TIMELINE OF THE MODELS* ? 460 BC Democritus “Atoms” 1800 John Dalton “Billiard Ball” 1897 JJ Thompson “Plum Pudding” 1911 Rutherford “Planetary” 1912 Niels Bohr “Bohr Model” Today Many scientists “Modern” *There are many more models. These are the ones we’ll cover in class. THE ANCIENTS – B.C. • Aristotle believed everything was made up of the fundamental “elements” • • • • Earth Wind (air) Fire Water DEMOCRITUS • Indivisible = atomos • atoms were distinct in size and shape • each element was therefore unique • substances of the world were made from combinations of different atoms EARLY SCIENTISTS • The alchemists-those wishing to turn lead into gold – where some of the first scientists. They documented their experiments. THE LAW OF CONSERVATION OF MASS BY ANTOINE LAVOISIER Try the following problem to see if you understand this law. Suppose you have 15 grams of substance A and 13 grams of substance B. How much substance C will be formed if you also produce 9 grams of substance D as shown below? A + 15 g B 13g Reactants C ?g + D 9g Products JOHN DALTON --1800 (A.K.A “THE MARBLE GUY”) • All matter is made of tiny indestructible particles called atoms. • All atoms of the same element are identical • Atoms of different elements combine to form compounds in An atom fixed ratios. (Close-up view) • Chemical reactions are rearrangements of atoms. Which of these statements are still considered correct? JJ THOMSON (1897) • Was used a Crooke’s vacuum tube • Found that running electricity through a gaseous element produced a stream. OBSERVATION CONCLUSIONS The beam can push a paddle wheel so Beam is made of particles The mass of the tube did not change particles came from inside the atom, so the atom is not indivisible The stream moved from – to + so Atoms are neutral, so, atoms must also contain charges that are... Has a negative charge Positive PLUM PUDDING MODEL • Thomson figured out that atoms contained positive and negative charges but had no idea how they were arranged. • He guessed there was a diffuse positive cloud with negative charges randomly distributed - Diffuse positive cloud - - ERNEST RUTHERFORD (1910) • Performed the famous gold foil experiment • Won a Noble Prize for Chemistry GOLD FOIL EXPERIMENT • Rutherford used Radium as the source of the alpha particles and shot them at a thin gold foil like aluminum foil but made of gold • A fluorescent screen sat behind the gold foil on which he could observe the alpha particles’ impact. GOLD FOIL EXPERIMENT • When the particles bounced back Rutherford reasoned that it hit something massive and positive. This mass became know as the nucleus. • When the alpha particles went straight through it hit nothing. • This happened most often so the atom is mostly empty space RUTHERFORD’S “PLANETARY MODEL Rutherford’s said the negative electrons orbited a positive center (NUCLEUS)like our planets orbit the sun. • The nucleus has most of the mass of the atom. • The distance between the positive center (nucleus) and the electrons was huge-like a marble in the center of a football field. • The atom was mostly empty space!!!! PLANETARY THEORY • Nucleus of atom contains @99.9% of the mass of the atom • Nucleus is positively charged • Electrons orbit the nucleus randomly and take up @99.9% of the space • Electrons are negatively charged JAMES CHADWICK 1932 DISCOVERED THE NEUTRON neutron •Predicted by Rutherford in1920, but very difficult to detect. •New tool for probing and changing the nucleus of an atom. ONE LITTLE PROBLEM… • Opposite charges attract each other and the electrons should gradually lose energy and spiral inward toward the nucleus. (BOOM! No more atom.) SHREK MODEL • Neils Bohr (1922) proved that electrons have energy and don’t orbit randomly around the nucleus • They circle in well-defined energy levels like the layers in an onion. • Jumping to and from energy levels absorbs or releases energy BOHR’S MODEL 31 21 Nucleus 32 ERWIN SCHRODINGER • Regions where electrons are most likely found are called “electron clouds”. • Different types of clouds have different shapes and different amounts of energy. • Results were spectacular! • New model of the atom explained the physical properties of atoms, and the Periodic Table, perfectly. ( more later) HEISENBERG'S UNCERTAINTY PRINCIPLE • The world of the atom is so small that just by us looking for sub atomic particles changes their location. • Thus we can’t be sure certain about the size and shape of energy levels but now…. 1980’S Atoms can be “seen” with a scanning tunneling microscope. SCANNING TUNNELING MICROSCOPE Fermi lab scientists in Batavia, Illinois study and detect six types of quarks Quarks are particles believed to make up protons and neutrons Cern Lab in Switzerland may have found Higgs-Boson More on this in your Physics class.
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