Learning Objectives for revision session CHAPTER 1: FUNDAMENTAL IDEAS 1. 2. 3. 4. 5. 6. 7. 8. Be confident with the periodic table Know what elements are made from Know what a compound is Know how to draw and label an atom Recognise the difference between atomic mass and atomic number Balance equations successfully (H) Know the difference between ionic, covalent and metallic bonds (H) Know what conservation of mass is Look at your periodic tables Title: chapter 1- fundamental ideas 1. What is the periodic table? Table of all known elements 2. What do we call group 1 elements? Alkali metals 3. What do we call group 2 elements? Alkaline Earth metals 4. What do we call the elements between group 2Transition and 3?metals 5. What do we call the elements in group 7? halogens 6. What do we call group 8/0 elements? Noble gases 7. Chlorine and fluorine are in group 7. What does that tell you about the two elements? They both have 7 electrons in their outer shell. They have similar properties Atomic number and atomic mass 1. Write down the what the atomic number and atomic mass is 2. Write down the numbers of protons, neutrons and electrons for each element 3. Look at the last two. What elements are they? Ionic, covalent and metallic bonding • Ionic- metal and non-metal • Covalent- non-metals • Metallic- only metal CaO CH4 MgCl2 NaCl Balancing equations Question: why are atoms neutral? • They have the same number of protons (positive) and electrons (negative) so they balance each other out and are neutral. + Neutron Same number of electrons in their outer shell OR They have similar properties Look at carbon on the periodic table. It has: 6 electrons 6 protons and 12-6= 6 neutrons The neutrons and protons go in the middle (in the nucleus) This makes the mass number. The electrons go in the outside, and have to be arranged properly. 2 in the first shell and 4 in the other (2+4= 6) a) (i) H2 + O2 → H2O *both circled correct for 1 mark 1 (ii) A1 + O2 → A12O3 all circled correct for 1 mark 1 (b) idea that: must end up with the same number of atoms as at the start any 2 each otherwise matter is shown to be lost/gained for 1 mark won’t show correct amount of each element/compound 2 1 electron in outer shell OR Similar properties Look on the periodic table. It has an atomic number of 11. So 11 is the answer 23-11= number of neutrons= 12 1 mark- 2 sodium atoms reacts with 2 chlorine atoms. They are both the reactants 1 mark- sodium chloride is the product 1 mark- sodium chloride is a compound as sodium is bonded to chlorine 1 3 Something that is made up of the SAME atoms Argon element is made up of argon atoms Electon Nucleus (contains protons and neutrons) It is made up of only one type of atom- lithium atoms Carbon as it has 6 electrons. nucleus electon nucleus You can’t say they have similar properties even though they do. As the question is asking you to look at them....so looking at them, the answer must be that they have the same number of electrons in their outer shell Electron (neg) Proton (pos) Neutron (no charge) Full number of electrons in outer shell. ANY ELECTON IN GROUP 8 HAS A FULL NUMBER OF ELECRTONS IN THEIR OUTER SHELL a) 9 protons /Proton Number 9 mass / atomic number is neutral 1 10 neutrons 1 electron arrangement 2,7 / 9 electrons incorrect configurations neutral if no points scored, allow 1 mark for nucleus surrounded by electrons or nucleus contains neutrons and protons 1 Electron (neg) Neutrons Nucleus (contains protons and neutrons) Protons (neg) It has one electron in its outer shell. So it must be group 1! ( EXTRAThere are 3 electrons altogether so it must be the element lithium) Learning Objectives for revision session CHAPTER 2: ROCKS AND BUILDING MATERIALS 1. 2. 3. 4. 5. Recognise what a carbonate is Know the word and chemical equation for the breakdown of limestone Be able to describe the limestone cycle Know the test for carbon dioxide (and what happens!) Know how to make cement, concrete, mortar and glass using calcium carbonate 6. Longer answer question: limestone issues Write down the advantages and disadvantages of limestone quarrying • Before you start writing, always do a 30 second quick table like this. Examiners like this. And it helps you remember things when writing.... Advantages Disadvantages Old quarries turned into parks Noise pollution Jobs so helps the economy Traffic New roads Dust means greater chance of occupational diseases such as asthma Better roads means more tourists which helps support local shops Destroys habitats Use the limestone for buildings or use the limestone