86. CHENlCAL A N D P H Y S I C A L FACTORS I N V O L V f D IN FRANKFURTER P E E L A B I L I T Y J. A. CARPENTER and R . L. SAFFLE IMlRODUCT ION Since the advent of the skinless frank, new problems have a r i s e n i n t h e sausage f i e l d . One of t h e most serious t o t h e processor i s the removal of the cellulose casing o r "peeling" of the process frank. Tauber (1958) and Wilson (1960) reported t h a t two of the main f a c t o r s r e l a t e d t o peeling of franks a r e surface formation o r coagulation of the soluble prot e i n by heat t o form a "skin" and the moisture relationship between the surface of the f r a n k f u r t e r and the casing. Although surface formation and moisture relationships of t h e frankf'urter a r e undoubtedly important factors in peeling, neither of' the above two autkors presented any research information t o substantiate t h e i r reports, nor was any research information found i n the l i t e r a t u r e concerning t h i s problem. To investigate t h i s problem, a study was conducted t o determine the chemical composition of t h e surf-ace and the center of a skinless frank as affected by the smokehouse temperature, t w o d i f f e r e n t types o f fat, the addition of collagen and the relationship of smokehouse temperature and the diameter of casing t o the formation of a surface skin. Further study was made t o determine the e f f e c t s of humidity, t e m perature, and types and l e v e l s of corn-syrup s o l i d s on peeling characteri s t i c s of frankfurters. These studies were conducted both i n t h e laboratory and i n a sausage plant under a c t u a l plant conditions. The same basic formula was used f o r a l l of t h e various treatments conducted and i s reported by Saffle e t al . (1963). All batches were handled in t h e same manner except where t h e treatment was involved. The e f f e c t of two extremes i n smokehouse temperatures on the migration of chemical constituents was studied by placing one-half of each batch i n t o a smokehouse a t 1300F and the other half of the batch i n t o a smokehouse a t 170°F f o r 2 hours. After showering, samples 3 mm i n diameter from the center and 1 m i n thickness from t h e surface of t h e f r a n k f u r t e r were removed f o r analysis. Protein, s a l t , moisture, sugar and f a t analyses were conducted on both surface and center s m p l e s . The e f f e c t of type of f a t WE; studied by s u b s t i t u t i n g beef kidney knob f a t f o r pork f a t and processing a t 130°F i n i t i a l temperature and r a i s i n g t h e temperature 10 degrees every 15 minutes u n t i l a smokehouse temperature of 180°F was obtained. Casing s i z e was investigated by s t u f f i n g i n t o 21 mm casings and 30 m casings and processing a t both 130°F and 180°F i n i t i a l temperature. The e f f e c t of collagen on peeling ease ms determined by the 87. addition of 1055 of t h e meat block a s pork skin emulsion and processing i n 2 1 mm casings a t the two d i f f e r e n t i n i t i a l temperatures, 130°F and 180°F. All frankfurters were processed t o 15S°F i n t e r n a l temperature i n the conventional manner. The same basic formula and procedures were used t o study the e f f e c t s of corn-syrup s o l i d s on peeling ease except t h a t corn-syrup s o l i d s hzving dextrose equivalents (DOE,) of 30.2, 52 and 7 1 were added a t t h e rate of 0, 1, 2, and 3 percent of t h e meat block. A second s e r i e s of s t u d i e s were made concerning corn-syrup s o l i d s except only t h e 5 2 and 7 1 D,E.'s were used. Dextrose equivalent is defined a s a measure of the reducing sugar content of a sweetener calculated a s dextrose and expressed a s a percentage of t h e t o t a l dry substance. The same basic formula and procedures were used t o study the e f f e c t of four d i f f e r e n t l e v e l s of r e l a t i v e humidity (27, 52, 74, 88$) and 40, 50, and 60°F temperature l e v e l s on p e e l a b i l i t y of f r a W r t e r s . A l l of the frawere peeled by a t r a i n e d panel and scored on a hedonic scale of 11 points ranging from one (extremely d i f f i c u l t ) t o 11 (extremely easy). The frankfurters were held f o r a t l e a s t 6 hours but not more than 1 8 hours in a constant controlled humidity-temperature cabinet before