Vapour pressures and dry mole fractions for semi-volatile Compounds
1-13 and dry mole fractions for the involatile Compounds 14 and 15.
In all plots panels (a) and (b) are for the ideal model run, while panels
(c) and (d) are for the non-ideal model run using PDFiTE.
For Compounds 1-13 panels (a) and (c) show the size resolved
differences between vapour pressure (VP) over the aerosol particle
and the gas-phase partial pressure (PP), as well as the temporal
variation in partial pressure. Panels (b) and (d) show the size resolved
dry mole fractions of the SOA compounds within the condensed
phase.
In the Compound 14 and 15 plot panels (a)-(d) all show size resolved
dry mole fraction.
Compound 1
−13
x 10
(b)
0.10
−1
4
1.00
3
2
0.10
0.5
1
−2
6
12
18
Time [Hours]
24
0
−9
12
Time [hours]
18
24
x 10
(d)
1
0.10
1
0
−1
5
Dry Radius [µ m]
1.5
Dry Radius [µm]
2
1.00
4
1.00
3
2
0.10
0.5
1
−2
0
0
6
12
18
Time [Hours]
24
0
−4
x 10
2
PP [atm]
6
−13
x 10
2.5
(c)
PP − VP [atm]
0
0
Dry Mole Fraction
1
0
Dry Radius [µ m]
1.5
1
5
PP − VP [atm]
1.00
Dry Radius [µm]
2
2
PP [atm]
−4
x 10
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
−9
x 10
2.5
(a)
Compound 2
−13
−13
x 10
8
(a)
x 10
(b)
0.15
0.10
2
3
2
1.00
0.1
0.10
0.05
Dry Mole Fraction
4
4
Dry Radius [µ m]
1.00
5
PP − VP [atm]
PP [atm]
6
Dry Radius [µm]
6
1
0
0
0
6
12
18
Time [Hours]
24
0
−13
6
12
Time [hours]
18
24
0
−13
x 10
8
(c)
x 10
(d)
0.15
0.10
2
3
2
1.00
0.1
0.10
0.05
1
0
0
0
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
4
4
Dry Radius [µ m]
1.00
5
PP − VP [atm]
PP [atm]
6
Dry Radius [µm]
6
Compound 3
−14
x 10
(b)
3
−1
2.5
1.00
2
1.5
0.10
1
1
0.5
−2
6
12
18
Time [Hours]
24
0
−14
12
Time [hours]
18
24
x 10
(d)
3
2
0.10
1
0
−1
Dry Radius [µ m]
1.00
Dry Radius [µm]
2
3
2.5
1.00
2
1.5
0.10
1
1
0.5
−2
0
0
6
12
18
Time [Hours]
24
0
−5
x 10
4
PP [atm]
6
−14
x 10
5
(c)
PP − VP [atm]
0
0
Dry Mole Fraction
0.10
0
Dry Radius [µ m]
2
1
PP − VP [atm]
1.00
3
Dry Radius [µm]
2
4
PP [atm]
−5
x 10
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
−14
x 10
5
(a)
Compound 4
−11
x 10
(b)
1.00
6
4
0.10
2
−1
6
12
18
Time [Hours]
24
0
−11
12
Time [hours]
18
24
−3
x 10
x 10
(d)
2
0.10
1
0
8
Dry Radius [µ m]
1.00
Dry Radius [µm]
1
3
PP [atm]
6
−11
x 10
4
(c)
PP − VP [atm]
0
0
1.00
6
4
0.10
2
−1
0
0
6
12
18
Time [Hours]
24
Dry Mole Fraction