to make GLASS, CEMEMENT, CONCRETE OR MORTAR Reduces quality of life How to remember how glass, cement, concrete and mortar are made Substance How I remember it How it is made Glass L, S, S (the letters from glass) Limestone, sand, sodium carbonate Cement It’s sloppy Clay (sloppy) and limestone Concrete Its hard- C, C, S Cement (contains the limestone), crushed rock (also called aggregate) and sand Mortar Its like concrete but it’s softer, so doesn't contain crushed rock Cement and sand (and some water!) To make cement, you need clay and limestone. (remember it is SLOPPY!) The gas that goes in is methane (CH4) and the waste gases are nitrogen, argon and carbon dioxide. DONT FORGET THIS! Methane a) any two from: • nitrogen accept formulae N / N2 • carbon dioxide accept formula CO2 ignore CO • water (vapour) / steam accept formula H2O Calcium oxide Calcium hydroxide Calcium carbonate Carbon dioxide is a greenhouse gas So it causes climate change called GLOBAL WARMING Calcium oxide Calcium oxide Thermal decomposition Carbon dioxide 1 3 Remember in a safety precaution you say the risk and what you would do...e.g. Heat can burn, so use tongs to handle the products, or wear goggles or a mask Clay water limestone Heat limestone to make calcium oxide. If you then add water, you will make calcium hydroxide NAME not chemical formula. So the answer is calcium carbonate limestone quicklime + carbon dioxide Or Calcium carbonate calcium oxide + carbon dioxide Limestone 2 marks so A chemical reaction where you BREAK DOWN using HEAT to burn / react with air / oxygen 1 release energy / heat / exothermic / keeps temperature high Coal takes in carbon dioxide Calcium carbonate Calcium oxide Carbon dioxide Hydration (adding water) Calcium hydroxide/slaked lime mortar / neutralise acidity in soil / neutralise acid lake water / soften hard water / to make cement not in agriculture not to make lime water Learning Objectives for revision session CHAPTER 3: METALS AND THEIR USES 1. Know what the reactivity series is 2. Recognise what reactivity means 3. Know the definition of an ore 4. Know what an alloy is 5. Explain why alloys are stronger than pure metals 6. Describe the alloys steel, brass and bronze 7. Explain the uses of aluminium and titanium 8. Be able to explain how we can extract copper 9. Know what transition metals can be used for 10. Longer answer question: metallic issues (extraction) 11. Longer answer question: metallic issues (metals in construction) Key points you might have missed • • • • • • • • • • • • • Metals are mostly found on the earth’s crust An ore is a rock that contains enough metal to make it worth extracting There are different extraction methods depending on the reactivity of the metal Alloys are mixtures of metals and they are stronger than pure metals as they are not arranged in layers so don’t slide over each other. Steel is an alloy that contains a lot of the element iron. Brass and bronze are alloys that contain copper. Iron and steel can rust Aluminium and titanium are pure metals. They form oxide layers which makes them resist corrosion (resist rusting). Copper can be extracted by: smelting (heating the copper and then it undergoes electrolysis), phytomining (P for plants) or bioleaching (B for bacteria). Diplacement reactions are when a more reactive metal takes over a less reactive metal. E.g. Copper oxide + aluminium copper + aluminium oxide....because the aluminium is more reactive, it take the oxygen. Iron is cheap. COKE is just another name for carbon Smart alloys go back to their normal shape C + O2 CO2 Coke is just carbon! C + CO2 → 2 CO 3 2 3 Cathode Anode The traditional method of extracting copper is called quarrying and then smelting. The ore is copper sulfide (so it contains sulhur). Smelting requries heating the ore. So if you heat the ore, you will produce sulphur dioxide as oxygen from the air would react with the sulphur in the ore. Two environmental impacts1. acid rain from the sulphur dioxide 2. Large amounts of solid waste from quarrying Remember these, especially the second one as it comes up quite often- quarrying produces a lot of solid waste which is an environmental problem. oxygen The key word is expensive. It would be expensive as you would need a lot of ENERGY to extract just a little bit of copper. OR you could say it requires a lot of work to extract just a tiny bit. Told you- this question comes up again and again.... Traditional method is quarrying....so lots of solid waste is the answer. mixture metal There are 25 dots. Iron dots = 18. so 18/25= 0.72 x 