cumulus (0-75 cm vs 2 cm) and contain less plagioclase. orthopyroxene in the idealized section to emphasize Mess's Eggs. Most of the uppermost 50 m of OB-IV is composed of olivine gabbro. Just above the fine- the similar progression of rock types observed in OBscale layering is a zone that contains unusual bimi- III and OB-IV. neralic aggregates of olivine and plagioclase that Hess (1960) described as egg shaped and are here termed 'Hess's Eggs'. Hess's Eggs are ovoid in cross- MINERAL CHEMISTRY section with olivine in the lower half of the egg and plagioclase in the upper half. This texture is present Methods in the Western Contact Mountain and Central Mineral compositions were determined using the Contact Mountain sections but is not exposed in the JEOL 733 Superprobe at the University of Eastern Contact Mountain section and is poorly Washington. Operating conditions for clinodefined, if present at all, at the Picket Pin Mountain pyroxene, orthopyroxene and olivine were 15 kV section. and 25 nA with a beam diameter of 10 fim. OperDiscordant troctolite. Discordant troctolites found 0—ating conditions for plagioclase were similar except a 5 m below the base of AN-II are irregularly shaped 20 fim beam diameter was used. Natural minerals bodies that cross-cut the lamination in the olivine were used as standards and the raw data were 589 JOURNAL OF PETROLOGY Height above AN-I Foliation VOLUME 37 NUMBER 3 JUNE 1996 Textures Proportions of cumulus minerals discordant Iroctolites Hess's Eggs fine-scale layering orthopyroxene clinopyroxene olivine plagioclase AN-I.5 pervasively altered Foliated Zone plagioclase clots -Homogeneous troclolite Wispy layered troctolite Fig. 5. Idealized stratigraphic section through OB-III and OB-IV showing variation in cumulus modes. The locations of distinctive textural features are included. Rose diagrams of crystal orientations and associated alignment factors (0, completely random; 100, perfectly aligned) are provided to give a sense of the mineral lamination in the cumulates (Meurer, 1995). reduced using an on-line Bence-Albee (Bence & Albee, 1968) correction scheme. All mineral compositions determined in this study were compiled by Meurer (1995). Plagioclase More than 3000 microprobe analyses of plagioclase were collected from over 100 samples from OB-III and OB-IV. Representative analyses are presented in Table 2. Cumulus plagioclase occurs throughout the Middle Banded series and so potentially provides the best means of assessing igneous processes. Analyses were performed to characterize compositional variability from the scale of single grains, single thin-sections, outcrops and the entire thickness of the zones. The data are discussed in order of increasing scale (i.e. from zonation of grains to variations with stratigraphic height). Compositional contour maps of 14 plagioclase grains that range in maximum dimension from < 1 to 14 mm in length were constructed using spot analyses checked against optical zonation. The grains were contoured for weight percent FeO and KQO and mole percent An. Most grains are concentrically zoned although incomplete zones are common near the margins. Zonation patterns of FeO and K2O content are inversely correlated, with FeO generally increasing toward the margin. Variations in FeO are only loosely correlated with An content, but K2O generally varies inversely with An content. The smallest variation in An content observed in a mapped grain is four (from 74 to 78) and the largest variation is 14 (from 64 to 78). Most grains have a range in An of 10. Figure 6 shows a grain contoured for An content and wt% K2O that has a reversely zoned core, oscillatory zonation in the middle, and patchy and incomplete zonation near the margin. Of the grains that showed concentric zonation about 40% are normally zoned and 60% are reversely 590 Table 2: Selected electron microprobe analyses qfplagioclase Sample Type Section Height* SiO2 AlaOj FeO CaO Na2O K2O Sumt Si Al Fe Ca Na K Sumt An 92-M143I PBAc ECM 303 49-76 31-88 0-30 16-37 2-62 0-16 10008 2-271 1-715 0012 0-752 0-232 0009 4-992 76-4 92-M147 PAOc ECM 316 4906 31-64 0-47 15-52 2-73 0-10 99-51 2-258 1-717 0-018 0-766 0-244 0006 5008 76-8 92-Ml 57 PAOc ECM 613 49-57 32-30 0-45 1506 2-80 009 100-26 2-259 1-735 0017 0-736 0-248 0005 5000 74-8 92-M161 POc ECM 518 49-11 31-80 049 15-14 2-82 0-10 99-45 2-259 1-725 0019 0-747 0-252 0006 5-007 74-8 92-M117 PAOc ECM 154 48-97 31-57 0-41 15-63 2-71 008 99-35 2258 1-716 0016 0-772 0-242 0-005 5008 76-2 92-M116 Pc ECM 144 49-89 31-49 0-33 15-37 2-91 009 10008 2-279 1-696 0013 0-753 0-258 0005 5004 74-5 91-M5 Pc ECM 66 49-19 32-39 0-40 15-56 2-73 003 100-30 2-245 1-742 0015 0-761 0-242 0002 5006 75-9 91-M3 POc ECM 20 48-16 32-19 0-44 16-20 2-34 008 99-41 2-223 1-752 0017 0-801 0-209 0005 5008 79-3 92-M99A POc PPM 556 48-99 31-86 0-41 15-62 2-64 009 99-59 2-252 1-727 0-016 0-769 0-236 0006 5005 76-5 92-M85I PBAc PPM 303 49-77 31-51 0-29 14-77 2-99 0-19 99-51 2-284 1-704 0011 0-726 0-266 0011 5003 73-2 92-M77 PAOc PPM 216 48-76 32-30 0-39 15-89 2-35 0-10 99-78 2238 1-747 0O15 0-781 0-209 0006 4-997 78-9 92-M74 PAOc PPM 209 48-81 32-25 0-43 1603 2-37 009 99-98 2-237 1-742 0017 0-787 0-211 0005 5000 78-9 92-M70 PAOc PPM 192 48-78 32-54 0-45 15-76 2-54 008 100-13 2-232 1-755 0017 0-772 0-226 0005 5006 77-4 92-M2535 PBAc CCM 257 49-29 31-55 0-34 15-45 2-65 0-18 99-44 2-268 1-711 0013 0-761 0-237 0010 5000 76-3 91-M49 PBAOc CCM 333 48-20 32-30 0-38 15-84 2-33 008 99-13 2-228 1-759 0015 0-784 0-209 0005 5000 790 91-M42 POc CCM 632 49-43 3203 0-52 15-86 2-65 006 100-56 2-253 1-721 0020 0-775 0-235 0004 5006 76-8 91-M36 PAOc CCM 805 48-76 32-86 0-94 14-84 2-69 0-11 100-20 2-229 1-771 0036 0-727 0-238 0006 5008 76-3 91-M18 PAc CCM 363 48-87 31-64 0-38 15-81 2-58 on 99-39 2-253 1-720 0-015 0-781 0-231 0006 5006 77-2 91-M9 PBAc CCM 298 49-31 31-39 0-37 15-14 2-77 0-15 99-13 2-275 1-707 0014 0-748 0-248 0009 5000 75-1 91-M50 Pc WCM 403 48-55 3205 0-43 16-47 2-23 007 99-80 2-232 1-737 0017 0-811 0-199 0004 5000 80-3 91-M51 POc WCM 391 49-51 31-77 0-37 15-71 2-58 007 10001 2-265 1-713 0014 0-770 0-229 0004 4-995 77-1 91-M53 PBAc WCM 298 48-48 32-11 0-42 15-48 2-51 0-12 99-12 2-240 1-748 0016 0-766 0-225 0007 5002 77-3 91-M58 PAOc WCM 249 47-53 3304 0-57 17-27 1-77 004 100-22 2-183 1-788 0022 0-850 0-158 0002 5003 84-4 91-M63 POc WCM 93 49-45 31-85 0-41 15-56 2-74 0-10 100-11 2-261 1-717 0016 0-762 0-243 0006 6006 76-8 'Above base of OB-MI. tSum of oxide weight percents. tSum of cations normalized to 8 oxygens. SMafic layer. WCM, Western Contact Mountain; CCM, Central Contact Mountain; ECM, Eastern Contact Mountain; PPM, Picket Pin Mountain. PC, anorthosite; POc, troctolite; PAc, gabbro; PAOc, olivine gabbro; PBAc, gabbronorite. JOURNAL OF PETROLOGY VOLUME 37 NUMBER 3 JUNE 1996 0 nun An Hi 7 7 -79 ^ B 75 -77 I I 73 -75 ^^u 71 -73 1 169 -71 1 1 67-69 | ' ' 1 65-67 -65 • « Fig. 6. Contour maps of An content and weight percent K3O in a plagioclase grain from sample 92-M150 (an olivine gabbro from OBIII). Locations of microprobe analyses are indicated by the black dots. Contours are drawn to be consistent with both compositional data and optical zonation. Inset figure shows relationship of the mapped grain to surrounding grains. zoned. Many grains have high-An, incomplete outer zones. These high-An rims are observed on both normally and reversely zoned grains. Scheidle (1983) and Czamanske & Scheidle (1985) reported on the compositional variability of plagioclase grains from both AN-I and AN-II. Many of the features they reported are observed in the plagioclase throughout OB-III and OB-IV. These include (1) normal, reverse, oscillatory and irregular zonation, (2) high-An rims, (3) incomplete outer zones, (4) truncated zones (as if by grain breakage), and (5) variability of