NANO INK CLEAR

!
Safety Data Sheet according to Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No. 1272/2008
Date of issue: 01.06.2015
Revision:02
n/a. = not-applicable
n.d. = not determined
NANO INK CLEAR 1.
Identification of the mixture/article and of the company/undertaking
1.1
Identification of the substance or mixture
Trade name
Nano Ink Clear
Index-No:
none
EG-No.:
none
CAS-No.:
none
REACH-Registration No.:
none
Use of the Substance/preparation/article
Ink for industrial use
1.2
Company / undertaking identification
Supplier (manufacturer/importer/downstream user/distributor):
Muchcolours Srl
Via California, sn
63015 Montesilvano (PE) Italia
Telefono: +39085.4450572
email: [email protected]
1.3
Emergency telephone:
Centro Nazionale di Informazione Tossicologica (24h): +39 0382 24444
2.
Hazards description
2.1
Classification of the Substance / mixture / article
Classification according to Regulation (EC) No. 1272/2008
Flam. Liq.3; H226
STOT SE 3; H336
Label elements according to Regulation (EC) No. 1272/2008
Hazard pictograms:
!
!
Signal word:
Warning
Hazard statements:
H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness
Precautionary statements:
P210
Keep away from heat/sparks/open flames/hot
surfaces. — No smoking
P233
Keep container tightly closed.
P240
Ground/bond container and receiving equipment.
P243
Take precautionary measures against static discharge.
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P280
Indossare guanti/indumenti protettivi/Proteggere gli
occhi/il viso.
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Nano Ink Clear
Date of issue: 01.06.2015
Revision: 002
P305+P351+P338
IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P303 + P361 + P353+ IF ON SKIN (or hair): Remove/Take
off immediately all contaminated clothing. Rinse skin
with water/shower.
P370 + P378 In case of fire: Use … for extinction.
2.2
Information pertaining to special dangers for human
This mixture is flammable and can be ignited by heat, sparks, flames, or other sources of ignition.
2.3
Information pertaining to special dangers for environment
No
3.
Composition/information on ingredients
3.1
Chemical characterization:
CAS-No.:
alcoholic mixture
n.a.
Regulation (EC) Nr. 1272/2008
Hazardous ingredients
CAS-No. EC-No.
% [weight]
Classification
1272/2008
Remark
REACH-No.
ethanol
64-17-5
10-15
Flam. Liq. 2 H225
35-45
Flam. Liq. 3 H226
200-578-6
603-002-00-5
1-methoxy-2-propanol
107-98-2
203-539-1
STOT SE 3 H336
603-064-00-3
1-ethoxy-2-propanol
12-22
54839-24-6
Flam. Liq. 3 H226
STOT SE 3 H336
259-370-9
603-177-00-8
The full text of each classification is provided in Section 16.
3.2
Substances which are not to call in 3.1, which is a limit assigned
No
3.3
Additional information
No
4.
First Aid measures
4.1
General information
If you feel unwell seek medical advice. Remove/Take off immediately all
contaminated clothing.
4.2
In case of inhalation
Remove casualty to fresh air and keep warm and at rest if unconscious place
in recovery position and seek medical advice
4.3
In case of skin contact
In case of skin irritation, consult a physician. In severe case seek medical
emergency.
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Nano Ink Clear
Date of issue: 01.06.2015
Revision: 002
4.4
After Eye contact
In case of contact with eyes flush immediately with plenty of flowing water for
10 to 15 minutes holding eyelids apart and consult an ophthalmologist.
Remove contact lenses if possible.
4.5
In case of ingestion
Do not induce vomiting. Obtain medical attention if symptoms appear or if
large quantities have been ingested. Accidental ingestion at a level high
enough to be dangerous to health is unlikely. Consult a physician.
4.6
Information to physician
Symptoms of acute poisoning: Eyes:
Skin:
Inhalation:
Ingestion:
none
none
loss of consciousness
loss of consciousness
Instructions for first aid medical treatment: seek medical advice
Treatment
5.
Firefighting measures
5.1
Suitable extinguishing media
Carbon dioxide (CO2),
Dry extinguishing powder
Water spray
Alcohol-resistant foam
5.2
Extinguishing media which must not be used for safety reasons
Full water jet
5.3
In case of fire may be liberated
Carbon monoxide (CO), Carbon dioxide (CO2)
5.4
Special protective equipment for firefighting
Wear personal protective equipment (self-contained breathing apparatus, gloves, helmet, safety goggles,
fire-proof safety footwear)
5.5
Additional information
Use water spray jet to protect personnel and to cool endangered containers. Fire residues and
contaminated firefighting water must be disposed of according to local regulations.
6.