100= 72% Chromium dots = 5. So 5/25= 0.2 x 100= 20% Nickel dots= 2/25= 0.08 x 100= 8% Check by adding them all up. It should make 100% 20% 8% Copper is a good conductor of electricity Good conductor of electricity (a) any three from: • resources / aluminium / ores are conserved accept converse argument • less / no mining or less associated environmental problems eg quarrying / eyesore / dust / traffic / noise / loss of land / habitat ignore just pollution • less / no waste (rock) / landfill do not accept ‘wastes 50% of the ore’ • no purification / separation (of aluminium oxide) • (aluminium extraction / production) has high energy / electricity / heat / temperature requirements • less carbon dioxide produced accept no carbon dioxide produced ignore references to cost It can go back to its original shape Brass is an alloy- it contains a mixture of metals. Therefore, it is not arranged in layers (as the atoms are different sizes) so the atoms don’t slide over each other. Therefore, they don’t bend so easily, making it stronger A rock that contains enough metal to make it worth extracting Anything with carbon is a REDUCTION REACTION (LOSS OF OXYGEN) 2Fe2O3 + 3C 4Fe + 3CO2 It is only made up of one type of atom – 1 mark Iron atoms- 1 mark 2 2 The gas is sulphur dioxide It would cause acid rain which would make lakes acidic and kill fish A pie chart must add up to 100%. So 100- 89, 1, 5= 5% Remember to revise: • Methods of extracting copper (smelting then electrolysis, bioleaching or phytomining) • Traditional methods of extracting copper are quarrying then electrolysis. • An environmental impact of quarrying is lots of solid waste from rocks etc. • Iron is cheap Learning Objectives for revision session CHAPTER 4: CRUDE OIL AND FUELS 1. Recognise how crude oil is made 2. Recognise that crude oil has to be separated because it is a mixture of different hydrocarbons 3. Describe fractional distillation 4. Recognise that when we burn fuels with enough oxygen (complete combustion) we produce water and carbon dioxide 5. Recognise that when we burn fuels with little oxygen (incomplete combustion) we produce carbon monoxide which is poisonous 6. Know what cleaner fuels are 7. Recognise how we can produce other fuels Crude oil • • • • • • • • • • 1. 2. From under the ground (dead animals and plants turned into fossil fuels) Crude oil contains a mixture of different sized hydrocarbons Some hydrocarbons are small- so they have a low boiling point. Others are big so they have a high boiling point. We can separate hydrocarbons by a process called fractional distillation. Fractional distillation involves: heating, boiling, evaporating, cooling and condensing the hydrocarbons. This allows them to separate into similar sized hydrocarbons (e.g. Small ones go to the top, biggest ones go to the bottom). Burning fuels causes pollution. Fuels contain sulhpur too, which reacts with oxygen to produce sulphur dioxide. Unburnt carbon is called particulates that causes global dimming and bronchitis. Cayatlystic converters in cars remove nitrogen oxides (cause acid rain) and carbon monoxide (poisonous) before they go into the air from an exhaust. We can remove sulhpur from fuel too as it burns with oxygen to produce sulhur doixide otherwise. ALTERNATIVE fuels means other fuels instead of using crude oil. They are: Biofuels (made from plants- so they are renenwable)- e.gs of biofiuels are VEGETABLE OILS (priduced from olives, rapreseed oil etc by pressing) or ethanol- made from hydration of ethene or by fermentation. Biofuels use plants and the bad thing is we need plants for food not just fuel as it takes up a lot of space. But the good thing is plants take in carbon dioxide by photosynthesis. Hydrogen as a fuel- the good thing is the only waste product produced is water which is harmless. But it is a gas so it is difficult to store and takes up lots of space. It is produced by electrolysis of water. Fractional distillation butane / / 344 – 350(°C) 216(°C) The more carbon atoms, the higher the boiling point / Acid rain Global dimming It has a higher boiling point than gasoline but a lower boiling point than kerosene oxygen The only waste product it produces when it burns is water which is harmless Sulphur dioxide hydrogen Ethene is a monomer and lots of monomers (ethenes) bond together to form the polymer poly(ethene) Less carbon atoms Coal burns to produce carbon dioxide which is a greenhouse gas. Greenhouse gases produce climate issues like global warming. The sulfur burns with the oxygen to produce sulphur dioxide Sulfur dioxide