< Reference > Nov. 5, 2011 Tokyo Electric Power Company Recovery and processing of radioactive accumulated water at Fukushima Daiichi Nuclear Power Station ~Mechanism of water treatment (desalination) ~ 0 Overview of water treatment (desalination) A process where salt is removed from accumulated water (radioactivity has already been removed), and freshwater is produced to be used for reactor water injection. This limits more water accumulating due to reactor water injection. Limits production of accumulated water → Treated accumulated water is used for reactor water injection for reuse. Limits instruments corrosion R/B → removal of salt Process Main Building High Temperature Incinerator Building T/B Oil separator 「Removal of radioactive material」 Cesium Adsorption apparatus and 2nd cesium adsorption apparatus Water storage tank Water circulation Decontamination apparatus 「desalination of seawater」 Mid-low level tank Desalination system - RO - Evaporative concentration Vessel waste, sludge waste, etc 1 System structure of desalination apparatus Desalination apparatus ※ RO:Reverse osmosis membrane Cesium adsorption Coagulation settling Concentrated waste Desalination apparatus water storage (Evaporative concentration) ROconcentrated water RO concentrated water Temporary storage storage Buffer tank By switching valves, the order of water treatment can be changed from coagulation Evaporative concentration treated water storage settling to cesium adsorption RO treated water Desalination apparatus Waster water RO Supply tank temporary storage (RO) High temperature incinerator building SARRY SPT(B)tank P SPT waste water distill pump Process Main Building Cesium adsorption treated water transfer pump Cesium adsorption apparatus Oil separator Decontamination Chemical injection apparatus apparatus Oil separator Treated water tank P Cesium adsorption treated water tank Pressure dissolved air flotation apparatus P Incineration workshop building On-site bunker building Coagulation settling P P apparatus P Oil separator P Waste water Treated water transfer pump Waste water tank Decontamination Decontamination treated tank apparatus apparatus Accumulated water Pellet storage (D) treatment water tank transfer pump transfer pump SPT (A) tank P SPT waste water transfer pump To scrap sludge storing facility (in construction) Flow of water : Process Main Building Oil separator Cesium adsorption apparatus (2nd cesium adsorption apparatus) Coagulation settling apparatus Desalination apparatus 2 Removal of salt (Reverse osmosis membrane (RO) method) Removal of salt by RO method Removes salt in accumulated water by using the nature of reverse osmosis membrane; enables water to pass but does not allow others such as ion and salt to pass the membrane. Production rate of freshwater and concentrated salt water is approx. 4:6. O Fresh water Sea water sm is os Fresh water Sea water RO Pressure Instrument Treated amount [m3/d] Rate of desalination [%] Manufact urer RO-1A 270 approx.40 Ace Water Treatment RO-1B 300 approx.40 Ace Water Treatment RO-2 1200 approx.40 Hitachi RO-3 1200 approx.40 Hitachi <List of apparatus used(RO)> RO Fresh water <Osmosis and Reverse osmosis (RO)> Sea water 3 Desalination apparatus(Reverse Osmosis(RO)Method) Desalination apparatus (RO Method) is made from reservoir tank, filtration apparatus, RO, treated water tank. There are 4 sets of these, and by connecting them in parallel, treated volume can be adjusted from 11m3/h(270m3/day)to 75m3/day(1800m3/day). Overview flow of RO Method Treated water Reservoir tank Concentrated salt water Filtration apparatus RO Fresh water Treated water tank Filtration apparatus Filtration apparatus RO <Desalination apparatus (RO module)> < Desalination apparatus (Filtration apparatus)> 4 Removal of salt (Evaporative Concentration Method) Removal of salt by evaporative concentration method Heats and evaporates the concentrated salt water concentrated by RO method, and separates concentrated water (freshwater) and concentrated waste water. The production rate of freshwater and concentrated waste water, varies between two types; approx. 3:7, and approx. 7:3. apparatus Treatment amount [m3/d] Desalination rate [%] Manufacturer Evaporative concentration -1A 12.7 approx. 