zonation types within a single thin-section (e.g. normally and reversely zoned grains are found in the same thin-section). Czamanske & Scheidle (1985) noted that where plagioclase is in contact with quartz incomplete zones with lower An content are present, suggesting continued growth of the plagioclase from trapped liquid. In one grain we mapped that is in contact with quartz the relations are not as straightforward. Figure 7 shows that the zone in contact with the quartz is nearly complete, but additional incomplete zones with higher An are present on the other side of the grain. The plagioclase that makes up the monomineralic clots in OB-III and the plagioclase from the rocks that host these clots were analyzed to determine if they are compositionally distinct. We found that the average An and K2O contents of the plagioclase clots are indistinguishable from those of the host rocks. However, the plagioclase in the clots does have an average of 0-1 wt% more FeO than that in the host rock (which typically contain 0-3-035 wt% FeO). Mapping of plagioclase grains in the clots shows complex and variable zonation and high-An rims to be present. The variation of the average An content of plagioclase in an outcrop is small compared with withinsample variation. Figure 8 depicts the variation of An with stratigraphic height for a continuously exposed portion of the Western Contact Mountain 592 MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX An SO s<x<80 76£x<78 74<x<76 72<x<74 <72 5 mm Fig. 7. Contour maps of the An content and weight percent K 2 O and FeO in a plagiodase grain from sample 92-M159 (an anorthoiite from AN-I.5 at the base of O B - I V ) . Locations of microprobe analyses are indicated by the blade dots. Contours are drawn to be consistent with both compositional data and optical zonation. Inset figure shows relationship of the mapped grain to surrounding grains. 325- —© 225 .'•>£• » ^ > —I— •«» —i— 75 An 80 85 90 Fig. 8. Detail of the variation of An content in plagiodase with height from the Western Contact Mountain section. Averages are indicated by large circles and individual analyses are represented by smaller squares. A detail from the stratigraphic section showing the cumulus mineral proportions is included. section in OB-III. Individual analyses are included in the plot to emphasize their large variability (An = 70—88) compared with the variability of the sample averages (An = 74-5—80). The average analyses cluster around 77, which is the average value of An for plagiodase in OB-III, and do not define a trend. 593 Figure 9 shows An content vs stratigraphic height for the Picket Pin Mountain, Eastern Contact Mountain, Central Contact Mountain and Western Contact Mountain sections. An content may decrease modestly with height through OB-III but no large-scale variation of An with height is found in OB-IV. A decreasing trend in OB-III is suggested by JOURNAL OF PETROLOGY 8OO-1 PPM AN-n AN-n • •• • OB-rv • • OB-ra o- CCM AN-II 81 OB-IV 9-: OB-ni 100 • • • 71 75 • oUvine — J " •• 400 • 1 ° 77 WCM OB-IV plagtoclue o 200- isd§ c • r. OB-III • • OB-IV •a f nafic layer -T»-l 800- ± • • 77 : . 600 400- 75 . FeO o KjO • • • AN-D • 300- e. ECM 1 • •3 JUNE 1996 NUMBER 3 OB-IV 700 r 300 •a VOLUME 37 • 400- 0.0 OB-UI 75 77 An 75 77 An Fig. 9. Plot of An content vs height for Picket Pin Mountain (PPM), Eastern Contact Mountain (ECM), Central Contact Mountain (CCM) and Western Contact Mountain (WCM) section!. Averages of approximately 15 analyses per sample are plotted. data from the Eastern Contact Mountain and Picket Pin Mountain sections. However, the wide scatter of average values of An at any given height and the normative whole-rock An contents (Meurer, 1995) argue against the presence of any clear stratigraphic trends. The range of average values of An from OBIII (~6 mol% An) is larger than that for OB-IV ( ~ 3 m o l % An). Lateral variations in plagioclase composition can be evaluated by comparing the average compositions from distinctive layers in each of the sections. Analyses of plagioclase from both the mafic layer and the coarse-grained layer at the Western Contact Mountain, Central Contact Mountain, Eastern Contact Mountain, Camp Lake and Picket Pin Mountain sections show modest variations along strike. Going from east to west, the An content of the coarse-grained layer is 75-3-75-0-76-1-P-76-0, and that of the mafic layer is 74-8-74-9-75-5-74-4/ 75-9—76-8. The plagioclase analyses from two samples from a single outcrop of the mafic layer in the Central Contact Mountain area differ by 1-5 mol % An. The variations within the layers are 1-1 and 2-0 for the coarse-grained and mafic layers, respectively, and are of the same order as the variation between these two samples and are not deemed significant. The K2O and FeO contents of plagioclase from 0.4 Weight % 0.6 Fig. 10. Weight percent K 2 O a n d F e O in plagioclase from the Eastern Contact M o u n t a i n section is plotted against stratigraphic height. T h e analyses of the sample from t h e mafic layer a r e connected to emphasize its distinctive trace-element composition. Variation of cumulus mineral proportions with height is also included. • n- 0.2 OB-III and OB-IV show no systematic vertical or lateral variations. However, plagioclases from the mafic layer have K 2 O and FeO contents that differ from those for other samples although the An content is similar. Figure 10 shows the variations of K 2 O and FeO in plagioclase from the Eastern Contact Mountain section. Plagioclase in the mafic layer has a distinctly higher K 2 O content and notably lower FeO content. Average plagioclase from OB-III and OB-IV has =$010 wt % K 2 O and ~0-46 wt % FeO. Plagioclase from the mafic layer from all sections has average K 2 O of 0-17 wt % and FeO of 0-35 wt%. Pyroxenes Over 850 microprobe analyses of clinopyroxene and over 300 analyses of orthopyroxene were collected (Tables 3 and 4 contain representative analyses), and these data are discussed in order of increasing scale. Five clinopyroxene grains with an average size of 15 mm2 were mapped using 60-100 analyses per grain. Three of these grains show no discernible zonation and none have significant postcumulus overgrowths characterized by lower mg-number values [Mg/(Mg +Fe)]. Two zoned grains show consistent increases in m^-number, wt % CaO and wt% TiO 2 from the core to the rim (e.g. Fig. 11). Projection of the clinopyroxene analyses used to construct Fig. 11 onto the graphical thermometer of 594 MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX Table 3: Selected electron microprobe analyses ofclinopyroxene Sample: 91-U46 92-M253* 92-M259* 92-M157 92-M146t 92-M143* 91-M25 92-M204 91-M51 92-M99A Type: PAOc PBAc PBAc PAOc PBAc PBAc PAOc PAOc POc POc PAOc Section: CCM CCM CL ECM ECM ECM ECM WCM WCM PPM PPM Height* 385 357 627 301 303 138 290 391 557 198 52-74 52-44 51 37 52-71 52 18 52-24 5208 51-43 5292 0-43 0-32 0-80 0-32 0-35 0-51 0-49 0-51 0-35 1-72 1-92 1 -71 208 206 1-73 0-15 0-10 0-08 0-13 0-18 643 SI0 2 TiO 2 51-85 52-58 0-78 0-41 92-M70 AI2O3 2-26 1-63 1-69 1-78 2-05 Cr2O3 008 0-11 0-11 0-13 009 0-13 FeO 723 6-95 704 8-54 7-45 608 6-73 5-92 7-35 6-20 0-21 0-17 0-18 0-18 0-20 16-88 1606 15 87 15-63 16-35 MnO 0-19 0-19 0-19 0-21 0 19 0-18 MgO 15-37 1701 17-19 17-62 15-24 16-18 NiO 004 004 001 003 004 002 0 05 006 003 004 0-06 22 38 21-09 2286 21-69 22-71 21-80 CaO 22-42 2086 20-76 18-58 21-92 Na2O 0-13 007 007 001 009 0-14 0-26 009 0-39 007 001 99-22 99-82 99-82 99-70 100-22 98-94 99-99 SumS Si 100-35 99-81 100-20 99-62 1 918 1-941 1-939 1-940 1-922 1-946 1-929 1-934 0 012 0009 0-010 0014 1-926 1-923 1-949 Ti 0022 0011 0023 0009 0-014 0014 0-010 Al 0099 0071 0073 0078 0091 0075 0-084 0075 0091 0090 0O75 Cr 0002 0-003 0003 0004 0003 0004 0-004 0003 0002 0004 0-005 0-264 0-233 