0.10
1
0
Dry Radius [µ m]
2
8
PP − VP [atm]
1.00
Dry Radius [µm]
1
3
PP [atm]
−3
x 10
0
6
12
Time [hours]
18
24
Dry Mole Fraction
−11
x 10
4
(a)
Compound 5
−13
4
0.10
2
2
0
5
4
1.00
3
2
0.10
1
−2
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
−13
6
4
1.00
4
0.10
2
2
0
PP − VP [atm]
x 10
6
Dry Radius [µm]
PP [atm]
−13
x 10
8
(c)
−3
(d)
5
4
1.00
3
2
0.10
1
−2
0
0
6
12
18
Time [Hours]
24
0
x 10
Dry Radius [µ m]
0
0
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
1.00
(b)
Dry Mole Fraction
4
−3
x 10
Dry Radius [µ m]
6
PP − VP [atm]
x 10
6
Dry Radius [µm]
PP [atm]
−13
x 10
8
(a)
Compound 6
x 10
(b)
0.10
1
2
1.5
1
0.5
Dry Radius [µ m]
2
2.5
PP − VP [atm]
1.00
Dry Radius [µm]
3
3
PP [atm]
−3
−14
x 10
6
1.00
4
0.10
2
Dry Mole Fraction
−14
x 10
4
(a)
0
12
18
Time [Hours]
24
0
−14
12
Time [hours]
18
24
−14
x 10
4
(c)
x 10
(d)
0.10
1
2.5
2
1.5
1
0.5
Dry Radius [µ m]
2
Dry Radius [µm]
3
1.00
0
−3
x 10
3
PP [atm]
6
6
1.00
4
0.10
2
0
0
0
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
6
PP − VP [atm]
0
0
Compound 7
−10
−10
x 10
(a)
x 10
1.5
1
0.10
0.5
0
0.25
1.00
0.2
0.15
0.10
0.1
−0.5
0.5
6
12
18
Time [Hours]
−1
24
−10
0
6
12
Time [hours]
18
24
0
−10
x 10
(c)
x 10
1.5
(d)
1.5
1
0.10
0.5
0
0.25
1.00
0.2
0.15
0.10
0.1
−0.5
0.5
6
12
18
Time [Hours]
24
−1
0.05
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
1.00
Dry Radius [µm]
2
1
Dry Radius [µ m]
0.3
2.5
0
0
0.05
PP − VP [atm]
0
0
Dry Mole Fraction
1.5
PP − VP [atm]
1.00
Dry Radius [µm]
PP [atm]
2
1
Dry Radius [µ m]
0.3
2.5
PP [atm]
(b)
Compound 8
−14
x 10
(b)
3
5
1.00
3
2
0.10
2
1
0
−1
Dry Radius [µ m]
4
PP − VP [atm]
4
Dry Radius [µm]
1.00
3
2
0.10
1
1
−2
0
0
6
12
18
Time [Hours]
24
0
−14
6
12
Time [hours]
18
24
−14
x 10
6
(c)
−5
x 10
x 10
(d)
3
1.00
3
2
0.10
1
0
−1
Dry Radius [µ m]
4
2
PP − VP [atm]
4
Dry Radius [µm]
PP [atm]
5
1.00
3
2
0.10
1
1
0
0
0
−2
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
PP [atm]
−5
x 10
Dry Mole Fraction
−14
x 10
6
(a)
Compound 9
−11
−11
x 10
3
(b)
0.02
4
0.10
2
1
0
−1
−2
Dry Radius [µ m]
1.00
PP − VP [atm]
0.015
1.00
0.01
0.10
0.005
−3
0
0
6
12
18
Time [Hours]
24
0
−11
6
12
Time [hours]
18
24
−11
x 10
8
(c)
x 10
3
(d)
0.02
4
0.10
2
1
0
−1
−2
Dry Radius [µ m]
1.00
PP − VP [atm]
PP [atm]
6
Dry Radius [µm]
2
0
0
0
0.015
1.00
0.01
0.10
0.005
−3
