Nevinnomysskiy Azot 1 Nizyaeva St., Nevinnomysk -7, Stavropol Territory, 357107, Russia _____________________________________________________________________________ GPS Safety Summary This Product Safety Summary is intended to provide a brief overview of the information on the risk assessment results of the chemical product that we manufacture based on the chemical industry’s Global Product Strategy (GPS) to the general public as a social responsibility of a company that manufacture chemical substances. This summary is not intended to provide technical information in case of emergency situations, medical information or information on treatment in case of influence. In addition, it is not intended to be prepared as a document to replace a Safety Data Sheet (SDS) or a risk assessment report like a Chemical Safety Report under the REACH (Registration, Evaluation, Authorization and Restriction of Chemicals) (REACH CSR). 1. NAME OF SUBSTANCE Nitric acid. 2. GENERAL INFOMATION Producer: Nevinnomysskiy Azot. Address: 1 Nizyaeva St., Nevinnomysk-7, Stavropol Territory, 357107, Russia Tel: +7 (495) 795 25 27 Fax: +7 (86554) 7 95 77 Email: [email protected] 3. CHEMICAL IDENTIFICATION Chemical name Public name Brand name Customary name IUPAC name CAS number EC number Synonyms: Molecular formula Structural formula: 4. Nitric acid Nitric acid Non-concentrated nitric acid Nitric acid Nitric acid 7697-37-2 231-714-2 Hydrogen nitrate HNO3 PRODUCT USES AND CHARACTERISTICS Nevinnomyssky Azot produces non-concentrated nitric acid. Nonconcentrated nitric acid is used in the manufacture of ammonia nitrate, complex fertilizers, for metal surface treatment. Main Characteristics (according to GOST R 53789 – 2010): Standard for «A» brand Premium I grade II grade grade Colorless or weak yellow liquid Main values Appearance Weight percentage of nitric acid %, no less than Weight percentage of nitrogen oxides (N2O4), %, no more than Weight percentage of residue on ignition, %, no more than 5. 57,0 56,0 46,0 0,07 0,1 0,2 0,004 0,02 0,05 PHYSICAL/CHEMICAL PROPERTIES Physical state Odour Melting point/freezing point Boiling point Vapour pressure kow Water solubility Water miscibility Flammability Oxidizing properties Colorless liquid at 20°C and 1.013 hPa Pungent and suffocating - 41,59 °C at 1.013 hPa 83 °C at 1.013 hPa 6.1 KPa at 25 °С 2,3 at 25 °С 500 g/l at 20 °C > 90% at 15 °C Not applicable (the substance is inorganic) Oxidizing _____________________ Page 2 ot 9 Molecular weight Density Dynamic viscosity Physical state 63,01 g/mol 1,51 g/cm3 at 20 ° 0,761 mPa at 20°C Colorless liquid at 20°C and 1013 hPa 6. HEALTH INFORMATION Human Health Safety Assessment Skin irritation Eye irritation Skin sensitization Inhalation sensitization Mutagenicity Carcinogenicity Reproductive toxicity Teratogenicity Impact on fetus Workers (long-term – local effects, inhalation): DNEL 1,3 mg/m3 Workers (short-term acute – local effects, inhalation): DNEL 2,6 mg/m3 General population (long-term – local effects, inhalation): DNEL 0,65 mg/m3 General population (short-term acute – local effects, inhalation): DNEL 1,3 mg/m3 No data No data LC50 (rat): 1,562 mg/m3 Exposure time: 4h It has a corrosive effect It has a corrosive effect Testing does not need to be conducted Testing does not need to be conducted No mutagenic effect No carcinogenic effect The classification criteria are not met. No data available Not studied Gonadotrophic impact Not studied Specific target organ toxicity after single exposure Specific target organ toxicity after repeated exposure (sub-acute / sub-chronic) Corrosive for respiratory tract DNEL (Derived No Effect Level) Acute oral toxicity Acute dermal toxicity Acute inhalation toxicity Neurological disorders, damage to the gastro-intestinal tract, myokardosis, exposure to high levels produces adverse effects on lung and teeth Note: For more information on the health hazards of this substance and recommended protective equipment, please refer to the relevant (M)SDS. 7. ENVIRONMENTAL INFORMATION Environment Safety Assessment Predicted No-Effect Concentration (PNEC) No data _____________________ Page 3 ot 9 Toxicity (fish) No data Toxicity to aquatic invertebrates No data Toxicity to Aglae No data Toxicity to microorganisms No data Environmental fate Biodegradation The study does not need to be conducted as the substance is inorganic Not applicable (highly soluble) Product is neither a PBT nor vPvB substance Bioaccumulation PBT and vPvB assessment Note: For more information on the environmental hazards of this substance and recommended measures, please refer to the (M)SDS. 8. RECOMMENDATIONS ON RISK MANAGEMENT Closed manufacturing processes, high performance forced-air or local exhaust ventilation at the work zone, use of personal protection equipment. Minimization of quantity of exposed workers. Use of special dispensers and pumps designed to prevent splashes / spills. Effective removal of contaminants. Minimization of manual phases. Avoidance of contact with contaminated tools and objects. Regular cleaning of equipment and work area. Verification of the appropriate use of risk management measures. Ensure high levels of personal hygiene. Inform consumers through labeling. 