0-188 0-208 0-183 0-227 0-194 0-198 Fe 0-224 0-215 0-217 Mn 0006 0006 0006 0006 0006 0005 0007 0005 0006 0006 0006 Mg 0-848 0-936 0-942 0-972 0-850 0-891 0-931 0-887 0-876 0-871 0898 Ni 0001 0001 0000 0001 0001 0000 0-002 0002 0001 0001 0-002 0-885 0-836 0-907 0-860 0-910 0860 Ca 0-888 0-825 0-818 0-737 0-879 Na 0003 0003 0000 0002 0003 0001 0004 0004 0002 0003 0-004 Sumll 4001 4003 4001 4003 4001 3-995 4002 4006 3-995 4008 3-996 Wo 45-3 41-8 41-4 37 3 44-8 45-1 42-3 45-9 43-8 46-1 440 En 43-3 47-4 47-7 493 43-3 45-4 47-1 44-9 44-6 44-1 45-9 Fs 11-4 10-9 110 13-4 11-9 96 10-5 9-3 11-6 98 10-1 mg-no. 79-1 81-4 81-3 78-6 78-5 82-6 81-7 82-9 79-4 81-8 81-9 'Mafic layer. tCoarse-grained layer. tAbove base of OB-III. §Sum of oxide weight percents. MSum of cations normalized to 6 oxygens. WCM, Western Contact Mountain; CCM, Central Contact Mountain; ECM, Eastern Contact Mountain; PPM, Picket Pin Mountain. POc, troctolite; PAOc, olivine gabbro; PBAc, gabbronorite. Lindsley & Anderson (1983) indicates that minimum crystallization temperatures for core compositions are between 1000 and 1100°C but rim compositions yield submagmatic temperatures between 600 and 800°C. No systematic variation of /rig-number in clinopyroxene with height is found in either OB-III or OB-IV (Fig. 12). Cumulus clinopyroxene is absent throughout much of OB-IV, and therefore it is not meaningful to evaluate large-scale compositional variations of clinopyroxene in OB-IV. The average values of the mg-number from each stratigraphic 595 section in OB-III range from 80-5 to 81-5, and average values for OB-IV range from 79-0 to 81-5. Analysis of intercumulus clinopyroxene in three samples from Eastern Contact Mountain shows them to have substantially lower average m^-number values (average 74) than the cumulus clinopyroxene (average 81). Meurer & Boudreau (1993) reported on the lack of variation with height of trace elements (e.g. TiO2, A12O3, Cr2O3> NiO, Na2O) in cumulus clinopyroxene. Their data are primarily from the Central Contact Mountain section; however, additional data from Western Contact Mountain, JOURNAL OF PETROLOGY VOLUME 37 JUNE 1996 NUMBER 3 Table 4: Selected electron microprobe analyses qforthopyroxene Sample: 91-M93 92-M85' 92-M83 92-M26OT 92-M146t 92-M143* 92-M142 91-M36 92-M253* 92-M214 Type: POc PBAc PBAc PBAc PBAc PBAc PBAOc PAOc PBAc PAOc PAOc Section: PPM PPM PPM CL ECM ECM ECM CCM CCM WCM WCM Height* 539 303 294 301 303 284 806 257 316 276 92-M203 SiO2 54-52 54-79 54-20 53-89 53-86 55-12 54-49 53-61 54-64 54-18 54-35 TiO 2 0-24 0-21 0-25 0-28 0-39 0-26 0-21 0-29 0-20 0-24 0-23 AI 2 O 3 0-92 0-90 102 0-99 1-00 0-89 1-12 0-91 0-83 104 0-99 Cr 2 O 3 FeO 005 007 007 005 0-05 0-07 007 004 007 007 0-07 13-99 13-76 13-62 15-80 16-76 14-59 14-45 16-23 14-42 14-20 15-17 MnO 0-29 0-26 0-32 0-36 0-33 0-31 0-31 0-27 0-33 0-31 0-30 MgO 27-99 28-39 28-17 26-55 26-37 28-26 27-55 27-22 2835 26-92 27-70 NiO 006 003 004 007 0-04 0-05 006 003 005 003 004 CaO 1-69 1-58 1-60 1-41 1-52 0-99 1-92 1-13 0-96 2-22 1 -31 Na2O 001 001 001 001 001 001 001 000 001 001 001 SumS 99-72 99-96 99-25 99-38 100-29 100-51 100-14 99-73 99-82 99-18 100-14 Si 1-963 1-965 1-958 1-963 1-954 1-969 1-959 1-950 1-966 1-967 1-958 Tl 0006 0-006 0007 0008 0011 0007 0006 0008 0005 0006 0006 Al 0039 0038 0044 0-043 0043 0-038 0048 0039 0036 0045 0-042 Cr 0001 0002 0002 0001 0-0O1 0-O02 0002 0-001 0002 0-002 0002 Fe 0-421 0-413 0-411 0-482 0-508 0-436 0-434 0-494 0-434 0-431 0-457 Mn 0009 0008 0010 0011 0-010 0010 0010 0008 0010 0010 0009 Mg 1-503 1-518 1-518 1-442 1-426 1-505 1-477 1-477 1-621 1-457 1-488 Ni 0002 0001 0001 0002 0001 0-001 0002 0001 0001 0001 0-001 Ca 0065 0061 0062 0055 0059 0-038 0074 0044 0037 0086 0-051 Na 0004 0-002 0002 0005 0-002 0003 0-0O4 0002 0003 0002 0002 Sumll 4004 4002 4004 3-999 4-005 3-997 4004 4015 4-002 3-995 4006 Wo 3-3 3-1 3-1 2-8 30 1-9 3-7 2-2 1-9 4-4 25 En 75-5 76-2 76-2 72-9 71-5 76-1 74-4 73-3 76-3 73-8 74-6 Fs 21-2 20-7 20-7 243 25-5 220 21-9 24-5 21-8 21-8 22-9 mg-x\o. 78-1 78-6 78-7 750 73-7 77-5 77-3 74-9 77-8 77-2 76-5 'Mafic layer. tCourse-grained layer. tAbove base of OB-III. §Sum of oxide weight percents. llSum of cations normalized to 6 oxygens. WCM, Western Contact Mountain; CCM, Central Contact Mountain; ECM, Eastern Contact Mountain; PPM, Picket Pin Mountain. POc, troctolite; PAOc, olivine gabbro; PBAc, gabbronorite. Eastern Contact Mountain and Picket Pin Mountain also indicate little or no variation. Along-strike variation of average m£-number values in cumulus clinopyroxene is assessed using analyses from marker layers. Values of m^-number in the mafic layer going from east to west (i.e. Picket Pin Mountain—Camp Lake—Eastern Contact Mountain-Central Contact Mountain-Western Contact Mountain) are 82-881-5-828-82-4-810, giving a total range of 1-8, which is not significantly more than the range expected based on the average of the standard 596 deviation from individual analyses of ±0-84 for mgnumber values in clinopyroxene. The coarse-grained layer has the similar limited variability in mgnumber along strike (from east to west: 79-6— 79-5— 78-7-P-77-8). Cumulus orthopyroxene occurs only over a short interval in both OB-III (20-25 m) and OB-IV (<10 m), although postcumulus orthopyroxene is ubiquitous in both OB-III and OB-IV. Within-grain variability of cumulus orthopyroxene is small (~0'5 m£-number) and mapping of three cumulus MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX AN-II PPM ECM • 600- • OB-IV 400" OB-IV 200" oB-m OB-ni • • 0- 76 AN-II m • m D 80 84 72 78 CCM 80 8- WCM OB-IV OB-rv 300" OB-III • • j .•" J. OB-III • . 20072 78 80 mj-no. in cpx 84 72 76 80 mg-no. in cpx 84 Fig. 12. Plot of m^-number in clinopyroxene vs height for Picket Pin Mountain (PPM), Eastern Contact Mountain (ECM), Central Contact Mountain (CCM) and Western Contact Mountain (WCM) sections. Averages of approximately nine analyses Fig. 11. Contour maps of the mg-number and weight percent CaO per sample are plotted. and TiOj in a dinopyroxene grain from lample 92-M142 (an olivine gabbronorite from the foliated zone in OB-III). Locations of microprobe analyses are indicated by the black dots. Contours magmatic and reflect intergranular exchange as disare drawn to be consistent with compositional data; no optical cussed below. zonation is observed. Inset figure shows relationship of the mapped grain to surrounding grains. Olivine Olivine is found throughout OB-III and OB-IV grains indicates that they are not zoned. Post- except in AN-I.5. Representative analyses of the cumulus orthopyroxene m^-number values vary from >200 olivine analyses are presented in Table 5. 72-0 to 78-5 whereas those for cumulus orthopyr- Average mg-number values from OB-III range from oxene range from 73-5 to 79-5. Values of mg-number 69 to 76 whereas those from OB-IV show conin the mafic layer, going from east to west, are 78-7— siderable variability ranging from 64 to 75 (Fig. 14). 77-8-77-7-78-5-78-4, giving a total range of only Olivine from near the base and top of OB-III have 1-0. The coarse-grained layer has a slightly larger lower average m^-number values and larger withinrange in m^-number along strike, again from east to sample variability (range in m£-number values is west: 76-5-75-2-74-2-?