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
PP [atm]
6
Dry Radius [µm]
2
Dry Mole Fraction
x 10
8
(a)
Compound 10
−14
−15
−6
x 10
x 10
(b)
0.10
−2
Dry Mole Fraction
0.5
0
Dry Radius [µ m]
1.00
2.5
2
PP − VP [atm]
1
Dry Radius [µm]
PP [atm]
x 10
1.5
(a)
2
1.00
1.5
1
0.10
0.5
−4
6
12
18
Time [Hours]
24
0
−14
12
Time [hours]
18
24
0
−6
x 10
x 10
(d)
0.5
0.10
0
−2
2
1.00
1.5
1
0.10
0.5
0
0
−4
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
1.00
2.5
2
Dry Radius [µ m]
1
Dry Radius [µm]
PP [atm]
6
−15
x 10
1.5
(c)
PP − VP [atm]
0
0
Compound 11
−12
x 10
5
4
(b)
2
0.10
1
6
12
18
Time [Hours]
24
0.10
0.02
0
−12
6
12
Time [hours]
18
24
0
−12
x 10
6
(c)
x 10
5
4
0.10
1
0
1.00
0.04
0.10
0.02
−2
6
12
18
Time [Hours]
24
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
2
Dry Radius [µ m]
3
2
0.06
PP − VP [atm]
1.00
Dry Radius [µm]
(d)
4
0
0
0.04
−2
0
0
PP [atm]
0
1.00
Dry Mole Fraction
3
2
Dry Radius [µ m]
1.00
0.06
PP − VP [atm]
4
Dry Radius [µm]
PP [atm]
−12
x 10
6
(a)
Compound 12
0.2
2
0
−2
(b)
15
1.00
10
0.10
5
−4
6
12
18
Time [Hours]
24
0
−12
6
12
Time [hours]
18
24
−13
x 10
1
(c)
0.4
0.10
0.2
4
2
0
−2
x 10
(d)
Dry Radius [µ m]
1.00
0.6
Dry Radius [µm]
0.8
15
1.00
10
0.10
5
−4
6
12
18
Time [Hours]
24
0
−4
x 10
6
PP − VP [atm]
0
0
Dry Mole Fraction
0.10
PP [atm]
x 10
Dry Radius [µ m]
0.4
4
PP − VP [atm]
1.00
0.6
Dry Radius [µm]
PP [atm]
0.8
0
0
−4
−13
x 10
6
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
−12
x 10
1
(a)
Compound 13
−12
−13
x 10
(b)
12
0.10
6
4
0.3
1.00
0.25
0.2
0.15
0.10
0.1
2
6
12
18
Time [Hours]
0
24
−12
0
6
12
Time [hours]
18
24
−13
x 10
1.5
(c)
x 10
(d)
12
0.5
0.10
8
6
4
0.3
1.00
0.25
0.2
0.15
0.10
0.1
2
0
0
6
12
18
Time [Hours]
24
0
0.05
0
6
12
Time [hours]
18
24
Dry Mole Fraction
1.00
10
0.35
Dry Radius [µ m]
1
Dry Radius [µm]
PP [atm]
0.05
PP − VP [atm]
0
0
Dry Mole Fraction
0.5
8
Dry Radius [µ m]
1.00
10
0.35
PP − VP [atm]
1
Dry Radius [µm]
PP [atm]
x 10
1.5
(a)
Compound 14
Compound 15
1.00
0.3
0.2
0.10
0.1
6
12
Time [hours]
18
24
1.00
0.2
0.10
0.1
0
0
6
12
Time [hours]
18
24
0
0.4
1.00
0.3
0.2
0.10
0.1
6
12
Time [hours]
18
24
0
Dry Radius [µ m]
(d)
Dry Mole Fraction
Dry Radius [µ m]
(c)
0
0.3
0.4
1.00
0.3
0.2
0.10
0.1
0
6
12
Time [hours]
18
24
0
Dry Mole Fraction
0
0.4
Dry Mole Fraction
0.4
Dry Radius [µ m]
(b)
Dry Mole Fraction
Dry Radius [µ m]
(a)