30 AREVA Evaporative concentration -1B 27 approx. 30 AREVA Evaporative concentration -1C 52 approx. 30 AREVA Evaporative concentration -2A 80 approx. 30 Toshiba Evaporative concentration -2B 80 approx. 30 Toshiba Evaporative concentration -3A 250 approx. 70 Toshiba Evaporative concentration -3B 250 approx. 70 Toshiba Evaporative concentration -3C 250 approx. 70 Toshiba Heat pump Vacuum pump Concentrated seawater Concentrated water Concentrated seawater Concentrated water tank Circulation pump Concentrated water Vapor Concentrated waster water <Example of evaporative concentration method> < List of apparatus used (Evaporative Concentration Method)> 5 Desalination apparatus (Evaporative Concentration Method) Desalination apparatus (Evaporative Concentration Method) is made from reservoir tank, evaporative concentration apparatus, cooling tower. There are 8 sets of these, and by connecting them in parallel, treated volume can be adjusted from 0.5m3/h(12.7m3/day)to 31m3/day(750m3/day). Overview flow of evaporative concentration apparatus 2A Concentrated seawater Preheated undiluted solution tank Preheated undiluted solution tank Concentrated water Concentrated waste water Chemical tank Retention solution tank Retention solution tank Evaporative concentration apparatus Evaporative concentration apparatus Cooling tower Chemical tank Cooling tower < Evaporative concentration apparatus 2A (Overview)* It is currently covered by tent> 6 Construction record of desalination apparatus Apr. RO method StageⅠ (RO-1A/1B/2) RO method StageⅡ (RO-3) May Jun. Jul. Aug. Sep. Oct. Installment Commissioning Treatment in operation(6/17) Installment Commissioning Treatment available(7/20) Installment Evaporative concentration apparatus StageⅠ ( Evaporative concentration 1A/1B/1C) ( Evaporative concentration 2A/2B) Commissioning Treatment in operation (8/7) (2A/2B) Commissioning Treatment available (8/31) (1A/1B/1C) Evaporative concentration apparatus StageⅡ ( Evaporative concentration 3A/3B/3C) Installment Commissioning Treatment available (10/10) ※Treatment in operation from 11/1 Circulating water injection Circulating water injection(6/27) 7 Record of removal of salt 7/ 1 20 11 / 7/ 8 20 1 1/ 7/ 15 2 01 1/ 7 /2 2 2 01 1/ 7 /2 9 2 01 1/ 8 /5 20 1 1/ 8/ 1 2 20 1 1/ 8/ 1 9 20 11 / 8/ 26 2 01 1/ 9 /2 2 01 1/ 9 /9 2 01 1/ 9 /1 6 2 01 1/ 9 /2 3 20 1 1/ 9/ 3 0 20 1 1/ 10 / 2 01 7 1/ 1 0/ 14 500 450 400 350 300 250 200 150 100 50 0 20 1 1/ 20 1 1/ 6/ 2 4 淡水化装置入口塩化物イオン濃度 Chloride ion density at inlet of desalination apparatus 淡水化装置出口塩化物イオン濃度 Chloride ion density at outlet of desalination apparatus 出口塩化物イオン濃度[ppm] 20,000 18,000 16,000 14,000 12,000 10,000 8,000 6,000 4,000 2,000 0 Chloride ion density at outlet Chloride ion density at inlet 入口塩化物イオン濃度[ppm] RO method Lowered chloride ion (maximum around 1.9%) to 0.025%. Evaporative concentration method Lowered chloride ion density of concentrated water from RO method to 0.0001%. ※1ppm = 0.0001% <Compare of chloride ion density at inlet and outlet of RO method desalination apparatus > As a result of water circulation, chloride ion of accumulated water is tends to be decreasing 8 Record of water treatment Produced approx. 60,000m3 freshwater from approx. 140,000m3 accumulated water [as of 2011/10/31] ※Evaporative concentration method produced approx. 2,250m3 freshwater Desalination apparatus(RO method)operation Desalination apparatus(Evaporative concentration apparatus 2A, 2B) Commissioning completed Desalination apparatus( Evaporative concentration apparatus 1A, 1B, 1C)Commissioning completed Desalination apparatus( Evaporative concentration apparatus 3A, 3B, 3C)Commissioning completed 1,200 Volume of freshwater produced (m3) 淡水発生量(m3) 淡水発生量 Volume of freshwater produced Accumulated volume of freshwater produced 累積淡水発生量 60,000 50,000 800 40,000 600 30,000 400 20,000 200 10,000 0 0 (Date) Accumulated volume of freshwater produce (m3) 1,000 70,000 累積淡水発生量(m3) Jun. 17 Aug. 7 Aug. 31 Oct. 9 6月 1 6 月 7日 2 6 月 2日 27 7月 日 7 月2日 7 月 7日 1 7 月 2日 1 7 月 7日 2 7 月 2日 27 8月 日 1 8月 日 8 月 6日 1 8 月 1日 1 8 月 6日 2 8 月 1日 2 8 月 6日 31 9月 日 9 月 5日 1 9 月 0日 1 9 月 5日 2 9 月 0日 2 9 月 5日 3 1 0 0日 月 10 5 月 日 10 10日 月 10 15 月 日 10 20日 月 10 25日 月 30 日 9
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