-74-2. The average standard five) than do other samples from OB-III (range in deviation of mg-number in orthopyroxene is ± 0-64, mg-number values <2). The lower average mgwhich is more than the variability seen in the mafic number values may reflect postcumulus equilibration layer and only slightly less than that in the coarse- with trapped liquid. This effect should be more siggrained layer. Thus lateral variability in m^-number nificant for rocks with low mafic mineral contents in clino- and orthopyroxene is deemed minimal. (Barnes, 1986), as is the case for these samples. Projection of pyroxene compositions onto the graOlivine from the Middle Banded series typically phical thermometer of Lindsley & Anderson (1983) contains <005 wt% CaO and Cr2O3. The only shows that the bulk of the clinopyroxene composi- trace elements present in significant amounts are tions are consistent with equilibration at tempera- NiO and MnO, which are negatively correlated in tures between 700 and 900°C and orthopyroxene most samples. The NiO content remains essentially compositions give similar or slightly lower tempera- constant in the lower half of OB-III and then tures (Fig. 13). These temperatures are too low to be declines modestly in the upper half as depicted in 597 JOURNAL OF PETROLOGY VOLUME 37 Wo NUMBER JUNE 1996 Wo _ , . ^ , . . , T . . . Fs Fig. 13. Clinopyroxene and orthopyroxene compositions for all analyses projected onto the Wo—En—F» ternary (wollastonite—enstatiteferrosilite). The compositional fields for clinopyroxene and orthopyroxene from individual sections, defined in the ternary plots, are shown on the pyroxene quadrilateral contoured for temperature (Iindsley & Anderson, 1983). Fig. 14 but no stratigraphic trends are found in OBIV. 800- olivinc —- ^M ^^^J ^^^^1 * 600" 1 ° p o o DISCUSSION a D ° o° plagiociasc i * 400- 200- o PPM OB -'V 1 * WCM «=!« — • % J o- o o 1 a ECM c^ o ^^^^B 66 8 • a A AAA _ a a 71 76 mg-no. 0.1 0.3 NiO Fig. 14. Compoiite plot of mj-number and NiO in olivine vs height for Picket Pin Mountain (PPM), Eaitem Contact Mountain (ECM), Centra] Contact Mountain (CCM) and Western Contact Mountain (WCM) sectioni. Averages of approximately seven analyies per sample are plotted. 598 Before the cumulus and postcumulus processes that resulted in the textures and compositions preserved in OB-III and OB-IV can be understood, an adequate description of the vertical and lateral variations in these units is required. This study is primarily directed at characterizing these units and assessing the vertical and lateral variations. However, preliminary interpretations of the data arc useful as a means of directing and stimulating discussion and investigation of some of the proposed processes. In the following sections we consider the origin of some of the textural and chemical features observed in these zones. The discussion is organized in terms of increasing size of the features (i.e. from thin-section scale to the scale of the entire Middle Banded series). The treatment of individual features is not meant to be exhaustive; rather, we present preliminary interpretations that are consistent with our data and the results of previous work. 37-97 37-38 350 385 356 ECM ECM ECM CCM CCM CCM WCM WCM POc PAOc POc PAOc PAOc PBAOc PAOc PBAOc POc PAOc 91-M3II 92-M125 92-M162 92-M157 91-M37 91-M16 91-M46 91-M54 91-M62 92-M196 93 297 37-86 38-30 37-82 38-30 37-99 627 808 37-66 38-66 37-50 36-63 38-36 38-71 37-86 32-38 37 02 36-89 34-11 37-69 38-18 38-87 MgO 22-94 21-53 22-95 25-26 23-47 22-39 24-87 3001 24-43 24-57 28-55 23-30 22-89 22-32 FeO 0-26 0-28 0-21 0-27 0-18 0-20 0-19 0-21 0-26 0-36 0-26 0-27 0-27 0-29 NiO 0-30 0-29 0-27 0-33 0-28 0-35 0-33 0-46 030 0-31 0-35 0-30 0-33 0-29 MnO 99 02 9906 98-31 100-46 100-11 99-94 101-25 99-50 99-92 10006 100-30 99-39 99-70 99-78 Sumt 0-999 1003 0-995 0-998 0-990 0-998 0-989 0-993 0-998 0-998 0-992 0-997 0-997 0-993 1-483 1-510 1-488 1-436 1-497 1-504 1-469 1-315 1-453 1-448 1-363 1-481 1-492 1-514 Mg 0-506 0-472 0-511 0-555 0-514 0-488 0-541 0-684 0-538 0-541 0-640 0-513 0-502 0-488 Fe 0006 0006 0005 0006 0004 0004 0004 0005 0006 0008 0006 0006 0006 0006 Nl 0-007 0006 0006 0007 0006 0008 0007 0011 0007 0007 0008 0007 0007 0007 Mn 3001 2-997 3005 3002 3010 3002 3011 3007 3002 3002 3008 3003 3007 3003 Sum* 74-5 76-2 74-4 72-1 74-5 75-5 73-1 65-8 730 72-8 68-1 74-3 75-6 74-8 mg-no. "Above base of OB-III. tSum of oxide weight percents. tSum of cations normalized to 4 oxygens. § Wispy-layered troctoiite. IlHomogeneous troctoiite. WCM, Western Contact Mountain; CCM, Central Contact Mountain; ECM, Eastern Contact Mountain; PPM, Picket Pin Mountain. POc, troctoiite; PAOc, olivine gabbro; PBAOc, olivine gabbronorite. WCM ECM 36-45 37-91 37-93 3703 493 253 20 5 37-83 ECM POc 661 PPM PAOc 3803 91-M2S 3801 325 92-M101 PPM 210 PAOc PPM PAOc SiO2 92-M89 Height* 92-M75 Section Typo Sample Table 5: Selected electron microprobe analyses of olivine bd d d1 tw JOURNAL OF PETROLOGY VOLUME 37 NUMBER 3 JUNE 1996 thereby lowering the plagioclase liquidus temperature. Although some of the high-An partial rims may Plagioclase habit have formed by partial dissolution, the concentric The habit of the plagioclase varies from blocky and nature of other high-An partial rims (such as equant in plagioclase-rich layers to tabular in layers depicted in Fig. 7) suggests they did not form as a with 20% or more mafic minerals. The upper consequence of selective dissolution (which would be portion of the Sept lies layered intrusion is char- localized at high stress contact points between acterized by zones with tabular, well-laminated grains). If the quartz depicted in Fig. 7 crystallized anorthosites in massive anorthosite with blocky pla- before the growth of the incomplete high-Anrimon gioclase. Higgins (1991) suggested that the well- the opposite side of the grain, then isolated pockets laminated anorthosites formed as a consequence of of liquid were crystallizing while interstitial liquid shearing within the boundary layer in which the was flowing through the cumulates. An alternative crystals were growing. A shear event that could explanation for the relations depicted in Fig. 7 is influence the shape of the crystals should also that the quartz was deposited by fluids that resorbed produce a lineation (e.g. Brothers, 1964; Benn & part of the plagioclase grain before precipitating the Allard, 1989). However, there is no significant quartz. We favor the former interpretation because lineation in either the laminated anorthosites from the compositional zone in contact with the quartz is the Sept lies layered intrusion or the rocks of OB-III also in contact with other plagioclase grains. Noneand OB-IV. theless, both models require that late-stage liquidBecause no lineation is observed, we favor an fluid flow through the cumulates be spatially alternative model that involves crystal growth restricted: in the former case to produce the high-An under uniaxial stress to explain the tabular vs rim opposite the quartz, and in the latter case to blocky habits of the plagioclase. If AN-I, AN-I.5 resorb part of the high-An rim and deposit the and AN-II formed by accumulation of plagioclase quartz. suspended in the magma column and not at the More dramatic evidence of the influence of latefloor of the chamber as has been proposed (e.g. stage liquids-fluids on rock textures and minerRaedeke, 1982), then the blocky habit of their pla- alogies is provided by the discordant troctolites and gioclase reflects growth under relatively isostatic pegmatites. The textures of the troctolites indicate stress conditions. Plagioclase with a tabular habit that they formed by metasomatic replacement of may have grown in a uniaxial stress field as might host olivine gabbro (McCallum et al., 1980; be expected in the (compacting) crystal pile. McBirney & Sonnenthal, 1990). The textures and Unfortunately, experimental studies of plagioclase relations of pegmatites from the foliated zone are like growth habits (e.g. Corrigan, 1982; Lofgren, 1983; those described by Braun et al. (1994) for pegmatites Kouchi et al., 1986) have not dealt with habits pro- below the J-M reef, interpreted to have formed by duced under uniaxial stress fields. In the absence of recrystallization of host cumulates by channelized definitive experimental results, we suggest that the fluid flow. habit