Problem Set 10. 1. Write a formula for these compounds: cobalt(II) chloride; Iron(III) nitride; chromium(II) phosphide; manganese(III) fluoride; copper(I) oxide; Iron(III) sulfide; copper(II) oxide Co2+ ClFe3+ N3Cr2+ P3Mn3+ FCu+ O2Fe3+ S2Cu2+ O2CoCl2 FeN Cr3P2 MnF3 Cu2O Fe2S3 CuO 2. Name the following compounds: FeS, CuI; MnCl3 ; ZnS; Ni3 N2 ; CoBr2; Fe2S3; Fe S2- since the ratio of Fe to S is 1 : 1 then the charge of the iron ion is Fe2+ because it has the same magnitude as that of the sulfide ion 6 iron(II) sulfide; Cu I- since the ratio of Cu to I is 1 : 1 then the charge of the copper iron is I- because it has the same magnitude as the charge of iodide ion 6 copper(I) iodide Mn3+ Cl- manganese (III) chloride zinc sulfide nickel nitride Br- cobalt(II) bromide Co2+ 3+ Fe S2- iron(III) sulfide In all of these problems use your knowledge of the charge of the -ide ion to deduce the charge of metal ions. 3. How many atoms of zinc are in 2.5 mol Zn? 1 mol Zn = 6.02 x 1023 Zn atoms 2.5 mol Zn 6 Number of significant digits 2 Given 2.5 mol Zn Target ? Zn atoms Path: mol Zn 6 Zn atoms Factor: Computation: 4. How many atoms of chlorine are in 0.3 mol FeCl2? 1 mol FeCl2 = 6.02 x 1023 FeCl2 molecules 2 Cl atoms 6 1 FeCl2 molecule 0.3 mol FeCl2 6 Number of significant digits 1 Given: 0.3 mol FeCl2 Target: ?Cl atoms Path: mol FeCl2 6 FeCl2 molecules 6 Cl atoms Factors: Computation: 5. Determine the formula mass of cobalt(III) bromide. Formula of cobalt(III) bromide: Co3+ Co BrBr3 CoBr3 Table: Symbol of element Number of atoms Atomic Mass Product Co 1 58.93 amu 58.93 amu Br 3 79.90 amu 239.7 amu Formula Mass = 298.6 amu The uncertain digits is in the first decimal place 6. Determine the formula mass of chromium(III) oxide. Formula of cobalt(III) bromide: Cr3+ Cr2 O2O3 Cr2O3 Symbol of element Number of atoms Atomic Mass Product Cr 2 52.00 amu 104.0 amu O 3 16.00 amu 48.00 amu Formula Mass = 152.0 amu Molar Mass Product The uncertain digits is in the first decimal place 7. Compute the molar mass of manganese(III) sulfide. Formula of cobalt(III) bromide: Mn3+ S2Mn2 S3 Mn2S3 Symbol of element Number of moles Mn 2 109.9 g Mn S 3 96.21 g S Molar Mass = The uncertain digits is in the first decimal place 8. We weigh a 1.5g of potassium oxide and put into a test tube. How many moles of potassium oxide are in the test tube? Molar mass of potassium oxide: Formula: K+ O2K2 O Symbol of element Number of moles Molar Mass K 2 78.20 g K O 1 16.00 g O Molar Mass = Product 9. Determine the mass of 0.45 mol of sodium oxide. Molar mass of potassium oxide: Formula: Na+ O2Na2O Symbol of element Number of moles Molar Mass Product Na 2 45.98 g Na O 1 16.00 g O Molar Mass = 0.45 mol Na2O 6 2 significant digits Given: 0.45 mol Na2O Target: g Na2O Path: mol Na2O 6 g Na2O Factor: Computation: 10. A product of a laboratory experiment is a sample of of iron(II) nitride that has mass equal to 1.41 g. Determine the molar mass of iron(II) nitride and then determine now many atoms of nitrogen are in the sample. Formula: Fe2+ N3Fe3N2 1.41 g Fe3N2 6 3 significant digits Molar mass Symbol of element Number of moles Molar Mass Fe 3 167.6 g Fe N 2 28.02 g N Molar Mass = The uncertain digits is in the first decimal place 1 mol Fe3N2 6 2 mol N 1 mol N = 6.02 x 1023 N atoms Given: 1.41 g Fe3N2 Target: ? N atoms Path: g Fe3N2 6 mol Fe3N2 6 mol N 6 N atoms Factors: Computation: Product
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