Accidental release measures
6.1
Personal Precaution
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. No smoking.
6.2
Environmental precaution (Disposal considerations, see section 13.). Do not allow to enter into soil/
subsoil. In case of entry into waterways, soil or drain, inform the responsible authorities. Recycle according
to official regulations. Collect in closed and suitable containers for disposal. To limit VOC emissions
(volatile organic compounds), emissions controlling units are possible.
6.3
Methods for cleaning up
Collect in closed and suitable containers for disposal, in case using absorbing material.
6.4
Additional information
Keep away from sources of ignition - No smoking, Keep away from naked flames. Please adopt measures
described at sections 7, 8, 13.
7.
Handling and Storage (national regulations, see section 15 and 16)
7.1
Handling
Advices on safe handling
See section 8.
Avoid contact with skin and eyes. (Use personal protection equipment). Keep away from food and drink
and animal feeding stuffs while handling the product. Do not store open containers. Wash hands after the
use. Remove all contaminated clothing and personal protection equipment when leaving the working area.
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Nano Ink Clear
Date of issue: 01.06.2015
Revision: 002
Precautions against fire and explosions
No smoking. Therefore keep away from fire and sources of ignition. Protect from extreme temperatures
and take precautionary measures against static discharges. Solvent vapour are heavier than air. Explosive
mixture vapour/air can occur even at room temperature. In the area when this risk can occur, use only nonsparking tools. Keep away from flammable and/or oxidant agents.
7.2
Storage:
Technical measures and storage conditions
Keep/Store only in original containers and keep container tightly closed. Store in a dry, well-ventilated
area, with a solvent-resistant floor or a collecting basin. Protect from extreme temperatures and take
precautionary measures against static discharges. Proper storage condition: Room temperature, do not
store at temperatures above 20°C.
Hints on joint storage
Incompatible with Pharmaceutical products
Food and beverages
Feed
Flammable products
Substances that can produce flammable gas in contact with water
Organic peroxides
Oxidizing agents
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
7.3
Specific use(s)
The recommended use for this mixture is as ink in piezoelectric inkjet printing machines.
8.
Exposure controls and Personal Protection
8.1
Exposure limit values
Occupational exposure limits
Ingredients
CAS-No.
ethanol
64-17-5
1-methoxy-2-propanol
107-98-2
1-ethoxy-2-propanol
54839-24-6
Long term
[ppm]
Limit value 8
h [mg/m3]
Peak limitation
-
-
-
100 (skin)
-
150 (skin)
-
-
-
Source
[ppm]
*
* = D. Lgs. 81/2008 e smi, Decreto Legislativo del Governo n.277, 15/08/1991 Decreto Legislativo n.66,
25/02/2000, Decreto Ministeriale 26/02/2004
8.1.1 DNEL- und PNEC- values
8.2
DNEL oral:
none
PNEC aqua (fresh water)
PNEC aqua (Sea water)
none
none
PNEC Sediment (fresh water)
PNEC Soil
PNEC Sewage plant
PNEC oral
none
none
none
none
Occupational and Environmental exposure controls
Personal protective equipment (PPE)
Respiratory protection
Hand protection
Eye protection
A well ventilated room and/or a room with a solvent extractor
from air is normally sufficient. If not, wear self contained
breathing apparatus.
Solvent resistant gloves
Safety goggles, including lateral protection (EN 166:2001)
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Nano Ink Clear
Date of issue: 01.06.2015
Revision: 002
Protective clothing
Health and safety measures
Wear protective clothing
See sections 7 and 8.
9.
Physical and chemical Properties 9.1
General Information
Physical state: liquid
2.
Important health, safety and environmental information
Melting point / melting range:
no data
Boiling temperature: (1013 hPa)
80°C
Solidification point:
no data
Flashing point:
26,5 °C
Partition coefficient (log POW)
no data
Dynamic Viscosity (mPas, 20 °C)
10
Density: (20 °C)
0,9 kg/dm3
pH-value: (10 g/L)
5,5
Solubility (Water)
no data
Lower explosion limit:
no data
Upper explosion limit:
no data
Colour: light
Odour: alcoholic
Explosion hazards
Product is not explosive, but in use may form flammable/
explosive vapor-air mixture.
Additional information
none
10. Stability and Reactivity
10.1
Conditions and Materials to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Hazardous reaction: the mixture can react with strong oxidizing agents and strong reducing agents with a
high release of heat; it reacts with acids with high release of heat; it reacts with acid anhydrides and
alkaline metals with high release of heat. Plastics and rubbers can be attacked.
10.2
Hazardous decomposition products
Burning produces carbon mono oxide (CO), carbon dioxide (CO2). In case of contact with oxidant
agents, alkaline metals and acids, flammable gas or dangerous vapours can occur.
