1. Which element has chemical properties that are most similar to the chemical properties of calcium? A) beryllium C) lithium B) sodium D) magnesium 2. Which statement correctly describes a sample of gas confined in a sealed container? A) It always has a definite volume, and it takes the shape of the container. B) It takes the shape and the volume of any container in which it is confined. C) It has a crystalline structure. D) It consists of particles arranged in a regular geometric pattern. 9. The elements on the Periodic Table are arranged in order of increasing A) atomic mass C) molar mass B) atomic number D) oxidation number 10. Which orbital notation represents a noble gas in the ground state? what element do each of these orbital notations represent? A) B) C) 3. What is the electron configuration of an Fe (iron) atom in the ground state? A) B) C) D) 11. Calculate the energy, in Joules, of a quantum of radiant energy (the energy of a photon) with a frequency of 5.00 X 1015s -1 . 1s 22s 22p 63s 2 1s 22s 22p 63s 23p 64s 23d 6 1s 22s 22p 63s 23p 64s 13d 54p 1 1s 22s 22p 63s 23p 63d 7 4. What is the electron configuration of a fluoride (F) in the ground state? A) 1s 22s 22p 4 C) 1s 22s 22p 6 B) 1s 22s 22p 5 D) 1s 22s 22p 7 5. Which of the following elements in Period 2 has all of its sublevels completely filled? A) Li B) B C) N D) Ne 6. What is the total number of valence electrons in an atom with the electron configuration 1s 22s 22p 63s 23p 3? A) 6 B) 2 C) 3 D) 5 7. Which list of elements is arranged in order of increasing atomic radii? A) Li, Be, B, C C) Sc, Ti, V, Cr B) Sr, Ca, Mg, Be D) F, Cl, Br, I 8. Which element requires the least amount of energy to remove the most loosely held electron from a gaseous atom in the ground state? A) bromine C) sodium B) calcium D) silver A) 3.31 X 1049 J C) 3.31 X 10 -18J B) 1.32 X 10-49 J D) 33.1 X 10 -18J 12. What frequency is radiation with a wavelength of 5.00 x 10 -6 cm? A) 6.00 x 10 15 s -1 C) 1.5 x 10 17 s -1 B) 6 x 10 15 s -1 D) 1.50 x 10 17 s -1 13. Which orbital notation represents a noble gas in the ground state? A) B) C) D) 14. Bronze contains 90 to 95 percent copper and 5 to 10 percent tin. Because these percentages can vary, bronze is classified as A) a compound C) a mixture B) an element D) a substance 15. Which must be a mixture of substances? A) solid C) gas B) liquid D) solution 16. An example of a homogeneous mixture is A) B) C) D) aqueous solution of salt and water sugar carbon monoxide carbon dioxide 17. How did Mendeleev organize the elements in his original periodic table? 22. Which particle diagram represents a mixture of an element and a compound? A) B) C) D) A) atomic mass B) physical properties C) chemical properties D) all of the above 18. In Rutherford's gold foil experiments, some alpha particles were deflected from their original paths but most passed through the foil with no deflection. Which statement about gold atoms is supported by these experimental observations? A) Gold atoms consist mostly of empty space. B) Gold atoms are similar to alpha particles. C) Alpha particles and gold nuclei have opposite charges. D) Alpha particles are more dense than gold atoms. 19. If 70.0% of the isotopes of an element have a mass of 63.0 amu and 30.0% of the isotopes have a mass of 65.0 amu, what is the atomic mass of the element? A) 65.0 amu C) 63.6 amu B) 64.0 amu D) 31.8 amu 20. What is the mass number of a carbon atom that contains six protons, eight neutrons, and six electrons? A) 6 B) 8 C) 14 D) 20 23. Crystals of salt were added to water and stirred until all solids have dissolved. Which statement best describes the resulting mixture? A) The mixture is homogeneous and can be separated by filtration. B) The mixture is homogeneous and cannot be separated by filtration. C) The mixture is heterogeneous and can be separated by filtration. D) The mixture is heterogeneous and cannot be separated by filtration. 24. Given the diagrams X, Y, and Z below: 21. Two grams of potassium chloride are completely dissolved in a sample of water in a beaker. This solution is classified as A) B) C) D) an element a compound a homogeneous mixture a heterogeneous mixture Which diagram or diagrams represent a mixture of elements A and B? A) X, only C) X and Y B) Z, only D) X and Z 25. Which statement is an identifying characteristic of a mixture? A) A mixture can consist of a single element. B) A mixture can be separated by physical means. C) A mixture must have a definite composition by weight. D) A mixture must be homogeneous. 