9. REGULATORY INFORMATION / CLASSIFICATION AND LABELLING 9.1 Classification according to REGULATION (EC) No 1272/2008 Oxidizing liquid: category 3 H272 Substance or mixture, corrosive to metals, hazard category 1 H290 Corrosive / irritant to skin, hazard category 1A H314. _____________________ Page 4 ot 9 EUH071: Corrosive to the respiratory tract 9.2 Labeling according to REGULATION (EC) No 1272/2008 Hazard pictogram(s): : GHS03: Oxidizing : Danger Signal Word Hazard statements Additional statements : H272 H290 H314 hazard Precautionary statements GHS05: Corrosion : May intensify fire; oxidizer : May be corrosive to metals : Causes severe skin burns and eye damage EUH071 : Corrosive to the respiratory tract. : Prevention: P210 : Keep away from heat/sparks/open flames/hot surfaces. : P221 Take any precaution to avoid mixing with combustibles P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.. Response: P301+P330+P331+P310: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. P303+P361+P353+P310: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. P305+P351+P338+P310: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. 9.3 PBT assessment The substance is not PBT / vPvB _____________________ Page 5 ot 9 10. REGISTRATION INFORMATION Nitric acid Registration number 11. : 01-2119487297-23-0003 CONCLUSIONS Non-concentrated nitric acid produced by Nevinnomyssky Azot is used in manufacture of ammonia nitrate, complex fertilizers and surface treatment of metals. In the Product Safety Summary for risk calculations the following Exposure scenarios are used: Identifiers ES1 - M1 ES2 - F1 ES3 - IW1 Market Sector Titles of exposure scenarios and the related contributing scenarios Manufacture - Manufacture - Manufacture (ERC 1) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Formulation - Formulation - Formulation (ERC 2) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use at industrial site - Use at industrial site - Use at industrial site (ERC 4) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) _____________________ Page 6 ot 9 Identifiers ES4 - IW2 ES5 - IW3 ES6 - IW4 ES7 - PW1 Market Sector Titles of exposure scenarios and the related contributing scenarios - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use at industrial site - Use at industrial site - Use at industrial site (ERC 6a) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use at industrial site - Use at industrial site - Use at industrial site (ERC 6b) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use at industrial site - Use at industrial site - Use at industrial site (ERC 7) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8a) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) _____________________ Page 7 ot 9 Identifiers Market Sector ES8 - PW2 ES9 - PW3 Titles of exposure scenarios and the related contributing scenarios - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8b) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8e) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 8b) - Worker contributing scenario (PROC 9) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) - Worker contributing scenario (PROC 15) Thus, GPS safety risk calculations performed only for production, processing, use and disposal of chemicals (in accordance with the ECHA Guidelines on Safety Assessment). The analysis shows that risks could be adequately controlled through the use of standardized technical, organizational measures, which are designed and operated by Nevinnomysskiy Azot. 12.CONTACT DATA For more information on the matter, please contact at: [email protected] or visit: http://www.eurochem.ru/ _____________________ Page 8 ot 9 13.DATE OF ISSUE 08.04.2015 Notes: For more information on first aid measures, fire fighting, prevention and elimination of accidents and emergency situations and their consequences, recycling, safe use and transportation and storage rules, refer to the Safety Data Sheet (SDS) for this chemical or chemical products. While the data and information contained herein are presented in good faith and believed to be accurate at the date of printing, it is provided for your guidance only and may be revised in the future. No warranties of any kind, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made regarding the data or information provided. Further, it is expressly understood that the data and information furnished by EuroChem hereunder are given gratis and EuroChem assumes no obligation or liability whatsoever resulting from use of or reliance on the data and information given. EuroChem makes no commitment to update or correct any information that appears on the Internet. _____________________ Page 9 ot 9
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