each peeling panel conducted. Unless otherwise specified the tempera t u r e was 50°F and the r e l a t i v e humidity was 88$. The minimum degrees of freedom f o r any one s e r i e s of panels were 287. Plant t e s t s were conducted under a c t u a l plant condition.; with d i f f e r e n t l e v e l s and amounts of corn-spxp solids. Results were expressed a s t h e percent of those which were peeled by a Wdel 5GC Ty peeler. - R E W S AMD DISCUSSION Results showed that more protein and f a t were found a t t h e surface of t h e franks than f r o m t h e center sample in both 13OoF and 170°F treatments (Ta31e 1). These differences were highly s i g n i f i c a n t . Soluble protein did migrate t o t h e furface and was deposited a s moisture evaporated, forming a smooth s k i n needed f o r good peeling. There was more difference i n surface and center samples f r o m t h e 130'F treatment than from the 170°F treatment, This may have been due t o a higher i n t e r n a l temperature i n -the 170° which coagulated t h e soluble protein before it could migrate t o the surface t o foxm a smooth skin. It i s postulated t h a t a smoother surface and b e t t e r peeling i s aided by s t a r t i n g t h e processing a t lower temperatures. Increasing the amount of f a t , even t o the point of "greasing out" o r forming "whitecaps" will improve the peeling of franks but r e s u l t s i n a greasy, uneconomical product. The s u b s t i t u t i o n of a higher melting point, l e s s unsaturated f a t , beef kidney knob, f o r pork f a t i n t h e f o m l a resulted i n l e s s f a t migration t o t h e surface of the frank during processing. However, franks w i t h pork f a t had higher peeling scores than franks with beef f a t probably due, i n part, t o t h e g r e a t e r amount of f a t on the surface. This e f f e c t is shown by a comparison of treatments 3 and 5 (Table 2 ) . Treatments 3 and 6 (Table 2) show t h e e f f e c t of i n i t i a l processing temperatures on t h e peeling ease of the frank. The lower s t a r t i n g texnperature 88 . of treatment 3 allowed time for a g r e a t e r migration of soluble protein t o t h e surface, thus c r e a t i q a smoother surface and aiding p e e l a b i l i t y of the f rankf'urter. The e f f e c t s of casing s i z e on peeling i s shown by comparison of treatments 1 and 4 (Table Z), The difference of the mean peeling scores w86 s i g n i f i c a n t and cannot be explained by only surface formation due t o soluble protein migration a s the low temperature frankf'urter (treatment 4) should have a t h i c k e r skin. There is no evidence t h a t a surface skin can be too thick as f a r as peeling ease i s concerned. A possible explanation might be that a t a higher temperature more f a t migrates t o the surface due t o melting point c h a r a c t e r i s t i c s , thus a i a n g peeling. A comparison of treatments 2 and 7 (Table 2) shows that franks with pork skins added a t a r a t e of 105 of the meat block and processed a t an i n i t i a l temperature of 180°F have g r e a t e r peelizq ease than those processed a t 130°F i n i t i a l temperature. This may be p a r t i a l l y explained by the format i o n of a glue-like material from collagen, heat, and moisture i n t h e franks processed a t a lower temperature which would not form as completely i n t h e franks processed a t higher temperatures due t o i n s u f f i c i e n t time, Also, franks processed a t higher temperaturns may have prevented the migration of collagen t o the suzface where i t s concentration could have affected t h e peeling of the franks. The reasons f o r these differences a r e not known and warrant f u r t h e r study. An analysis of the s a l t content o f surface and center samples of frankf'urters before and a f t e r showering revealed that showering leaches t h e s a l t f r o m the surface, thus r e s u l t i n g i n loner salt concentration (dry w t . b a s i s ) on the surface than i n the center of the frank (Table 1). The r e s u l t s a s shown in Table 3 revealed t h a t peeling ease increased as the percent r e l a t i v e humidity increased for each temperature, It is postulated that one of t h e f a c t o r s necessary f o r good peeling is a l a y e r of moisture between t h e frankfUrter and t h e