of the plagioclase may provide insight into the relative stress field under which plagioclase grain Postcumulus reequilibration growth occurred. The subsolidus temperatures recorded by rims of the zoned clinopyroxene grains and coexisting orthoEvidence for late-stagefluid flow pyroxene reflect intergranular exchange between Several models have been proposed for the origin of clinopyroxene and orthopyroxene. During cooling, the high-An rims on cumulus plagioclase. Cza- exchange between ortho- and clinopyroxene manske & Scheidle (1985) suggested that high-An enriched the rims of the clinopyroxene in CaO at rims on plagioclase may be a product of pressure- the expense of MgO and FeO. The higher mginduced dissolution along grain margins that would number at therimin the clinopyroxene is consistent effectively concentrate the anorthite component. with this exchange because clinopyroxene has a Morse & Nolan (1984) described strongly reversed higher K]-, for Mg than does orthopyroxene [see zonation in cumulus plagioclase from the Kiglapait. Raedeke (1982)]. The distribution of these rims indicates that they formed from the last liquid to crystallize. Wager & Brown (1967) suggested that the reverse rims on Internal evolution of Olivine-Bearing plagioclase from the Bushveld formed when the zones HI and IV partial pressure of water increased in the magma The evolution of OB-III and OB-IV is discussed in Cumulus and postcumulus crystallization features 600 MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX order of increasing stratigraphic height from the base of OB-III to the top of OB-IV. However, this sequence may not represent the sequence of crystallization. As discussed below, there is evidence that the thicker anorthosites (AN-I.5 and AN-II) were crystallizing before some of the underlying cumulates. The sharp textural contrast between the wispylayered and homogeneous troctolites that mark the base of OB-III may reflect deposition under two different dynamic regimes. The segregation of olivine in the wispy-layered troctolite could have been produced by deposition from crystal-laden currents or by postcumulus slumping of the olivine—plagioclase mixture. We favor the former interpretation because of the regular nature of the texture, its widespread occurrence and the planar upper contact of this layer. Calculation of settling velocities shows that if the olivine crystals were even a tenth the size of the plagioclase crystals they could readily segregate during deposition because of their greater density contrast with the liquid (e.g. Irvine, 1980). In either case, the discontinuous nature of the olivine-rich layers in the wispy-layered troctolite is a consequence of deposition (or consolidation) in a relatively dynamic system. The homogeneous troctolite reflects accumulation and crystallization under more quiescent conditions. Field relations suggest that the disrupted zone was formed by slumping of partially consolidated layers. Anorthosite blocks of similar size are found at the same stratigraphic level in the disrupted zone and are consistent with the overstretching of an anorthositic layer as suggested by Foose (1985). However, other blocks are too widely scattered both laterally and vertically to be interpreted as disrupted anorthositic layers and suggest that portions of the section were jumbled during slumping, with fragments of anorthositic layers displaced both vertically and laterally. This process requires substantial transport of partially consolidated material. The change in thickness of this zone and the increase in layer disruption from Western Contact Mountain to Central Contact Mountain are consistent with slumping from the west toward the east. Discordant troctolites found in the disrupted zone are interpreted to have formed by reaction with infiltrating fluids as noted above [see Schiffries (1982) and Braun et al. (1994)]. The absence of discordant troctolites at the stratigraphically equivalent position at Eastern Contact Mountain suggests that slumping elsewhere may have been facilitated by volatile enrichment of the partially consolidated cumulates. There is no evidence for any large-scale physical 601 disruption of layering in OB-III above the disrupted zone or in OB-IV. The section between the disrupted zone and the first occurrence of plagioclase clots is predominantly anorthositic or troctolitic with olivine gabbro becoming increasingly abundant with height. Foose (1985) considered the origin of the plagioclase clots, and suggested three possible models: (1) the clots represent ripups of anorthositic layers formerly interlayered with the host rocks; (2) the clots are the remnants of fine-scale anorthositic layers that were disrupted by compaction of the cumulates; (3) the clots were initially megacrysts that were recrystallized to finer-grained aggregates during compaction. He ruled out the first explanation because the clots show no evidence of size sorting and because they are widespread whereas ripup events arc likely to be local. We find the second objection more compelling because plagioclase clots were probably close to neutrally buoyant so no size segregation should have occurred. There is no evidence that fine-scale layering ever existed in these rocks and so we agree with Foose in discounting the second model. Foose favored the third explanation, recrystallization of megacrysts, but our data do not support this model. The complex zonation observed in plagioclase from throughout the Middle Banded series is also observed in the plagioclase of the clots and there is no reason to expect recrystallization to generate complex zonation patterns. As an alternative to these models, we suggest that the clots were glomerocrysts formed during initial plagioclase nucleation and growth at the base of either AN-I.5 or AN-II and were carried down by plumes or density currents. Cumulus orthopyroxene occurs in the section just above the first occurrence of plagioclase clots (see Fig. 5), and abundant intercumulus orthopyroxene is associated with the plagioclase-clot-bearing layers just below the first cumulus orthopyroxene occurrence. Cotectic crystallization of significant amounts of orthopyroxene along with clinopyroxene and plagioclase might have caused the crystallizing layer to become gravitationally unstable and form density currents that carried the plagioclase clots to the floor. This model requires that crystallization of anorthosite be taking place above the floor of the magma chamber during the time needed to accumulate the 60—100 m thickness of cumulates that host the plagioclase clots. The lower boundary of the foliated zone lies 40 m above the lowest occurrence of plagioclase clots. The foliated zone is both texturally and mineralogically distinct and contains the only cumulus JOURNAL OF PETROLOGY VOLUME 37 orthopyroxene in OB-III. Despite the strong mineral lamination present in this zone, no lineation is observed to indicate alignment by flow, suggesting that the rock foliation developed by compaction. If compaction did occur, then the texture of the coarse-grained layer could owe its origin to recrystallization caused by liquids trapped below the mafic layer. The compositions of ortho- and clinopyroxene from the foliated zone and from the coarse-grained layer in particular support these conclusions. Figure 15 shows the variation of orthoand clinopyroxene m^-number values in the foliated zone. The wi^-number for the coarse-grained layer is significantly lower than that of the underlying layers. Lower m^-number values in the ortho- and clinopyroxene of the coarse-grained layer are consistent with its equilibrating with later intercumulus liquids, possibly those compacted out of underlying cumulates. Several features of the foliated zone provide evidence of