10.3
Additional Information
In case of proper use, no dangerous reaction is expected.
11.
Toxicological information
11.1 Toxicological Tests:
11.1.1 Acute effects / Specific symptoms in animal studies
Oral LD50: -/LD50 (oral, Rat): -/Dermal: -/Inhalation: -/LC50 (inhalation, Rat): -/2.
Irritation and corrosivity / sensitization
Dermal irritation
In case of skin contact
In case of eye contact
In case of inhalation
In case of digestive tract contact
none
May cause sensitization by skin contact.
none
none
none
11.1.3 Sub acute to chronic toxicity/carcinogenic, mutagenic, reproductive effects
carcinogenic effects
no
mutagenic effects
no
toxicity for reproduction
no
Chronic effect
no
3.
Additional Information
11.2
Practical experience
no
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Date of issue: 01.06.2015
Nano Ink Clear
Revision: 002
11.2.1 Observations relevant for classification
11.2.2 Other observations
no
no
11.3
no
General comments
12. Ecological informations
12.1
Eco-toxicity
Aquatic Toxicity
96 h LC50
(fish)
48 h EC50
(Daphnia)
72 h IC50
(algae)
Aquatic Toxicity Ethanol
96 h LC50
(fish)
48 h EC50
(Daphnia)
72 h IC50
(algae)
no data
no data
no data
11000 mg/l
9950 mg/l
9280 mg/l
12.2
3.
Mobility
Persistence and degradability
no data
no data
12.4
Bio-accumulative potential
not determined
12.5
Other adverse effects
Ozone depletion potential
Photochemical ozone creation potential
AOX-advice
Additional information
CSB-value
BSB-value
no data
Result of PBT and vPvB assessment
negative
12.6
12.7
no data
no data
no data
no data
13. Disposal considerations
13.1
Disposal in accordance with the Waste Catalogue Ordinance
Recommendation:
13.2
Contaminated packages
Recommendation:
Do not dispose the product as waste water. Dispose the product according
to local directive concerning dangerous goods.
Completely emptied packages can be recycled. Contaminated packages must
be completely emptied and can be re-used following proper cleaning.
Packing which cannot be properly cleaned must be disposed of (like
Substance). European Waste Catalogue for packing which cannot be properly
cleaned and emptied: EWC 15 01 10* packaging containing residues of or
contaminated by dangerous substances
14. Transport information 14.1
Land transport ADR / RID
UN-No.:
Classification code:
ADR/RID Packing group:
Proper shipping Name:
Remarks Land Transport
14.2
Inland waterway transport ADN
UN-No.:
ADN-Class
ADN Packing group:
Proper shipping Name:
UN 1263
3
II
PAINT
14.3
Sea transport IMDG
UN-No.:
UN 1263
UN 1263
3
II
PAINT
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Safety Data Sheet according to Regulation (EC) No 1907/2006
Date of issue: 01.06.2015
IMDG-Class:
Marine pollutant:
IMDG Packing group:
Proper shipping Name:
Remarks Sea transport
14.4
Air transport ICAO / IATA
UN-No.:
ICAO/IATA-Class:
ICAO-Packing group
Proper shipping Name
Nano Ink Clear
Revision: 002
3
NO
II
PAINT
1263
3
II
PAINT
15. Regulatory information
1.
National Regulations (Italy)
No further information available
2.
Other Regulations, restrictions and prohibition regulations
Chemical Safety Assessment:
For this substance a chemical safety assessment has not been carried out.
16. Other information
1.
Relevant H-phrases (Number and full text)
H225
Highly flammable liquid and vapour.
H226
Flammable liquid and vapour.
H336
May cause drowsiness or dizziness
2.
Relevant P-phrases (Number and full text)
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233
Keep container tightly closed.
P240
Ground/bond container and receiving equipment..
P243
Take precautionary measures against static discharge.
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing..
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
Skin with water/shower.
P370 + P378
In case of fire: Use … for extinction.
3.
Training advice
4.
Additional information
16.4
Department issuing MSDS: [A. Rabuffo/MuchColours srl]
Issue: 0002
The information in Chapters 4 to 8 and 10 to 12 are partially based on the use and proper application (see article
on use), but to liberation of major amounts in case of accidents and irregularities. The information contained in
this safety information is based on the knowledge available at the time of creation. The delivery specifications are
contained in the product data sheets. The description of the product is only in relation to health and safety
requirements. This document is not a guarantee of specific properties or specifications.(n.a. - not applicable, n.d. not determined).
Changes to version 1: Adoption of the requirements of Regulation (EC) No 1907/2006 (REACH) and
Regulation (EC) No. 1272/2008
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