causes acid rain hydrogen Evaporation as they have different boiling points CO2 H2O Evaporation (cant be melting as it is a liquid already) Condensation (turn back to a liquid) distillation Learning Objectives for revision session CHAPTER 5: PRODUCTS FROM OIL 1. Know what cracking is 2. Describe polymerisation 3. Give some examples of new and useful polymers 4. Recognise the problems with plastics (longer answer question) 5. Describe ethanol in detail Don’t forget • Fractional distillation is separating hydrocarbons • Cracking is breaking big hydrocarbons into smaller ones (using heat and a catalyst) • Polymerisation is making plastics using alkenes 1 mark- cracking is a thermal decomposition reaction 1 mark- cracking breaks down a large hydrocarbon into smaller ones 1 mark- cracking also requires a catalyst to speed up the reaction 1 mark- burning fossil fuels like crude oil or coal produces carbon dioxide 1 mark- carbon dioxide is a greenhouse gas 1 mark- greenhouse gases trap heat which leads to global warming as we are producing more greenhouse gases by burning hydrocarbons (fossil fuels) hydrogen Lots of propenes (the monomers in this case) bond together to form a polymer Poly(ethene) cracking hydrogen It contains one or more double bonds Many monomers bonding together to form a polymer water It is a catalyst A compound containing hydrogen and carbon atoms only water Carbon dioxide Remember- any hydrocarbon that burns with oxygen produces water and carbon dioxide It is poisonous and it binds with our haemoglobin in our blood more easily than oxygen 1 mark- cracking is a thermal decomposition reaction 1 mark- cracking breaks down a large hydrocarbon into smaller ones 1 mark- cracking also requires a catalyst to speed up the reaction Bromine water Bromine water is orange/browny. If an alkene (unsaturated hydrocarbon) is present, it will go colourless. If an alkane (saturated hydrocarbon) is present, it will stay the same. catalyst A compound containing hydrogen and carbon only C8H18 C3H8 It needs to be broken down using heat and a catalyst A compound that contains hydrogen and carbon only C5H12 A COMPOUND THAT CONTAINS HYDROGEN AND CARBON ONLY A HYDROCARBON THAT HAS NO DOUBLE BONDS AND HAS THE MAXIMUM AMOUNT OF HYDROGENS IT CAN POSSIBLY HOLD . THEY ARE ALSO CALLED ALKANES IN CRUDE OIL HYDROCARBONS THAT HAVE BEEN SEPARATED BY A PROCESS CALLED FRACTIONAL DISTILLATION AND HAVE A SIMILAR NUMBER OF CARBON ATOMS SO SIMILAR BOILING POINTS. C2H4 It increases with more carbon atoms Petroleum is another name for crude oil. So the method to separate crude oil is fractional distillation Learning Objectives for revision session CHAPTER 6: PLANT OILS 1. 2. 3. 4. 5. Describe how we can extract vegetable oils Describe why it is better to cook with oils than water Explain the difference between saturated and unsaturated oils Describe an emulsion Longer answer questions: evaluate the benefits and drawbacks of using vegetable oils and emulsifiers in foods Things to remember: • • • • • • • We can extract vegetable oils by a method which involves pressing. E.g. Using olives or rapeseeds. We can’t eat crude oil. But we can eat vegetable oils. Vegetable oils are also hydrocarbons and also contain saturated and unsaturated types. The saturated hydrocarbons are not good for our health if we have too many. Unsaturated ones are better, and we find them in fish, e.g. Cod liver oil. The test for unsaturation in vegetable oils is the same as the test for unsaturation in crude oil- bromine water. Cooking with oil can be better than cooking with water as oil has a higher boiling point so food tastes crispier. An emulsifier is something that has a hydrophobic and hydrophilic part to it. It can allow immiscible things such as oil and water to mix. The emulsifier has a head which is hydrophilic and attaches to water and a tail which is hydrophobic and attaches to the oil. This forms an emulsion (SO MANY KEY WORDS!!) We can turn oils into butter by a process called hydrogenation. It involves NICKEL as the catalyst and a temperature of 60 degrees celsius. It involves adding hydrogen's to make unsaturated oils into saturated fat (which is solid). D D C A To make margarine (solid) from sunflower oil (liquid) you need to: 1 mark- do a reaction called hydrogenation or hardening 1 mark- involves heating (60 degrees C) and using a nickel catalyst 1 mark- need to add hydrogen's to the oil to remove unsaturated bonds and make them saturated (to turn into solid) unsaturated hydrogen higher crushed It’s cheaper OR It’s easier Don’t say both as it