26. When sample X is passed through a filter paper a white residue, Y, remains on the paper and a clear liquid, Z, passes through. When liquid Z is vaporized, another white residue remains. Sample X is best classified as A) B) C) D) an element a compound a heterogeneous mixture a homogeneous mixture 27. Any substance composed of two or more elements that are chemically combined in a fixed proportion is A) an isomer C) a solution B) an isotope D) a compound 28. Describe diagrams X, Y, and Z using the following terms: Pure substance Compound Element Mixture of elements Mixture of compounds You may use more than one term for each diagram. 29. A mixture of sand and table salt can be separated by filtration because the substances in the mixture differ in A) boiling point C) freezing point B) density at STP D) solubility in water 30. At room temperature, a mixture of sand and water can be separated by A) ionization C) filtration B) combustion D) sublimation 31. Which property makes it possible to separate the oxygen and the nitrogen from a sample of liquefied air? A) boiling point C) hardness B) conductivity D) electronegativity 32. Recovering the salt from a mixture of salt and water could best be accomplished by A) B) C) D) evaporation filtration paper chromatography density determination 33. Define the following terms: 1) Conclusion 2) observation 3) Hypothesis 4) Inferences 34. The modern model of the atom is based on the work of A) B) C) D) one scientist over a short period of time one scientist over a long period of time many scientists over a short period of time many scientists over a long period of time 35. An aluminum sample has a mass of 80.01 g and a density of 2.70 g/cm 3. According to the data, to what number of significant figures should the calculated volume of the aluminum sample be expressed? A) 1 B) 2 C) 3 D) 4 36. A sample of an element has a mass of 34.261 grams and a volume of 3.8 cubic centimeters. To which number of significant figures should the calculated density of the sample be expressed? A) 5 B) 2 C) 3 D) 4 37. What is the safest method for diluting concentrated sulfuric acid with water? A) B) C) D) add the acid to the water quickly add the water to the acid quickly add the acid to the water slowly while stirring add the water to the acid slowly while stirring 38. Which particle has no charge? A) electron C) positron B) neutron D) proton 39. Which particles have approximately the same mass? A) B) C) D) an electron and an alpha particle an electron and a proton a neutron and an alpha particle a neutron and a proton 40. Which total mass is the smallest? A) B) C) D) the mass of 2 electrons the mass of 2 neutrons the mass of 1 electron plus the mass of 1 proton the mass of 1 neutron plus the mass of 1 electron 41. An electron has a charge of A) B) C) D) –1 and the same mass as a proton +1 and the same mass as a proton –1 and a smaller mass than a proton +1 and a smaller mass than a proton 42. In the late 1800s, experiments using cathode ray tubes led to the discovery of the A) electron C) positron B) neutron D) proton 43. Which subatomic particles are located in the nucleus of an He-4 atom? A) B) C) D) electrons and neutrons electrons and protons neutrons and protons neutrons, protons, and electrons 44. Which subatomic particle is negatively charged? A) electron C) positron B) neutron D) proton 45. Which statement best describes the nucleus of an silicon atom? A) It has a charge of +14 and is surrounded by a total of 10 electrons. B) It has a charge of + 14 and is surrounded by a total of 14 electrons. C) It has a charge of -14 and is surrounded by a total of 10 electrons. D) It has a charge of -14 and is surrounded by a total of 14 electrons. 46. List in the correct sequence the experiments and conclusions that lead to the model of the modern atomic theory. 