liquid—fluid redistribution, including the following: fractures lined with hornblende, plagioclase-quartz dikelets with hornblende selvages, hornblende-bearing pegmatoids, and myrmekitic lenses. The mafic layer, which marks the upper limit of the foliated zone, is considerably more dense than the underlying cumulates (3-25 g/ cm3 vs 2-90 g/cm3), and could have provided the driving force for the compaction of the foliated zone. It also seems likely that fluids moving through the cumulates promoted recrystallization and thereby facilitated compaction. NUMBER 3 JUNE 1996 Evolution of the Middle Banded series Several features of OB-III and OB-IV suggest that these units are intimately related to AN-I and ANIL Whereas none of the observations, taken individually, unequivocally demonstrates that all of the zones in the Middle Banded series are related, collectively they provide a basis for reaching this conclusion. Features that tie the Middle Banded series together are as follows: (1) AN-I.5 is essentially the same in grain size, texture and composition as AN-I and AN-I I. The only occurrences of laterally extensive, pervasively altered troctolites are found beneath AN-I, AN-I.5 and AN-II. These features suggest that these three anorthosite horizons formed in a similar manner. (2) Complex plagioclase zonation patterns noted in AN-I and AN-II (Scheidle, 1983; Czamanske & Scheidle, 1985) are also observed in the plagioclase throughout OB-III and OB-IV. This includes normally zoned grains, reversely zoned grains, high-An rims and truncation of zonation patterns as if by grain breakage. (3) Polyphase inclusions composed of clinopyroxene, apatite and mangano-ilmenite are found throughout AN-I and AN-II, and OB-III and OBIV, but have not been identified in the Lower Banded series or Upper Banded series. Loferski & Arculus (1993) suggested that these inclusions indicate that the entire Middle Banded series crystallized from a highly polymerized magma in the The general sequence of rock types in OB-IV is Stillwater chamber. (4) Plagioclase compositions are nearly constant the same as in OB-III, and both may have crystallized in a similar manner. The lower portions of throughout the entire Middle Banded series. both OB-III and OB-IV are predominantly anor- Although this compositional feature is enigmatic, it thositic and troctolitic (Fig. 5). In each, olivine suggests that AN-I and AN-II, and OB-III and OBgabbro becomes increasingly abundant at the IV, are related by the process responsible for the expense of anorthosite with height. Near the top of constant An content. OB-III and locally at the top of OB-IV, cumulus (5) The Pb isotopic values for AN-I, OB-III and orthopyroxene joins the assemblage; and three- and AN-II show little variation (Wooden et al., 1991). four-phase cumulates make up the uppermost porIf the Middle Banded series is considered as one tions of these zones. The progression of cumulate types is consistent with increasing fractionation in unit, any model for the genesis of the thick anorthoOB-III and OB-IV. However, the lack of sites must account for the genesis of OB-III and OBdecreasing trends with height in average mg-number IV. Four models for the origin of AN-I and AN-II values of mafic minerals and in the average An have been proposed: content of the plagioclase does not support this (1) Hess (1960) suggested that during the crystalconclusion. Comparison of the average mf-number lization of the Ultramafic Series, plagioclase crystalvalues of cumulus mafic minerals and the average lized and either rose buoyantly or remained in An content of coexisting plagioclase shows no cor- suspension and was displaced upward by density relation between these two primary indices of currents. This plagioclase was ultimately resorbed magma evolution (Fig. 16). Thus, if significant and, along with less dense interstitial liquid that fractionation took place during the crystallization of escaped from the crystal pile, formed a layer of OB-III and OB-IV, much of the chemical evidence magma enriched in plagioclase component. Repehas been obscured. tition of this process during the solidification of the 602 MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX 320-j mafic layer D D 00 D a D a ocO a oao DD D • [ 0 ] DC 280bO 0 '53 DC Increasing Foliation 240- D QDCD 0 a ao#a D o oa 74 78 76 mg-no. in cpx 320-, mDoo • 0 • Qix^ft DUD o 9 a mm c© a no ISCDO a o 280a '3 DC a 240-• 74 ©a m a * ID DC Omo o a B a %-, a 76 Increasing Foliation D 78 mg-no. in opx Fig. 15. Detailed plot of m^-number in clinopyroxene and orthopyroxene in the foliated zone for the Western Contact Mountain section. Average m^-numbers are indicated by the larger filled circles and individual analyses are indicated by the open squares. (Note the substantially lower m^-number for both types of pyroxenes in the coarse-grained layer.) ultramafic series resulted in a stratified magma chamber with the middle portion enriched in plagioclase component that crystallized to form the thick anorthosites. (2) McCallum et al. (1980) and Raedeke (1982) proposed that during the crystallization of the Ultramafic Series, plagioclase was crystallizing in the intermediate portion of the magma chamber because of a pressure gradient. This plagioclase remained in equilibrium with the main body of magma during the crystallization and formed anorthositic 'rockbergs'. Injection(s) of a magma with a different composition caused additional crystallization and the rockbergs sank in two episodes forming AN-I and AN-II. Support for the rockberg model, in principle, is found in the work of Haskin & Salpas (1992). They interpreted compositional characteristics of AN-I and AN-II to indicate that these zones were formed by the amalgamation of aggregates of crystalline plagioclase. (3) Irvine (1975) pointed out that because of the curvature of the cotectic surfaces, mixing of a primitive basaltic magma with a more evolved basaltic magma can result in crystallization in the plagioclase-only field. It has been suggested that AN-I and AN-II may therefore be the result of magma mixing 603 JOURNAL OF PETROLOGY VOLUME 37 85o o o O C o A AA 13004 o A * 75- D O 65 70 75 0 clinopyroxene * orthopyroxene 0 olivine 80 85 Mole Fraction An Fig. 16. Plot of average mj-number in clinopyroxene, orthopyroxene and olivine vs average An content in coexisting plagiodaie for all samples. upon injection of a more primitive magma into the more evolved Stillwater magma chamber. (4) Czamanske & Bohlen (1990) argued that AN-I and AN-II were injected into the Stillwater stratigraphy as plagioclase-phyric mushes derived from a fractionating magma chamber at the crust-mantle boundary. Two of these models are incompatible with the conclusions reached above. Formation of the Middle Banded series by mixing across cotectic surfaces (Irvine, 1975) would require enormous amounts of more primitive magma to yield anorthositic layers of the thickness of AN-I, AN-I.5 and AN-II. Also, crystallization of the hybrid magma, once mafic minerals are saturated, should be accompanied by evolution in m^-number in the remaining magma throughout OB-III and OB-IV. The model of Czamanske & Bohlen (1990) requires that the Stillwater Complex was invaded by three pulses of plagioclaseladen magma. That AN-I.5 is relatively thin presents a physical problem for intruding a viscous crystal mush into partially solidified cumulates to produce a horizon with such a large aspect ratio but relatively uniform thickness. This model also calls upon an exotic source for the thick anorthosites and does not explain their many similarities to OB-III and OB-IV. The models proposed by Hess (1960) and by McCallum et al. (1980) provide explanations for the thick anorthosites that are not inconsistent with our results. However, neither model