casing. This lack of moisture Table 1. Chemical analysis (dry weight b a s i s ) of frankfurthers heat processed a t 13OoF and 17OoF. Protein Salt Fat Sugar 13OoFc 130OFS 17OoFc 1709s 45 86 46.79 38.60 39.23 6.16 3.83 5.58 3.03 46.28 47.38 54.46 56.54 1.70 2.00 1.36 . C center sample S surface simple 1.20 89 Table 2. Treatment Number - Duncan's W t i p l e Range Test f o r mean peeling panel scores as affected by types of f a t , pork skins, size and processing temperature. cas- m e of Fat _ _ $ of Pork Skins Initial Casing Temp. of Mean Peeling Size (mm) 3nokehouse Panel Scores ~ 1 Pork 0 30 180 6.3 2 Pork 10 21 180 6.23 3 Pork 0 21 130 4 Pork 0 30 130 5.53 5 Beef 0 21 130 5.24 6 Pork 0 21 180 5.04 7 Pork 10 21 130 ] = . I 4.4 1 J any two o r more mans enclosed by the same bracket a r e not s i g n i f i c a n t l y d i f f e r e n t f r o m each other a t the 0.05 l e v e l of probability ( t o t a l degrees of freedom 503) i s probably the reason that frankfurters w i l l not peel inmediately a f t e r heat processing. It is believed that the l a y e r of moisture between the frankf i r t e r and t h e casing canes from the humlaity i n t h e air and/or the moisture migrated from the center of the frankfurter and the higher humidity retarded t h e evaporation of this l a y e r of moisture. For any one day the panel only peeled frankfurters a t only one temperature. To have a b e t t e r comparison of the e f f e c t of temperature on p e e l a b i l i t y a second study was made holding r e l a t i v e humidity constant a t 88$ and varying the temperature. The man values f o r each temperature were 8.12, 7.74, and 8.72 f o r 40, 50, and 60°F., respectively. These differences were highly s i g n i f i c a n t according t o Duncan's U t i p l e Range Test, indicating that higher temperatures increased peeling ease. The addition of various D. E. l e v e l s and amounts of corn-syrup s o l i d s showed t h a t the 52 D. E. corn-syrup solids were s i g n i f i c a n t l y superior t o the 31.2 and 7 1 D.E. corn-syrup s o l i d s a t both 455 and 88$ r e l a t i v e humidity with the g r e a t e r peeling ease again bea t t h e higher r e l a t i v e humidity. A t the 88$ r e l a t i v e humidity the 1 and 25 l e v e l of 52 D. E. cornsyrup s o l i d s were not s i g n i f i c a n t l y d i f f e r e n t from each other but were s i g n i f i c a n t l y superior t o a l l other treatments. To substantiate these findings, another s e r i e s of panel detelmiaations were made a t 885: r e l a t i v e humidity. Duncan's U t i p l e Range Test showed that t h e 52 D. El corn-SyrUp solids were s i g n i f i c a n t l y superior t o the 71 D, E. corn-syrup s o l i d s (Table 4). It was postulated t h a t the a i d t o peeling by corn-syrup s o l i d s could be due 90. t o t h e i r hygroscopic nature a t t h e surface of the frank. The degree of hygroscopicity increases a s t h e D, E. increases; thus, the higher D. E , ' s should be most effective. However, there is a tendency f o r t h e adhesiveness t o increase as the D, E. increases which might explain t h e reduction in peeling ease a t higher D, E . l s . Results of plant a l s o v e d f i e d t h a t increased peeling ease of 52 D. E, corn-syrup s o l i d s over 2 and 35 l e v e l s of 30.2 and 7 1 D, E. corn-symp solids. I n the former group 97$ of t h e batch was peeled while the highest of the l a t t e r groups only 83.3$ peeled. rufuj was obtained by t h e use of 25 Table 3. Effects of temperature and r e l a t i v e humidity on peeling ease a s expressed by panel mean scores. Relative €kuaidity 40°F 27 6.33 52 6.27 74 6.81 3 -~ 60°F 3.03 5.917 3.663 4.4j 7.6g 8.537 8.0d 88 - Constant Temperatures 5G°F 8.13 ~~ = any two means enclosed by the same bracket a r e not s i g n i f i - . cantly d i f f e r e n t from t h e other a t the 0.05 l e v e l of probability Table 4. 8 of Duncan's N t i p l e Range Test for the e f f e c t s of 2 types of corn-symp s o l i d s a t 3 l e v e l s a t 88$ r e l a t i v e humidity on peeling ease as indicated by mean panel scores. 71 c.s.s, 0 &ans 5.04 . 1 5.22 3 5.49 52 2 6.30 - 2 9.10 - 1 3 9.56 10.02 - Any two means underscored by the s8me line a r e not s i g n i f i c a n t l y different D, E. Dextrose equivalent. C.S*S.- c 0 r n - s ~ Solids. ~~~ - 91. 