47. Which conclusion is based on Rutherford's "gold foil experiment" and the resulting model of the atom? A) An atom is mainly empty space, and the nucleus has a positive charge. B) An atom is mainly empty space, and the nucleus has a negative charge. C) An atom has hardly any empty space, and the nucleus has a positive charge. D) An atom has hardly any empty space, and the nucleus has a negative charge. 48. As a result of the gold foil experiment, it was concluded that an atom A) B) C) D) contains protons, neutrons, and electrons contains a small, dense nucleus has positrons and orbitals is a hard, indivisible sphere 49. Every chlorine atom has A) B) C) D) 7 electrons 17 neutrons a mass number of 35 an atomic number of 17 50. What is the charge of the nucleus of an oxygen atom? A) 0 B) –2 C) +8 D) +16 51. All phosphorus atoms have the same A) B) C) D) atomic number mass number number of neutrons plus the number of electrons number of neutrons plus the number of protons 52. What is the total number of protons in an atom with the electron configuration 2-8-18-32-18-1? A) 69 B) 79 C) 118 D) 197 53. Compared to an atom of sulfur-32, an atom of sulfur-33 contains A) one less neutron C) one more neutron B) one less proton D) one more proton 54. Which quantity can vary among atoms of the same element? A) B) C) D) A) less mass C) more mass C) 14 A) 6 D) 20 A) B) C) D) A) adding the atomic number to the mass number B) subtracting the atomic number from the mass number C) adding the mass number to the atomic mass D) subtracting the mass number from the atomic number A) 7 B) 10 C) 3 58. What is the mass number of A) 9 B) 10 C) 19 B) 49 C) 86 ? D) 4 199 F? D) 28 D) 123 60. What is the total number of neutrons in the nucleus of a neutral atom that has 19 electrons and a mass number of 39? A) 19 B) 20 C) 39 D) 58 C) 18 D) 32 absorbs energy as it moves to a higher energy state absorbs energy as it moves to a lower energy state emits energy as it moves to a higher energy state emits energy as it moves to a lower energy state 65. When an electron in an atom of hydrogen moves from the second to the first principal energy level, the result is the emission of 59. What is the total number of protons and neutrons in an atom of ? A) 37 B) 8 64. When an excited electron in an atom moves to the ground state, the electron 56. The number of neutrons in the nucleus of an atom can be determined by 57. What is the total number of neutrons in an atom of B) less energy D) more energy 63. What is the maximum number of electrons that can occupy the fourth principal energy level (shell) of an atom? 55. What is the mass number of an atom that has six protons, six electrons, and eight neutrons? B) 12 A) all of the artificially produced isotopes of Mg B) all of the naturally occurring isotopes of Mg C) the two most abundant artificially produced isotopes of Mg D) the two most abundant naturally occurring isotopes of Mg 62. Compared to an electron in the first electron shell of an atom, an electron in the third shell of the same atom has mass number atomic number number of protons numbers of electrons A) 6 61. The atomic mass of magnesium is the weighted average of the atomic masses of A) protons C) energy B) electrons D) gas 66. Which subatomic particles are located in the nucleus of a neon atom? A) B) C) D) electrons and positrons electrons and neutrons protons and neutrons protons and electrons 67. Which statement best describes electrons? A) They are positive subatomic particles and are found in the nucleus. B) They are positive subatomic particles and are found surrounding the nucleus. C) They are negative subatomic particles and are found in the nucleus. D) They are negative subatomic particles and are found surrounding the nucleus. 68. An element that has a low ionization energy and good conductivity of heat and electricity is classified as a A) metal C) nonmetal B) metalloid D) noble gas 69. Which elements have the most similar chemical properties? A) Si, As, and Te C) Mg, Sr, and Ba B) N2, O2, and F 2 D) Ca, Cs, and Cu 70. What is a property of most metals? A) B) C) D) They tend to gain electrons easily when bonding. They tend to lose electrons easily when bonding. They are poor conductors of heat. They are poor conductors of electricity. 