provides an explanation for the compositional features of OB-III and 604 NUMBER 3 JUNE 1996 OB-IV. Both models can be extended to explain the abundance of complexly zoned plagioclase in OB-III and OB-IV. In each, the same processes that allowed the anorthositic zones to form could have resulted in accumulation of crystalline plagioclase between these two zones. Thus the lack of evolution in the plagioclase throughout the Middle Banded series can be explained by the mechanism that allowed the plagioclase to be concentrated. However, neither model explains the lack of evolution in the mafic minerals and the appearance of clinopyroxene before orthopyroxene in OB-III and OB-IV. Two explanations for the different crystallization sequence are most consistent with the data presented. Both require the addition of some liquid to the Middle Banded series whose composition changes the crystallization relations in these zones by changing the bulk composition of the liquid. McCallum et al. (1980) suggested that this additional liquid was a different parental magma injected into the complex at the level of OB-III and OB-IV. Assuming this were so, it seems rather fortuitous that the composition of the added liquid did not change the composition of the minerals that crystallized after its introduction from those in equilibrium before its addition, although periodic introductions of this liquid could have buffered the composition of the crystallizing minerals to produce the observed lack of compositional variation. Alternatively, the liquid could have been derived from the Ultramafic series as rejected solute enriched in plagioclase and clinopyroxene components that rose to the level of the Middle Banded series as buoyant plumes (Morse, 1986). Neither the mineral compositions nor the field relations require the Middle Banded series to have crystallized from more than one magma. Isotopic data (Martin, 1989; Lambert et al., 1989, 1994) have been used to infer that two or more magma sources were involved in the formation of the Banded series. Loferski et al. (1994) examined rareearth-element contents of plagioclase and concluded that at least two parental liquids were responsible for the formation of the Middle Banded series. The remarkable continuity in major- and trace-element compositions of the cumulus minerals throughout the Middle Banded series suggests that the isotopic and rare-earth-element data should not be considered as definitive. There is evidence that interaction with postcumulus fluids has disrupted isotopic systems locally in the Stillwater chromitites (Marcantonio et al., 1993). Similar or other postcumulus effects such as recrystallization may have also modified original rare-earth-element contents of the cumulus minerals. MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX ACKNOWLEDGEMENTS CONCLUSIONS Petrographic study of OB-III and OB-IV demonstrates that only portions of these zones show significant lateral continuity. However, despite lateral variations in cumulus mineral proportions, electron microprobe analyses reveal that the average mineral compositions show little or no lateral variability. Likewise, no pronounced stratigraphic trends are observed in their average major-element and traceelement compositions. Detailed examination has revealed the importance of smaller-scale processes involved in producing and modifying both the rock textures and chemistry. For example, correlation of rock fabric with plagioclase grain habit suggests that plagioclase grain morphology may be indicative of the stress conditions present during the solidification of cumulates. Channelized liquid and/or fluid flow through largely consolidated cumulates is evidenced by (on a small scale) high-An partial rims on some plagioclase grains and (on a larger scale) discordant bodies and pegmatites. Zonation preserved in clinopyroxene grains and the compositions of coexisting clino- and orthopyroxene indicate that submagmatic reequilibratdon has taken place. Petrographic and compositional data suggest that the entire Middle Banded series is petrogenetically related and that discussions of the origin of the two thick anorthosites (AN-I and AN-II) cannot be divorced from the origin of OB-III and OB-IV. We suggest that the thick anorthosite layer at the base of OB-IV (AN-I.5) formed in the same manner as AN-I and AN-II. The general sequence of rock types in OB-III and OB-IV is the same and implies that these zones formed through similar processes. The increase in the number of cumulus minerals with height implies continuous fractionation of the liquid that produced OB-III and OB-IV. This interpretation conflicts with the lack of observed fractionation in mineral compositions with height. Our results are consistent with both the models of Hess (1960) and McCallum et al. (1980) for the origin of the thick anorthosites. The major- and trace-element compositions of the cumulus minerals do not indicate that more than one parental liquid is required to form OBIII and OB-IV. This conclusion is in apparent conflict with the results of isotopic and rare-earthelement studies that indicate the presence of at least two distinct parental liquids. However, postcumulus processes may have obscured or completely overprinted some of the original compositional and textural features of the zones, and recognition of these processes and their effects is required before further speculation about the cumulus origins of the Middle Banded series is warranted. 605 Mike Zientek of the US Geological Survey and several geologists of the Johns Manville Co., especially Lynn LeRoy and Sam Corson, provided logistical support for the field-work in the Stillwater Complex. An earlier version of this work was much improved by the critical reading of Ellen Meurer. Thorough reviews by Stu McCallum and Patty Loferski and editorial comments by J.M. Rhodes improved both the quality of the material presented and its presentation. Financial support for this work was provided by GSA and Sigma Xi student research grants and by NSF Grants EAR 9217664 and 9417144. REFERENCES Barnes, S. J., 1986. The effect of trapped liquid crystallization on cumului mineral compositions in layered intrusions. Contributions to Mineralogy and Petrology 93, 524-531. Bence, A. E. & Albee, A. L., 1968. Empirical correction factors for the electron microanalysis of silicates and oxides. Journal of Geology 76, 382. Benn, K. & Allard, B., 1989. Preferred mineral orientations related to magmatic flow in ophiolite layered gabbros. Journal of Petrology 30, 925-946. Boudreau, A. E. & McCallum, I. S., 1992. Infiltration metasomatism in layered intrusions—an example from the Stillwater Complex, Montana. Journal of Volcanology and Geothtrmal Research 52, 171-184. Braun, K., Meurer, W., Boudreau, A. E. & McCallum, I. S., 1994. Compositions of pegmatoids beneath the J-M Reef of the Stillwater Complex, Montana, USA. Chemical Geology 113, 245257. Brothers, R. N., 1964. Petrofabric analyses of Rhum and Skaergaard layered rocks. Journal of Petrology 5, 255—274. Corrigan, G. M., 1982. The crystal morphology of plagioclase feldspar produced during isothermal supercooling and constant rate cooling experiments. Mintralogital Magazine 46, 433—439. Czamanske, G. K. & Bohlen, S. R., 1990. The Stillwater Complex and its anorthosites: an accident of magmatic underplating? American Mineralogist 75, 37-45. Czamanske, G. K. & Scheidle, D. L., 1985. Characteristics of Banded-series anorthosites. In: Czamanske, G. K. &. Zientek, M. L. (eds) The Stillwattr Complex, Montana: Geology and Guide. Montana Bureau of Mines and Geology Special Publication 92, 334— 345. Foose, M. P., 1985. Primary structural and itratigraphic relations in Banded-Series cumulates exposed in the East Boulder Plateau—Contact Mountain area. In: Czamanske, G. K. & Zientek, M. L. (eds) The Stillwater Complex, Montana: Geology and Guide. Montana Bureau of Mines and Geology Special Publication 92, 305-324. Haskin, L. A. & Salpas, P. A., 1992. Genesis of compositional characteristics of Stillwater AN-I and AN-II thick anorthosite units. Gcockimica et Cosmochimica Acta 56, 1187-1212. Hess, H. H., 1960. Stillwater igneous complex, Montana—a quantitative mineralogical study. Geological Society of America, Memoir 80, 230 pp. JOURNAL OF PETROLOGY VOLUME 37 Higgins, M. D., 1991. The origin of laminated and massive anorthoiite, Sept lies layered intrusion, Quebec, Canada. Contributions to Mineralogy and Petrology 106, 3+0-354. Irvine, T. N., 1975. Olivine-pyroxene-plagioclase relations in the system Mg 2 SiO 4 -CaAl 2 Si2O 8 -KAlSi 3 O8-SiO2 and their bearing on the differentiation of stratiform intrusions. Carnegie Institution of Washington, Yearbook 74, 492-500. Irvine, T. N., 1980. Magmatic infiltration metasomatism, doublediffusive fractional crystallization, and adcumulus growth in the Muskox intrusion and other layered intrusions. In: Hargraves, R. B. (ed.) Physics of Magmatic Processes. Princeton, NJ: Princeton University Press, pp. 325-383. Irvine, T. N., 1982. Terminology for layer intrusions. Journal of Petrology 23, 127-162. Jackson, E. D., 1961. Primary textures and mineral associations in the Ultramafic zone of the Stillwater Complex, Montana. US Geological Survey Professional Papers 358, 106 pp. Kouchi, A., Tsuchiyama, A. & Sunagawa, I., 1986. Effect of stirring on crystallization kinetics of basalt: texture and clement partitioning. Contributions to Mineralogy and Petrology 93, 429—438. Lambert, D. D., Morgan, J. W., Walker, R. J., Shirey, S. B., Carlson, R. W., Zientek, M. L. & Koski, M. S., 1989. Re-Os and Sm—Nd isotope systematics of the Stillwater complex, Montana. Science 244, 1169-1174. Lambert, D. D., Walker, R. J., Morgan, J. W., Shirey, S. B., Carlson, R. W., Zientek, M. L., Lipin, B. R., Koiki, M. S. & Cooper, R. L., 1994. Re-Os and Sm-Nd isotope geochemistry of the Stillwater complex, Montana: implication for the petrogenesis of the J-M Reef. Journal of Petrology 35, 1717-1753. Lindsley, D. H. & Anderson, D. J., 1983. A two-pyroxene thermometer. Journal of Geophysical Research, Supplement 88, A887-A906. Loferskd, P. J. & Arculus, R. J., 1993. Multiphase inclusions in plagioclase from anorthosites in the Stillwater Complex, Montana: implications for the origin of the anorthosites. Contributions to Mintralogy and Petrology 114, 6 3 - 7 8 . Lofenki, P. J., Arculus, R. J. & Czamanske, G. K., 1994. Rare earth element evidence for the petrogencsis of the Banded series of the Stillwater complex, Montana, and its anorthosites. Journal of Petrology 35, 1623-1649. Lofgren, G. E., 1983. Effect of heterogeneous nucleation on basaltic textures: a dynamic crystallization study. Journal of Petrology 24, 229-255. Marcantonio, F., Zindler, A., Reisberg, L. & Mathez, E., 1993. Re—Os isotopic systematics in chromitites from the Stillwater NUMBER 3 JUNE 1996 The Stillwater Complex, Montana: Geology and Guide. Montana Bureau of Mines and Geology Special Publication 92, 2 8 6 - 2 9 2 . Meurer, W. P., 1995. Postcumulus processes in igneous cumulates: theory and application to the Middle Banded series of the Stillwater complex, Montana. Ph.D. Thesis, Duke University, Durham, NC, 418 pp. Meurer, W. P. & Boudreau, A. E., 1993. The olivine bearing zones of the Middle Banded series, Stillwater complex, Montana: geochemistry and textures. EOS Transactions, American Geophysical Union 74(14), 337. Morse, S. A., 1986. Convection in aid of adcumulus growth. Journal of Petrology 27, 1183-1214. Morse, S. A. & Nolan, K. M., 1984. Origin of strongly reversed rims on plagioclase in cumulates. Earth and Planetary Science Letters 68, 485-498. Page, N. J., 1976. Serpentinization and alteration in an olivine cumulate from the Stillwater Complex, Southwestern Montana. Contributions to Mineralogy and Petrology 54, 127-137. Page, N. J. & Nocklcberg, W. J., 1974. Geologic map of the Stillwater Complex, Montana. US Geological Survey Miscellaneous Investigation Series 1-797, 5 sheets, scale 1:12 000. Page, N. J. & Zientek, M. L., 1985. Geologic and structural setting of the Stillwater Complex. In: Czamanske, G. K. & Zientek, M. L. (eds) The Stillwater Complex, Montana: Geology and Guide. Montana Bureau of Mines and Geology Special Publication 92, 1-8. Raedeke, L. D., 1982. Petrogenesis of the Stillwater Complex. Ph.D. Thesis, University of Washington, Seattle, 212 pp. Raedeke, L. D. & McCallum, I. S., 1984. Investigations in the Stillwater Complex: Part II. Petrology and petrogenesis of the Ultramafic Series. Journal of Petrology 25, 395-420. Salpas, P. A., 1985. A geochemical study of anorthosite from the Stillwater Complex, Montana. Ph.D. Thesis, Washington University, St Louis, MO. Salpas, P. A , Haskin, L. A. & McCallum, I. S., 1983. Compositions of samples from traverses of Stillwater anorthosites AN-I and A N - I I . In: Proceedings of the 14th Lunar and Planetary Science Conference (abstracted papers). Houston, TX: Lunar and Planetary Science Institute, pp. 664-665. Salpas, P. A., Haskin, L. A. & McCallum, I. S., 1984. The scale of compositional heterogeneities in Stillwater anorthosites AN-I and AN-II. In: Proceedings of the 15th Lunar and Planetary Science Conference (abstracted papers). Houston, TX: Lunar and Planetary Science Institute, pp. 713-714. Scheidle, D. L., 1983. Plagioclase zoning and compositional varcomplex. Geochunica et Cosmochimica Acta 57, 4029—4037. iation in Anorthosite I and II along the Contact Mountain Martin, C. E., 1989. Re-Os isotopic investigation of the Stillwater traverse, Stillwater Complex, Montana. M.S. Thesis, Stanford complex, Montana. Earth and Planetary Science Letters 93, 336— University, Stanford, CA, 112 pp. 344. Schiffries, C. M., 1982. The petrogenesis of a platiniferous dunite McBirney, A. R. & Noyes, R. M., 1979. Crystallization and pipe in the Bushveld Complex: infiltration metasomatism by a layering of the Skaergaard intrusion. Journal of Petrology 20, 487— chloride solution. Economic Geology 77, 1439-1453. 554. Segerstrom, K. & Carlson, R. R., 1982. Geological map of the McBirney, A. R. & Sonnenthal, E. L., 1990. Metasomatic replabanded upper zone of the Stillwater Complex and adjacent cement in the Skaergaard intrusion, East Greenland: prerocks, Stillwater, Sweet Grass, and Park Counties, Montana. US liminary observations. Chemical Geology 88, 245-260. Geological Survey Map vl-1383, 2 sheets, scale 1:24 000. McCallum, I. S., Raedeke, L. D. & Mathez, E. A., 1980. Wager, L. R. & Brown, G. M., 1967. Layered Igneous Rocks. San Investigations of the Stillwater Complex: Part I. Stratigraphy Francisco, CA: W. H. Freeman. and structure of the Banded zone. In; Irving, A. J. & Dungan, Wooden, J. L., Czamanske, G. K. & Zientek, M. L., 1991. A lead M. A. (eds) The Jackson Volume, American Journal of Science 280-A, isotopic study of the Stillwater complex, Montana: constraints 59-87. on crustal contamination and source regions. Contributions ie Mineralogy and Petrology 107, 8 0 - 9 3 . McCallum, I. S., Raedeke, L. D., Mathez, E. A. & Criscenti, L. J., 1985. A traverse through the Banded series in the Contact Zientek, M. L., Czamanske, G. K. & Irvine, T. N., 1985. Mountain area. In: Czamanske, G. K. & Zientek, M. L. (eds) Stratigraphy and nomenclature for the Stillwater Complex. In; 606 MEURER AND BOUDREAU MIDDLE BANDED SERIES, STILLWATER COMPLEX Czamanake, G. K. & Zientek, M. L. (eda) The StiUwattr Complex, Montana: Geology and Guide. Montana Bureau of Mints and Geology Special Publication 92, 21-32. 607 RECEIVED OCTOBER 12, 1995 REVISED TYPESCRIPT ACCEPTED JANUARY 4, 1996
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