1. Protein and f a t migrated t o t h e surface of franks during processing and a r e important f a c t o r s i n peeling ease. 2. Franks i n 21 m casings peeled e a s i e r when p o c e s s e d a t lower (130OF) i n i t i a l smokehouse temperature. 3. Franks i n 30 mm casings peeled e a s i e r when processed a t higher (180'F) smokehouse temperature. 4, The addition of collagen i n the form of 10% pork s k i n s resulted i n e a s i e r peeling of franks processed a t higher smokehouse temperatures a s cornpared with those processed a t lower smokehouse temperatures . 5. Less f a t migrated t o t h e surface when beef f a t was substituted f o r pork f a t which resulted i n poorer peeling characteristics. 6. Showering lowered the s a l t content of t h e surface of the frank. 7. The 52 dextrose equivalent corn-syrup s o l i d s resulted i n superior peeling c h a r a c t e r i s t i c s as coqpared with other dextrose equivalents t e s t e d i n both t h e laboratory and commercial plant studies. A , 0. A , C, 1960. O f f i c i a l Ikthods 02 AnalysiS of O f f i c i a l Agriculture Chemists. Eighth edition, Washington, D. C, I _ _ American Meat I n s t i t u t e Comittee on Textbooks. 1953. Sausage and Readyto-Serve Meats. Second revised edition. I n s t i t u t e of Meat Packing, University of Chicago, Chicago, Ill. Dische, C. E, and A , H, Zacharias. 1955. Anthrone reaction. Methods of Biochemical Analysis. Interscience Publishers, Inc , New E r k and London . . Saffle, R, L., J. A. Carpenter and D. G. Moore. 1963. Peeling ease of frankfurters. 1, Ef'fect of chemical composition, heat, collagen and type of f a t . Tauber, Id, F. Food Technol. 17; (In p r e s s ) , 1958. Visking Service Mmual, Visking Company, Chicago, Ill. Wilson, G, D. 1960. Chapter ll. Sausage products. The science of meat and meat products. 11, H. Free= and Company, San Francisco and London. NR. W: I think we a r e picking up some time here, and we do have time f o r some discussion. If anybody has questions 92. t o anyone of the previous three speakers, we would be happj Lo have them a t t h i s time. MI, GEXXGE BRISSEY: I think J i m Price mentioned the t e n s i l e strength measurement of the bologna, and I wonder if you could t e l l us, Jim, how you made that measurement? MR. PRICi?,: I'm not sure I can c i t e the reference t h a t Harold used t o design t h e instruments, I d i d n ' t see it, and I don't know i f anyone e l s e here can t e l l us o r not. MR. SWIFT: I could answer that, t h i s was a design t h a t a man in Be1tsviU.e made i n a s t u w of bologna about f i f t e e n years ago and we got h i s permission t o describe it i n a peper and Dr. Bratzler had it duplicated with 8ome minor modifications rounding off some corners, and w h a t it simply is that across a couple of blocks he s t r e t c h e s a s t r i p of product and adds weight i n t h e middle u n t i l it snaps, and i n t h i s way he measured t h e strength of t h i s s t r i p of product. ElR. SAFFE3: Any other questions? Lf not, Jim, I'll turn it back to you. CmIRTaN KEW: We will now have a recess of about twelve minutes. MR. SPFLE: I don't believe everybody i s back i n yet, b u t we are t r y i n g t o make up our time and we are about on schedule again and we will go i n t o the second part of our Neat Processing Committee's program which is Meat Pigments, which i n v i r t u a l l y ail. cases o r most cases, whether it i s f r e s h o r processed, we f i n d t h a t the shelf l i f e i s b a s i c a l l y dependent upon t h e color. IT the color fades we have l o s t t h e shelf l i f e , and it i s b a s i c a l l y a matter of color rather than spoilage per se. I n the area of color, of course, a number of schools have worked i n t h i s area, and I believe t h a t i n the way of fundamental information that became available concerning some of t h e pigments, etc., we would have t o take our hats off t o t h e A.M.I.F., and s p e c i f i c a l l y t o J, B o Fox, who w i l l present t h e area under t h e Fundamentcl Properties of k a t Pigments and Chemistry of Curing. To cover t h e first part, I should have DR. J, B. FOX (A.M.I.F.): had some s l i d e s , but I will cover fiome of t h e basic c h a r a c t e r i s t i c s on the blackboard .
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