71. Which elements have the most similar chemical properties? A) B) C) D) boron and carbon oxygen and sulfur aluminum and bromine argon and silicon B) CO and NH 3 D) Xe and NH3 73. Which is a property of most nonmetallic solids? A) B) C) D) high thermal conductivity high electrical conductivity brittleness malleability B) Al C) Si D) Cl 75. What are two properties of most nonmetals? A) high ionization energy and poor electrical conductivity B) high ionization energy and good electrical conductivity C) low ionization energy and poor electrical conductivity D) low ionization energy and good electrical conductivity B) upper left D) upper right 77. Which element at STP is a poor conductor of electricity and has a relatively high electronegativity? A) Cu B) S C) Mg D) Fe 78. Which atom in the ground state has a stable electron configuration? A) carbon C) neon B) magnesium D) oxygen 79. Which element is a noble gas? A) neon C) antimony B) chlorine D) manganese 80. Which list of elements consists of metalloids only? B) B, Al, Ga D) O, S, Se 81. Which of the following atoms has the greatest tendency to attract electrons? A) bromine C) beryllium B) barium D) boron 82. Which general trend is demonstrated by the Group 17 elements as they are considered in order from top to bottom on the Periodic Table? A) B) C) D) 74. Which element is classified as a nonmetal? A) Be A) lower left C) lower right A) Si, Ge, As C) C, N, P 72. Which two gases can not be broken down by chemical means? A) CO and He C) Xe and He 76. In which area of the Periodic Table are the elements with the strongest nonmetallic properties located? an increase in first ionization energy a decrease in atomic radius a decrease in electronegativity an increase in nonmetallic behavior 83. Which term represents the attraction one atom has for the electrons in a bond with another atom? A) B) C) D) electronegativity electrical conductivity first ionization energy mechanical energy 84. Which atom has the weakest attraction for electrons in a chemical bond? A) a boron atom C) a fluorine atom B) a calcium atom D) a nitrogen atom 85. As the elements in Group 1 of the Periodic Table are considered from top to bottom, each successive element has a A) B) C) D) smaller ionization energy larger ionization energy smaller number of protons larger number of valence electrons 86. Which atom in the ground state requires the least amount of energy to remove its valence electron? A) cesium atom C) rubidium atom B) potassium atom D) sodium atom 92. Which quantity is equivalent to 50 kiloJoules? A) 5000 J C) 5 × 10 3 J B) 0.05 J D) 5 × 10 4 J 93. Which measurement contains a total of three significant figures? A) 0.12 B) 012 C) 120 D) 120. 94. Which set of laboratory equipment would most likely be used with a crucible? A) 87. Which grouping of circles, when considered in order from the top to the bottom best represents the relative size of the atoms of Li, Na, K, and Rb, respectively? A) B) C) D) B) C) 88. An atom of which element has the largest atomic radius? A) Mg B) Fe C) Si D) D) Zn 89. As the elements is Period 3 are considered in order of increasing atomic number, there is a general decrease in A) B) C) D) atomic mass atomic radius electronegativity first ionization energy 95. Which piece of laboratory equipment should be used to remove a heated crucible from a ring stand? A) B) C) D) 90. Which mass measurement contains four significant figures? A) 0.086 g C) 1003 g B) 0.431 g D) 3870 g 91. How many kiloJoules are equivalent to 10 Joules? A) 0.001 kJ C) 1000 kJ B) 0.01 kJ D) 10,000 kJ 96. An atom of argon rarely bonds to an atom of another element because an argon atom has A) B) C) D) 2 electrons in the first shell 8 valence electrons 3 electron shells 22 neutrons 97. Magnesium and calcium have similar chemical properties because a magnesium atom and a calcium atom have the same A) B) C) D) total number of valence electrons atomic number mass number total number of electron shells 98. The elements in Group 2 have similar chemical properties because each atom of these elements has the same A) B) C) D) atomic number mass number number of electron shells number of valence electrons 99. Use dimensional analysis to calculate how many seconds are present in 4.5 years? 100. Which piece of laboratory equipment should be used to hold a heated test tube? A) B) C) D)
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