Date of Issue: 11/2013
Page 1 of 3
Cyclohexylmagnesium Chloride, typ. 20 %
solution in THF / Toluene (typ. 1.3 M)
PRODUCT
Cyclohexylmagnesium Chloride, typ. 20 % solution in THF / Toluene (typ. 1.3 M)
Product No. 408473
CAS-No. 931-51-1
EINECS-No. 213-237-1
FURTHER
INGREDIENTS
THF
CAS-No. 109-99-9 EINECS-No. 203-726-8
Toluene
CAS-No. 108-88-3 EINECS-No. 203-625-9
APPLICATION
Grignard-reactions: reagent for the introduction of the cyclohexyl group; metalation of CH-acidic
compounds.
APPEARANCE
dark brown liquid
FORMULA
C6H11ClMg
PHYSICAL
PROPERTIES
Molecular weight:
142.91
Density:
0.95 g/ccm (at 20 °C)
Boiling Point:
66 °C for THF
Flash Point:
-21.5 °C for THF
Thermal Stability:
Crystallization below
around -10 °C
SPECIFICATION
Cyclohexylmagnesium 19 – 21 %
Chloride
THF
typ. 40 %
Toluene
typ. 40 %
The above details have been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current
state of our long practical experience. No liabilities or guarantees
deriving from or in connection with this leaflet can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 7165-2053
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623
Product No. 408473
Date of Issue: 11/2013
Page 2 of 3
METHOD OF
ANALYSIS
Determination of assay as total base by acidimetric titration after hydrolysis; detailed description
available on request.
HANDLING
Organomagnesium compounds should only be handled under inert gas (nitrogen or argon).
Never add water, acids or oxidizing materials to the product. In case of fire use dry extinguishers
on basis of sodium chloride or limestone powder. Never use water or CO2-extinguishers.
Pay attention to official safety regulations (see also: ”Transport regulations“and “GHS Hazard
Pictograms”).
STORAGE
Under exclusion of air and humidity stable over practically unlimited periods. As material tends to
crystallize at lower temperatures, it should be stored above -5 °C. Keep container dry and tightly
closed.
TRANSPORT
REGULATIONS
UN-No.:
2924
Rail/Road (RID/ADR):
Class 3
PG II
Label 3 (8)
Sea (IMDG-Code):
Class 3
PG II
Label 3 (8)
Air (IATA-DGR):
Class 3
PG II
PAX 352
CAO 363
GHS HAZARD
PICTOGRAMS
SIGNAL WORD
Danger
H&P phrases: See Material Safety Data Sheet
PACKING
Glass bottles of 100, 250, 500 and 1,000 ml. Steel drums up to 200 l. Steel bottles with volumes of
7.4, 27, 127 or 450 l. For safety reasons these are filled to a maximum of 90 %.
TIME OF DELIVERY
To be agreed upon.
The above details have been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current
state of our long practical experience. No liabilities or guarantees
deriving from or in connection with this leaflet can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 7165-2053
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623
Product No. 408473
Date of Issue: 11/2013
Page 3 of 3
FURTHER RELATED
DOCUMENTS
Organomagnesium Compounds brochure, Material Safety Data Sheet
The above details have been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current
state of our long practical experience. No liabilities or guarantees
deriving from or in connection with this leaflet can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 7165-2053
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623