specifically asks for one answer! Decolourises pressing unsaturated Turns colourless Nothing/stays the same - Nickel catalyst - 60 degrees C - Hydrogen gas needed to remove double bonds Water and oil don’t mix Water and oil have mixed. So the additive must be an emulsifier Learning Objectives for revision session CHAPTER 7: OUR CHANGING PLANET 1. Draw the structure of the Earth (and label it) 2. Know Wegener’s theory 3. Know the evidence Wegener had why the continents may have been JOINED 4. Explain why not many people believed Wegener 5. Describe the gases in the atmosphere past and present 6. State what the primordial soup is 7. Explain the carbon cycle (how carbon dioxide comes and leaves our atmosphere) C A B -Similar rocks containing fossils on the edges of Africa and South America -Both continents seem to fit together like a jigsaw NH3 / ammonia because the gases are unreactive accept because the measuring equipment was not very precise core It was so long ago! The boiling point of water is 100 degrees C and venus is hotter than this, so it would have evaporated!! Remember this- the boiling point of water is 100degrees C so anything above this, the water turns into water vapour (steam) Similar fossils on both continents He had evidnece why they were once joined, but no evidence why they could have moved People thought the continents were fixed Can also mention a landbridge crust Mantle year tectonic radioactive -Body’s can’t be found -Records not available (ii) any two from: • cannot predict earthquakes / plate movement • (cannot) accurately (predict earthquakes) • (earthquakes / tsunamis) are random / not regular / sudden • do not know what is happening below / in the Earth’s crust / in the mantle • very slow / thousands of years build up of pressure ignore references to technology / equipment the Earth is not cooling OR Radioactivity keeps the core hot Acid rain Remove the sulfur before it gets burnt to produce sulfur dioxide oxygen water Carbon dioxide oxygen any three from: there are many earthquakes predicted by scientists each year expense / inconvenience / panic caused by government / people taking action most / some earthquakes do little or no damage scientists do not know what is happening below the crust scientists cannot (accurately) predict where the earthquake will occur scientists cannot (accurately) predict when the earthquake will occur scientists cannot (accurately) predict the strength of the earthquake Did you know: The earth’s early atmosphere (billions of years ago, is just like that of Mars and Venus today! 1. mars- more carbon dioxide THAN EARTH (or other way, earth has less carbon dioxide than mars) 2. Mars- has less nitrogen THAN EARTH (or say it other way round, i.e. Earth has more nitrogen than mars) 3. There is very little/no oxygen on mars compared to Earth which has 21% oxygen. mantle Inner core (c) (i) remains almost the same / increases then decreases slightly from 1000 to 1800 1 increases / rises after 1800 1 rapidly (owtte) Crust Inner core is solid whereas the outer core is liquid During the first billion years of the earth’s existence, there were lots of volcanoes. Theey released gases like carbon dioxide and water vapour (water but in the gas form). The water vapour condensed (gas turns into liquid) to form the oceans! Carbon dioxide is removed from the atmosphere by: 1. Photosynthesis of plants- plants take up carbon dioxide by a process called photosynthesis. Plants do this to produce oxygen (which we need!) (when we burn trees or cut them down (deforestation), they release carbon which reacts with oxygen to form carbon dioxide again!) 2. Coal takes up carbon dioxide! (when we burn coal, we release carbon which reacts with oxygen to form carbon dioxide again!) 3. Oceans (yes oceans!) take in carbon dioxide and therefore, also reduce the amount of carbon dioxide in the atmosphere (a good thing!) 4. Carbon dioxide also becomes locked up in sedimentary rock like limestone. When we heat the limestone, we release the carbon dioxide again (thermal decomposition reaction, remember?!) The opposite of the last slide: 1. Deforestation (so plants don’t take it up) 2. Burning fossil fuels (like coal or oil) continental crust tectonic The lithosphere is the crust and upper part of the mantle. It is broken into pieces called tectonic plates In the mantle, heat is produced because of radioactive decay. This heat causes convection currents in the mantle (so the liquid moves). This makes the tectonic plates above it move.
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